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四川西部里伍式富铜矿床黄铜矿Re-Os定年及其成矿意义 总被引:1,自引:0,他引:1
川西里伍式富铜矿系指产于扬子地台西缘和松潘-甘孜造山带接合带江浪穹窿中的呈层状-似层状或透镜状的富铜矿床。矿床地质特征、矿化类型及矿相学研究表明其为热液型矿床。为精确厘定热液成矿作用发生的时间,本文对占主体的块状-脉状矿石中的黄铜矿进行了高精度NTIMS Re-Os同位素定年,获得等时线年龄为150.2±4.9~151.1±4.8Ma(2σ),说明里伍式富铜矿主要形成于晚侏罗世,明显晚于赋矿围岩新元古界里伍岩群,与江浪穹窿边部出露的花岗岩体年龄较为接近;初始187Os/188Os比值为3.65±0.29,说明其金属成矿物质来源主要为大陆地壳,很可能主要来源于赋矿岩层里伍岩群。结合成穹构造—岩浆事件,本文认为早燕山期区域伸展构造背景下的岩浆热隆作用不仅为铜富集提供了热动力和部分流体,同时为矿体最终定位提供了良好的导矿—容矿空间,是里伍式富铜矿形成的关键因素。 相似文献
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四川省白玉县呷村银多金属矿床是中国著名的VHMS矿床之一,前人曾进行过详细的矿床模型研究。对于矿床下部脉状矿体大致呈层状平行于上部块状矿体的地质现象,前人曾提出"层状矿席+层控网脉状矿带"等模式。文章通过对呷村矿床地质特征的详细研究后认为,呷村矿床在印支期形成之后,遭受到燕山期弧-陆碰撞造山的强烈改造,导致矿区地层直立并倒转,并在能干性弱的流纹质火山岩中普遍发生层内韧性剪切变形,使原先近于垂直层状矿体和喷气沉积岩的下-中部脉状-网脉状矿体被构造置换为紧闭褶皱状、无根褶皱状、透镜体状,并近于平行于上部层状矿体。构造恢复表明,下-中部脉状-网脉状矿体原始三维形态为不整合的筒状或漏斗状,与上部层状矿体组成典型的"下筒上层"的"双层结构"。根据脉状-网脉状矿体和层状矿体的空间展布特征,在构造恢复的基础上重新建立了呷村VHMS矿床的双通道夹卤水池的矿床模型。该模型对矿区外围找矿有一定的指导意义。 相似文献
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川西江浪穹隆在大地构造上位于松潘-甘孜造山带东南缘。环穹窿腰部分布着一系列产状、矿床特征相似的铜多金属矿床——里伍式铜矿床,包括里伍、中咀、笋叶林、柏香林、挖金钩、黑牛洞等矿床。这些矿床的矿体主要呈似层状产出于中元古代里伍群中,其成因模式目前尚不明确。本研究选择里伍和黑牛洞铜矿中的含矿石英-电气石脉作为重点研究对象,对其中的代表性电气石单矿物进行了电子探针分析及LA-MC-ICPMS原位硼同位素测试,据此制约矿床的成矿物质来源。背散射及显微图像特征揭示两矿床的含矿电气石具有单一的流体来源;电子探针分析结果表明这些电气石在类型上均属镁电气石;硼同位素测试结果显示两矿床的电气石δ11 B值分别为-15.47‰±0.83‰~-13.06‰±0.77‰(n=10)及-13.19‰±0.57‰~-5.91‰±0.67‰(n=16),与花岗岩的δ11B值区间非常一致,表明这两个矿床属(区内燕山期)岩浆期后热液矿床。通过对比研究,本文进一步提出在松潘-甘孜造山带内很可能存在一条NE-SW向的铜多金属成矿带,即松潘-甘孜铜多金属构造成矿带。本次研究不仅可以丰富层状型矿床成矿理论,而且对指导该造山带中其他穹窿体的找矿具有较为重要的实际意义。 相似文献
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新疆阿尔泰山南缘产于泥盆纪火山-沉积盆地铅锌矿床地质特征--以可可塔勒铅锌矿为例 总被引:9,自引:1,他引:8
可可塔勒矿床位于新疆阿尔泰造山带南缘,产于泥盆纪火山-沉积盆地内铅锌矿(可可塔勒)体呈似层状、透镜状,矿石构造以条纹条带状、块状、斑杂状为主,矿物成分相对简单,矿体直接容矿围岩为火山-沉积岩.矿床属火山-沉积岩容矿的块状硫化物矿床.为介于典型的火山岩容矿的块状硫化物型矿床(VHMS)和典型沉积岩容矿的硫化物矿床(SEDEX型)之间的过渡类型(一种新类型块状硫化物矿床),其矿化特征与伊比利亚型矿床相类似. 相似文献
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德兴斑岩铜矿田黄铁矿Re-Os同位素定年及其地质意义 总被引:1,自引:1,他引:0
德兴斑岩铜矿田是中国东部最大的斑岩铜矿系统,一直以来,德兴铜矿的成矿过程和成因机制都是矿床学家关注的热点问题。前人在德兴铜矿的围岩蚀变、矿化期次、流体特征、成岩年代等方面取得了较为一致的认识,但其成矿时代仍争议较大。文章首次对矿田内与黄铜矿密切共生的黄铁矿进行了Re-Os同位素定年,10件样品中的4件w(Re)极低,模式年龄变化范围大,且误差较大,故不对其进行讨论;其余6件的w(Re)为10.58×10~(-9)~102.59×10~(-9),普通w(Os)较低(0.0054×10~(-9)~0.0113×10~(-9)),w(~(187)Os)较高(0.019×10~(-9)~0.177×10~(-9)),Re/Os比值较高(4406~73 422),为低含量高放射性Os成因硫化物。研究获得黄铁矿Re-Os同位素加权平均模式年龄为(165.3±2.3)Ma(MSWD=1.04)。因此,德兴铜矿的铜成矿年龄为中侏罗世,综合前人资料,德兴铜矿最可能形成于古太平洋板块俯冲的远程效应影响下的陆内伸展的地质背景,为陆内环境斑岩铜矿。 相似文献
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Re-Os isotopes were used to constrain the source of the ore-forming elements of the Tharsis and Rio Tinto mines of the Iberian
Pyrite Belt, and the timing of mineralization. The pyrite from both mines has simila]r Os and Re concentrations, ranging between
0.05–0.7 and 0.6–66 ppb, respectively. 187Re/188Os ratios range from about 14 to 5161. Pyrite-rich ore samples from the massive ore of Tharsis and two samples of stockwork
ore from Rio Tinto yield an isochron with an age of 346 ± 26 Ma, and an initial 187Os/188Os ratio of about 0.69. Five samples from Tharsis yield an age of 353 ± 44 Ma with an initial 187Os/188Os ratio of about 0.37. A sample of massive sulfide ore from Tharsis and one from Rio Tinto lie well above both isochrons
and could represent Re mobilization after mineralization. The pyrite Re-Os ages agree with the paleontological age of 350 Ma
of the black shales in which the ores are disseminated. Our data do not permit us to determine whether the Re-Os isochron
yields the original age of ore deposition or the age of the Hercynian metamorphism that affected the ores. However, the reasonable
Re-Os age reported here indicates that the complex history of the ores that occurred after the severe metamorphic event that
affected the Iberian Pyrite Belt massive sulfide deposits did not fundamentally disturb the Re-Os geochronologic system. The
highly radiogenic initial Os isotopic ratio agrees with previous Pb isotopic studies. If the initial ratio is recording the
initial and not the metamorphic conditions, then the data indicate that the source of the metals was largely crustal. The
continental margin sediments that underlie the deposits (phyllite-quartzite group) or the volcanic rocks (volcanogenic-sedimentary
complex) in which the ores occur are plausible sources for the ore-forming metals and should constrain the models for the
genesis of these deposits.
Received: 15 March 1999 / Accepted: 26 July 1999 相似文献
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Re–Os isotope compositions of mantle-derived magmas are highly sensitive to crustal contamination because the crust and mantle have very different Os isotope compositions. Crustal contamination may trigger S saturation and thus the formation of magmatic Ni–Cu–(PGE) sulfide deposits. The ∼287-Ma Kalatongke norite intrusion of NW China are hosted in carboniferous tuffaceous rocks and contain both disseminated and massive sulfide mineralization. The Re–Os isotope compositions in the intrusion are highly variable. Norite and massive sulfide ores have γ Os values ranging from +59 to +160 and a Re–Os isochron age of 239 ± 51 Ma, whereas disseminated sulfide ores have γ Os values from +117 to +198 and a Re–Os isochron age of 349 ± 34 Ma. The variability of Os isotope compositions can be explained as the emplacement of two distinct magma pulses. Massive sulfide ores and barren norite in the intrusion formed from the same magma pulse, whereas the disseminated sulfide ores with more radiogenic Os isotopes formed from another magma pulse which underwent different degrees of crustal contamination. Re–Os isotopes may not be suitable for dating sulfide-bearing intrusions that underwent variable degrees of crustal contamination to form magmatic sulfide deposits. 相似文献
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滇东北会泽超大型铅锌矿Re-Os同位素特征及喜山期成矿作用动力学背景探讨 总被引:2,自引:0,他引:2
会泽超大型铅锌矿是滇东北铅锌多金属成矿域中典型的密西西比河谷型(MVT)或会泽型(HZT)矿床,因其独特的成矿系统以及矿床中富锗而被地质学者熟知,由于该类型矿床成矿温度较低且缺少合适的定年矿物,其成矿时代一直存在较大的争议。本文在会泽铅锌矿麒麟厂矿区1584中段0-11号穿脉坑道块状铅锌硫化物矿石中挑选了9件硫化物样品(黄铁矿、方铅矿和闪锌矿),采用负离子热表面电离质谱法进行Re-Os同位素分析,获得Re-Os等时线年龄为40.7±2.6 Ma(n=9),与模式年龄加权平均值40.0±2.6Ma(n=8)在误差内完全一致,闪锌矿和方铅矿模式年龄分别为38.24±0.41 Ma和36.57±0.40 Ma。上述同位素年龄揭示了会泽超大型铅锌矿的成矿时代可能为始新世。结合滇东北铅锌矿集区NE向逆冲断层和冲断褶皱控矿构造区域构造解析以及断裂、矿体构造-岩相蚀变特征,提出会泽超大型铅锌矿经历了燕山期、喜山期两阶段构造-流体贯入的成矿作用模型。 相似文献
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滇东南八布地区发育一套晚古生代超镁铁质-镁铁质杂岩,是认识古特提斯分支洋构造演化的重要窗口,而其中以火山岩为赋矿围岩的杨万铜矿床,被视作区域找矿的突破点。目前,对这套超镁铁质-镁铁质杂岩的构造属性及赋存铜矿床的成矿时代及成因联系还存在争议。通过对杨万铜矿床中黄铜矿和黄铁矿进行Re-Os同位素定年,获得Re-Os等时线年龄为269±3 Ma,表明该矿床形成于早中二叠世,与火山岩(~270 Ma)大致同时;而初始187Os/188Os值为0.31±0.17,暗示成矿时存在热液流体与古海水的相互作用。区内玄武岩围岩和其它超镁铁质-镁铁质岩石的地球化学特征对比分析显示,八布超镁铁质-镁铁质杂岩为一套N-MORB型蛇绿岩组合,代表了古特提斯分支洋盆的洋壳残片。杨万铜矿床应划归为与古特提斯分支洋裂解有关的火山成因块状硫化物(VMS)矿床,其周边地区具有较好的找矿潜力。 相似文献
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Dania Tristá-Aguilera Fernando Barra Joaquin Ruiz Diego Morata Oscar Talavera-Mendoza Shoji Kojima Fernando Ferraris 《Mineralium Deposita》2006,41(1):99-105
The Lince–Estefanía stratabound copper deposit in the Michilla district is one of the most important deposits in the Coastal Cordillera of northern Chile and is one of the most representative of this type of deposit. Chalcocite and bornite characterize the main stage of hypogene copper sulfide mineralization. Rhenium and osmium isotopes are used here to constrain the age of hypogene mineralization and the source of osmium contained in these ore minerals. A Re–Os isochron yielded an age of 160±16 Ma (2σ), with an associated initial 187Os/188Os ratio of 1.06±0.09 (mean square of weighted deviates=1.8). This age is consistent with available geochronological data from volcanic rocks that host the mineralization and associated alteration phases. The high initial 187Os/188Os ratio indicates a lower crustal component for the source of Os and, by inference, the Cu sulfides that contain this Os. Late hematite occurs as an isolated phase or, more commonly, is associated with the chalcocite–bornite and supergene chalcocite–covellite associations. Analyses performed on pure hematite indicate a disturbance of the Re–Os system, and hence, this mineral phase is not useful as a Re–Os geochronometer. 相似文献
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罗河铁矿床是20世纪80年代在长江中下游成矿带庐枞盆地中发现的规模最大的铁矿床。经深部找矿勘探工作,2013年在罗河铁矿床主矿体800~1000 m之下又发现了小包庄铁矿床,这是近年来在长江中下游成矿带深部找矿工作中的重大进展之一,对该矿床地质特征的总结和形成时代的精确厘定,是正确分析矿床成因机制,完善玢岩型铁矿床成矿理论的关键。文章在已有研究的基础上,通过详细的钻孔岩芯观察、系统的岩相学和矿相学及电子探针分析测试工作,查明了罗河铁矿和小包庄铁矿的矿化蚀变特征,厘定了矿化阶段,初步探讨了成矿作用过程;对小包庄铁矿床进行了高精度金云母~(40)Ar-~(39)Ar同位素年代学研究,获得坪年龄为(130.32±0.78)Ma,相应的等时线年龄为(130.5±1.5)Ma,反等时线年龄为(130.4±1.3)Ma。结合庐枞盆地及区域成岩成矿时代,认为盆地内玢岩型铁矿床集中形成于130 Ma左右,是长江中下游成矿带第二阶段(135~126 Ma)成矿作用的产物。 相似文献
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Both stratiform/stratabound and granite-related models have been used to explain the genesis of W(Mo) deposits in the Okiep
copper district in western Namaqualand, South Africa. Apparently, stratabound mineralization (Fe-rich wolframite with accessory
molybdenite) occurs in foliation-parallel quartz veins in high-grade (∼750 °C, 5–6 kbar) metapelites of the Wolfram Formation,
and less commonly in small bodies of silicified leucogranites and pegmatites. Six Re–Os ages for molybdenites from four deposits
(Nababeep Tungsten Far West, Kliphoog, Narrap, Tweedam) range between 1000 ± 4 and 1026 ± 5 Ma. These molybdenites define
a well-constrained 187Re–187Os isochron with an age of 1019 ± 6 Ma, which is interpreted as the age of W(Mo) mineralization. This age is significantly
younger than Proterozoic protolith ages for supracrustal rocks and the emplacement ages for the main intrusive suites, but
geologic evidence requires overlap with a period of high-grade metamorphism. We suggest that W(Mo) mineralization is genetically
linked to intra-crustal magmatic processes at ∼1020 Ma, thereby precluding the ∼1060 Ma Concordia granite as the source for
mineralizing fluids. A narrow range of positive δ34S compositions (+3.6 to +4.5‰) for eight molybdenites from five W(Mo) mines is consistent with a SO2-rich fluid and a granite-related genetic model. Post-peak metamorphic deformation and metamorphism of W(Mo) ores is most
likely related to the retrograde stage of the Namaquan orogeny, which overlaps emplacement of late-orogenic, evolved granites
and pegmatites, and the formation of W(Mo) deposits in western Namaqualand. Therefore, the effects of retrograde Namaquan
metamorphism extend at least to ∼1020 Ma or, alternatively, these W(Mo) veins were affected by a poorly constrained later
event (e.g. early Pan-African).
Received: 12 September 1999 / Accepted: 20 April 2000 相似文献
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The absolute timing of epigenetic mineralization, including most types of gold deposits, is difficult to resolve due to the
absence of suitable minerals in veins and replacement zones. However, gold is commonly closely associated with pyrite and
arsenopyrite, which may be amenable to Re–Os geochronology, providing sufficient Re and Os are present within them. This short
paper outlines the use of this method to date two gold deposits in Newfoundland using pyrite. Although the Os contents of
the pyrites are extremely low (≪0.1 ppb), the Os is almost exclusively radiogenic 187Os, and data are amenable to model age calculations, as used in Re–Os molybdenite dating. The pyrites from these deposits
correspond to low-level highly radiogenic sulphides, as defined by other studies. The Stog’er Tight and Pine Cove gold deposits
yield mean Re–Os model ages of 411 ± 7 Ma (n = 4) and 420 ± 7 Ma (n = 5), respectively, which agree with isochron regression of 187Os against 187Re. The Re–Os age for Stog’er Tight is within uncertainty of a previous U–Pb age from ‘hydrothermal’ zircon (420 ± 5 Ma) in
spatially related alteration. A latest Silurian–earliest Devonian age for the mineralization is consistent with indirect age
constraints from some other gold deposits in central Newfoundland and suggests a broad temporal link to the mid-Silurian Salinic
Orogeny. However, the gold mineralization appears to be younger than most plutonic activity associated with this event. The
results illustrate the potential value of Re–Os pyrite geochronology in understanding the temporal framework of epigenetic
mineralization, especially if future improvements in analytical precision and reductions in procedural blanks allow wider
application to material with similarly low Re and Os concentrations. 相似文献