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1.
《Polar Science》2008,2(3):175-194
Y000027, Y000047, and Y000097 are new lherzolitic shergottites that show a poikilitic texture with interstitial non-poikilitic basaltic areas. They have identical mineral compositions and petrography, confirming their pairing. The Y00 shergottites first crystallized olivine and chromite, which were then partially enclosed by low-Ca pyroxenes. Interstitial areas of melt then formed as a result of oikocryst accumulation. Plagioclase and Fe-rich pyroxene crystallized from the interstitial melt, forming the non-poikilitic basaltic areas. The cooling rate during crystallization of the basaltic area was fast enough to preserve chemical zoning within olivine and pyroxene in poikilitic areas. The Y00s have similar petrology and mineralogy to other lherzolitic shergottites: all are likely to have originated from the same igneous block on Mars. The subtle mineralogical differences that exist are probably due to spatially variable cooling rates during crystallization of the basaltic area. In terms of mineral composition, the Y00s are most similar to (although distinct from) LEW88516, Y-793605, and NWA1950. Olivine and pyroxene compositions within interstitial areas may be related to the abundance of intercumulus melt, which, as with the nakhlite case, varied spatially in the igneous block. Although the Y00s and other lherzolitic shergottites (ALH77005, LEW88516, Y-793605, GRV99027, GRV020900, and NWA1950) were located within deeper levels of the block, RBT04262, a new shergottite similar in petrology and mineralogy to lherzolitic shergottites, may have been located at a slightly shallower level characterized by abundant, evolved interstitial melts. 相似文献
2.
The distribution pattern of the trace elements Rb, Sr, Nd and Sm for Yamato 984028 (Y984028) is consistent with its classification as a lherzolitic shergottite. The Sm–Nd mineral isochron of this lherzolitic shergottite defines its age to be 170 ± 10 Ma for an initial ?Nd = +11.6 ± 0.2. The corresponding Rb–Sr mineral isochron yields an identical age of 170 ± 9 Ma and an initial 87Sr/86Sr = 0.710389 ± 0.000029. The concordant Sm–Nd and Rb–Sr isochron ages suggest that Y984028 crystallized 170 ± 7 Ma ago contemporaneously with five other lherzolitic shergottites and ten enriched basaltic and olivine-phyric shergottites. The age, Sr- and Nd- isotopic signatures further suggest that Y984028 and Y-793605, and also probably Y000097 could come from a single magmatic body. Using a two-stage evolution model, the time-averaged 87Rb/86Sr-ratio for the mantle source of the parent magma of Y984028 is ～0.182, within the range of 0.178–0.182 that has been reported for other lherzolitic shergottites. The corresponding time-averaged 147Sm/144Nd-ratio for the source mantle of its parent magma is super-chondritic at ～0.217, implying its source was a depleted mafic part of the Martian mantle similar to that of diabasic shergottite Northwest Africa (NWA) 1460. Rb, Sr, Sm and Nd distributions in Y984028 are likely produced by pyroxene and olivine accumulation, probably from a NWA 1460-like parental melt, in an intrusive magma body. 相似文献
3.
《Polar Science》2008,2(3):163-174
Isotopic analysis of the Martian lherzolitic shergottite Yamato 000097 yields a Rb–Sr age of 147 ± 28 Ma with an initial 87Sr/86Sr ratio of 0.710490 ± 0.000072, a Sm–Nd age of 152 ± 13 Ma with an initial ɛ143Nd-value of +11.7 ± 0.2, and a 39Ar–40Ar age of ∼260 Ma. The near concordance of these ages, in combination with the Rb–Sr and Sm–Nd initial isotopic signatures, suggests that Yamato 000097 crystallized from low Rb/Sr, light rare earth element depleted source materials ∼150 Ma ago. Although the obtained 39Ar–40Ar age is significantly higher than the Rb–Sr and Sm–Nd ages, Yamato 000097 shows little or no evidence of trapped Martian atmospheric 40Ar. The trapped 40Ar concentration of Yamato 000097 is similar to that of Zagami, suggesting that both basaltic and lherzolitic shergottites may have similarly inherited excess 40Ar from their magmas.The Rb–Sr and Sm–Nd ages, and initial 87Sr/86Sr and ɛ143Nd-values of Yamato 000097 and Yamato 793605 lie on the same isotopic ingrowth curves, suggesting that they came from very similar mantle sources. Allan Hills 77005 was also probably derived from the same source, but Lewis Cliff 88516 appears to be from a distinct but similar source. Yamato 000097 represents the most recent known magmatism from its source, and is the youngest Martian meteorite for which concordant Rb–Sr and Sm–Nd ages have been determined. 相似文献
4.
Amy J.V. Riches Yang Liu James M.D. Day Igor S. Puchtel Douglas Rumble III Harry Y. McSween Jr. Richard J. Walker Lawrence A. Taylor 《Polar Science》2011,4(4):497-514
We report the petrography, mineral and whole-rock chemistry (major-, trace-, and highly-siderophile element abundances, and osmium and oxygen isotope compositions) of a newly recognized lherzolitic shergottite, Yamato (Y) 984028. Oxygen isotopes (Δ17O = 0.218‰) confirm a martian origin for this meteorite. Three texturally distinctive internal zones and a partially devitrified fusion crust occur in the polished section of Y 984028 studied here. The zones include: 1) a poikilitic region with pyroxene enclosing olivine and chromite (Zone A); 2) a non-poikilitic zone with cumulate olivine, interstitial pyroxene, maskelynite and Ti-rich chromite (Zone B) and; 3) a monomict breccia (Zone C). The pyroxene oikocryst in Zone A is chemically zoned from Wo3–7En76–71 in the core region to Wo33–36En52–49 at the rim, and encloses more Mg-rich olivine (Fo74–70) in the core, as compared with olivines (Fo69–68) located at the oikocryst rim. Constraints from Fe–Mg partitioning between crystals and melt indicate that constituent minerals are not in equilibrium with the corresponding bulk-rock composition, implying that Y 984028 represents a cumulate. The whole-rock major- and trace-element compositions, and initial 187Os/188Os value (0.1281 ± 0.0002) of Y 984028 are similar to other lherzolitic shergottites and this sample is probably launch-paired with Y 793602, Y 000027, Y 000047, and Y 000097. The Os isotopic composition and highly-siderophile element (HSE) abundances of Y 984028 and other lherzolitic shergottites are consistent with derivation from a martian mantle source that evolved with chondritic Re/Os. 相似文献
5.
Shin Ozawa Masaaki Miyahara Eiji Ohtani Makoto Kimura Yoshinori Ito 《Polar Science》2011,4(4):550-557
Yamato 984028 (Y984028) is a newly identified lherzolitic shergottite, recovered from the Yamato Mountains, Antarctica, in 1999. As part of a consortium study, we conducted petrographic observations of Y984028 and its melt vein in order to investigate its shock metamorphism. The rock displays the typical non-poikilitic texture of lherzolitic shergottite, characterized by a framework of olivine, minor pyroxene (pigeonite and augite), and interstitial maskelynite. Shock metamorphic features include irregular fractures in olivine and pyroxene, shock-induced twin-lamellae in pyroxene, and the complete conversion of plagioclase to maskelynite, features consistent with those found in other lherzolitic shergottites. The melt vein is composed of coarse mineral fragments (mainly olivine) entrained in a matrix of fine-grained euhedral olivine (with several modes of compositional zoning) and interstitial glassy material. Some coarse olivine fragments consist of an assemblage of fine-grained euhedral to subhedral olivine crystals, suggesting shock-induced fragmentation, recrystallization, and/or a process of sintering. The implication is that the fine-grained olivine crystals in the matrix of the melt vein represent complicated crystallization environments and histories. 相似文献
6.
We have investigated secondary influences on the noble gas budget in rim and interior pairs of three Martian meteorites from Antarctica: the lherzolitic shergottites Y000027 and Y000097, and the nakhlite Y000593. Three factors have been found to influence the original Martian noble gas budget: shock metamorphic overprint, cosmic irradiation, and terrestrial weathering. The 3He/4He ratio of the shergottites is between 0.189 and 0.217, which indicates almost complete loss of radiogenic 4He. This is expected from the high shock pressure observed in the shergottite samples. The concentration of 4He in these shergottite samples ranges from 33.8 to 39.4 × 10−8 ccSTP/g. 22Ne in the shergottites is on the order of 14 × 10−9 ccSTP/g. The nakhlite has 800 × 10−8 ccSTP/g 4He and 26 × 10−9 ccSTP/g 22Ne. An indication for solar cosmic ray contribution to the neon budget can be found in the shergottites. As Y000027 and Y000097 are reported to be paired we conclude the cosmic ray exposure (CRE) age T(3+21) of this shergottite to be 4.41 ± 0.54 Ma. For the nakhlite Y000593 T(3+21) is 11.8 ± 0.3 Ma. Heavy noble gas concentrations show large differences between rim and interior samples with the rim samples having 1.3–2.9, 1.7–38, and 1.4–20 times as much 36Ar, 84Kr, and 132Xe, respectively. The enrichment of heavy noble gases in the rim samples indicates severe terrestrial contamination. The relation between 129Xe/132Xe and 84Kr/132Xe in the rim samples shows that the incorporation mechanism caused elemental fractionation of Kr and Xe to the extent that in the Y000027 shergottite samples any Martian signature is completely masked by terrestrial contamination, if the total is taken. Only the 1400 °C steps show clear evidence for Martian atmosphere. The Y000593 nakhlite interior sample, on the other hand, shows low 84Kr/132Xe in relation to 129Xe/132Xe, which is characteristic for fractionated Martian atmosphere observed in nakhlites. 相似文献
7.
《Polar Science》2008,2(3):195-214
We used total melting and stepwise heating methods to measure noble gases within bulk samples from Yamato 000027 and Yamato 000097 lherzolites as well as a melt-vein sample from Yamato 000027. He and Ne are dominated by cosmogenic noble gases. The obtained cosmic-ray exposure age of 4.6 ± 1.5 Ma, an average age based on cosmogenic 3He, 21Ne, and 38Ar for these samples, is consistent with the ages of other lherzolitic shergottites, indicating a common impact event for the ejection of lherzolites from Mars. Heavy noble gases released from the bulk samples at low temperatures were elementally fractionated terrestrial atmosphere. Martian noble-gas isotopic signatures, 40Ar/36Ar = 1900 and 129Xe/132Xe = 1.3, were observed at high temperatures (>1000 °C). The melt-vein sample released greater amounts of atmospheric Ar, Kr, and Xe at low temperatures than the bulk samples. Large amounts of Ar and Kr, as well as excess 40Ar and 129Xe, were evolved from the melt-vein sample at 1400 °C, and the gas shows very high 36Ar/132Xe (=3100) and 84Kr/132Xe (=76) values. Maximum 40Ar/36Ar and 129Xe/132Xe values of the melt sample were 1100 and 1.6, respectively, at 1600 °C. Cosmogenic Kr shows an absence of 80Kr and 82Kr produced by neutron capture on Br, which suggests a small pre-atmospheric body. Overall noble gas compositions for Y000027 and Y000097 support pairing for the Yamato 00 shergottites. 相似文献
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10.
黄河宁蒙段穿越腾格里沙漠、河东沙地、乌兰布和沙漠和库布齐沙漠,风沙水沙交互强烈,形成典型的沙漠宽谷冲积河道。对黄河河道及周边沙源区沉积物进行了系统的采集、测定、分析工作。结果表明:宁蒙河段沉积物相对富集SiO_(2)、CaO、Al_(2)O_(3)、Ce、Zr、Hf和Nd,亏损K_(2)O、Na_(2)O、Rb、Zn、Ni和Sr。与周边沙源区对比,黄河宁夏段下河沿上游河道、清水河、腾格里沙漠和河东沙地沉积物均富集Co和Ti,亏损Sr、Ni、Hf和Y,且Hf、Ni、Y、Zn、MgO和CaO含量的变异系数较大。在内蒙古段,来自乌海上游河道、乌兰布和沙漠、库布齐沙漠和十大孔兑的沉积物相对富集Co和Ti,亏损Hf,Ni和Y,其中Cr、Hf、Ni、Y、Zn和MgO的元素含量变异系数较大。黄河宁蒙河段沉积物化学元素空间分布特征具有明显的波动和差异性,主要受到岩性、气候和局地物源输入的影响。 相似文献
11.
南极GRV 99027陨石是二辉橄榄岩质辉玻无球粒陨石(L-S)的火星陨石,具有嵌晶、非嵌晶和冲击熔融袋结构。矿物模式组成以橄榄石(55%)、辉石(37.5%)为主,有少量熔长石(6%)、铬铁矿(1.5%)以及微量白磷钙石、陨硫铁等。本文在阐述该陨石的岩石学和矿物化学特征的基础上进一步研究了稀土元素及氢同位素的地球化学特征。该陨石∑REE总量低;橄榄石及辉石以HREE富集为特征;熔长石富LREE,且具高正的δEu;副矿物白磷钙矿含量虽少(约0.2%),但具有极高的∑REE,LREE≈HREE,δEu负异常明显。GRV99027全岩稀土元素分配模式与L-S陨石的模式十分相似,而与SNC其它类型陨石的REE分配模式不同,反映不同类型火星陨石物质源区不同。火星陨石氢同位素以高δD为特征,各类含水矿物对陨石δD的贡献不同。陨石磷酸盐矿物中δD-水含量间一般没有正相关性,间或存有弱的负相关性。根据GRV99027陨石的矿物学模式,REE分配模式,及氢同位素特征,可以确定GRV99027陨石为L-S陨石。为了探讨GRV99027陨石的物质源区及演化历史,我们广泛收集了L-S火星陨石的Sr,Nd,Pb,Os和稀有气体同位素... 相似文献
12.
The results of the geochemical investigation on bulk sediment fromthree cores collected in Albano crater lake (Central Italy) are reported, andthe main markers of the palaeoenvironmental changes in the last 26ka are discussed. The sediment of Lago Albano consists of greysilt and mud, and is made of volcanogenic, calcareous, siliceous and organicmaterial. Some tephra layers provide a chronological framework for thesequence. The chemical features of the sediments are strongly impacted by theAlban Hills volcanism (Roman volcanic area), but there are also strong changesof organic/inorganic matter ratios, owing to variations in biologicalproductivity and terrigeous supply from the catchment. Six chemostratigraphiczones record the main steps of the transition from the cold and dry climate ofGlacial Maximum to the warmer and more humid Holocene climate. The most usefulgeochemical indices are: biogenic silica, CO2, Br and organiccontent (OM) for biological productivity; Al, Y, CIA (Chemical Index ofAlteration), Al/Rb, Ti/Zr and Y/Al ratios for terrigenous clasticmaterial; OM/Al ratio for organic/terrigenous ratio; S/Fe andMo/Fe ratios and Authigenic U for redox diagenetic conditions of the lakesediment. The geochemical records agree rather well with those of thelithological and paleomagnetic studies, and despite the information obtainedare less detailed than those acquired by the study of biological remains, thepalaeoenvironmental significance inferred is consistent. A comparison of thechemostratigraphic results of Lago Albano with those obtained on coevalsediments from Central and Southern Italy lakes supports the role of thegeochemical investigation as important complement to more sophisticatedtechniques in the palaeoenvironmental reconstructions. 相似文献
13.
来自南极格罗夫山蓝冰地区的GRV 99027陨石为一无球粒陨石,主要由橄榄石及辉石组成。棕色橄榄石具堆晶结构及镶嵌结构等火成岩浆分异结晶的特征。陨石的矿物模式组成及化学成分显示与SNC族陨石特征相似,特别是与ALHA77005陨石十分接近。后者被确定为二辉橄榄岩质辉玻无球粒陨石类(Lherozolitic-Shergotty,L-S)火星陨石。GRV 99027陨石的矿物化学特征以及FeO/MnO比值也与L-S类相似。可以初步认为GRV 99027陨石为SNC族火星陨石一个新的成员。二辉橄榄岩相当于地球的上地幔成分。陨石来自火星探部,为世界上极为稀有的火星样品,极具研究价值。 相似文献
14.
对乔治王岛上白垩统半三角组火山岩样品进行了 Rb- Sr同位素等时线年龄测定 ,所获结果为 71 .3 3± 0 .3 Ma。通过 εND(T) - 14 7Sm/14 4Nd,14 3 Nd/14 4Nd- 87Sr/86 Sr,87Sr/86 Sr- Sr和 87Sr/86 Sr- K2 O/(K2 O+Na2 O)的相关性研究表明 ,该火山岩物质主要来自亏损地幔 (DMM)源区 ,基本上未受到地壳物质混染。其中 6个样品的平均 Sm- Nd模式年龄 (TNd DM)为 443 .3± 2 0 .6 Ma,可能反映了在研究地区的岩浆源区化学分异事件的时代。微量元素的特点表明 ,半三角组样品属典型的钙碱性火山岩系列 ,与长城站地区第三系火山岩相类似 ,同属于岛弧火山活动的产物。 相似文献
15.
K. W. Keatings I. Hawkes J. A. Holmes R. J. Flower M. J. Leng R. H. Abu-Zied A. R. Lord 《Journal of Paleolimnology》2007,38(2):261-283
The utility of ostracod-based palaeoenvironmental reconstruction was evaluated using instrumental data for Lake Qarun, Egypt.
The euryhaline ostracod Cyprideis torosa was the only species found in the lake’s recent sediment record. This species is known to tolerate salinity levels and water
solute compositions that may prevent colonisation by other species. Oxygen and carbon isotope ratios of ostracod carbonate
from lake sediments covary with changes in instrumental values for lake level and salinity for the period 1890–1974. δ13C-values correlate negatively with lake water salinity (r
2 = 0.87) and δ18O-values correlate negatively with measured lake level changes (r
2 = 0.41). Other ostracod proxy data provide qualitative information on lake level trends. Fossil assemblage data (juvenile/adult
and valve/carapace ratios and valve preservation) provide information on wave energy. Ecophenotypic variation of C. torosa valves provided some useful palaeolimnological information. Sr/Ca and Mg/Ca ratios in ostracods were not found to reflect
water composition, due to the uncoupling of these ratios with salinity in Lake Qarun. Overall, our results highlight the need
to calibrate ostracod proxy data in modern systems prior to their use for palaeoenvironmental reconstruction. 相似文献
16.
《Basin Research》2018,30(1):132-147
The development of fast and reliable instrumental methods for U‐Pb dating and Lu‐Hf isotope analysis of zircon has caused detrital zircon to become a popular provenance indicator for clastic sediments and an important tool in basin analysis. In parallel with the increasing ease of access to data, advanced methods of data interpretation have been developed. The downside of some techniques for visualization and comparison of detrital zircon distribution patterns is that the results are difficult to relate to what the zircon grains really record: The age and nature of geological processes in a protosource terrane. Some simple methods of data presentation and inter‐sample comparison that preserve a direct and intuitively understandable relationship between the data and the age of zircon‐forming processes in the protosource are proposed here: Comparison of confidence intervals around empirical, cumulative distribution curves combined with the use of a plot of upper vs. lower quartile values of cumulative zircon U‐Pb age or Lu‐Hf model age distributions. This approach allows a robust and transparent separation to be made between samples whose detrital zircon distributions are indistinguishable from each other, and those that are more or less similar. Furthermore, it allows simple comparison between detrital zircon distributions and the geological age record of potential protosource terranes, or the detrital zircon distributions of possible sedimentary precursors. 相似文献
17.
近百年广东沿海海平面变化趋势 总被引：5，自引：3，他引：2
为预估本世纪末广东海平面的可能上升量,从探讨近百年来广东海平面上升率的阶段性变化入手,通过对广东沿海验潮站潮位观测资料的统计分析,得出广东沿海海平面近86年(1925-2010年)、近40年(1970-2010年)和近20年(1993-2010年)的上升率分别为2.1 mm/a、2.5 mm/a和3.2 mm/a,存在加速上升的趋势,并与全球大体呈准同步变化.20世纪90年代以来,广东沿海海平面上升和热带西太平洋的海平面出现突变上升有密切关系. 相似文献
18.
反射光谱技术:研究南极企鹅古生态演化的一种新方法 总被引：2，自引：0，他引：2
为探求快速、廉价、无损和同步的光谱技术在南极生态环境研究中的可能性,本文利用南极阿德雷岛的四根企鹅粪土沉积柱样品的反射光谱,通过逐步多元线性回归和主成分回归两种数学运算方法,建立了反射光谱数据与企鹅粪九种标型元素浓度之间的关系,并探讨了南极企鹅粪土沉积物光谱数据的古生态意义。结果表明:南极粪土沉积样品反射率光谱与企鹅粪九种标型元素(P、Ca、Cu、F、Ba、S、Zn、Sr、Se)含量之间存在良好的相关性,预测值与实测值之间的相关系数R都达到了0.9以上,在深度剖面上预测浓度与实测浓度具有非常一致的变化趋势;南极粪土沉积物光谱数据包含有明确的古生态变化信息,可利用主成分分析快速恢复历史时期企鹅数量演化过程。本研究结果为在偏远的南极地区开展古生态环境研究提供了一种新的快捷方法和技术途径。 相似文献
19.
应用循环曲线法研究了在353 K的乙酰胺-尿素-NaBr熔体中Co2+在Cu电极上的电化学行为,获知Co2+电还原为金属Co是一步不可逆过程,测得a=0.25和Do=3.24×10-6cm2.s-1;而Ce(Ⅲ)、Sm(Ⅲ)不能单独还原为Ce和Sm,但可以被Co(Ⅱ)诱导而共沉积;由恒电位电解法得到非晶态的Ce-Sm-Co合金膜,合金膜中Ce和Sm的含量随电位、时间和浓度的变化而变化。其合金膜中Sm的最高质量分数可以达到47.98%,Ce的最高质量分数可以达到47.32%。 相似文献
20.
Sapphirine is a metamorphic mineral that forms in the deep crust in rocks with distinctive bulk compositions, in particular high concentrations of Mg and Al. This study investigates a thin, discontinuous layer of sapphirine-bearing garnet-orthopyroxene (SGO) granulite within a Palaeoproterozoic mafic granulite together with metamorphosed mafic and ultramafic rocks, micaceous rocks rich in magnetite and pyrite, and marble. All of these rocks occur within a low-strain zone in the Lewisian complex of South Harris, NW Scotland. Data on mineral compositions and major, trace, and rare earth element (REE) patterns provide evidence for the origin of the precursor of the SGO granulite. The host mafic granulite has a trace element signature and REE pattern comparable with that of E-type MORB. The chemical abundances of Nb, Ta, La, Ce, Nd, Zr, Hf, Ti, and V in the SGO granulite, except for one sample that records total element loss, are similar to those of the host mafic granulite; however, in terms of whole-rock element abundances, the former is relatively enriched in MgO and depleted in CaO, Na2O, MnO, Sr, and Eu. Elements within the SGO granulite that were apparently unaffected by hydrothermal alteration—V, Y, Zr, and Cr—are within the range of values observed in the host mafic granulite. Sm–Nd whole-rock isotope systematics suggest that both the host mafic granulite and SGO granulite were metamorphosed at 1.9 Ga, and the Nd initial ratio is consistent with a MORB source at that time. There is no significant difference in the Nd values of the two rock types, suggesting that they originally belonged to the same protolith. Chemical trends within a narrow zone between the SGO and host rock granulite suggest that the former was derived from a basaltic precursor of the latter by a process of infiltration metasomatism, comparable with the chemical exchange that takes place when hydrothermal fluids in present-day oceanic crust pass through vents in a “recharge zone.” The geological and chemical relations observed in the South Harris rocks are consistent with the following model: hydrothermally altered oceanic basaltic crust was trapped in an accretionary wedge and subducted, followed by granulite-facies metamorphism in a deep continental environment during arc–continent collision. This is the first report of hydrothermally altered oceanic crust that was converted to sapphirine-bearing granulite deep in the continental crust. 相似文献