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1.
Solutes in saline groundwater (total dissolved solids up to 37 000 mg/L) in the Lake Cooper region in the southern margin of the Riverine Province of the Murray Basin are derived by evapotranspiration of rainfall with minor silicate, carbonate and halite dissolution. The distribution of hydraulic heads, salinity, percentage modern carbon (pmc) contents, and Cl/Br ratios imply that the groundwater system is complex with vertical flow superimposed on lateral flow away from the basin margins. Similarities in major ion composition, stable (O, H, and C) isotope, and 87Sr/86Sr ratios between groundwater from the shallower Shepparton Formation and the deeper Calivil – Renmark aquifer also imply that these aquifers are hydraulically interconnected. Groundwater in the deeper Calivil – Renmark aquifer in the Lake Cooper region has residence times of up to 25 000 years, implying that pre-land-clearing recharge rates were <1 mm/y. As in other regions of the Murray Basin, the low recharge rates account for the occurrence of high-salinity groundwater. Shallow (<20 m) groundwater yields exclusively modern 14C ages and shows a greater influence of evaporation over transpiration. Both these observations reflect the rise of the regional water-table following land clearing over the last 200 years and a subsequent increase in recharge to 10 – 20 mm/y. The rise of the regional water-table also has increased vertical and horizontal hydraulic gradients that may ultimately lead to the export of salt from the Lake Cooper embayment into the adjacent fresher groundwater resources.  相似文献   

2.
High arsenic levels in groundwater of the aquifers, belonging to the Pliocene terrestrial layers and Quaternary alluvial sediments, have become a significant problem for the inhabitants living in Sarkisla (Turkey). The main objective of this study was to determine the origin and arsenic contamination mechanisms of the Sarkisla drinking water aquifer systems. The highest arsenic concentrations were found in Pliocene layers and alluvial sediments with concentrations ranging from 2.1 to 155 mg/kg. These rocks are the main aquifers in the study area, and most of the drinking groundwater demand is met by these aquifers. Groundwater from the Pliocene aquifer is mainly Ca-HCO3 and Ca-SO4 water type with high EC values reaching up to 3,270 μS/cm, which is due to the sulfate dissolution in some parts of the alluvial aquifer. Stable isotope values showed that the groundwater was of meteoric origin. Tritium values for the groundwater were between 8.31 and 14.06 TU, representing a fast circulation in the aquifer. Arsenic concentrations in the aquifers were between 0.5 and 345 μg/L. The highest arsenic concentrations detected in the Pliocene aquifer system reached up to 345 μg/L with an average value of 60.38 μg/L. The arsenic concentrations of the wells were high, while the springs had lower arsenic concentrations. These springs are located in the upper parts of the study area where the rocks are less weathered. The hydrogeochemical properties demonstrated that the water–rock interaction processes in sulfide-bearing rocks were responsible for the remarkably high groundwater arsenic contamination in the study area. In the study area, the arsenic levels determined in groundwater exceeded the levels recommended by the WHO. Therefore, it is suggested that this water should not be used for drinking purposes and new water sources should be investigated.  相似文献   

3.
Groundwater in shallow unconsolidated sedimentary aquifers close to the Bornheim fault in the Lower Rhine Embayment (LRE), Germany, has relatively low δ2H and δ18O values in comparison to regional modern groundwater recharge, and 4He concentrations up to 1.7?×?10?4 cm3 (STP) g–1?±?2.2 % which is approximately four orders of magnitude higher than expected due to solubility equilibrium with the atmosphere. Groundwater age dating based on estimated in situ production and terrigenic flux of helium provides a groundwater residence time of ～107 years. Although fluid exchange between the deep basal aquifer system and the upper aquifer layers is generally impeded by confining clay layers and lignite, this study’s geochemical data suggest, for the first time, that deep circulating fluids penetrate shallow aquifers in the locality of fault zones, implying  that sub-vertical fluid flow occurs along faults in the LRE. However, large hydraulic-head gradients observed across many faults suggest that they act as barriers to lateral groundwater flow. Therefore, the geochemical data reported here also substantiate a conduit-barrier model of fault-zone hydrogeology in unconsolidated sedimentary deposits, as well as corroborating the concept that faults in unconsolidated aquifer systems can act as loci for hydraulic connectivity between deep and shallow aquifers. The implications of fluid flow along faults in sedimentary basins worldwide are far reaching and of particular concern for carbon capture and storage (CCS) programmes, impacts of deep shale gas recovery for shallow groundwater aquifers, and nuclear waste storage sites where fault zones could act as potential leakage pathways for hazardous fluids.  相似文献   

4.
The geochemical and isotopic composition of surface waters and groundwater in the Velenje Basin, Slovenia, was investigated seasonally to determine the relationship between major aquifers and surface waters, water–rock reactions, relative ages of groundwater, and biogeochemical processes. Groundwater in the Triassic aquifer is dominated by HCO3 –, Ca2+, Mg2+ and δ13CDIC indicating degradation of soil organic matter and dissolution of carbonate minerals, similar to surface waters. In addition, groundwater in the Triassic aquifer has δ18O and δD values that plot near surface waters on the local and global meteoric water lines, and detectable tritium, likely reflecting recent (<50 years) recharge. In contrast, groundwater in the Pliocene aquifers is enriched in Mg2+, Na+, Ca2+, K+, and Si, and has high alkalinity and δ13CDIC values, with low SO4 2– and NO3 – concentrations. These waters have likely been influenced by sulfate reduction and microbial methanogenesis associated with coal seams and dissolution of feldspars and Mg-rich clay minerals. Pliocene aquifer waters are also depleted in 18O and 2H, and have 3H concentrations near the detection limit, suggesting these waters are older, had a different recharge source, and have not mixed extensively with groundwater in the Triassic aquifer.  相似文献   

5.
The quantification of submarine and intertidal groundwater discharge (SiGD) or purely submarine groundwater discharge (SGD) from coastal karst aquifers presents a major challenge, as neither is directly measurable. In addition, the expected heterogeneity and intrinsic structure of such karst aquifers must be considered when quantifying SGD or SiGD. This study applies a set of methods for the coastal karst aquifer of Bell Harbour in western Ireland, using long-term onshore and offshore time series from a high-resolution monitoring network, to link catchment groundwater flow dynamics to groundwater discharge as SiGD. The SiGD is estimated using the “pollution flushing model”, i.e. a mass-balance approach, while catchment dynamics are quantified using borehole hydrograph analysis, single-borehole dilution tests, a water balance calculation, and cross-correlation analysis. The results of these analyses are then synthesised, describing a multi-level conduit-dominated coastal aquifer with a highly fluctuating overflow regime draining as SiGD, which is in part highly correlated with the overall piezometric level in the aquifer. This concept was simulated using a hydraulic pipe network model built in InfoWorks ICM [Integrated Catchment Modeling]® version 7.0 software (Innovyze). The model is capable of representing the overall highly variable discharge dynamics, predicting SiGD from the catchment to range from almost 0 to 4.3 m3/s. The study emphasises the need for long-term monitoring as the basis for any discharge studies of coastal karst aquifers. It further highlights the fact that multiple discharge locations may drain the aquifer, and therefore must be taken into consideration in the assessment of coastal karst aquifers.  相似文献   

6.
Groundwater systems in the San Luis Valley, Colorado, USA have been re-evaluated by an analysis of solute and isotopic data. Existing stream, spring, and groundwater samples have been augmented with 154 solute and isotopic samples. Based on geochemical stratification, three groundwater regimes have been identified within 1,200 m of the surface: unconfined, upper active confined, and lower active confined with maximum TDS concentrations of 35,000, 3,500 and 600 mg/L, respectively. The elevated TDS of northern valley unconfined and upper active confined systems result from mineral dissolution, ion exchange and methanogenesis of organic and evaporate lake sediments deposited in an ancient lake, herein designated as Lake Sipapu. Chemical evolutions along flow paths were modeled with NETPATH. Groundwater ages, and δ13C, δ2H and δ18O compositions and distributions, suggest that mountain front recharge is the principle recharge mechanism for the upper and lower confined aquifers with travel times in the northern valley of more than 20,000 and 30,000 14C years, respectively. Southern valley confined aquifer travel times are 5,000 14C years or less. The unconfined aquifer contains appreciable modern recharge water and the contribution of confined aquifer water to the unconfined aquifer does not exceed 20%.  相似文献   

7.
The combined effects of low rainfall, groundwater withdrawal in excess of 300 GL/year and reduced recharge in areas covered by pine plantations has caused the water table in a sandy unconfined aquifer on the Gnangara Mound in Western Australia to drop by up to 5 m and aquifer storage to decline by about 500 GL over the last 20 years. Groundwater has become acidic in areas of high drawdown, with pH values typically being less than 5.0 at the water table, and elevated concentrations of SO4 2?, Al, Fe, Zn, Cu, Ni and Pb. Trends of increasing acidity and base cation concentrations in deep water supply wells in the Mirrabooka wellfield indicate that about 0.7 keq/ha/year of base cations are being leached from soil within cones of depression of pumping wells. These results indicate that the assessment of the sustainable yields of aquifers under conditions of low rainfall needs to consider geochemical interactions between groundwater, aquifer sediments, soils and vegetation, and not be just based on aquifer hydraulics and water-balance changes.  相似文献   

8.
A tritium (3H) profile was constructed in a long-screened well (LSW) of the Fontainebleau Sands Aquifer (France), and the data were combined with temperature logs to gain insight into the potential effects of the ambient vertical flow (AVF) of water through the well on the natural aquifer stratification. AVF is commonly taken into account in wells located in fracture aquifers or intercepting two different aquifers with distinct hydraulic heads. However, due to the vertical hydraulic gradient of the flow lines intercepted by wells, AVF of groundwater is a common process within any type of aquifer. The detection of 3H in the deeper parts of the studied well (approximate depth 50 m), where 3H-free groundwater is expected, indicates that shallow young water is being transported downwards through the well itself. The temperature logs show a nearly zero gradient with depth, far below the mean geothermal gradient in sedimentary basins. The results show that the age distribution of groundwater samples might be biased in relation to the age distribution in the surroundings of the well. The use of environmental tracers to investigate aquifer properties, particularly in LSWs, is then limited by the effects of the AVF of water that naturally occurs through the well.  相似文献   

9.
A significant component of domestic demand for water of urban areas located in the Gangetic plains is met by heavy pumping of groundwater. The present study is focused on the Patna municipal area, inhabited by 17 million people and spanning over 134 km2, where entire urban water demand is catered from pumping by wells of various capacities and designs. The present study examines the nature of the aquifer system within the urban area, the temporal changes in the water/piezometric level and the recharge mechanism of the deeper aquifers. The aquifer system is made up of medium-to-coarse unconsolidated sand, lying under a ~40-m-thick predominantly argillaceous unit holding 8- to 13-m-thick localised sand layers and continues up to 220 m below ground. Groundwater occurs under semi-confined condition, with transmissivity of aquifers in 5,500–9,200 m2 day?1 range. Hydraulic head of the deeper aquifer remains in 9–19 m range below ground, in contrast to 1–9 m range of that of the upper aquitard zone. The estimated annual groundwater extraction from the deeper aquifer is ~212.0 million m3, which has created a decline of 3.9 m in the piezometric level of the deeper aquifer during the past 30 years. Unregulated construction of deep tube wells with mushrooming of apartment culture may further exacerbate the problem. The sand layers within the aquitard zone are experiencing an annual extraction of 14.5 million m3 and have exhibited stable water level trend for past one and half decades. This unit is recharged from monsoon rainfall, besides contribution from water supply pipe line leakage and seepage from unlined storm water drains.  相似文献   

10.
Pico, the youngest island of the Azores archipelago, is composed of basaltic volcanic deposits less than 300,000 years old. The principal aquifer system consists mainly of recent lava flows that are very permeable and whose head is influenced by tidal fluctuations. Groundwater abstraction is almost entirely by drilled wells. The hydraulic gradient is very low, about 10–4, which agrees with observations made on similar volcanic islands. Groundwater also occurs in perched-water bodies, but the spring discharge from them is very low, about 10–3 L/s. The transmissivity of the volcanic rocks ranges from 9.44×10–3 to 3.05×10–1 m2/s, indicating the heterogeneity of the aquifers. The hydraulic diffusivity, estimated from observations of the effects of tidal fluctuations, also confirms the high permeability of the aquifer system; the average value is higher than published values for other volcanic islands. A mixing process for fresh water and seawater, often coupled with ion-exchange mechanisms, explains the groundwater composition, which is mainly of the sodium-chloride type. The water salinity influences the groundwater quality, resulting in a chloride content that exceeds the recommended chloride limit in 91% of the wells . Water–rock interactions are dominant in the chemical evolution of the perched water, which is characterized by bicarbonate-anion type water. Electronic Publication  相似文献   

11.
The study area is a part of central Ganga Plain which lies within the interfluve of Hindon and Yamuna rivers and covers an area of approximately 1,345 km2. Hydrogeologically, Quaternary alluvium hosts the major aquifers. A fence diagram reveals the occurrence of a single aquifer to a depth of 126 m below ground level which is intercalated by sub-regional clay beds. The depth to water level ranges from 9.55 to 28.96 m below ground level. The general groundwater flow direction is northwest to southeast. Groundwater is the major source of water supply for agricultural, domestic, and industrial uses. The overuse of groundwater has resulted in the depletion of water and also quality deterioration in certain parts of the area. This has become the basis for the preparation of a groundwater vulnerability map in relation to contamination. The vulnerability of groundwater to contamination was assessed using the modified DRASTIC-LU model. The parameters like depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone, hydraulic conductivity of the aquifer, and land use pattern were considered for the preparation of a groundwater vulnerability map. The DRASTIC-LU index is computed as the sum of the products of weights and rating assigned to each of the inputs considered. The DRASTIC-LU index ranges from 158 to 190, and is classified into four categories, i.e., <160, 160–170, 170–180, and >180, corresponding to low, medium, high, and very high vulnerability zones, respectively. Using this classification, a groundwater vulnerability potential map was generated which shows that 2 % of the area falls in the low vulnerable zone, 38 % falls in the medium vulnerable zone, and 49 % of the area falls in the high vulnerable zone. About 11 % of the study area falls in the very high vulnerability zone. The groundwater vulnerability map can be used as an effective preliminary tool for the planning, policy, and operational levels of the decision-making process concerning groundwater management and protection.  相似文献   

12.
A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers.  相似文献   

13.
The Barwon Downs Graben lies on the northern flanks of the Otway Ranges and is situated approximately 70 km southwest of Geelong, Victoria, Australia. The major lower Tertiary Barwon Downs Graben aquifer comprises highly permeable sands and gravels interbedded with clays and silts of the hydraulically interconnected Pebble Point, Dilwyn and Mepunga Formations. Groundwater flows east into the Barwon Downs Graben from the Barongarook High, and yields 14C ages up to ～20 ka implying that recharge rates are low and, consequently, that the resource could be impacted by overabstraction. The presence of three different lithological units has led to the development of localized flow systems that has resulted in a lack of regular spatial variations in groundwater chemistry. Stable isotopic data suggests that groundwater was recharged under similar climatic conditions as of today. The major ion chemistry of the freshest groundwater is dominated by Na and HCO3 while higher TDS groundwater, from the confining Narrawaturk Marl, is dominated by Na and Cl. Cl/Br ratios are close to rainfall suggesting that halite dissolution is not the principle source of salts. An excess of Na relative to Cl in fresher groundwater suggests that feldspar dissolution has occurred, however, water–rock interaction is limited. The concentrations of Ca, Mg, and SO4 are controlled by silicate dissolution and ion-exchange reactions with clays.  相似文献   

14.
Hydrogeologic framework of the Maku area basalts, northwestern Iran   总被引：1，自引：0，他引：1  
The Maku area in northwestern Iran is characterized by young lava flows which erupted from Mount Ararat in Turkey. These fractured volcanic rocks overlie alluvium associated with pre-existing rivers and form a good basalt-alluvium aquifer over an area of 650 km2. Groundwater discharge occurs from 12 large springs, ranging from 20 to 4,000 L s?1, and from some extraction wells. Permian and Oligo-Miocene age limestones along the northern boundary of the Bazargan and Poldasht Plains basalts are intensively karstified and groundwater from these high lands easily enters the basalt-alluvium aquifers. The transmissivity of the basalt-alluvium aquifer ranges from 24 to 870 m2 d?1, indicating heterogeneity. Groundwater of the aquifer is a sodium-bicarbonate and mixed cation-bicarbonate type and the concentration of fluoride is higher than the universal maximum admissible concentrations for drinking. In order to determine the chemical composition and identify the source of the high fluoride concentrations in the groundwater of the basaltic area, water samples from the springs, wells and rivers were analyzed. The results indicate that the high fluoride water enters the study area from the Sari Su River.  相似文献   

15.
The Salt Basin is a semiarid hydrologically closed drainage basin in southern New Mexico, USA. The aquifers in the basin consist largely of Permian limestone and dolomite. Groundwater flows from the high elevations (～2,500 m) of the Sacramento Mountains south into the Salt Lakes, which are saline playas. The aquifer is ‘underfit’ in the sense that depths to groundwater are great (～300 m), implying that the aquifer could transmit much more water than it does. In this study, it is speculated that this characteristic is a result of a geologically recent reduction in recharge due to warming and drying at the end of the last glacial period. Water use is currently limited, but the basin has been proposed for large-scale groundwater extraction and export projects. Wells in the basin are of limited utility for hydraulic testing; therefore, the study focused on environmental tracers (major-ion geochemistry, stable isotopes of O, H, and C, and 14C dating) for basin analysis. The groundwater evolves from a Ca–HCO3 type water into a Ca–Mg (Na) – HCO3–Mg (Cl) water as it flows toward the center of the basin due to dedolomitization driven by gypsum dissolution. Carbon-14 ages corrected for dedolomitization ranged from less than 1,000 years in the recharge area to 19,000 years near the basin center. Stable isotopes are consistent with the presence of glacial-period recharge that is much less evaporated than modern. This supports the hypothesis that the underfit nature of the aquifer is a result of a geologically recent reduction in recharge.  相似文献   

16.
An approach combining the use of water dissolved chemical species and isotopic fingerprints has been used to understand the behavior of a phreatic aquifer and to determine the origin of its different water components. This aquifer is located in the large sedimentary basin of the Great Oriental Erg (Algeria) and overlies two deeper aquifers: the Complexe Terminal (CT) and the Continental Intercalaire (CI). Besides the deterioration of its groundwater quality, its water table has risen during the last 20 years. A water budget surplus between 950 and 2500 l s?1 was estimated. Down-gradient groundwater evolution (south-north) has shown that the mineralisation increases from 1.23 to 5.20 g l?1 due to evaporite minerals dissolution. Chemical and isotopic data demonstrated that in addition to rainfall there is a contribution from the CT and CI aquifers. The latter are tritium-free and less mineralized than the phreatic aquifer. Their radiocarbon contents are very low (<10 pmC, percent modern Carbon) (Pleistocene recharge) whereas quite the contrary is observed for the superficial aquifer which exhibits fairly high and variable C-14 activities (50–100 pmC), evidence of recent recharge. On the basis of tritium contents, two groundwater groups were identified for the phreatic aquifer.  相似文献   

17.
The aquifer system in the Thon Buri sedimentary basin below the deltaic flood plain of the Chao Phraya River, central Thailand, has been exploited for public water supply for the capital Bangkok since the early 1920s. Groundwater withdrawal, currently 1.4 million m3/d, has resulted in a maximum decline in hydraulic head of up to 40 m. This has induced land subsidence of as much as 1.7 m (1940–1992) in the eastern suburbs of the metropolis. Artificial injection of purified water within an area-wide network of recharge wells could constitute a remedy to slow the water level depression within the sedimentary basin, and thus the subsidence. This requires a prior shutdown of water withdrawal. The flow paths of the injected water can be traced by changes in the 87Sr/86Sr ratio of the groundwater and injected water mixture within the three main aquifers in the basin that are used for public supply. The ratios, monitored at five monitoring stations within the cone of depression, have been constant over 3 years. Injection of the calculated cone volume of 5.2?×?109 m3 would take at least 10 years, depending on the injection pressure and the number and position of wells.  相似文献   

18.
Groundwater pumped from the semi-confined Complex Terminal (CT) aquifer is an important production factor in irrigated oases agriculture in southern Tunisia. A rise in the groundwater salinity has been observed as a consequence of increasing abstraction from the aquifer during the last few decades. All sources of contamination were investigated using hydrochemical data available from the 1990s. Water samples were taken from wells tapping both the CT and the shallow aquifers and analyzed with regard to chemistry tracers. Hydrochemical and water quality data obtained through a sampling period (December 2010) and analysis program indicate that nitrate pollution can be a serious problem affecting groundwater due to the use of nitrogen (N) fertilizers–pesticides in agriculture. The concentration of nitrate in an groundwater-irrigated area in Gafsa oases basin was studied, where abstraction from an unconfined CT aquifer has increased threefold over 25 years to 34 million m3/year; groundwater levels are falling at up to 0.7 m/year; and groundwater is increasingly mineralised (TDS increase from 500 to 4,000 mg/L), with nitrate concentrations ranging from 16 to 320 mg/L.  相似文献   

19.
The Agadir-Essaouira area in the occidental High Atlas Mountains of Morocco is characterized by a semi-arid climate. The scarcity and quality of water resources, exacerbated by long drought periods, constitute a major problem for a sustainable development of this region. Groundwater resources of carbonate units within Jurassic and Cretaceous aquifers are requested for drinking and irrigation purposes. In this study, we collected 84 samples from wells, boreholes, springs, and rivers. Hydrochemical and isotopic data were used to examine the mineralization and origin of water, which control groundwater quality. The chemical composition of water seems to be controlled by water-rock interactions, such as dissolution of carbonates (calcite and dolomite), weathering of gypsum, as well as ion exchange processes, which explain the observed variability. Stable isotopes results show that groundwater from the mainly marly Cretaceous aquifer are submitted to an evaporation effect, while samples from the chiefly calcareous Jurassic aquifer indicate a meteoric origin, due to a rapid infiltration of recharge runoff through the karstic outcrops. The low values of δ18O and δ2H suggest a local recharge from areas with elevations ranging from 400 to 1200 m for the Cretaceous aquifer and from 800 to 1500 m for the Jurassic units.  相似文献   

20.
The purpose of this study is to evaluate the groundwater-withdrawal potential of the Fraser River watershed, a mountainous drainage system in north-central Colorado. Laboratory tests, field investigations, and numerical modeling are conducted to present a quantitative understanding of the watershed’s groundwater-flow system. Aquifer hydraulic conductivity values obtained from aquifer tests range from 1E?5 to 1E?3 m/s. Groundwater withdrawal is concentrated in channel-fill deposits of the Troublesome Formation within the Fraser basin. A steady state groundwater-flow model of the Fraser River watershed is developed and calibrated using 24 observation wells in the Fraser River valley and estimated baseflow of the Fraser River. Modeling results suggest that surface recharge is the major source of groundwater in the watershed. Groundwater exits the watershed through evapotranspiration and discharge to rivers. Transient groundwater-flow modeling evaluates future withdrawal scenarios using the hydraulic head distribution from the steady state model as the initial condition. Drawdown within Troublesome Formation aquifers from the current pumping schedule approaches 2 m. When the daily pumping rate is doubled, drawdown approaches 4 m. The radius of influence is hundreds of meters to 1 km. Pumping wells withdraw approximately 2 and 15 % of groundwater flowing through the well field for hydraulic conductivity of 1E?3 and 1E?5 m/s, respectively. This study suggests that the groundwater system at the Fraser Valley could sustain current and future withdrawals, given that the current recharge condition is maintained.  相似文献   

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