Rb/Sr dating of the Upper Proterozoic basement of Zambesia,Mozambique     

Mario Costa  Giorgio Ferrara  Rosalino Sacchi  Sonia Tonarini 《International Journal of Earth Sciences》1992,81(2):487-500

The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.

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Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.

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Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.

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Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry     

Elisa Lopez Capel  Jos Maria de la Rosa Arranz  Francisco J. Gonzlez-Vila  Jos Antonio Gonzlez-Perez  David A.C. Manning 《Organic Geochemistry》2006,37(12):1983

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.  相似文献   

Gravity signature of crustal subduction inferred from numerical modelling     

Anna Maria Marotta  Elisa Spelta  Catia Rizzetto 《Geophysical Journal International》2006,166(2):923-938

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Hydrochemistry and isotope geochemistry as tools for groundwater hydrodynamic investigation in multilayer aquifers: a case study from Lomellina, Po plain, South-Western Lombardy, Italy     

Giorgio Pilla  Elisa Sacchi  Gianmaria Zuppi  Giovanni Braga  Gianfranco Ciancetti 《Hydrogeology Journal》2006,14(5):795-808

A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers.  相似文献   

Deconvolution of teleseismic recordings for mantle structure     

M. G. Bostock  M. D. Sacchi 《Geophysical Journal International》1997,129(1):143-152

Delineation of detailed mantle structure frequently requires the separation of source signature and structural response from seismograms recorded at teleseismic distances. This deconvolution problem can be posed in a log-spectral domain where the operation of time-domain convolution is reduced to an additive form. The introduction of multiple events recorded at many stations leads to a system of consistency equations that must be honoured by both the source time functions and the impulse responses associated with propagation paths between sources and receivers. The system is inherently singular, and stabilization is accomplished through the supply of an initial estimate of the source time function. Although alternative choices exist, an effective estimate is derived from the eigenimage associated with the largest eigenvalue in a singular-value decomposition of the suite of aligned seismograms corresponding to a given event. The relation of the deconvolution scheme to simultaneous least-squares deconvolution is examined. Application of the methodology to broadband teleseismic P waveforms recorded on the Canadian National Seismograph Network demonstrates the retrieval of effective Green's functions including secondary phases associated with upper-mantle structure.  相似文献   

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches          下载免费PDF全文

Sebastiano Piccolroaz  Elisa Calamita  Bruno Majone  Aurélien Gallice  Annunziato Siviglia  Marco Toffolon 《水文研究》2016,30(21):3901-3917

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Natural highways for end-of-life solutions in the LEO region     

Elisa Maria Alessi  Giulia Schettino  Alessandro Rossi  Giovanni B. Valsecchi 《Celestial Mechanics and Dynamical Astronomy》2018,130(5):34

We present the main findings of a dynamical mapping performed in the Low Earth Orbit region. The results were obtained by propagating an extended grid of initial conditions, considering two different epochs and area-to-mass ratios, by means of a singly averaged numerical propagator. It turns out that dynamical resonances associated with high-degree geopotential harmonics, lunisolar perturbations and Solar radiation pressure can open natural deorbiting highways. For area-to-mass ratios typical of the orbiting intact objects, these corridors can be exploited only in combination with the action exerted by the atmospheric drag. For satellites equipped with an area augmentation device, we show the boundary of application of the drag, and where the Solar radiation pressure can be exploited.  相似文献   

Effects of two offshore gas platforms on soft-bottom benthic communities (northwestern Adriatic Sea, Italy)     

Sarine Manoukian  Alessandra Spagnolo  Giuseppe Scarcella  Elisa Punzo  Roberta Angelini  Gianna Fabi   《Marine environmental research》2010,70(5):402-410

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GPS ground deformation patterns at Mount St. Helens (Washington,USA) from 2004 to 2010     

Mimmo Palano  Elisa Guarrera  Mario Mattia 《地学学报》2012,24(2):148-155

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Simultaneous iterative time-domain sparse deconvolution to teleseismic receiver functions     

Christian Escalante  Yu J. Gu  Mauricio Sacchi 《Geophysical Journal International》2007,171(1):316-325

In this paper, we present a new approach to estimate high-resolution teleseismic receiver functions using a simultaneous iterative time-domain sparse deconvolution. This technique improves the deconvolution by using reweighting strategies based on a Cauchy criterion. The resulting sparse receiver functions enhance the primary converted phases and its multiples. To test its functionality and reliability, we applied this approach to synthetic experiments and to seismic data recorded at station ABU, in Japan. Our results show Ps conversions at approximately 4.0 s after the primary P onset, which are consistent with other seismological studies in this area. We demonstrate that the sparse deconvolution is a simple, efficient technique in computing receiver functions with significantly greater resolution than conventional approaches.  相似文献