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1.
湘东北中生代基性岩脉岩石地球化学及构造意义   总被引:8,自引:1,他引:8  
湘东北中生代发育以辉绿岩类和煌斑岩类为代表的基性岩脉,属陆内拉斑玄武岩系,部分煌斑岩属于碱性系列。岩石富集LREE,δEu负异常不明显,其形成主要受软流圈地幔部分熔融作用制约。煌斑岩类微量元素总体上具有洋岛玄武岩(OIB)岩浆源区特征,富集Nd、P、Cs而K、Rb、Sr、U、Th等富集程度不明显,Ta、Nb略有富集。辉绿岩类表现出Ta、Nb、Ti亏损,但LILE并不富集,反映地壳混染程度的增强。基性岩脉形成于陆内拉张带的构造环境,岩浆活动未受到中生代大洋板块俯冲的影响。基性岩脉在时、空及物质组成上与湘东南玄武质岩石基本一致,属于整个湘东南岩石圈拉张-减薄带的一部分。  相似文献   

2.
Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ18O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.  相似文献   

3.
苏海图组火山岩发育自然铜矿化,具有从拉斑玄武岩系列向钙碱性玄武岩系列过渡的特点。依据地球化学特征,表明其TiO2含量较低(1%),玄武岩高的Al2O3含量、低的稀土含量,并且稀土元素曲线具有平缓型到轻稀土低度富集的特点。微量元素原始地幔标准化图解上,它们均富集大离子亲石因素(LILE),亏损高场强元素(HFSE),具有强的Nb和Ta的负异常,Ti的低负异常,以及P和Sm的低正异常。Zr/Nb值和Sm/Nd值接近MORB的范围,Th/Nb值大于0.11,Nb/Zr值小于0.04。以上这些特征均显示出典型岛弧岩浆的特点。所以,苏海图组火山岩为火山弧火山岩,其构造背景为大陆岛弧,源区可能为被流体或沉积物交待改造的亏损地幔。  相似文献   

4.
四川木洛稀土矿床碳酸岩地球化学   总被引:1,自引:1,他引:0       下载免费PDF全文
木洛稀土矿床成因上与碳酸岩-碱性杂岩密切相关。碳酸岩主要由方解石组成,CaO/(CaO+MgO+FeO+Fe2O3+MnO)比值在95.7%~99.6%,为方解石碳酸岩。碳酸岩相对富集大离子亲石元素Ba、Sr、LREE,亏损高场强元素Nb、Ta、Ti、Zr、P,高Zr/Hf和La/Nb值,低Sm/Nd和Rb/Sr值,暗示岩石来自富集地幔EMI。地质、地球化学研究表明,木洛碳酸岩是在峨眉山地幔柱地幔遗存物经喜马拉雅造山运动再次活化的产物,但碳酸岩熔浆在上侵过程中受到地壳物质混染。碳酸岩-碱性岩熔浆带来大量稀土元素,并在喜马拉雅造山期造山运动派生的局部引张部位成矿。  相似文献   

5.
In order to decipher element mobility in ultrahigh-pressure (UHP) eclogite-facies metamorphic rocks during subduction and exhumation of continental crust, major-trace elements and Sr-Nd isotopes were systematically investigated for two continuous core segments of about 3 m length from the Chinese Continental Scientific Drilling (CCSD) project in the Sulu orogen. The segments are composed of lithological transitions between UHP eclogite and granitic gneiss. The eclogite exhibits a large variation in major and some trace elements such as LILE (e.g., Rb, Ba and K) and LREE, but a relatively limited range in HFSE and HREE. This suggests high mobility of LILE and LREE but immobility of HFSE and HREE during continental collision-zone metamorphism. Some eclogites have andesitic compositions with high SiO2, alkalis, LREE, and LILE but low CaO, MgO and FeO contents. These features likely result from chemical exchange with gneisses, possibly due to the metasomatism of felsic melt produced by partial melting of the associated gneisses during the exhumation. On the other hand, some eclogites appear to have geochemical affinity to refractory rocks formed by melt extraction as evidenced by strong LREE and LILE depletion and the absence of hydrous minerals. These results provide evidence of melt-induced element mobility in the UHP metamorphic rocks. In particular, large variations in the abundance of such elements as SiO2, LREE and LILE occur at the contact between eclogite and granitic gneiss, indicating their mobility between different slab components. Petrographic observations also show the presence of felsic veins on small scales in the UHP metamorphic rocks, demonstrating the occurrence of hydrous melt in local open-systems during the continental collision. As a whole, nevertheless, the protolith nature dictates the geochemical differences in both eclogite and granitic gneiss between the two core segments because mass transport during the subduction-zone metamorphism is principally dictated by the lithological differences at contact. The eclogite and granitic gneiss from the first core segment have high εNd(t) values, whereas those from the second core segment show relatively low εNd(t) values in concordance with majority of UHP metaigneous rocks outcropped along the Dabie-Sulu orogenic belt. Thus contrasting origins of bimodal igneous rocks were involved in the continental collision, demonstrating that the subducted continental crust is the magmatic product of active rifting margin during supercontinental breakup in the middle Neoproterozoic.  相似文献   

6.
在1.5GPa,950℃,恒温101h条件下对华北北缘太古宙地体中的斜长角闪岩块状样品进行了脱水部分熔融实验,实验产物组合为Hb+Cpx+Gt+Gl,获得的熔体为花岗闪长质成分。利用LA-ICP-MS测试了矿物和熔体的微量元素,获得该体系内各矿物/熔体的微量元素分配系数。角闪石、单斜辉石和石榴石的分配系数与前人在类似条件下的实验结果基本一致。这说明无论实验的初始物质是粉末状还是块状,对元素的分配没有太大的影响。各矿物的REE分配系数对离子半径的拟合曲线很好地符合晶格应变弹性模型。整体特征上,角闪石、单斜辉石和石榴石的LILE,LREE分配系数较低,而HREE的分配系数较高,石榴石具有强烈富集HREE的特征。由此,造成实验熔体表现出LILE、LREE富集而HREE亏损的特征。残留相中无金红石,使得熔体中没有明显的Nb、Ta负异常。熔体的主-微量元素特征符合华北北缘中生代埃达克质岩石的基本特征,进一步支持了该类岩石"可能起源于古老下地壳的部分熔融"的成因模式。  相似文献   

7.
The main hole (MH) of the Chinese Continental Scientific Drilling Project (CCSD) in southern Sulu has penetrated into an ultrahigh-pressure (UHP) metamorphic rock slice which consists of orthogneiss, paragneiss, eclogite, ultramafic rock and minor schist. Recovered eclogites have a UHP metamorphic mineral assemblage of garnet + omphacite + rutile ± phengite ± kyanite ± coesite ± epidote. Ultramafic rocks contain garnet + olivine + clinopyroxene + orthopyroxene ± Ti-clinohumite ± phlogopite. Gneisses and schists contain an amphibolite-facies paragenesis, but their zircons have coesite, garnet, omphacite (or jadeite) and phengite inclusions, indicating that eclogites and gneisses have been subjected to in situ UHP metamorphism. Using available geothermobarometers, P–T estimates of 3.1–4.4 GPa and 678–816°C for eclogites were obtained. If surface outcrops and neighboring shallow drill holes are considered together, we suggest that a huge supracrustal rock slab (> 50 km long × 100 km wide × 5 km deep) was subducted to a depth > 100 km and then exhumed to the surface. The depth interval (0–2,050 m) of the CCSD-MH can be divided into six lithological units. Unit 1 consists of alternating layers of quartz-rich and rutile-rich eclogites, with thin interlayers of gneiss and schist. Eclogites of unit 1 are characterized by Nb, Ta, Sr and Ti depletions, low Mg number and general LREE enrichment. Unit 2 comprises rutile- and ilmenite-rich eclogite and minor “normal” eclogite and is characterized by high TiO2, total Fe, V, Co and Sr, and very low SiO2, alkali, Zr, Ba, Nb, Ta and total REE contents, and LREE-depleted REE patterns with slightly positive Eu anomalies. Unit 3 contains ultramafic rock and minor MgO-rich eclogite. Protoliths of UHP rocks from units 1, 2 and 3 represent a layered mafic to ultramafic intrusion at crustal depth. Units 4 and 6 consist of interlayered eclogite and paragneiss; the eclogites are characterized by Th, U, Nb, Ta and Ti depletion and K enrichment and LREE-enriched REE patterns. Paragneisses show Nb, Ta, Sr and Ti depletions and LREE-enriched REE patterns occasionally with slightly negative Eu anomalies, indicating that their protoliths represent metamorphic supracrustal series. Unit 5 consists mainly of orthogneisses, showing distinct Nb, Ta, Sr and Ti depletions, and LREE-enriched REE patterns with pronounced negative Eu anomalies, suggesting granitic protoliths. In conclusion it is proposed that the southern Sulu UHP belt consists of a series of meta-supracrustal rocks, a layered mafic–ultramafic complex and granites.  相似文献   

8.
The Late Cretaceous Alihoca ophiolite in the Inner Tauride suture zone (ITSZ) of South-Central Turkey represents part of a single ophiolitic thrust sheet that originated from the Inner Tauride ocean. The ophiolite contains upper mantle peridotites, cumulate wehrlites, layered-to-isotropic gabbros, and microgabbroic-to-doleritic dikes. An ophiolitic mélange beneath the Alihoca ophiolite includes blocks of limestone, peridotite, dolerite, basalt, and deep-sea sedimentary rocks (radiolarite, chert) in a matrix comprising sheared serpentinite and mudstone. Isotropic gabbro and dolerite dike rocks show enrichment in Sr, K, Rb, Ba, and Th (LILE) and depletion of Ta, Nb, Zr, Ti, and Y (HFSE), indicating an island arc tholeiite (IAT) affinity. Relatively younger dolerite rocks display low TiO2 (<0.5 wt.%) contents, concave REE profiles with low HREE concentrations, and high LREE values, typical of boninitic affinities. The Alihoca ophiolite, hence, displays an IAT to boninitic geochemical progression in its magmatic evolution, reminiscent of many other Tethyan ophiolites in the region. It represents the remnant of a forearc oceanic crust, which developed during the early stages of subduction within the Inner Tauride ocean. Volcanic, volcano-sedimentary, and sedimentary rocks of the Uluk??la–Çamard? basin north of the ITSZ disconformably overlie the mafic-ultramafic rocks of the Alihoca ophiolite. Pillowed and massive lavas of the latest Cretaceous–Palaeocene Uluk??la Formation have alkaline basalt-to-basaltic andesite compositions, displaying relatively enriched LILE and LREE patterns with negative Nb and Ta anomalies. These geochemical features suggest that magmas of the Uluk??la–Çamard? volcanic rocks formed from partial melting of a metasomatized lithospheric mantle. This melting event was triggered by the influx of asthenospheric heat through a slab breakoff-induced window in the downgoing Tethyan oceanic lithosphere.  相似文献   

9.
西秦岭天水地区的早古生代李子园群为一套中浅变质的沉积-火山岩系。沉积岩系主要由变质碎屑岩和碳酸盐岩组成,火山岩系主要由变玄武岩、变玄武安山岩和变安山岩组成,包括岛弧型火山岩和玻安岩。岛弧型火山岩SiO2含量介于48.79%~54.64%之间,TiO2含量较低(0.29%~0.88%);稀土元素分布型式呈LREE略富集型,富集大离子亲石元素(LILE)Cs、Sr、Th、U,相对亏损Rb、K和高场强元素(HFSE)Nb、P、Sm、Ti和Y,具Nb负异常,类似于低钾岛弧拉斑玄武岩和钙碱性玄武岩特征。玻安岩具有中等的SiO2含量(53.59%~59.28%),低的TiO2含量(0.24%~0.48%);相对中等的MgO含量(4.90%~4.96%)、较低的CaO/Al2O3比值(0.39~0.54)和较高的Mg#值(0.54~0.58)、Al2O3/TiO2比值(33.88~64.29);同时具有较低的Ti/Zr比值(15~83)、V/Zr比值(2.18~8.35)和较高的Zr/Y比值(3.82~12.08),相对富集大离子亲石元素(LILE),特别是Rb、Ba、Th,而亏损高场强元素(HFSE),如Nb、Ta、P、Ti、Y、Yb,显示为亏损MREE的U型稀土元素分布型式。岛弧型火山岩和玻安岩的存在表明,李子园群及其中的中基性火山岩系形成于俯冲带之上的岛弧或弧前环境。  相似文献   

10.
北京西山东岭台组粗面质火山岩地球化学:下地壳熔融成因   总被引:13,自引:2,他引:11  
北京西山东岭台组粗面岩表现出LREE富集和HREE平坦的稀土配分型式 ,富集LILE (Ba、K和Sr)、和亏损Nb Ta、Th U和Ti,Sr Nd同位素组成富集 (87Sr/ 86Sr(t) =0 .70 6 38~ 0 .70 6 72 ,Nd(t) = 1 6 .3~ - 1 5 .7)。结合所表现出的明显Nb/Ta分馏和高的Zr/Sm比值 ,认为它们来源于大陆下地壳含石榴子石的角闪岩部分熔融作用而成 ,主要的残留相为石榴子石 +斜长石±角闪石±辉石。根据地壳岩石熔融实验研究结果 ,西山地区东岭台组粗面岩的熔融要求有外来的热源参与 ,与区域上同时代发生的玄武岩浆底侵作用具时空上的密切联系 ;这些岩石所显示的高Sr和Ba特征也暗示至少有部分底侵的玄武质岩石参与了部分熔融作用  相似文献   

11.
青藏高原南部中国境内是否存在寒武纪地层一直是地质界关注的焦点。研究表明,冈底斯北缘西藏尼玛县控错南帮勒村一带,原划的前震旦纪念青唐古拉岩群为一套浅变质的拉斑系列双峰式火山岩。通过高精度LA-ICP-MS(激光剥蚀等离子体质谱)锆石微区原位U-Pb同位素测年,获得其中变流纹岩206Pb/238U年龄加权平均值为(536.4±3.6)Ma,确定该套火山岩形成于早寒武世。地球化学分析表明,变玄武岩富集LREE、LILE、部分HFSE,Nb、Ta、Zr、Hf等亏损,Zr/Nb比值(2.53~3.61)低;变流纹岩明显富集LREE、LILE、Th、HFSE,具有Eu负异常和Sr、Nb、Ta、Ti负异常。同时,变玄武岩的εNd(t)为负值(-2.80~-4.56),源区为富集地幔端元EMⅡ,反映其源区为岩石圈和软流圈相互作用的产物,并遭受了地壳物质的混染。综合分析认为该套火山岩形成于陆缘裂谷环境,为冈底斯北缘存在寒武纪裂解作用提供了佐证。  相似文献   

12.
A combined petrological, geochronological and geochemical study was carried out on felsic veins and their host rocks from the North Qaidam ultrahigh‐pressure (UHP) metamorphic terrane in northern Tibet. The results provide insights into partial melting of deeply subducted continental crust during exhumation. Partial melting is petrograpically recognized in metagranite, metapelite and metabasite. Migmatized gneisses, including metagranite and metapelite, contain microstructures such as granitic aggregates with varying outlines, small dihedral angles at mineral junctions and feldspar with magmatic habits, indicating the former presence of felsic melts. Partial melts were also present in metabasite that occurs as retrograde eclogite. Felsic veins in both the eclogites and gneisses exhibit typical melt crystalline textures such as large euhedral feldspar grains with straight crystal faces, indicating vein crystallization from anatectic melts. The Sr–Nd isotope compositions of felsic veins inside gneisses suggest melt derivation from anatexis of host gneisses themselves, but those inside metabasites suggest melt derivation from hybrid sources. Felsic veins inside gneisses exhibit lithochemical compositions similar to experimental melts on the An–Ab–Or diagram. In trace element distribution diagrams, they exhibit parallel patterns to their host rocks, but with lower element contents and slightly positive Eu and Sr anomalies. The geochemistry of these felsic veins is controlled by minerals that would decompose and survive, respectively, during anatexis. Felsic veins inside metabasites are rich either in quartz or in plagioclase with low normative orthoclase. In either case, they have low trace element contents, with significantly positive Eu and Sr anomalies in plagioclase‐rich veins. Combined with cumulate structures in some veins, these felsic veins are interpreted to crystallize from anatectic melts of different origins with the effect of crystal fractionation. Nevertheless, felsic veins in different lithologies exhibit roughly consistent patterns of trace element distribution, with variable enrichment of LILE and LREE but depletion of HFSE and HREE. There are also higher contents of trace elements in veins hosted by gneisses than veins hosted by metabasites. Anatectic zircon domains from felsic veins and migmatized gneisses exhibit consistent U–Pb ages of c. 420 Ma, significantly younger than the peak UHP eclogite facies metamorphic event at c. 450–435 Ma. Combining the petrological observations with local P–T paths and experimentally constrained melting curves, it is inferred that anatexis of UHP gneisses was caused by muscovite breakdown while anatexis of UHP metabasites was caused by fluid influx. These UHP metagranite, metapelite and metabasite underwent simultaneous anatexis during the exhumation, giving rise to anatectic melts with different compositions in various elements but similar patterns in trace element distribution.  相似文献   

13.
晚白垩世(95Ma),白垩纪末(69Ma)和古新(6765Ma)玄武质岩石,呈脉状零星露头产于燕山期崂山岗岩体中,岩性分别为碱性玄武岩,碧岩和斑玄武岩,碱性玄武岩和碧玄岩以高度富集LILE和LREE为特征,(La/Yb)N=25.5-46.6,两者表现为程度不等的Nb,Ta,Zt,Ti等高场强元素亏损,与我国华北新生代碱性玄武岩相比,Ba,Rb,Th更为富集,Sr,Nd同位素比值(碧玄岩)为^87Sr/^86Sr=0.705517,^143Nd/^144Nd=0.512777.它们很可能均起源一刊中生代扬子板块玄武岩类似,微量元素总量及LILE和LREE含量均较低,(La/Yb)N=4.7-6.4,其典型的微量元素比值(如Zr/Nb,Rb/Nb,Nb,Ta等)与EM1型OIB类似,^87Sr/686Sr=0.706054-0.706146;^143Nd/^144Nd=0.572387-0.512392,它可能起于受上涌软流圈交代的大陆岩石圈(软流圈顶部的“metasome”)的部分熔融,是软流圈流体与大陆岩石圈相互作用的产物。上述不同类型玄武岩的顺序侵位,可能反映在晚白垩世一早第三纪期间,本区曾经历地壳拉张强度逐渐增大一地壳持续减薄-软流圈不断上涌的动力学过程。  相似文献   

14.
The granitic gneisses from the ultrahigh-pressure (UHP) metamorphic terrain of the southeastern Dabie Mountains encompass two types: monzonitic granitic gneiss and alkali-feldspar granitic gneiss, which are characterized by rich alkalis, poor CaO, high FeO/MgO, particularly high Ba, Rb, Th, Ta, REE (except Eu), Ga, Nb and Zn, and low Sr, Eu, Cr, Co and Ni. The gneisses, particularly the alkali-feldspar granitic gneiss, have typical chemical characteristics of A-type granites. They resulted from partial melting of crustal materials existing in the rift zone along the northern margin of the South China block during the Neoproterozoic. These gneisses might not have undergone UHP metamorphism during the late Triassic, but were involved into UHP rocks by the tectonic mixing process and kept the exhumation message of the UHP rocks from the middle and upper crust.  相似文献   

15.
The Jiangzhuang ultrahigh‐pressure (UHP) metamorphic peridotite from south Sulu, eastern China occurs as a layer within gneiss with eclogite blocks, and consists of coarse‐grained garnet porphyroblasts and a fine‐grained matrix assemblage of garnet + forsterite + enstatite + diopside ± phlogopite ± Ti‐clinohumite ± magnesite. Both types of garnet are characterized by high MgO content and depletion of light rare earth element (LREE) and enrichment of heavy rare earth element, but the matrix garnet has lower MgO, TiO2 and higher Cr2O3 and REE contents. Diopside displays LREE enrichment, and has low but variable large‐ion lithophile element (LILE) contents. Phlogopite is a major carrier of LILE. Ti‐clinohumite contains high Nb, Ta, Cr, Ni, V and Co contents. The P–T conditions of 4.5–6.0 GPa and 850–950 °C were estimated for matrix mineral assemblages. Most peridotites are depleted in Al2O3, CaO and TiO2, and enriched in SiO2, K2O, REE and LILE. In contrast to phlogopite‐free peridotites, the phlogopite‐bearing peridotites have higher K2O, Zr, REE and LILE contents. Zircon occurs only in the phlogopite‐bearing peridotites, shows no zoning, with low REE contents and Th/U ratios, and yields tight UPb ages of 225–220 Ma, indicating the peridotites experienced consistent Triassic UHP metamorphism with subducted supercrustal rocks. These data demonstrate that the Jiangzhuang peridotites were derived from the depleted mantle wedge of the North China Craton, and experienced various degrees of metasomatism. The phlogopite‐free peridotites may have been subjected to an early cryptic metasomatism at UHP conditions of the mantle wedge, whereas the phlogopite‐bearing peridotites were subjected to a subsequent strong metasomatism, characterized by distinctly enrichment in LILE, LREE, Zr and K as well as the growth of zircon and volatile‐bearing minerals at UHP subduction conditions. The related metasomatism may have resulted from the filtration of fluids sourced mainly from deeply subducted supracrustal rocks.  相似文献   

16.
念青唐古拉早始新世中基性侵入岩由角闪辉长岩及二长闪长岩组成,其中角闪辉长岩锆石LA-MC-ICPMS U-Pb年龄为(49.92±0.24)Ma。中基性侵入岩属于高钾钙碱系列至钾玄岩系列;稀土总量较高且轻稀土富集;富集大离子亲石元素(Rb,Th,K),亏损高场强元素(Nb,Ta,Ti),具有弧岩浆岩的微量元素特征。中基性侵入岩具有较高的初始锶((87Sr/86Sr)i为0.708 77~0.713 71)、低的εNd值(-6.9~-6.1)、古老的亏损地幔模式年龄(TDM为1 329~1 995Ma),以及εNd、Nb/La与MgO无明显相关性,表明其源区为受古老地壳交代的富集地幔。稀土元素模拟表明中基性侵入岩的成岩过程受地幔中轻程度部分熔融作用所控制。动力学背景分析表明其与新特提斯洋板片的断离及软流圈物质的上涌密切相关。  相似文献   

17.
Feng Guo  Weiming Fan  Ming Zhang 《Lithos》2004,78(3):291-305
K-Ar dating, major- and trace-element and Sr-Nd isotopic analyses were carried out for early Cretaceous (122-127 Ma) lamprophyres from the Sulu orogen in eastern China. The results show strong fractionation in rare-earth elements with (LREE) >100 times chondrite, but HREE <10 times chondrite, indicating the presence of residual garnet in the melting source. These rocks are characterized by significant LILE and LREE enrichment but Nb and Ta depletion with moderate Zr/Hf (39.8-50.8 with regard to 36 for primitive mantle) and Nb/Ta (17.8-23.0, compared with 17.5 for primitive mantle) fractionations, probably as a consequence of carbonate- and rutile-rich melt metasomatism induced by dehydration and/or melting of subducted continental slab at mantle depths. Age-correlated Sr-Nd isotope ratios show moderate ranges of 87Sr/86Sr(i) from 0.70787 to 0.70934 and −17.2 to −11.6 of εNd(t). The lamprophyres from the Sulu orogen were derived from decompression melting of such a metasomatized lithospheric mantle that was mainly composed of phlogophite garnet peridotites and experienced crystal fractionation of a mineral assemblage of olivine+clinopyroxene±plagioclase en route to the surface. Such geochemical and isotopic signatures are also prevalent in the contemporaneous basaltic lavas in the Dabie-Sulu belt, suggesting predominant enrichment processes by carbonate- and rutile-rich metasomatic assemblage beneath the continental collisional belt.  相似文献   

18.
相山两种不同成因角闪石的地球化学特征对比   总被引:1,自引:0,他引:1  
通过详细研究相山两种不同成因角闪石的元素及同位素地球化学发现:江西相山铀矿田北部同时存在两种不同成因的角闪石:正变质成因的角闪石,寄主岩石为斜长角闪(片)岩,微量元素以富集大离子亲石元素(LILE)(K,Rb,Th,Ta,U)、稍为富集Ti,Se和相对贫高场强元素(HFSE)(Zr,Hf,Y,Yb,Cr,HREE)为特征,稀土总量低,稀土分布型式为近水平型,δ^18O为7.95~8.58,显示变质火成岩的氧同位素特征;副变质成因的角闪石,寄主岩石为含石榴角闪石英片岩.微量元素以高度富集大离子亲石元素(LILE)(K,Rb,Th,U)、稍为富集Ta,Nb,Ce,Zr,Hf,Sm和相对贫高场强元素(HFSE)(Ti,Y,Yb,Cr)、强烈亏损Sc为特征,稀土总量高.轻重稀土相互分离程度高,轻稀土富集,O同位素组成(δ^18O)较高,为9.95~10.02,显示碎屑沉积变质岩的氧同位素特征。  相似文献   

19.
赵军  张作衡  张贺  刘敏  洪为  蒋宗胜 《地质学报》2013,87(4):525-541
新疆阿吾拉勒山西段是伊犁石炭-二叠纪裂谷的重要组成部分,本文对该区下二叠统典型的双峰式玄武岩-流纹岩组合进行了系统的岩相学和岩石地球化学研究。岩石整体高Na2O、高Al2O3、低TiO2、富碱。玄武岩富集大离子亲石元素Ba、K、LREE和P,亏损高场强元素Th、U、Ta、Nb。粗面斑岩和流纹斑岩富集大离子亲石元素Rb、K、LREE、高场强元素Th、Zr、Hf,亏损Ta、Nb、Sr、Ti和P。玄武安山玢岩的蛛网图与粗面斑岩和流纹斑岩较为一致,但少量元素的特征与玄武岩相似。玄武岩浆来源于弱亏损地幔,并受到了下地壳物质的混染,而玄武安山玢岩、粗面斑岩和流纹斑岩则可能来源于地壳物质的部分熔融。双峰式火山岩的形成可能与上地幔玄武岩浆的底侵作用有关。裂谷演化导致的陆相火山活动持续到早二叠世晚期达到顶峰,中二叠世以后,构造环境由拉伸转为挤压,裂谷演化趋于终止。该区石炭纪末-早二叠世的裂谷活动与整个天山地区晚古生代的构造演化背景具有一致性。  相似文献   

20.
对西天山伊宁县北琼阿希河谷出露的火山岩进行了地球化学特征研究,结果表明,该地区火山岩属于钙碱性火山岩系列,LREE强烈富集[(La/Yb)N介于2.76~7.03之间],具有弱的Eu负异常,样品的强不相容元素(Cs、Rb、Ba、Th、U)LILE均明显富集,总体在原始地幔的10倍以上,显示了岛弧火山岩的Nb-Ta负异常特征。但是,其(Th/Nb)N、(La/Nb)N的比值远远大于1,Ba/Nb、La/Nb的变化范围较大,Zr/Nb、Zr/Hf接近N-MORB的比值,Ta/Nb却接近上地壳的比值,暗示该地区的火山岩岩浆在上升过程中受到一定程度的地壳混染,所有样品均显示为中钾-高钾系列,这种钾质类型的优势地位也反映了陆壳基质在岩浆活动中占有重要的地位。样品的Zr均大于300、Zr/Y均大于4,显示了板内玄武岩的成分特征,在Zr-Zr/Y判别图解中,大多数样品投到板内玄武岩的构造环境区域内。结合区域上的地质特征,认为该地区在泥盆世一直处于抬升阶段,在石炭纪时碰撞结束并进入碰撞后伸展阶段,局部地区产生一定的裂谷化特征。琼阿希河谷的火山岩的Nb-Ta负异常特征应为地壳混染引起,火山岩的形成环境为碰撞后伸展的构造环境。  相似文献   

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