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1.
Water quality of a lowland stream in a New Zealand dairy farming catchment   总被引：3，自引：2，他引：1  
A small stream in a predominantly dairying catchment in the Waikato region of New Zealand was monitored for 2 years at three sites. Total nitrogen (TN) concentrations were up to 7.09 g m‐3 in winter, with the bulk comprising nitrate nitrogen (NO‐ 3‐N). During summer NO‐ 3‐N was near zero and TN mostly comprised organic nitrogen. Maximum concentrations of total phosphorus (TP) and dissolved reactive phosphorus (DRP) were 1.64 and 0.555 g m‐3, respectively, and peaks coincided with spring and autumn applications of phosphorus fertiliser. Ammoniacal nitrogen concentrations exceeded 1 g m‐3 on several occasions and mean concentrations at the three sites were 0.165–0.272 g m‐3. Faecal coliform and enterococci bacteria concentrations were 64–26000 and 7–23000 cfu per 100 ml, respectively. Specific yields of TN and NO‐ 3‐N (35.3 and 30.7 kg ha yr‐1, respectively) were much greater than any previously reported for New Zealand pasture catchments, whereas TP and DRP yields (1.16 and 0.54 kg ha yr‐1, respectively) were more in accord with other studies. Greater use of land treatment of liquid wastes will reduce stream inputs of faecal organisms, NH4‐N and P.  相似文献   

2.
Abstract

The water chemistry, flora, and fauna of Lake Rotokawa (38° 37.8’ S, 176° 11.2'E) was studied in 1975–76. The mean pH is 2.1 and thermal inflows may elevate the mean summer temperature of the surface waters 4.2°c above that of nearby cold water Lake Rotongaio (18.9°c). The temperature range of surface water was from 10.1 °c in winter to 23.1°c in summer. The major anions were SO4 2? 679 g.m?3, and Cl‐ 314 g.m?3. Mean concentrations of major cations were Na+ 224 g.m?3, K+ 28.9 g.m?3, Ca2+ 13.3 g.m?3, and Mg2+ 2.6 g.m?3.

Two species of flagellate algae were recorded, of which Euglena anabaena was predominant. Only two benthic macroinvertebrates were found, larvae of Chironomus zealandicus, mean density 253 per square metre, and Helobdella sp., 1.3 per square metre.

The Parariki Stream was influenced by thermal springs in its upper and lower reaches, being cooler (24–25°c) about halfway along its length than near its source (27.8–39.0°c) or confluence (26.5°‐28.0°c) with the Waikato River. In the cooler stretch of the stream where unidentified benthic algae were not limited by high temperature, chlorophyll and total pigment increased from 3.9 to 377.9 mg.m?3 and from 17.5 to 534.4 mg.m?3 respectively, and nutrient levels fell (NO3‐N, 22–10.5 mg.m?3; NH4‐N, 6440–230 mg.m?3; and PO4‐P, 51–19 mg.m?3).  相似文献   

3.
Maintaining stable water quality is one of the key processes for recirculating coral aquaculture. Traditional aquarium systems which mainly utilized a nitrification of nitrifying bacteria attached to the surface of massive artificial filter material are difficult to maintain the oligotrophic conditions necessary for coral aquaculture. This study investigated the removal effects of dissolved inorganic nitrogen(ammonia and nitrate) by live rock(LR), a key component in the "Berlin system" coral aquarium. The expression levels of bacterial functional genes, AOA3,amo A and nos Z, were measured on the exterior and interior of LR. The nitrifying and denitrifying bacterial abundance on LR was quantified and the nitrogen nutrient regulatory effects of LR were evaluated. The results demonstrated that LR mainly removed ammonium(NH_4~+) from the water with a mean efficiency of 0.141 mg/(kg·h), while the removal of nitrate(NO_3~–) was not significant. Bacterial diversity analysis showed that ammonia-oxidizing bacteria(AOB) were the most common bacteria on LR, which accounted for 0.5%–1.4% of the total bacterial population, followed by denitrifying bacteria, which accounted for 0.2% of the total population, and the ammonia-oxidizing archaea(AOA) were the least common type(0.01%). The low abundance of denitrifying bacteria may be responsible for the poor nitrate(NO_3~–) removal of LR. Thus, other biological filtration methods are needed in coral aquaria to control nitrates generated from nitrification or biological metabolism.  相似文献   

4.
This paper gives the data and methods used to calculate the nitrogen and phosphorus loads of the Ngongotaha Stream, near Rotorua, New Zealand. The variations in concentration with time and with flow rate are given in some detail, as examples of what may happen in other streams of the central volcanic plateau, and a novel way to define a flow‐concentration curve is described. Nitrate, ammonia, dissolved reactive phosphorus (DRP), total phosphorus (TP), and total Kjeldahl nitrogen (TKN) concentrations were measured, and mean concentrations in 1976 base flow were found to be 527, 25, 32, 48, and 162 mg m‐3 respectively. Nitrate concentrations showed seasonal variations, and although changes occurred during floods, they were not correlated with flow rate. DRP concentrations showed little variation, except that they dropped at the peak of the largest floods. TP was strongly correlated with flow rate during floods, and TP loads could best be calculated by allowing for a curvilinear relationship between concentration and flow rate. The logarithms of the TP load carried by a flood and the peak flow rate of the flood were highly correlated (R = 0.984). The annual loads of nitrate, ammonia, DRP, TP, and TKN were estimated to be 34, 1.3, 2.9, 6.0, and 26 tonnes in 1976.  相似文献   

5.
Abstract

The Whangamaire Stream (North Island, New Zealand) has high concentrations of nitrate nitrogen (NO? 3‐N), biochemical oxygen demand (BOD5), and Kjeldahl nitrogen (TKN) as a result of catchment land use practices. The lower reaches of the stream drain intensively farmed land and have dissolved oxygen (DO) levels of 10–50% saturation. The dominant riparian vegetation, Apium nodiflorum, provides a large organic loading by intercepting nutrients in run‐off and then decaying in the stream channel. Water quality and reaeration aspects of the stream were studied in order to explain the observed low DO levels. Measurements of the reaeration coefficient at 20°C, K2 20, using methyl chloride (CH3Cl) as a gas tracer, yielded values of 1.1–3.0 d?1 for the upper part of the study reach and 15.5–16.2 d?1 for the lower reach (overall average 12.5 ± 2.5 d?1). These were in agreement with values inferred from single‐station diurnal curve analysis, which also showed that respiration was dominant in the lower reach where photo‐synthetic activity was inhibited by shade. The relatively large reaeration coefficients ensure that parts of the stream do not become anoxic at night time. Better riparian management and reduced nutrient inputs are likely to improve stream water quality.  相似文献   

6.
A baseline groundwater quality survey of 120 household wells in an unsewered area at Yaldhurst, near Christchurch, was carried out between September and December, 1976. Ammonia‐N levels were below the detection limit (0.02 g m‐3) in all samples. Nitrate‐N, conductivity, and chloride levels tended to vary according to well depth and location, being lower in the deeper wells and in wells located in an area of shallow, stony soils. Approximately 33% of the wells contained coliform bacteria, faecal coliform bacteria or faecal streptococci. A subset of 25 wells was sampled fortnightly from January to August 1977. From January to June, mean nitrate‐N and conductivity levels remained stable at approximately 1.5 g m‐3 and 11.2 mS m‐1 respectively. An increase in these levels to 3.3 g m‐3 and 15.8 mS m‐1 in July‐August corresponded with a rise in the water table. Leaching losses from soils probably accounted for most of the nitrate entering the Yaldhurst aquifers, the contribution by septic tank systems being estimated at 20–30%. No direct evidence of contamination of the wells by septic tank effluent was found, although 23 of the 25 wells exhibited intermittent contamination by indicator bacteria throughout the 8 month sampling programme. Although a localised health hazard may exist, septic tank systems in the area were not considered likely to constitute a health threat to the confined aquifers underlying Christchurch city.  相似文献   

7.
Lake Waikaremoana, the North Island's deepest lake (248 m), lies in a natural forested catchment, but the lake itself has been modified for hydro‐electric power generation and by the introduction of trout, smelt, and adventive aquatic plants. The lake is a warm monomictic water body of low conductivity (82 μS cm‐1) and a high seasonal water column stability. The waters are oligotrophic, with epilimnetic dissolved reactive phosphorus concentrations typically < 1 mg m‐3. The concentration of NO3‐N is seasonally variable but generally high in winter and spring with maximum epilimnetic values approaching 70 mg m 3. This contrasts with other central North Island lakes. Horizontal variability in surface chlorophyll a is low as are the absolute values (< 1–2 mg m‐3). A notable feature is the formation of a deep chlorophyll maximum within the metalim‐nion comprised largely of Sphaewcystis schweteri as opposed to diatoms and flagellates which normally dominate the epilimnion. Vascular macro‐phytes (maximum biomass 659 g m2 dry weight) extended to 9 m and characeans (maximum biomass 447 g m2dry weight) to 16 m. Total phyto‐plankton primary production was calculated as 4524 tCy‐1 and macrophyte production as 578 t C y‐1. The proportion of macrophyte to phy‐toplankton production (0.14) is higher than in the other deep lakes of the central North Island.  相似文献   

8.
Lake Ototoa is a warm monomictic lake at 36° 31’ S, 174° 14'E. During a year's study (March 1969‐March 1970), the lake became thermally stratified in November, the metalimnion being between depths of 12 m and 16 m. Surface temperatures ranged between 10.2°c (in August) and 25.2°c (in late January), and bottom temperatures between 9.7°c and 17.5°c. The annual heat budget was calculated to be 642 354 KJ.m‐2 (15 500 cal.cm‐2) and the work of the wind in distributing the heat income 1.730 KJ.m‐2 (1766 g.cm.cm‐2). Secchi disc transparencies ranged between 5 m and 9.2 m (mean 7.07 m) and were greatest in the summer. Light transmission per metre was also high, ranging between 61% and 87%. Surface waters were normally supersaturated with oxygen, but during summer stratification oxygen concentrations in the bottom waters dropped to a minimum of 2.3 mg.litre‐2 and a positive heterograde distribution of oxygen with depth was found. The oxygen deficit was 0.015 mg.cm‐2.day‐1 and showed the lake to be oligotrophic. Mean surface pH was 7.82, and the ionic composition of the waters was similar to that of other small New Zealand and Australian lakes located near the sea. Compared with other New Zealand lakes PO4‐P concentrations (range 1.00–10.20 μg.litre‐1) were low and NO3—N concentrations (range 0.12–0.60 mg.litre‐1) high.  相似文献   

9.
Water samples taken at 19 locations in the Mawheraiti River catchment at weekly intervals during 1979–80 were analysed for sodium, magnesium, potassium, calcium, phosphate, nitrate, and ammonium ion concentrations and for electrical conductivity. Seasonal discharge effects were apparent, and lithology and land management practice also influenced solute concentrations. Solute concentrations were generally very low; nitrate and soluble phosphate were rarely greater than 0.05 mg.L‐1 and ammonium was rarely greater than 0.01 mg.L‐1. The 4 major cations (Na, Mg, K, and Ca) usually summed to less than 6 mg.L‐1 much of which was supplied by precipitation. Forest management (clearfelling and slash‐burning) caused significant increases in solute concentrations, but concentrations declined rapidly during succeeding months and approached pretreatment levels after 2–3 years. The higher concentrations associated with forest management in small experimental catchments were rapidly diluted downstream; together with the low natural solute concentrations this suggests that harmful downstream effects of management practices are unlikely under low flow conditions.  相似文献   

10.
The nitrogen isotopic composition of dissolved nitrate (δ15N-NO3−) in surface water of the Yangtze River estuary was determined in four seasons of 2006. δ15N-NO3− ranged from 0.4‰ to 6.5‰ and varied with seasons and geographic regions, reflecting the dynamics of nitrogen cycling in the estuarine ecosystem. δ15N-NO3− was markedly lower in February than in other seasons and exhibited conservative mixing, which was probably attributed to the NO3− being sourced from the atmospheric deposition and agricultural fertilizer. In the upper estuary, the influence of riverine inputs was important during all surveys. In the turbidity maximum zone, nitrification was found with nitrate depleted in 15N in May, whereas denitrification resulting in heavy δ15N-NO3− played an important role in August. More enriched δ15N-NO3− values coinciding with losses of nitrate concentrations based on the conservative mixing model were found in the adjacent marine area in May, and may reflect obvious phytoplankton assimilation of dissolved nitrate. In this manner, δ15N-NO3− may be a sensitive indicator of nitrogen sources and biogeochemical processing existing in this estuary in conjunction with the variations of dissolved nitrate and other environmental factors.  相似文献   

11.
Absorbance at 360 nm and dissolved organic carbon (DOC) concentration were measured on 47 filtered water samples collected from streams and rivers of the west coast of South Island, New Zealand. The regression equation (DOC (g m‐3) = 59.6 Abs1 cm + 1.9) calculated from the data, reliably predicted DOC concentration within the range 1.6–43.2 gm‐3. This relationship is similar to that found fsr some Venezuelan and south‐eastern United Stales waters indicating that it may have widespread utility for estimating DOC concentrations in soft waters where DOC is dominated by humic substances  相似文献   

12.
Rates of net nitrification were calculated for four large (13 m3) estuarine-based microcosms that had been subjected to inorganic nutrient enrichment. Calculated rates were based on two years of weekly nitrate and nitrite measurements and ranged from a maximum of 0·55 μmol NO2+3− produced l−1 day−1 in the control tank (no enrichment) to over 13 μmol NO2+3− produced l−1 day−1 in the most enriched tank (receiving 18·6 μmol NH4 l−1 day−1). Almost all NO2+3− production was pelagic, little was benthic. Net NO3− production or net NO2− production dominated the net nitrification rates during different seasons. Good correlations were found between various oxidation rates and substrate concentrations. The calculated net nitrite production rates were 10 to 1000 times higher than previously reported rates for open ocean systems, demonstrating the potential importance of nitrification to estuarine systems.  相似文献   

13.
Abstract

The effects of shade on periphyton and invertebrates were investigated by comparisons in 12 replicate channels beside a pasture stream where shade cloth reduced the photosynthetically available radiation (PAR) by 0, 60, 90, and 98%. Periphytic productivity decreased with increasing shade. Periphyton chlorophyll a was consistently low (< 30 mg m?2) under 98 and 90% shade and usually low at 60% shade, whereas blooms were common during summer in the unshaded channels. More periphytic taxa occurred in the open than shaded channels and the relative concentration of the photo‐protective pigment beta‐carotene decreased with increasing shade. Nitrate uptake rates by periphyton, measured in separate chamber studies, decreased progressively as shade increased from 60% through 90% to 98%, and were more strongly correlated with gross primary productivity than periphyton chlorophyll a and particulate carbon levels. Total invertebrate and chironomid densities declined significantly as shade increased from 60 to 90% and invertebrate taxa richness declined markedly between 90 and 98% shade. Most collector‐browsing invertebrates (other than chironomids) had similar densities under 0–90% shade and only declined at 98%. This suggests a weak coupling of these invertebrates with local periphyton production and also suggests that energy derived from up‐stream sources may be their most important food in these pastoral streams.  相似文献   

14.
Chemical data on samples from tributaries to Lake Rotorua are used to show that a large proportion of the chloride load on the lake comes from a source other than the surface tributaries. This source is probably a flow of c. 0.6 m3 s‐1 of geothermal water with a chloride concentration of c. 500 g m‐3.  相似文献   

15.
Abstract

The density and biomass of fish and crayfish, and the production of eels, was compared among streams in native forest, exotic forest, and pasture. Populations were estimated by multiple‐pass electroshocking at 11 sites in hill‐country streams in the Waikato region, North Island. Three sites were in native forest, four in exotic forest, and four in pasture. Length of stream sampled at each site was 46–94 m (41–246 m2 in area), and catchment areas up stream of the sites ranged from 0.44 to 2.01 km2.

A total of 487 fish were caught. The species were longfinned and shortfinned eels, banded kokopu, Cran's and redfinned bullies, and common smelt. Eels were the most abundant fish in all three land‐use types, and shortfinned eels were more abundant at pastoral sites (mean density 1.11 fish m?2) than longfinned eels (mean density 0.129 fish m?2). Banded kokopu were present only at forested sites. Mean fish densities were greater at pastoral sites (1.55 fish m?2) than under either native forest (0.130 fish m?2) or exotic forest (0.229 fish m?2). Mean fish biomass was also greater at pastoral sites (89.7 g m?2) than under native forest (12.8 g m?2) or exotic forest (19.3 g m?2). Longfinned eels made a greater contribution to the fish biomass at all sites than did shortfinned eels. Densities of crayfish were high (0.46–5.40 crayfish m?2), but were not significantly different between land‐use types. Crayfish biomass ranged from 1.79 to 11.2 g m?2. Total eel production was greater at pastoral sites (mean 17.9 g m?2 year1) than at forest sites (mean 2.39 gm?2 year?1).  相似文献   

16.
Measurements were made of suspended sediment (SS), volatile suspended solids, dissolved organic carbon (DOC), nitrogen (N) and phosphorus (P) concentrations, turbidity, black disk visibility, pH, alkalinity, and temperature, at monthly intervals for 2–5 years on nine streams draining catchments with pasture, pine plantation, and native forest land uses. Stream flow and flow‐weighted concentrations of SS, N, and P were also measured for up to 2 years from pasture, native forest, and mixed land‐use catchments enabling calculation of export (kg ha‐1 yr‐1). During 1996–97, export from the pasture stream was 2.5‐ to 7‐fold higher for SS (988), total P (1.50), total Kjeldahl N (5.65), nitrate N (4.37), and ammoniacal N (0.34) than from the stream draining native forest. In contrast, export of DOC (25.5) and dissolved reactive P (DRP) (0.25) from the pasture stream were within 20% of the native stream's values. Export of SS and nutrients (except DRP) from the pasture catchment was 4‐ to 15‐fold higher during the winters of 1995 and 1996 than winter 1997 when rainfall was half the normal level. Streams draining native forest had lower temperature, sediment, and nutrient concentrations (except DRP), and higher water clarity, than those draining pine forest and pasture. A pine/scrub stream had the highest SS and turbidity and lowest DRP, pH, and alkalinity. Pasture streams had the highest concentrations of all N species (geometric means 2‐to 4‐fold > native), total P, and DOC, and also showed the greatest variation in water quality attributes in relation to season and flow. The influences of land use were attributable to differences in both source materials of sediment and nutrients available for transport and changes in rates of in‐stream processing.  相似文献   

17.
Fluxes of allochthonous litter were studied in a 93‐m long section of a small stream flowing through mountain beech forest at Cass in the South Island of New Zealand. Litter entered the stream throughout the year with maximum input from October to March. Mean annual input of beech litter was estimated to be 567 g.m‐2 (dry weight). Down‐stream movement of litter correlated strongly with maximum stream discharge during the collection period. The seasonal distribution and accumulation of litter within the stream was examined using 1‐mm‐mesh colonisation trays. Litter was unevenly distributed over the stream bed, but the average amounts taken from riffles, pools, and among large stones were similar. Litter accumulations were greatest in a pool in summer. The most important factor governing the quantity and transport of litter within the stream was stream flow.  相似文献   

18.
The results of measurements of surface ozone in central European Russia in 2004–2010 are presented. The variation coefficient for hourly, monthly, and annual mean ozone concentrations is 78, 26, and 12%, respectively. The measurements established a link between increased (>60 μg/m3) and minimum (<12 μg/m3) hourly mean ozone concentrations with the existence of a temperature inversion in the lower 300-m atmospheric layer. Sixty-seven percent of the total number of increased hourly mean ozone concentrations over the 2004–2010 period took place in 2010. A maximum hourly mean ozone concentration of 218.5 μg/m3 was recorded at 17:00 on August 1, 2010. The annual mean ozone concentration in a climatically significant range of hourly mean concentrations from 12 to 60 μg/m3 increased by 45% in a linear approximation over the period of record. The spectral analysis of monthly mean concentrations of surface ozone identified composite oscillations with periods from 3 to 60 months. To approximate the temporal dynamics of ozone, a statistical model was used. This model satisfactorily describes the experimental monthly and annual mean concentrations.  相似文献   

19.
Changes in water column nitrate and particulate nitrogen (PN) concentrations and rates of nitrate assimilation at 50°N 145°W were measured over a four-month interval for 1984, 1987 and 1988. Rates of nitrate depletion in the upper 80m of the water column averaged 12mg N m−2d−1, but most of the net depletion occurred during May when rates were high (75mg N m−2d−1) compared to later in the year. Particulate nitrogen (collected on GF/F filters) increased 2- to 3-fold during the month of May and accounted for 30–60% of the net nitrate depletion for May. Mean rates of PN accumulation for the 4-month intervals were 2.4mg N m−2d−1 and accounted for about 20% of the net nitrate depletion. Rates of nitrate assimilation (measured in incubation bottles with 15N) averaged 45.0±4.5mg N m−2d−1 (mean±SD), and appeared to decrease between May and September. A good correspondence between in situ and incubation estimates of nitrate assimilation was found for the 4-month comparison, but not for the month of May when net changes in nitrate concentrations were greatest. Vertical and horizontal inputs of nitrate are about the same order of magnitude as biological removal, thus the high inout of nitrate into the euphotic zone contributed to the continuously high nitrate concentrations in this region. Seasonal changes in nitrate and PN were significant and need to be considered in comparisons of new and export production.  相似文献   

20.
Nitrification and nitrate reduction were measured simultaneously by a 15N-isotope dilution technique in the top 2 cm of sandy sediments in Great South Bay, Long Island, New York. Experiments were done at three times, under three different sets of environmental conditions. Nitrification rates remained between 0.010 and 0.015 μg-at N (g dry wt)−1 (24 h)−1 despite decreasing temperature. Nitrate reduction ranged from 0.02 to 0.11 μg-at N (g dry wt)−1 (24 h)−1. Nitrate reduction exceeded nitrification in two experiments. In the third, at low temperature and apparently high oxygen levels, rates of nitrification and nitrate reduction were comparable. We conclude that there is not a constant relationship between nitrification and nitrate reduction in this environment. Attempts to measure rates of nitrification by using the inhibitor chlorate were not successful.  相似文献   

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