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1.
Abstract— We have used radiochemical neutron activation analysis (RNAA) to determine 15 trace elements, including 10 moderately to highly volatile ones—Rb, Ag, Se, Cs, Te, Zn, Cd, Bi, Tl, In (in increasing volatility order), in 6 H chondrite falls with low-3He contents. These (plus prior RNAA data) provide a compositional database of 92 H4-6 chondrite falls. Three suites of samples can be identified from their noble gas contents: 44 with “normal” contents and, therefore, “normal” orbits and cosmic-ray exposure histories; 8 that lost radiogenic gases, presumably by shock late in their histories; and 17 that lost cosmogenic gases by heating during close solar approach. We used the standard multivariate statistical techniques of linear discriminant analysis and logistic regression to compare contents of the 10 moderately and highly volatile trace elements, listed above, in these three suites. We found no significant differences. This contrasts sharply with similar comparisons involving random falls and H4-6 chondrites that landed on Earth at specific time intervals. Apparently, contents of volatile trace elements in H4-6 chondrites were established early in their histories, and they are so retentively sited that loss during later heating episodes did not occur.  相似文献   

2.
Abstract— We report radiochemical neutron activation analysis (RNAA) data for U, Co, Au, Sb, Ga, Rb, Cs, Se, Ag, Te, Zn, In, Bi, Tl, and Cd (ordered by increasing ease of vaporization and loss from the Murchison CM2 chondrite during open-system heating) in nine Antarctic C2 and C3 chondrites. These meteorites exhibit properties (obtained by reflectance spectroscopy, O isotopic mass spectrometry and/or mineralogy-petrology) suggesting thermal metamorphism in their parent bodies. Five of these meteorites (Asuka (A) 881655, Yamato (Y) 793495, Y-790992, Pecora Escarpment (PCA) 91008, and Y-86789—paired with Y-86720) exhibit significant depletion of the most thermally mobile 1–5 trace elements, which is consistent with open-system loss during extended parent-body heating (under conditions duplicated by week-long heating of the Murchison C2 chondrite, heated at 500–700 °C in a low-pressure (initially 10?5atm) H2 atmosphere). From earlier data, three other C3 chondrites—Allan Hills (ALH) 81003, ALH 85003, and Lewis Cliffs (LEW) 85332—show significant Cd depletion. Nine additional C2 and C3 chondrites show no evidence of mobile trace element depletion—including Y-793321, which by all other criteria was mildly metamorphosed thermally. Either metamorphism of these nine meteorites occurred under closed conditions and/or alteration took place under such mild conditions that even Cd could not be lost. The RNAA data suggest that 10 of the 46 Antarctic carbonaceous chondrites (including 4 of 37 from Victoria Land and 6 of 9 from Queen Maud Land) exhibit open-system loss of at least some thermally mobile trace elements by heating in their parent bodies, whereas none of the 25 non-Antarctic falls experienced this. These results are consistent with the idea that the Antarctic sampling of near-Earth material differs from that being sampled today.  相似文献   

3.
Abstract— We report noble gas data for 37 H chondrites collected from the Allan Hills by EUROMET in the 1988–1989 field season. Among these are 16 specimens with high levels (>100 krad) of natural thermoluminescence (NTL), originally interpreted as signaling their derivation from a single meteoroid with an orbit that became Earth‐crossin‐100 ka ago. One of these 16 is an H3 chondrite with a cosmic‐ray exposure age of ～33 Ma and clearly represents a separate fall. The other 15 H4–6 chondrites derive from three separate meteoroids, each of which is represented by a five or six member group. These groups have mean exposure ages of 3.7, 4.1, and 6.6 Ma: the middle‐group members all contain solar Ne. The two younger groups also seem to each include a few H chondrites with normal NTL levels. Measurements of cosmogenic 10Be (1.5 Ma), 26AI (710 ka), and 36CI (301 ka) in 14 of the high‐NTL chondrites indicate that all reflect a simple irradiation history. In contrast, many of a different (38 member) randomly selected suite of Antarctic H chondrites seem to have different cosmic‐ray irradiation histories. The 3.7 and 6.6 Ma groups from the 37 member Allan Hills suite come from about 5–30 and about 5–10 cm depths in 80–125 and 60–125 cm radius meteoroids, respectively.  相似文献   

4.
Abstract— We report concentrations of cosmogenic 10Be, 26Al, 36Cl, and 41Ca in the metal phase of 26 ordinary chondrites from Frontier Mountain (FRO), Antarctica, as well as cosmogenic 14C in eight and noble gases in four bulk samples. Thirteen out of 14 selected H chondrites belong to two previously identified pairing groups, FRO 90001 and FRO 90174, with terrestrial ages of ?40 and ?100 kyr, respectively. The FRO 90174 shower is a heterogeneous H3–6 chondrite breccia that probably includes more than 300 individual fragments, explaining the high H/L chondrite ratio (3.8) at Frontier Mountain. The geographic distribution of 19 fragments of this shower constrains ice fluctuations over the past 50–100 kyr to less than ?40 m, supporting the stability of the meteorite trap over the last glacial cycle. The second H‐chondrite pairing group, FRO 90001, is much smaller and its geographic distribution is mainly controlled by wind‐transport. Most L‐chondrites are younger than 50 kyr, except for the FRO 93009/01172 pair, which has a terrestrial age of ?500 kyr. These two old L chondrites represent the only surviving members of a large shower with a similar preatmospheric radius (?80 cm) as the FRO 90174 shower. The find locations of these two paired L‐chondrite fragments on opposite sides of Frontier Mountain confirm the general glaciological model in which the two ice flows passing both ends of the mountain are derived from the same source area on the plateau. The 50 FRO meteorites analyzed so far represent 21 different falls. The terrestrial ages range from 6 kyr to 500 kyr, supporting the earlier proposed concentration mechanism.  相似文献   

5.
Ronald A. Fevig  Uwe Fink 《Icarus》2007,188(1):175-188
Results of our visible to near-infrared spectrophotometric observations of 41 near-Earth asteroids (NEAs) are reported. These moderate-resolution spectra, along with 14 previously published spectra from our earlier survey [Hicks, M.D., Fink, U., Grundy, W.M., 1998. Icarus 133, 69-78] show a preponderance of spectra consistent with ordinary chondrites (23 NEAs with this type of spectrum, along with 19 S-types and 13 in other taxonomic groups). There exists statistically significant evidence for orbit-dependent trends in our data. While S-type NEAs from our survey reside primarily in (1) Amor orbits or (2) Aten or Apollo orbits which do not cross the asteroid main-belt, the majority of objects with spectra consistent with ordinary chondrites in our survey are in highly eccentric Apollo orbits which enter the asteroid main-belt. This trend toward fresh, relatively unweathered NEAs with ordinary chondrite type spectra in highly eccentric Apollo orbits is attributed to one or a combination of three possible causes: (1) the chaotic nature of NEA orbits can easily result in high eccentricity orbits/large aphelion distances so that they can enter the collisionally enhanced environment in the main-belt, exposing fresh surfaces, (2) they have recently been injected into such orbits after a collision in the main-belt, or (3) such objects cross the orbits of several terrestrial planets, causing tidal disruption events that expose fresh surfaces.  相似文献   

6.
Abstract— Fifty‐four fragments of ordinary chondrites from 50 finds representing all searched areas in central Oman and all weathering stages were selected to compare the physical, chemical, and mineralogical effect of terrestrial weathering with 14C terrestrial ages. 14C ages range from 2.0 to >49 kyr with a median value of 17.9 kyr. The peak of the age range, which is between 10–20 kyr, falls in an arid climate period. A comparison of the chemical composition of Omani chondrites with literature data for unweathered H and L chondrites demonstrates a strong enrichment in Sr and Ba, and depletion in S during weathering. Water contents in H chondrites increase with terrestrial age, whereas L chondrites show a rapid initial increase followed by nearly constant water content. Correlating Sr, Ba, and H2O with age indicates two absorption trends: i) an initial alteration within the first 20 kyr dominated by H2O uptake, mainly reflecting Fe‐Ni metal alteration, and ii) a second Ba‐and Sr‐dominated stage correlated with slower and less systematic weathering of troilite that starts after H2O reaches ?2 wt%. Sulfur released from troilite partly combines with Ba and Sr to form sulfate minerals. Other parameters correlated with 14C age are degree of weathering, color of powdered meteorites, and the Ni/Fe ratio. Chemical analyses of 145 soils show a high degree of homogeneity over the entire interior Oman Desert, indicating large‐scale mixing by wind. Soil samples collected from beneath meteorite finds typically are enriched in Ni and Co, confirming mobilization from the meteorites. High Cr and Ni concentrations in reference soil samples, which decrease from NE to SW, are due to detrital material from ultramafic rocks of the Oman Mountains.  相似文献   

7.
Abstract— The nature and isotopic composition of carbonaceous components in a variety of ordinary chondrites have been studied using stepped combustion. The samples were chosen to include falls, finds and Antarctic meteorites; specimens from all three chemical groups (H, L and LL) have been analysed. Effort was concentrated mostly on the low petrologic type meteorites (i.e., type 3); however, types 4–6 were also included in the study. Apart from terrestrial contaminants and weathering products, some of the unequilibrated ordinary chondrites appear to contain an indigenous organic component. In addition, most of the samples studied show evidence for an amorphous/graphitic component. This exists as C-rich aggregates or as carbon associated with “Huss” matrix. There does not appear to be any difference in δ13C for this carbon between Antarctic and non-Antarctic meteorites. In contrast, low temperature carbon in Antarctic samples is characterized by a 13C-enrichment. This is thought to be due to the influence of terrestrial weathering products introduced in the Antarctic. Curiously, the low temperature carbon in non-Antarctic finds appears to be intermediate in δ13C between Antarctic finds and non-Antarctic falls. This suggests that the weathering processes which are so obviously apparent from Antarctic samples may also extend, albeit in a more limited way, to non-Antarctic meteorites.  相似文献   

8.
The chemical effects of terrestrial alteration, with a particular focus on lithophile trace elements, were studied for a set of H chondrites displaying various degrees of weathering from fresh falls to altered finds collected from hot deserts. According to their trace element distributions, a considerable fraction of rare earth elements (REEs), Th, and U resides within cracks observed in weathered meteorite specimens. These cracks appear to accumulate unbound REEs locally accompanied by Th and U relative to the major element abundances, especially P and Si. The deposition of Ce is observed in cracks in the case of most of the weathered samples. Trace element maps visually confirm the accumulation of these elements in such cracks, as previously inferred based on chemical leaching experiments. Because the positive Ce anomalies and unbound REE depositions in cracks occur in all weathered samples studied here while none of such features are observed in less altered samples including falls (except for altered fall sample Nuevo Mercurio), these features are interpreted to have been caused by terrestrial weathering following chemical leaching. However, the overall effects on the bulk chemical composition remain limited as the data for all Antarctic meteorites studied in this work (except for heavily weathered sample A 09516, H6) are in good agreement with published data for unaltered meteorites.  相似文献   

9.
Abstract— We measured the concentrations of noble gases in 32 ordinary chondrites from the Dar al Gani (DaG) region, Libya, as well as concentrations of the cosmogenic radionuclides 14C, 10Be, 26Al, 36Cl, and 41Ca in 18 of these samples. Although the trapped noble gases in five DaG samples show ratios typical of solar or planetary gases, in all other DaG samples, they are dominated by atmospheric contamination, which increases with the degree of weathering. Cosmic ray exposure (CRE) ages of DaG chondrites range from ?1 Myr to 53 Myr. The CRE age distribution of 10 DaG L chondrites shows a cluster around 40 Myr due to four members of a large L6 chondrite shower. The CRE age distribution of 19 DaG H chondrites shows only three ages coinciding with the main H chondrite peak at ?7 Myr, while seven ages are <5 Myr. Two of these H chondrites with short CRE ages (DaG 904 and 908) show evidence of a complex exposure history. Five of the H chondrites show evidence of high shielding conditions, including low 22Ne/21Ne ratios and large contributions of neutron‐capture 36Cl and 41Ca. These samples represent fragments of two or more large pre‐atmospheric objects, which supports the hypothesis that the high H/L chondrite ratio at DaG is due to one or more large unrecognized showers. The 14C concentrations correspond to terrestrial ages <35 kyr, similar to terrestrial ages of chondrites from other regions in the Sahara but younger than two DaG achondrites. Despite the loss of cosmogenic 36Cl and 41Ca during oxidation of metal and troilite, concentrations of 36Cl and 41Ca in the silicates are also consistent with 14C ages <35 kyr. The only exception is DaG 343 (H4), which has a 41Ca terrestrial age of 150 ± 40 kyr. This old age shows that not only iron meteorites and achondrites but also chondrites can survive the hot desert environment for more than 50 kyr. A possible explanation is that older meteorites were covered by soils during wetter periods and were recently exhumed by removal of these soils due to deflation during more arid periods, such as the current one, which started ?3000 years ago. Finally, based on the 26Al/21Ne and 10Be/21Ne systematics in 16 DaG meteorites, we derived more reliable estimates of the 10Be/21Ne production rate ratio, which seems more sensitive to shielding than was predicted by the semi‐empirical model of Graf et al. (1990) but less sensitive than was predicted by the purely physical model of Leya et al. (2000).  相似文献   

10.
Metamorphic CK carbonaceous chondrites display matrix textures that are best explained by a transient thermal event with temperatures in the 550–950 K range and durations in the order of days to years, longer than what is commonly admitted for shock events but shorter than what is required for nuclide decay. We propose that radiative heating of small carbonaceous meteoroids with perihelia close to the Sun could account for the petrological features observed in CK chondrites. Numerical thermal modeling, using favorable known NEOs orbital parameters (perihelion distances between 0.07 and 0.15 AU) and physical properties of CV and CK chondrites (albedo in the range 0.01–0.1, 25% porosity, thermal diffusivity of 0.5–1.5 W m?1 K?1), shows that radiative heating can heat carbonaceous meteoroids in the meter size range to core temperatures up to 1050 K, consistent with the metamorphic temperatures estimated for CK chondrites. Sizes of known CV and CK chondrites indicate that all these objects were small meteoroids (radii from a few cm to 2.5 m) prior to their atmospheric entry. Simulations of dynamic orbits for NEO objects suggest that there are numerous such bodies with suitable orbits and properties, even if they are only a small percentage of all NEOs. Radiative heating would be a secondary process (superimposed on parent-body processes) affecting meteoroids formed by the disruption of an initially homogeneous CV3-type parent body. Different petrologic types can be accounted for depending on the sizes and heliocentric distances of the objects in such a swarm.  相似文献   

11.
As follows from dynamical studies, in the course of evolution, most near-Earth objects reach orbits with small perihelion distances. Changes of the asteroids in the vicinity of the Sun should play a key role in forming the physical properties, size distribution, and dynamical features of the near-Earth objects. Only seven of the discovered asteroids are currently moving along orbits with perihelion distances q < 0.1 AU. However, due to the Kozai–Lidov secular perturbations, the asteroids, having recently passed near the Sun, could by now have moved to orbits farther from the Sun. In this study, we found asteroids that have been recently orbiting with perihelion distances q < 0.1 AU. Asteroids may be on such orbits for hundreds to tens of thousands of years. To carry out astrophysical observations of such objects is a high priority.  相似文献   

12.
Abstract— To examine the thermal history of the parent body/bodies of equilibrated H chondrites, we treated data for 11 volatile trace elements (Co, Rb, Ag, Se, Cs, Te, Zn, Cd, Bi, Tl, and In in order of putative volatility) in 90 falls: 15 H4; 46 H5, and 29 H6. Using univariate statistical tests, contents of few of these elements differ significantly between any two of these suites. One element, Cs, differs systematically between all three pairs of suites; Co and Tl differ between two pairs of suites. For Co and Cs, contents varied as H4 > H5 > H6; while for Tl, contents varied as H4 < H5 < H6. Using multivariate statistical tests, all three suites can be distinguished compositionally, with trace element contents in the H5 suite being intermediate to those of H4 and H6. Surprisingly, the multivariate distinguishability reflects contents of less volatile Co, Rb, Ag, Se and Cs, and not of highly volatile Te, Zn, Cd, Bi, Tl and In. The compositional trends apparently reflect heterogeneous accretion >600 K, with the suites deriving from a stratified parent body/bodies.  相似文献   

13.
Abstract— We examined an improved system for extraction of carbon from meteorites, using a vacuum‐tight RF melting method. Meteorite samples mixed with an iron combustion accelerator, including a specific amount of carbon (0.052%), were combusted in a RF furnace (LECO HF‐10). 14CO2 extracted from the meteorite was diluted with a known amount of nearly 14C‐free CO2, evolved from the iron accelerator on combustion. The 14C activities of the recently fallen Holbrook (L6) and Mt. Tazerzait (L5) meteorites were measured by this method. The mean value was 56.5 ± 3.0 dpm/kg, which is similar to the values reported for recently fallen L6 chondrites. Furthermore, terrestrial ages were measured for four Antarctic meteorites: 1.8 ± 0.5 kyr for Yamato (Y‐) 75097 (L6), 1.8 ± 0.5 kyr for Y‐75108 (L6), and 0.1 ± 0.1 kyr for Y‐74192 (H5). For Y‐74190 (L6), an apparent age of 0.8 ± 0.5 kyr was calculated. After consideration of the shielding effect by using 22Ne/21Ne values, we obtained about 1.8 kyr for the terrestrial age of this chondrite. The five samples Y‐74190, Y‐75097, and Y‐75108, together with Y‐75102 (L6) and Y‐75271 (L6), have been reported to be paired and fragments of an L‐chondrite shower (Honda 1981; Takaoka 1987). The result of this work and literature data for the latter two samples confirmed that they are paired. More discussion and experimental work are needed for other recently fallen meteorites, both for L and H chondrites, and a correction for the shielding effect should be done to determine a more reliable terrestrial age.  相似文献   

14.
Abstract— Mössbauer spectroscopy is a very useful tool for identifying ferric iron weathering products in meteorites because of the capability to quantify the relative amounts of ferric iron in them. Mössbauer measurements were made of 33 Antarctic H chondrites (predominately H5) and two paired Antarctic CR chondrites. The primary goals of this study are to determine if Mössbauer spectroscopy can be used to determine which phases are weathering in Antarctic meteorites and if the relative amounts of ferric iron correlate with terrestrial age. Determining which minerals are weathering in ordinary chondrites appears very difficult due to variations in composition for different ordinary chondrites of the same meteorite class and possible problems in preparing homogeneous samples. The analysis of the two paired CR chondrites appears to indicate that metallic iron is predominately weathering to produce ferric iron for this class of meteorite. No correlation is seen between the relative amounts of ferric iron and terrestrial age for ordinary chondrites. One Antarctic H5 chondrite (ALHA77294) with a short 14C age of 135 ± 200 years from the dating of interior carbonate weathering products does have a relatively low amount of ferric iron, which is consistent with this meteorite being exposed on the surface for a relatively short time.  相似文献   

15.
Abstract— The cumulative mass distributions (mass range > 100 g) of each type of Japanese and U.S. Antarctic ordinary chondrites are compared with those of non-Antarctic falls and those obtained from the present-day flux of meteorites. The steeper slope of the mass distribution of Antarctic chondrites is indicative of the presence of several chondrite showers. The fall-to-specimen ratio of Antarctic ordinary chondrites larger than 100 g is about 1:2, indicating that half of them are shower components. The fall-to-specimen ratios of each group range from 1:1 to 1:6; those of the Japanese and U.S. Antarctic meteorite collections are 1:1 to 1:2 and 1:4 for H chondrites, 1:1 to 1:2 and 1:2 for L chondrites, and 1:2 and 1:6 for LL chondrites, indicating that the Japanese collection includes less abundant shower components than the U.S. collection. The fall-to-specimen ratios of each H4-6 and L4-6 type range from 1:1 to 1:4, and U.S. H6 and Japanese H4 have the low ratios of 1:4.  相似文献   

16.
Abstract— The recovery of large numbers of meteorites from Antarctica has dramatically increased the amount of extraterrestrial material available for laboratory studies of solar system origin and evolution. Yet, the great age of Antarctic meteorites raises the concern that significant amounts of terrestrial weathering has corrupted their pre‐terrestrial record. Organic matter found in carbonaceous chondrites is one of the components most susceptible to alteration by terrestrial processes. To assess the effects of Antarctic weathering on both non‐Antarctic and Antarctic chondritic organic matter, a number of CM chondrites have been analyzed. Mössbauer spectroscopy has been used to ascertain pre‐terrestrial and terrestrial oxidation levels, while pyrolysis‐gas chromatography‐mass spectrometry was used to determine the constitution of any organic matter present. Increased oxidation levels for iron bearing minerals within the non‐Antarctic chondrites are likely to be a response to increased amounts of parent body aqueous alteration. Parent body processing also appears to remove ether bonds from organic material and alkyl side chains from its constituent units. The iron in Antarctic chondrites is generally more oxidized than that in their non‐Antarctic counterparts, reflecting terrestrial weathering. Antarctic weathering of chondritic organic matter appears to proceed in a similar way to parent body aqueous alteration and simply enhances the organic responses observed in the non‐Antarctic data set. Degradation of the record of preterrestrial processes in Antarctic chondrites should be taken into account when interpreting data from these meteorites.  相似文献   

17.
Abstract On the basis of reported optical measurements of iron and stony meteorites, upper and lower limits for solar absorptance and hemispherical emittance of the surfaces of meteoroids have been established. Temperatures of three classes of meteoroids, none larger than approximately 10 meters in radius, have been calculated for various orbits and a/e ratios. These classes are light chondrites, dark chondrites and the irons. Temperatures for a meteoroid in a Mercury orbit range from 100° C for a light chondrite to 400° C for an iron.  相似文献   

18.
Abstract— We have previously identified a subgroup of Antarctic H chondrites that are significantly different from H chondrites among the modern falls in terms of induced thermoluminescence (TL), metallographic cooling rate, and cosmogenic inert gas contents. Here we examine their terrestrial and thermal history as apparent in their natural TL and radioactive cosmogenic isotope abundances. These meteorites have a tendency towards high 26Al activities and fairly short 14C and 36Cl terrestrial ages (generally <100 ka). They also sometimes exhibit unusually high natural TL levels, which we have previously interpreted as indicating orbital evolution from perihelia >1.2 AU to ～1 AU within the last <105 years. We suggest that the nature of the meteorites falling to Earth is not independent of time but depends on stochastic events, such as the breakup of parent bodies and recent variations in orbit.  相似文献   

19.
In this paper we present new results obtained from our spectroscopic survey of near-Earth objects (called SINEO). We show a set of 36 visible and near-infrared spectra, recorded with the 3.5-m Italian Telescopio Nazionale Galileo at La Palma (Canary Island). We discuss their taxonomic classification (resulting in 25 objects belonging to the S-complex, five to the C-complex and six to the X-complex), and their overall compositional linkage with the principal source of near-Earth objects, namely the Main Belt. Moreover, for some near-Earth objects we found good spectral fit among meteorites. In particular, we achieved an excellent fit for chondrites of different clans. Finally, we discuss the influences of space weathering among small S-type near-Earth objects.  相似文献   

20.
We describe the geological, geomorphological, and paleoclimatic setting of the Sahara of North Africa in particular, focused on the main meteorite dense collection areas (DCA; Morocco, Algeria, Tunisia, and Libya). We report on the outcome of several meteorite recovery field expeditions in Morocco and Tunisia since 2008, by car and by foot, that applied systematic search methods. The number of meteorites collected is 41 ordinary chondrites and one brachinite. The statistics of unpaired ordinary chondrites indicates that H chondrites are more abundant (21) than L chondrites (12), while LL chondrites are rare (2). Our meteorite density estimates for Tunisia and Morocco are in the order of magnitude of 1 met km?2. An estimate of the total maximum number of meteorites that could be recovered from the Sahara is 780,000 meteorites. We selected 23 meteorites from Aridal, Bou Kra, Bir Zar, and Tieret DCAs for 14C dating. The results show a wide range of terrestrial ages from 0.4 to more than 40 kyr with a majority of meteorites showing ages between 0.4 and 20 kyr. The weathering degree of these meteorites is ranges from minor (W1) to strong (W4). The highest weathering grades result from repeated oscillations between high and low humidity in the Sahara. However, there appears to be no correlation between weathering grade and terrestrial age of meteorites.  相似文献   

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