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1.
在莱恩海山链MP2海山的一块富钴结壳样品新壳层中,发育有"褐红色碎屑物质",这种物质粒度细小,呈浸染状分布,以Fc-Mn壳层柱状结构间的填隙物的形式产出.基于对该海区结壳样品手标本和光片的观察,认为这种"褐红色碎屑物质"可作为新壳层的一个标志物.利用电子探针技术,对这块富钴结壳样品进行了分析,获得了该结壳新壳层中"褐红...  相似文献   

2.
太平洋海山富钴结壳中铂族元素赋存状态与富集机理   总被引:2,自引:1,他引:1  
通过选择性化学提取法,对太平洋采薇海山富钴结壳样品中铂族元素进行分级提取实验,利用电感耦合等离子体质谱仪(ICP-MS)测定了铂族元素含量。赋存状态结果显示,富钴结壳中铂族元素在各个化学相态中富集比例从大到小依次为:铁氧化物相、残渣态、锰氧化物相、碳酸盐相、吸附态,未磷酸盐化新壳层和磷酸盐化老壳层中铂族元素都主要赋存于铁氧化物相中,其富集比例为59.26%~82.19%,残渣态中磷酸盐对铂族元素具有一定的富集能力,其富集比例为17.23%~35.37%。不同类型地质体中铂族元素的赋存状态结果,也证实了富钴结壳和海山结核中铂族元素富集主要受到铁氧化物相和残渣态的影响。太平洋海山富钴结壳中铂族元素的富集机理推测为铁氧/氢氧化物胶体粒子的吸附作用,使海水中PtC l24-离子被吸附到铁氧化物相中,从而使富钴结壳中铂族元素富集。  相似文献   

3.
西太平洋Lamont海山中新世以来富钴结壳成矿环境的演化   总被引:5,自引:0,他引:5  
分析了西太平洋Lamont海山12个站位33个富钴结壳样品的主元素和稀土元素,结果表明,该海山富钴结壳成因类型属于水成成因,并且在形成过程中基本未受到磷酸盐化作用的影响。Lamont海山的一个富钴结壳样品剖面的电子探针数据显示,该海山富钴结壳的成矿环境在新第三纪以来至少存在2个演化阶段:第1阶段,23~15 Ma,富钴结壳中Mn相对富集,成矿环境以富氧贫硅为特征;第2阶段,15~0 Ma,富钴结壳中Fe相对富集,成矿环境以贫氧富硅为特征。成矿环境的氧化能力总体上呈现下降的趋势。联系新生代世界大洋,尤其是西太平洋的地质演化背景,认为引起成矿环境演变的原因主要是西太平洋大洋板块的WNW向漂移和新第三纪以来全球水道开合,造成了Lamont海山所处海区最低含氧带逐渐减薄。  相似文献   

4.
富钴结壳是一种经济价值高、开发前景好的海洋矿产资源,其外部形态、内部构造和地球化学特征记录了古海洋环境的演变信息。本次研究借助富钴结壳细致分层的显微构造及元素地球化学的差异分析,探讨中太平洋莱恩海山富钴结壳成因及形成过程。富钴结壳样品由上至下可分为5层,顶部较致密Ⅰ层黑褐色,表面光滑,杂质较少,具有雪松状叠层石构造,反映了沉积水动力较强;较致密Ⅱ层与Ⅰ层宏观特征类似,具有柱状和胡萝卜状叠层石构造,沉积水动力最强;疏松Ⅲ层和疏松Ⅳ层黄褐色,内含沉积物杂质,多见斑杂状构造,沉积水动力比较弱;致密Ⅴ层为磷酸盐层,具有亮黑色的沥青光泽,富含有孔虫化石,底部Ⅴ层Sr、P、Ca等元素明显富集,表明了海洋生物的明显参与,沉积水动力最弱。莱恩海山Ce异常及高钴高锰低铁特征,表明结壳长期处于氧化环境;而Mn、Fe、Co等元素地球化学特征综合表明,海洋水动力及氧化性总体表现为由底部Ⅴ层至Ⅱ层氧化性逐渐增强,至顶部Ⅰ层有所减弱的趋势;依据元素分配系数、Ce正异常、Ho正异常、Y负异常及成因三角图,判定结壳为南极底流影响下的海水成因。综合结壳年代学数据,在元素剖面中记录了三期磷酸盐化事件,恢复了莱恩海山富钴结...  相似文献   

5.
全球三大洋海山钴结壳资源量估算   总被引:8,自引:0,他引:8  
钴结壳具有Co、Ni、Cu和Mn及其他金属的潜在矿产资源和储存在结壳层中古环境信息的双重意义。与深海多金属结核和热液硫化物矿床相比,具有较高Co、Ni和Pt含量的海山钴结壳有可能成为商业勘探的潜在目标。为合理地估算出全球三大洋海山钴结壳资源量,基于我国西太平洋海山钴结壳拖网采样调查资料和对太平洋海山钴结壳资源分布规律和钴结壳矿区圈定参数指标的深入研究,按海山不同高度、不同洋壳年龄赋予不同结壳厚度,进而计算出全球三大洋海山钴结壳分布面积为3 039 452.14km2和干结壳资源量为(1 081.166 1~2 162.332 2)×108 t。太平洋海山钴结壳分布面积为2 123 087.12km2和干结壳资源量为(513.244~1 026.488)×108 t,大西洋海山钴结壳分布面积为512 509.74km2和干结壳资源量为(116.503 2~233.006 4)×108 t,印度洋海山钴结壳分布面积为403 855.28km2和干结壳资源量为(81.484 9~162.969 8)×108 t。三大洋海山钴结壳的Mn、Co、Ni和Cu金属量分别为(138.848 0~277.696 0)×108 t,(3.967 6~7.935 2)×108 t、(2.793 6~5.587 2)×108 t和(0.825 1~1.650 2)×108 t。根据钴结壳的Co含量、Co通量和厚度相关分析,所赋予的钴结壳厚度占理论推测厚度的6.10%~12.20%,这与Ku等得出"钴结壳生长时间约占其整个生命史4%"的认识非常相近。三大洋海山钴结壳实测厚度与赋值厚度对比分析表明,太平洋海山钴结壳赋值厚度平均值为1.87cm,实测厚度平均值为1.77cm,相对误差为5.35%,大西洋和印度洋相对误差分别为18.18%和23.23%。研究数据表明按海山高度和洋壳年龄所赋的钴结壳厚度基本合理,估算出的钴结壳资源量基本可靠。本文首次估算出三大洋海山钴结壳资源量,为整个海盆和三大洋海山钴结壳资源量估算提供了新方法。  相似文献   

6.
中太平洋海山演化史及与富钴结壳的关系   总被引:6,自引:0,他引:6  
中太平洋海山区是海山富钴结壳广泛分布的一个重点地区,目前我国正在该区进行富钴结壳资源调查,了解该区海山形成演化史对研究富钴结壳的成因及其分布规律有重要意义。根据大量的文献资料,对该区海山演化史进行了综述,并对海山与其上生长的富钴结壳的关系进行了探讨。  相似文献   

7.
富钴结壳是一种富含Mn、Co、Ni和稀土元素(镧系元素加钇,简称REY)等元素的海底矿产资源。本文研究的富钴结壳样品是“科学”号在2018年HOBAB5航次于西北太平洋采薇海山的山顶边缘上通过电视抓斗获得的。利用扫描电镜、X射线衍射仪(XRD)、电感耦合等离子体发射光谱仪(ICP-OES)和电感耦合等离子体质谱仪(ICP-MS)分析了富钴结壳的显微构造、矿物学特征和地球化学特征,并探讨了其成因类型和形成机制。富钴结壳的结构从内到外可分为土黄色的疏松层(C8-5)、黑色铁锰致密层(C8-2、C8-3和C8-4)和发育葡萄状球体的粗糙表面(C8-1)。土黄色疏松层孔隙度较高,主要组成矿物为水羟锰矿、石英、钙长石、钠长石、钙十字沸石和钡镁锰矿,Mn的含量较低,Al的含量较高。黑色的铁锰致密层孔隙度较低,呈柱状构造,主要组成矿物为水羟锰矿、石英、钙长石和钠长石,Al含量有所下降,Mn含量升高,说明陆源物质的供应逐渐变少。在富钴结壳的生长后期,其主要显微构造由柱状构造向斑杂构造转变,二者的过渡区域为铁锰氧化物与富Si碎屑物质组成的层状构造。富钴结壳各层位的Mn/Fe比值为1.16~1.85,且各...  相似文献   

8.
中太平洋海山富钴结壳与基岩关系的研究   总被引:18,自引:5,他引:13  
对我国首次取得的中太平洋海山基岩和富钴结壳样品的结构构造、矿物和化学组成特征的研究表明,该区主要基岩类型为碱性玄武岩、磷块岩、磷酸盐化碳酸盐岩和燧石等,碱性玄武岩分布最广,并均有不同程度的风化.观察表明,富钴结壳的载体可以是各种岩性的基岩.玄武岩、风化火山岩和磷块岩上的结壳厚度比燧石的大,有较高的经济价值,是选矿冶炼的主要对象.对于调查区内富钴结壳形态总体上可分为三种类型:板状、砾状和结核状结壳.从以下四个方面探讨结壳与基岩之间的关系:(1)海水、基岩和结壳中主要金属元素含量特点;(2)通过聚类分析方法探讨结壳与基岩之间的亲疏程度;(3)结壳的分布特征;(4)不同基岩类型对结壳生长的影响.分析结果表明,调查区内的火山岩及磷块岩对结壳形成的贡献大(比其他类型岩石).  相似文献   

9.
为了释读蕴藏在富钴结壳中的环境变化信息,运用电子探针技术对中太平洋海山CXD05结壳进行了详细的构造和地球化学研究.结果表明:1)CXD05结壳约从19.4 Ma BP(早中新世)开始发育,从基部至顶部依次发育了斑杂构造、柱状构造和纹层构造;2)结壳中亲氧元素和碎屑组分从老至新发生规律性变化.结壳构造序列反映了其生长过程中海洋动力环境能量由高到低的变化;而壳层亲氧元素和碎屑组分的变化则记录了海水的氧化程度和风尘影响强度的变化.  相似文献   

10.
采用X射线衍射和微区电子探针法,对2006年"大洋一号"考察船在中太平洋C海山取得的典型富钴结壳样品进行了铁锰矿物的组成和成分特征分析,结果显示:(1)结壳的老壳层中铁锰矿物具有水羟锰矿、钡镁锰矿和钠水锰矿的特征组合,其相对含量分别为45.5%、30.1%和24.4%;中间壳层和年轻壳层中铁锰矿物为水羟锰矿,表明结壳各层生长的环境条件不同.(2)铁锰矿物集合体中Mn/Fe值从老壳层到年轻壳层具有明显降低的趋势,老壳层Mn/Fe值大于20,最高达90;中间壳层Mn/Fe值在2~5之间,年轻壳层Mn/Fe值在1~2之间.铁锰矿物集合体探针测得的结壳老壳层元素的总百分含量稳定在75%左右,中间壳层和年轻壳层为50%~80%.Si、Ti元素含量从老壳层到年轻壳层有增加的趋势,在中间疏松层中百分含量均达到最高值,分别为3.17%和1.53%,表明自老壳层到年轻壳层,碎屑物质或有机质等对结壳的影响程度有增大的趋势.由此可见,研究区富钴结壳主要为水成成因,主要发育了水羟锰矿;老壳层生长期间受到局部海水氧化还原条件变化的影响,铁锰相矿物发生重结晶或重组而形成了水羟锰矿、钡镁锰矿和钠水锰矿特征组合,这种特征铁锰矿物组合的研究对于全面理解海水环境条件变化与结壳成因的关系具有重要的意义.  相似文献   

11.
1Introduction Besidestheprecipitationandriverdischarges,the watersinthePacificOceanandtheAtlanticOceanare thesourcesoftheArcticOceanwater.TheAtlantic waterenterstheArcticOceanviatheFramStraitand theBarentsSea.Foritsdenserfeatureduetohigh salinity,mostofitsinkstothenorthofSvaldbardand circulatesinallthedeepbasinsintheArcticOcean, formingthedeepandbottomwatersoftheArcticO- cean(Aagaardetal.,1985;Rudelsetal.,1999).The BeringStraitistheonlychannelforthePacificwater toflowintotheArcticOce…  相似文献   

12.
This paper analyses the global tendency of the sea level rise (SLR) and its long term influence on the sea level upstream drainage cascade based on the example of the level’s variation in the Vistula Lagoon of the Baltic Sea compared to the other lagoons and coastal regions of the southeastern part of the Baltic Sea. A steady positive trend in the water level variations was revealed; its magnitude varies significantly depending on the time period. In general, during the 100–150 year period, the rate of the SLR in the lagoons and coastal areas of the Baltic Sea (1.7–1.8 mm per year) is close to the SLR rate in the World Ocean. In the second half of the 20th century, the increased rate of the SLR in the lagoons and marine areas became stronger (up to 3.6 mm per year in the Vistula Lagoon and in 1959–2006 in the sea and exceeded the rate of global ocean SLR). It dramatically increased at the end of the last century both in the lagoons and in the sea (up to 10.0–15.0 mm per year). This is the response not only to the global climate warming but it is likely that it is also a response to the changes of the climate driving forces that influence the regimes of the local wind and precipitation in the catchment.  相似文献   

13.
1 古新-下渐新统含油气层系 古新-始新统母岩形成于滨海和湖泊沉积环境中,并在大量冲积源的参与之下,促进了含分散有机质混合类型砂-黏土质陆源岩层的堆积。在中国东北诸盆地中,含工业油气的白垩-早第三纪建造形成于开阔的浅水和深水湖泊环境中。与中国的盆地类似,在下第三系下部  相似文献   

14.
A. A. Maximov 《Oceanology》2006,46(2):185-191
The data on the bottom concentrations of dissolved oxygen in the eastern part of the Gulf of Finland obtained in 1923–1939 and in 1962–1989 were analyzed. No statistically reliable differences were found between the two periods studied. It was found that, during the 20th century, the fluctuations in the oxygen concentration were caused by the interannual variability of the winter severity and water salinity. A strong oxygen deficit in the summer was recorded after cold winters, when early freezing suppressed the vertical mixing, and/or in the years of a significant inflow of salt waters from the Baltic Sea with low oxygen contents. It is likely that the long-term dynamics of the oxygen concentration near the bottom in the open parts of the bay is determined by the large-scale variability of the hydrometeorological parameters.  相似文献   

15.
Izvestiya, Atmospheric and Oceanic Physics - The Great Andaman–Sumatra earthquake (GASE) on December 26, 2004, with magnitude Mw of 9.2, occurred in the Indian Ocean near the northwestern...  相似文献   

16.
Data on the contents and compositions of the hydrocarbons (HCs)—aliphatic (AHCs) and polycyclic aromatic (PAHs)—are provided in comparison with the contents of the total organic carbon (Corg), the lipids in the particulates, and the Corg in bottom sediments. Particular attention has been paid to the distribution of the HCs in the water area of the Kravtsov oil field. It has been established that the concentrations of AHCs in the water are governed by the content of particulates, and the elevated AHC concentrations are confined to the coastal areas. In the water area of platform D-6, the sandy bottom sediments were notable for the great variability of the HC concentrations, both laterally and from year to year. In the summer of 2010, the content of AHCs averaged 40 μg/g (19% in the Corg), and that of PAHs, 23 ng/g. Natural seepage from the sediment mass is considered to be a source of HCs along with oil contamination.  相似文献   

17.
A relationship between paths of the Kuroshio and Kuroshio Extension (KE) is investigated, using the satellite-derived altimetry dataset of 1993–2008. When the Kuroshio takes the nearshore nonlarge meander path or typical large meander path and resultantly goes through the deeper channel (about 2500 m) of the Izu-Ogasawara Ridge, the KE path adopts a relatively stable state with the two quasi-stationary meanders. On the other hand, when the Kuroshio takes the offshore nonlarge meander path and then passes over the shallower part of the Ridge (about 1000 m), the KE path tends to be convoluted, i.e., an unstable state.  相似文献   

18.
19.
The role of the small-size (SF; 0.1–0.5 mm) and large-size (LF; 0.5–20.0 mm) fractions in the biomass and abundance of mesozooplankton (0.1–20.0 mm) was assessed using the database of samples obtained during the cruises of RV Akvanavt in the northeastern Black Sea in November 2000 and October 2006. The mesozooplankton was collected by means of Juday nets (37/50, filtering gauze 160 μm) and Niskin bottles in two areas: (1) the shelf and continental slope (30–1480 m depth) and (2) the deep sea (depths of more than 1500 m). The plankton net was considerably less effective in collecting the SF of the mesozooplankton (by a factor of 30–36) than the Niskin bottles. When comparing the SF and LF, we estimated the abundance and biomass of the SF in the samples obtained with the Niskin bottles. The abundance of the SF in the deep-sea area was 2.5 times lower compared to the shelf and continental slope, and the LF abundance was 5.0 times lower in the same way. The abundance of the SF constituted 88% of the total mesozooplankton on the shelf and continental slope, and 78% in the deep-sea area. The biomass of the SF was higher as well on the shelf and continental slope. Meroplankton played a significant role in the SF zooplankton abundance (0.5 × 103 + 0.16 ind. m−3) in this area. The SF grazing impact was 10% of the total mesozooplankton grazing on the shelf and continental slope, and 17% in the deepsea area. Appendicularia and nauplii of copepods had the greatest contribution to the mesozooplankton grazing among the SF group.  相似文献   

20.
This paper presents an evaluation of the effectiveness of the regulatory regime in the management of oil pollution on Kenya's marine and coastal environment. The prospect of chronic oil pollution along the Kenyan coastline and the port of Mombasa is discussed. A review of the vulnerable marine and coastal resources, commonly used indicators of effectiveness in oil pollution management and the legislation governing oil pollution is given. The author concludes by emphasising that despite having the right legislation in place, there is need for the establishment of criteria and indicators necessary for evaluation of policy effectiveness.  相似文献   

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