首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 187 毫秒
1.
Open cast mining of lignite leads to dumps containing highly mineralised pore waters. To predict the impact of the dump waters on the undisturbed aquifers two steps are necessary. (1) The prediction of dump water quality at times when steady state flow conditions will be established. (2) The simulation of the dump ground water migration with a model that is able to handle the complexity of the homogeneous and heterogeneous interactions of the migration process.For the investigated site Jänschwalde, which is still dewatered, a chemical mass balance was performed. The predicted alkalinity potentials exceed acidity potentials for the dump as a whole. The distribution of these parameters show high alkalinity potentials for the northern part.In order to model the migration process the transport code PCGEOFIM® [Anwenderdokumentaion, IBGW Leipzig, (in German)] was coupled with the geochemical equilibrium code PHREEQC [USGS, Water-Resources Investigations Report]. This was done to simulate redox reactions, mineral dissolution and precipitation, and cation exchange in the ground water zone. The model is verified by a column flow test. The results of the simulations show a small effect of the migrating dump waters on the quartenary aquifer with respect to acidity changes. This results from calcite buffering and cation exchange. The impact on the quartenary aquifer by sulphate is much higher.  相似文献   

2.
  相似文献   

3.
Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.  相似文献   

4.
Historical mining dumps are useful archives for the investigation of weathering processes. The objective of this study was to investigate the weathering behavior of waste-rock material derived from the 800-year-old silver ore mining in Freiberg, Germany. For identifying time-dependent weathering indices, dumped material of four dumps of different ages and corresponding rock was examined regarding the geochemical composition. The dumped material is characterized by high contents of heavy metal containing sulfidic ores, such as pyrite, arsenopyrite, sphalerite and galena. Acid mine drainage is produced by the oxidative weathering of the sulfide minerals and causes the increased dissolving of soluble metals with increasing age of dumps. As a result of these weathering processes, a clear depletion of chalcophile elements in the older dump material (800 years) compared to the youngest dump (100 years) was observed. In the soil horizons downstream the dumps, high quantities of heavy metals (e.g., up to 12,000 ppm As, 3,300 ppm Pb, 640 ppm Zn), mainly adsorbed on organic matter, were determined and indicate a time-dependent element transfer from the dumps into their surrounding soils.  相似文献   

5.
The gold mining process at Kolar gold field (KGF) mines has generated about 32 million tons of tailings. Gold was extracted from the mined ores using cyanidation technique that involved dissolution of gold in the ore by water soluble alkali metal cyanides (example, sodium cyanide or potassium cyanide). Of the several dumps that received the mine tailings only the Kennedy’s Line dump was active prior to closure of the KGF mines in the year 2000. The Kennedy’s Line dump received sulfide bearing tailings in slurry form that comprised of spent ore and process water bearing soluble alkali metal cyanide. Depending on the pH of the tailing slurry, the free cyanides may exist as aqueous hydrogen cyanide that can escape to the atmosphere as hydrogen cyanide gas or occur as soluble cyanide (CN−) ions that can be leached by infiltrating water to the sub-surface environment. Additionally, the presence of pyrite minerals in the Kennedy’s Line dump makes them susceptible to acid drainage. This study examines the potential of gold tailings of Kennedy’s Line dump to release cyanide ions (CN−) and acid drainage to the sub-surface environment by performing physico-chemical and leaching tests with tailing samples collected from various depths of the dump, sub-surface soil samples beneath the dump and groundwater samples from vicinity of Kennedy’s Line dump. The chemical mechanisms responsible for the ambient cyanide and pH levels of the tailing dump, sub-surface soil samples and groundwater are also inferred from the laboratory results.  相似文献   

6.
For waste dump slopes that form basements, landslides can be prevented by determining a stability evolving law of dynamic development. Keeping this issue in mind, the relationship between the mechanical structure and stability of waste dumps with basements is studied. Three key factors that influence waste dump stability are presented, and judgment criteria for self-locking and unlocking states of dump basements are provided. From the friction coefficient of waste dump basement stability analyses of the Shengli open pit mine, the results indicate that waste dump basements on the right side of fault F8 and on the left side of fault F61 are subjected to self-locking. However, between faults F61 and F8, the basement is subjected to unlocking. Regarding the residual thrusting of unlocking areas, structure and stability optimization schemes for waste dumps in the Shengli open pit mine are provided through a mechanics analysis. Reducing the slopes and basement angles of waste dumps can enhance their stability by increasing basement roughness levels.  相似文献   

7.
《Applied Geochemistry》2004,19(3):261-271
The distribution of Rare Earth Elements (REE) was investigated in the acidic waters (lake and groundwater) of a lignite mining district (Germany). The Fe- and SO4-rich lake water (pH 2.7) displays high REE contents (e.g. La∼70 μg/l, Ce∼160 μg/l) and an enrichment of light REE (LREE) in the NASC normalised pattern. Considering the hydrodynamic model and geochemical data, the lake water composition may be calculated as a mixture of inflowing Quaternary and mining dump groundwaters. The groundwater of the dump aquifer is LREE enriched. Nevertheless, the leachates of dump sediments generally have low REE contents and display flat NASC normalised patterns. However, geochemical differences and REE pattern in undisturbed lignite (LREE enriched pattern and low water soluble REE contents) and the weathered lignite of the dumps (flat REE pattern and high water soluble REE contents) suggest that lignite is probably the main REE source rock for the lake water.  相似文献   

8.
典型草原露天煤矿区地下水环境演化机理研究   总被引：1，自引：0，他引：1       下载免费PDF全文
伊敏露天煤矿位于中国东北部呼伦贝尔草原上,多年来的矿业活动对区域地下水环境造成严重影响,同时也给原本脆弱的草原生态环境带来威胁。文章以伊敏煤矿区地下水为研究对象,对比煤矿开采前（1973年）后（2016年）地下水系统的变化特征,运用流场对比、数理统计、Piper三线图、库尔洛夫式等对矿区地下水流场和水化学场的时空演化规律进行研究,以揭示强烈人工干预下草原矿区地下水与环境的相互作用机制。结果表明:露天煤矿开采活动使矿区地下水原生的还原环境变为氧化环境,煤层中的黄铁矿(FeS 2)被氧化、产酸并引发后续一系列反应,其结果导致矿区地下水pH值降低,总硬度(TH)、SO 2- 4、Fe 2+、Fe 3+、Ca 2+、Mg 2+离子浓度升高;水化学类型由以HCO 3—Na ·Ca ·Mg型为主演化为以HCO 3 ·SO 4—Na ·Ca ·Mg型为主;煤矿开采强烈疏排地下水加速了区域地下水循环速度,使地下水向着淡化方向发展,TDS、COD、Na ++K +等均呈降低趋势。  相似文献   

9.
Hydrogeochemical surveys were carried out in SW Sardinia (Italy) to investigate the impact of past mining activities on the quality of groundwater. The chemistry of waters from flooded galleries, adits and dumps has been compared with that of springs and wells in the same area at sites relatively far from any mine legacy. A feature, common to all waters, is the circumneutral pH, since the carbonate formations in the area neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. However, groundwater interacting with mine workings is degraded in quality; it shows high dissolved SO4, Zn, Cd and Pb contents. In some cases groundwater exceeds the limit established by the guidelines of the World Health Organization for Pb content in drinking water, so that groundwater is mixed before entering the local aqueducts. Results from this study suggest that more attention needs to be paid to the impact on the streams from contaminated water flowing out from some mine areas because during the dry season these streams are only fed by mine groundwater. We recommend focusing efforts to reduce the chemical contamination prior to discharge.  相似文献   

10.
Drainage from active and inactive pyrite mines has produced chemical and physical pollution of both ground- and surface water in Amjhore region. In the present case, chemical pollution is caused by exposing pyrite minerals to oxidation or leaching, resulting in undesirable concentrations of dissolved materials. Pyrite mining suddenly exposed large quantities of sulfides to direct contact with oxygen, and oxidation proceeds rapidly, resulting in acidity and release of metal (Fe) and sulfates to the water system, eventually resulting in water pollution in the region. The magnitude and impact of the problem is just being recognized and, as the present and the future projected demand for clean water is of top priority, the present studies were undertaken.Mine drainage includes water flowing from the surface and underground mines and runoff or seepage from the pyrite mines. This article describes the various hydrologic factors that control acid water formation and its transport. The mine drainage is obviously a continuing source of pollution and, therefore, remedial measures mainly consisting of a double-stage limestone-lime treatment technique have been suggested. The present results will be used to develop an alternative and more effective abatement technology to mitigate acid production at the source, namely, the technique of revegetation of the soil cover applied to the waste mine dump material.Water quality change is discussed in detail, with emphasis on acidity formed from exposed pyrite material and on increase in dissolved solids. Preventive and treatment measures are recommended.  相似文献   

11.
Small-scale mining and mineral processing at the Webbs Consols polymetallic PbZnAg deposit in northern New South Wales, Australia has caused a significant environmental impact on streams, soils and vegetation. Unconfined waste rock dumps and tailings dams are the source of the problems. The partly oxidised sulphidic mine wastes contain abundant sulphides (arsenopyrite, sphalerite, galena) and oxidation products (scorodite, anglesite, smectite, Fe-oxyhydroxides), and possess extreme As and Pb (wt% levels) and elevated Ag, Cd, Cu, Sb and Zn values. Contemporary sulphide oxidation, hardpan formation, crystallisation of mineral efflorescences and acid mine drainage generation occur within the waste repositories. Acid seepages (pH 1.9–6.0) from waste dumps, tailings dams and mine workings display extreme As, Pb and Zn and elevated Cd, Cu and Sb contents. Drainage from the area is by the strongly contaminated Webbs Consols Creek and although this stream joins and is diluted by the much larger Severn River, contamination of water and stream sediments in the latter is evident for 1–5 km, and 12 km respectively, downstream of the mine site. The pronounced contamination of local and regional soils and sediments, despite the relatively small scale of the former operation, is due to the high metal tenor of abandoned waste material and the scarcity of neutralising minerals. Any rehabilitation plan of the site should include the relocation of waste materials to higher ground and capping, with only partial neutralisation of the waste to pH 4–5 in order to limit potential dissolution of scorodite and mobilisation of As into seepages and stream waters.  相似文献   

12.
The present-day landscape in Central Germany, in particular the region of Leipzig, Halle and Bitterfeld, is characterized by the scars of former industrial activities. Vast districts have been devastated by lignite strip mining. Industrial and domestic waste, residues from ore smelting, and highly toxic waste products from petrochemical plants and pesticide production were deposited in abandoned pits near population centers. The chief effects of waste on the environment are the contamination of groundwater by dissolved pollutants, the acidification of soil and water by the oxidation of pyrite-containing mining waste, and the salinization of shallow aquifers by rising brines from adjacent confined groundwater affected by mining. The consequences for the region are serious: mining lakes used for recreational purposes are contaminated by leachates from adjacent waste dumps. Pyrite-containing refuse from lignite mining under oxidation gives rise to the acidification of surface and groundwater, a basic condition for pollutant mobilization. In former metal mining districts, metalliferous and radioactive residues from smelting jeopardize public health. These effects are described in detail using three case studies. Received: 30 July 1996 · Accepted: 24 February 1997  相似文献   

13.
Phosphate mining in southeastern Idaho has historically resulted in the release of dissolved metals and inorganics to groundwater and surface water, primarily due to leachate from waste rock in backfilled pits and overburden storage piles. Selenium (Se) is of particular concern due to its high concentration in leachate and its limited attenuation downgradient of source zones under oxic conditions. Assessments of potential groundwater/surface water impacts from waste rock typically involve laboratory characterization using saturated and unsaturated flow columns packed with waste rock. In this study, we compare the results of saturated and unsaturated column tests with groundwater quality data from the Mountain Fuel, Champ, South and Central Rasmussen Ridge Area (SCRRA), Smoky Canyon, Ballard, Henry, and Enoch Valley Mines, to understand the release and attenuation of Se in different geochemical environments. Column studies and field results demonstrate that the ratio of aqueous Se to aqueous sulfate (Se:SO4 ratio) is a useful metric for understanding Se release and attenuation, where the extent of sulfate reduction is much less than Se reduction. Comparison of dissolved Se and sulfate results suggests that the net leachability of Se from unsaturated waste rock is variable. Overall, Se concentrations in groundwater directly beneath waste rock dumps is not as high as would be predicted from unsaturated columns. Lower Se:SO4 ratios are observed immediately beneath waste rock dumps and backfilled pits relative to areas receiving shallow waste rock runoff. It is hypothesized that Se released in the oxic upper portions of the waste rock is subsequently attenuated via reductive precipitation at depth in unsaturated, low-oxygen portions of the waste rock. This highlights an important mechanism by which Se may be naturally attenuated within waste rock piles prior to discharge to groundwater and surface water. These results have important implications for mining practices in the region. A better understanding of Se dynamics can help drive waste rock management during active mining and capping/water management options during post-mining reclamation.  相似文献   

14.
The old Senhora das Fontes uranium mine, in central Portugal, consists of quartz veins which penetrated along fracture shear zones at the contact between graphite schist and orthogneiss. The mine was exploited underground until a depth of 90 m and was closed down in 1971. The ores from this mine and two others were treated in the mine area by the heap-leach process which ended in 1982. Seven dumps containing a total of about 33,800 m3 of material and partially covered by natural vegetation were left in the mine area. A remediation process took place from May 2010 to January 2011. The material deposited in dumps was relocated and covered with erosion resisting covers. Surface water and groundwater were collected in the wet season just before the remediation, in the following season at the beginning of the remediation and also after the remediation in the following dry season. Before, at the beginning and after the remediation, surface water and groundwater have an acid-to-alkaline pH, which decreased with the remediation, whereas Eh increased. In general, before the remediation, uranium concentration was up to 83 μg/L in surface water and up to 116 μg/L in groundwater, whereas at the beginning of the remediation it increases up to 183 μg/L and 272 μg/L in the former and the latter, respectively, due to the remobilization of mine dumps and pyrite and chalcopyrite exposures, responsible for the pH decrease. In general, after the remediation, the U concentration decreased significantly in surface water and groundwater at the north part of the mine area, but increased in both, particularly in the latter up to 774 μg/L in the south and southwest parts of this area, attributed to the remobilization of sulphides that caused mobilization of metals and arsenic which migrated to the groundwater flow. Uranium is adsorbed in clay minerals, but also in goethite as indicated by the geochemical modelling. After the remediation, the saturation indices of oxyhydroxides decrease as pH decreases. The remediation also caused decrease in Cd, Co, Cr, Ni, Pb, Zn, Cu, As, Sr and Mn concentrations of surface water and groundwater, particularly in the north part of the mine area, which is supported by the speciation modelling that shows the decrease of most dissolved bivalent species. However, in general, after the remediation, Th, Cd, Al, Li, Pb, Sr and As concentrations increased in groundwater and surface water at south and southwest of the mine area. Before and after the remediation, surface water and groundwater are contaminated in U, Cd, Cr, Al, Mn, Ni, Pb, Cu and As. Remediation caused only some improvement at north of the mine area, because at south and southwest part, after the remediation, the groundwater is more contaminated than before the remediation.  相似文献   

15.
Groundwater and soil pollution from pyrite oxidation, acid mine drainage generation, and release and transport of toxic metals are common environmental problems associated with the mining industry. Nickel is one toxic metal considered to be a key pollutant in some mining setting; to date, its formation mechanism has not yet been fully evaluated. The goals of this study are 1) to describe the process of nickel mobilization in waste dumps by introducing a novel conceptual model, and 2) to predict nickel concentration using two algorithms, namely the support vector machine (SVM) and the general regression neural network (GRNN). The results obtained from this study have shown that considerable amount of nickel concentration can be arrived into the water flow system during the oxidation of pyrite and subsequent Acid Drainage (AMD) generation. It was concluded that pyrite, water, and oxygen are the most important factors for nickel pollution generation while pH condition, SO4, HCO3, TDS, EC, Mg, Fe, Zn, and Cu are measured quantities playing significant role in nickel mobilization. SVM and GRNN have predicted nickel concentration with a high degree of accuracy. Hence, SVM and GRNN can be considered as appropriate tools for environmental risk assessment.  相似文献   

16.
If a mine waste pile is left open, an active chemical reaction of oxidation is often found due to the commonly high content of pyritic materials. The oxidation of pyrites is an exothermic process and the released heat will promote the flow of fresh oxygen from the surrounding atmosphere into the waste dump. As a result, oxidation reaction will accelerate and temperature within the dump can increase to as high as 60°C above the ambient temperature. The oxidation process also releases sulphuric acid and hydrogen ions into ground water to cause water contamination. Low‐permeability covers such as clay liners have been recently proposed to abate the oxidation process in mine wastes. The effectiveness of using low‐permeability materials to cover mine wastes in order to suppress the pyrite oxidation is examined. By conducting the theoretical analysis of the onset of convective air flow within waste rocks, the conditions under which soil gas flow is significant are identified. By comparing the results with previous field measurements and theoretical analysis for the uncovered conditions, it is shown that low‐permeability covers can effectively suppress soil gas flow and slow down the pyrite oxidation process in mine wastes. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

17.
In any open cast mine, the management of stripped spoil during mining is crucial to the mine’s successful operation. The improper management of the overburden (OB) dump can result in stability issues which may affect safety and production of the mine. Various literatures have reported the failure of open pit dumps and the consequences in loss of life, production and impact on neighbouring amenities. Recently, the failure of an out-of-pit OB dump at an Indian Colliery was reported. The failed OB dump displaced spoil approximately 70 m from the original location of the dump toe and impacted on neighbouring amenities. This paper back analyse material properties and investigates the probable mechanism of this OB failure. Well established tools including limiting equilibrium and continuum numerical methods have been used to understand and identify the failure kinematics of this dump. It has been found that the residual friction angle of the material comprising the dump structural unit dominates stability. Mobilisation of residual strength can occur by operational induced strains and/or the presence of water. The shear strength of the foundation was fully mobilised and provided a slip surface for the overlying dump material. The resultant failure is manifest as a bilinear wedge movement of two ridged blocks defined by linear rupture planes.  相似文献   

18.
Because of the high degree of automation in the coal mining industry in the Ruhr area, Germany, about 1 metric ton of crushed rock/colliery spoil is brought to the surface for every metric ton of coal. Most of the colliery spoil disposed of must be dumped. These colliery spoil dumps are anthropogenic geological sediment bodies, which have a characteristic facies resulting from geological, technical, and economical factors connected with the formation of the dumps. The relation between the facies of the dumps and these factors, for example, is examplified with the pyrite content within the colliery spoil. Pyrite content within the dumps is dependent both on the conditions during sedimentation and (early) diagenesis and the techniques used for mining and processing. Thus, this geologic-technical facies of the dumps controls the weathering processes on and in dumps. These humaninduced processes are mainly responsible for the environmental impact on soil and groundwater. Oxidation of pyrite as well as alteration of pyrite under anoxic conditions yields dissolution of carbonates, accompanied by gypsum formation, by acid attack and strong acidification takes place.  相似文献   

19.
 A field survey and modelling of the oxidation and carbonate buffering reactions inside the alum-shale-containing waste rock dumps located in Maardu, Estonia, was accomplished. In the slope areas, the shale has been altered at high temperatures due to the spontaneous combustion and the pyritic acidity has been eliminated through migration of SOx gases out from the dump. In the central parts of the waste rock plateaus, low temperature pyrite oxidation fronts develop towards the dump depth and towards the centres of individual shale lumps. The main secondary phases precipitating in the weathering profile are gypsum, ferric oxyhydroxide, K-jarosite and smectite. The respective field data made it possible to calibrate the two-stage oxygen diffusion model and the characteristic pyrite oxidation rate 0.06–0.08 mol of pyrite reacted per kg of available water (pyrox/H2O value) was estimated to describe the first tens of years of dump performance. The model is capable to compare different shale disposal strategies that are illustrated with two case scenarios. The buffering of sulphuric acid by Mg-calcite appears to be an incongruent reaction with gypsum precipitating that leads to the build-up of the high Mg/Ca ratio in the leachate. Application of the Mg/Ca method estimates the pyrox/H2O value in the range of 0.05–0.14 mol/kg. Received: 26 January 1999 · Accepted: 23. February 1999  相似文献   

20.
Hydrogeochemical evaluation of groundwater in the lower Offin basin,Ghana   总被引：3，自引：0，他引：3  
Alumino-silicate mineral dissolution, cation exchange, reductive dissolution of hematite and goethite, oxidation of pyrite and arsenopyrite are processes that influence groundwater quality in the Offin Basin. The main aim of this study was to characterise groundwater and delineate relevant water–rock interactions that control the evolution of water quality in Offin Basin, a major gold mining area in Ghana. Boreholes, dug wells, springs and mine drainage samples were analysed for major ions, minor and trace elements. Major ion study results show that the groundwater is, principally, Ca–Mg–HCO3 or Na–Mg–Ca–HCO3 in character, mildly acidic and low in conductivity. Groundwater acidification is principally due to natural biogeochemical processes. Though acidic, the groundwater has positive acid neutralising potential provided by the dissolution of alumino-silicates and mafic rocks. Trace elements’ loading (except arsenic and iron) of groundwater is generally low. Reductive dissolution of iron minerals in the presence of organic matter is responsible for high-iron concentration in areas underlain by granitoids. Elsewhere pyrite and arsenopyrite oxidation is the plausible process for iron and arsenic mobilisation. Approximately 19 and 46% of the boreholes have arsenic and iron concentrations exceeding the WHO’s (Guidelines for drinking water quality. Final task group meeting. WHO Press, World Health Organization, Geneva, 2004) maximum acceptable limits of 10 μg l−1 and 0.3 mg l−1, for drinking water.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号