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1.
The newly discovered Chalukou giant porphyry Mo deposit, located in the northern Great Xing’an Range, is the biggest Mo deposit in northeast China. The Chalukou Mo deposit occurs in an intermediate-acid complex and Jurassic volcano-sedimentary rocks, of which granite porphyry, quartz porphyry, and fine-grained granite are closely associated with Mo mineralization. However, the ages of the igneous rocks and Mo mineralization are poorly constrained. In this paper, we report precise in situ LA-ICP-MS zircon U–Pb dates for the monzogranite, granite porphyry, quartz porphyry, fine grained granite, rhyolite porphyry, diorite porphyry, and andesite porphyry in the Chalukou deposit, corresponding with ages of 162 ± 2 Ma, 149 ± 5 Ma, 148 ± 2 Ma, 148 ± 1 Ma, 137 ± 3 Ma, 133 ± 2 Ma, and 132 ± 2 Ma, respectively. Analyses of six molybdenite samples yielded a Re–Os isochron age of 148 ± 1 Ma. These data indicate that the sequence of the magmatic activity in the Chalukou deposit ranges from Jurassic volcano-sedimentary rocks and monzogranite, through late Jurassic granite porphyry, quartz porphyry, and fine-grained granite, to early Cretaceous rhyolite porphyry, diorite porphyry, and andesite porphyry. The Chalukou porphyry Mo deposit was formed in the late Jurassic, and occurred in a transitional tectonic setting from compression to extension caused by subduction of the Paleo-Pacific oceanic plate.  相似文献   

2.
The Jiguanshan porphyry Mo deposit is located in the southern part of Xilamulun metallogenic belt at the northern margin of the North China Craton (NCC). In the Jiguanshan mining district, two stages of granitoids intrusions have been recognized: a pre-ore granite porphyry with stockworks and veins of Mo mineralization, and a granite porphyry with disseminated Mo mineralization. Zircon U–Pb data and Hf isotope analyses show that the dissemination-mineralized granite porphyry yielded a weighted mean 206Pb/238U age of 156.0 ± 1.3 Ma, with a crustal εHf(t) values from − 5.6 to + 0.2, and that the main group of magmatic zircons from the pre-ore granite porphyry have a weighted mean 206Pb/238U age of 167.7 ± 1.7 Ma with εHf(t) values from − 3.2 to + 1.0. Combined with groundmass Ar–Ar age data of the granite porphyry and molybdenite Re–Os age, it is suggested that the Mo mineralization of Jiguanshan deposit was formed in the late Jurassic (153 ~ 155 Ma) during tectonic and magmatic events that affected northeast China. The Mo mineralization was a little bit later than the host granite porphyry. Besides disseminated in the host granite porphyry, Mo mineralization also presents in middle Jurassic pre-ore granite porphyry, Jurassic fine-grained diabase, Triassic quartz porphyry, and in rhyolitic volcanic rocks as well as syenite of Devonian age.The Jiguanshan mining district was affected by the tectonic events associated with the Paleo-Asian Ocean closure, and later by far-field tectonism, related to subduction of the Paleo-Pacific plate (Izanagi) in the Jurassic-Cretaceous. The tectonic and thermal events linked with the latter are commonly referred to as Yanshanian tectono-thermal event, and consists of a series of geodynamic, magmatic and ore-forming processes, which in the mining district area included the intrusion of the pre-ore granite porphyry, the host granite porphyry, Mo mineralization, and fine-grained diabase. Major and trace element analyses show that the host granite porphyry is characterized by high silica abundances (SiO2 = 77.16 to 77.51%), high Rb/Sr ratios (13.57 to 14.83), high oxidation (Fe2O3/FeO = 34.25 to 62.00) and high alkalies (Na2O + K2O = 8.21 to 8.38%). Petrographic and microthermometry studies of the fluid inclusions from Mo mineralized veins, characterized by plenty of daughter mineral-bearing inclusions, showed that the predominant homogenization temperatures range from 250 to 440 °C. Combined with Laser Raman analysis of the fluid inclusions, it is indicated that Mo mineralization is related to a high-temperature, hypersaline and high-oxygen fugacity H2O–NaCl fluid system, with high F contents.Based on geology, geochronology, isotope systematics, geochemistry and fluid inclusion studies as well as regional geology, we propose, for the first time, a genetic model for the Jiguanshan porphyry Mo deposit. During the Jurassic geodynamic evolution of northeast China, high silicic, high oxidized and alkaline-rich granitic magma probably derived from partial melting of the lower crust, episodically intruded along faults into the country rocks. This fluid system, fractionating from the highly differentiated granitic magma and bearing Mo with minor Cu metals, migrated upwards and interacted with the older wall rocks and associated fractures, in which the ore minerals precipitated, resulting in the development of what we refer to as the “Jiguanshan-type” porphyry Mo deposit.  相似文献   

3.
The Chalukou giant porphyry Mo deposit, located in the northern Great Xing'an Range, is the largest Mo deposit in the Xing'an–Mongolia orogenic belt. This deposit's ore bodies are mainly hosted in an intermediate–felsic complex and Jurassic volcanic sedimentary rocks, of which Late Jurassic granite porphyry, quartz porphyry and fine grained granite are closely associated with the Mo mineralization. Three types of fluid inclusions (FIs) are present in the quartz associated with oxide and sulphide minerals, i.e., liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs. The FIs in the quartz phenocrysts of the granite porphyry contain liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs. The homogenization temperatures vary from 230 °C to 440 °C and 470 °C to 510 °C, and their salinities vary from 0.7% to 53.7% NaCl eq. and 6.2% to 61.3% NaCl eq., respectively. The FIs of K-feldspar–quartz–magnetite veins of the early stage are composed of liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs with homogenization temperatures and salinities of 320 °C to 440 °C and 4.2% to 52.3% NaCl eq., respectively. The FIs of quartz–molybdenite veins and breccia of the middle stage are composed of liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs with homogenization temperatures and salinities of 260 °C to 410 °C and 0.4% to 52.3% NaCl eq., respectively. FIs of quartz–fluorite–galena–sphalerite veins of the late stage are liquid-rich two-phase FIs with homogenization temperatures and salinities of 170 °C to 320 °C and 0.5% to 11.1% NaCl eq., respectively. The ore-forming fluids of the Chalukou deposit are characterised by high temperature, high salinity and high oxygen fugacity, belonging to an F-rich H2O–NaCl ± CO2 system. The δ18OW values vary from − 4.5‰ to 3.2‰, and the δDW values vary from − 138‰ to − 122‰, indicating that the ore-forming fluids were a mixture of magmatic and meteoric water. The δ34S values range from − 1.9‰ to + 3.6‰ with an average of + 1.6‰. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values of the metallic minerals are in the ranges of 18.269–18.501, 15.524–15.567 and 38.079–38.264, respectively. Both the S and Pb isotopic systems indicate that the ore metals and fluids came primarily from a deep-seated magma source from the juvenile lower crust. The Mo mineralization in the Chalukou deposit occurred at a depth of 0.5 to 1.3 km, and multiple stages of phase separation or immiscibility of ore-forming fluid was critical for the formation of the Chalukou deposit.  相似文献   

4.
The newly discovered Yuanlingzhai porphyry molybdenum (Mo) deposit in southern Jiangxi province belongs to the group of Mo-only deposits in the Nanling region. The mineralization developed at contact zones between the Yuanlingzhai granite porphyry and Neoproterozoic metamorphic rocks of the Xunwu Formation. Precise LA–MC–ICPMS zircon U–Pb dating of the Yuanlingzhai porphyry, as well as the adjacent western Keshubei and eastern Keshubei granites, yielded ages of 165.49 ± 0.59 Ma, 159.68 ± 0.43 Ma, and 185.13 ± 0.52–195.14 ± 0.63 Ma, respectively. Molybdenite Re–Os isochron ages of the ores are 160 ± 1–162.7 ± 1.1 Ma, which is consistent with the age of large-scale W–Sn deposits in South China. The Yuanlingzhai porphyry is characterized by high K2O, P2O5, and A/CNK (1.33–1.59), and low CaO and Na2O. The rock shows relatively enriched LREE without significant Eu anomalies (Eu/Eu* = 0.80–0.90). Geochemical and mineralogical characteristics indicate that the ore-hosting porphyry is a typical S-type granite generated from the partial melting of crustal material with only minor mantle contribution. Both Harker and evolutionary discrimination diagrams indicate that the Yuanlangzhai and western Keshubei granites are not products of co-magmatic evolution. The Keshubei granites and Xunwu Formation were not significant sources for the components in the porphyry mineralization, but the Yuanlangzhai granite may have supplied some ore-forming material. However, the main ore-forming material was carried by fluids from deep sources, as demonstrated by fluid inclusion and stable isotope data from the molybdenum deposit. The Mo porphyry deposit formed in an extensional setting, and was possibly associated with Jurassic subduction of the Izanagi Plate.  相似文献   

5.
The Xinan Cu–Mo deposit, newly-discovered in the Zijinshan Au–Cu–Mo Orefield (the largest porphyry–epithermal system in SE China), is featured by the presence of abundant multi-phase granitoids, which reflects the complex Mesozoic tectono-magmatic evolution in the region.New and published LA-ICP-MS zircon U–Pb age data reveal that the Mesozoic Zijinshan magmatism occurred in two major phases: (1) Middle to Late Jurassic (ca. 169–150 Ma), forming the Zijinshan complex granite and the Xinan monzogranite; (2) late Early Cretaceous to earliest Late Cretaceous (ca. 112–98 Ma), forming the Shimaoshan volcanic rocks, Sifang granodiorite, and the Xinan (fine-grained) granodiorite porphyry, porphyritic granodiorite and late aplite dykes. Additionally, a possible earliest Cretaceous magmatism (ca. 141 Ma) may have occurred based on inherited zircon evidence. Major and trace element geochemistry indicates that all the Zijinshan igneous rocks show subduction-related geochemical affinities. Zircon Ce4 +/Ce3 + values of the late Early Cretaceous to earliest Late Cretaceous granitoids (Ce4 +/Ce3 + = 190–1706) are distinctly higher than the Middle to Late Jurassic ones (Ce4 +/Ce3 + = 27–457), suggesting that the former were derived from more oxidized parental magma. The Middle to Late Jurassic Zijinshan complex granite and monzogranite have εHf (t) values of − 8.02 to − 10.00, with the two-stage Hf model ages (TDM2) of 1.72 to 1.84 Ga (similar to the Paleoproterozoic metamorphosed Cathaysia Block basement), suggesting that they were derived from partial melting of the basement. The late Early Cretaceous to earliest Late Cretaceous Sifang granodiorite and Xinan (fine-grained) granodiorite porphyry, porphyritic granodiorite and aplite dykes contain higher and wider range of εHf (t) values (0.66 to − 6.05), with TDM2 of 1.12 to 1.56 Ga, indicating that they were also partial melting product of the Cathaysia basement but with more mantle and/or juvenile mafic lower crustal input. We propose that the Zijinshan Orefield was in a compressive, Pacific subduction-related tectonic setting during the Middle to Late Jurassic. The regional tectonic regime may have changed to extensional in the late Early Cretaceous to earliest Late Cretaceous, during which the Pacific plate subduction direction change and the accompanying subduction roll-back and slab window-opening occurred. The tectonic regime transition, high oxygen fugacity and mantle/mafic lower crustal materials involvement in the late Early Cretaceous to earliest Late Cretaceous may have generated the Zijinshan porphyry-related Au–Cu–Mo mineralization.  相似文献   

6.
Available cores of porphyritic granite and aplitic granite from the Diyanqinamu porphyry Mo deposit in the north central Great Xing’an Range presented an opportunity to examine and analyze Mesozoic igneous rocks far from the Paleo-Pacific subduction zone. The Diyanqinamu granites are highly fractionated I-type, distinguished from the M-, A- or S-type granite by: high SiO2, and Rb; low Zr, Nb, Y, and Ce; low Fe2O3total/MgO and (K2O + Na2O)/CaO ratios; low alumina saturation index (<1.1); low initial ISr ratios (0.70137–0.70451); positive εNd(t) values (2.37–3.77); and negative correlation between P2O5 and SiO2. The aplitic granites were generated by fractional crystallization of the porphyritic granite, as evidenced by: spatial proximity; consistent zircon U–Pb ages (156 Ma) within error; correlations between other oxides and SiO2 in Haker diagrams; low Ba, Sr, Nb, P, Ti, Eu; linear relationship in both (La/Yb)N vs. La and Sr vs. Ba diagrams; and, decreasing LREE and ∑REE with increasing SiO2. The Diyanqinamu granites have young depleted-mantle two-stage model ages (avg. TDM2 = 660 Ma) similar to those of most Mesozoic voluminous felsic magmas in northeastern China, and were likely sourced from pre-existent crustal components both “old” and juvenile that had been juxtaposed during the tectonic evolution of the Paleo-Asian Ocean. These granites project in the transitional field from syn-collision to post-collision tectonic settings on tectonic discrimination diagrams, implying emplacement in an extensional environment. Extensional volcanism and basin formation in the Great Xing’an Range region in Late Jurassic is coeval with the Diyanqinamu granites, demonstrating that post-orogenic lithospheric extension related to the closure of the Mongol-Okhotsk Ocean was the main driving force for Late Jurassic magmatism in this region.  相似文献   

7.
We performed zircon U–Pb dating and analyses of major and trace elements, and Sr–Nd–Pb isotopes for granitoids in the Bengbu area, central China, with the aim of constraining the magma sources and tectonic evolution of the eastern North China Craton (NCC). The analyzed zircons show typical fine-scale oscillatory zoning, indicating a magmatic origin. Zircon U–Pb dating reveals granitoids of two ages: Late Jurassic and Early Cretaceous (206Pb/238U ages of 160 Ma and 130–110 Ma, respectively). The Late Jurassic rocks (Jingshan intrusion) consist of biotite-syenogranite, whereas the Early Cretaceous rocks (Huaiguang, Xilushan, Nushan, and Caoshan intrusions) are granodiorite, syenogranite, and monzogranite. The Late Jurassic biotite-syenogranites and Early Cretaceous granitoids have the following common geochemical characteristics: SiO2 = 70.35–74.56 wt.%, K2O/Na2O = 0.66–1.27 (mainly < 1.0), and A/CNK = 0.96–1.06, similar to I-type granite. The examined rocks are characterized by enrichment in light rare earth elements, large ion lithophile elements, and U; depletion in heavy rare earth elements, Nb, and Ta; and high initial 87Sr/86Sr ratios (0.7081–0.7110) and low εNd (t) values (? 14.40 to ? 22.77), indicating a crustal origin.The occurrence of Neoproterozoic magmatic zircons (850 Ma) and inherited early Mesozoic (208–228 Ma) metamorphic zircons within the Late Jurassic biotite-syenogranites, together with the occurrence of Neoproterozoic magmatic zircons (657 and 759 Ma) and inherited early Mesozoic (206–231 Ma) metamorphic zircons within the Early Cretaceous Nushan and Xilushan granitoids, suggests that the primary magmas were derived from partial melting of the Yangtze Craton (YC) basement. In contrast, the occurrence of Paleoproterozoic and Paleoarchean inherited zircons within the Huaiguang granitoids indicates that their primary magmas mainly originated from partial melting of the NCC basement. The occurrence of YC basement within the lower continental crust of the eastern NCC indicates that the YC was subducted to the northwest beneath the NCC, along the Tan-Lu fault zone, during the early Mesozoic.  相似文献   

8.
黑龙江省岔路口超大型斑岩钼矿床位于大兴安岭北部,是目前我国东北地区最大的钼矿床,矿体赋存于中酸性杂岩体及侏罗系火山-沉积岩内,其中花岗斑岩、石英斑岩、细粒花岗岩与钼矿化关系密切.本文采用LA-ICP-MS锆石U-Pb定年方法,获得了矿区内二长花岗岩、花岗斑岩、石英斑岩、细粒花岗岩、流纹斑岩、闪长玢岩及安山斑岩的结晶年龄分别为162±1.6 Ma、149±4.6 Ma、148±1.6 Ma、148±1.2 Ma、137±3.3 Ma、133±1.7Ma和132±1.6 Ma.岔路口矿区内至少存在3期岩浆活动,其顺序为侏罗纪火山-沉积岩、二长花岗岩→晚侏罗世花岗斑岩、石英斑岩、细粒花岗岩→早白垩世流纹斑岩、闪长玢岩、安山斑岩.岔路口矿床成矿时代为晚侏罗世,是东北亚大陆内部构造-岩浆活化的产物,形成于古太平洋板块俯冲作用引起的挤压向伸展构造体制转折背景,与我国东部大规模钼矿化爆发期相对应.  相似文献   

9.
Mineralization with ion adsorption rare earth elements (REEs) in the weathering profile of granitoid rocks from Nanling region of Southeast China is an important REE resource, especially for heavy REE (HREE) and Y. However, the Jurassic granites in Zhaibei which host the ion adsorption light REE (LREE) ores are rare. It is of peraluminous and high K calc-alkaline composition, which has similar geochemical features of high K2O + Na2O and Zr + Nb + Ce + Y contents and Ga/Al ratio to A-type granite. Based on the chemical discrimination criteria of Eby [Geology 20 (1992) 641], the Zhaibei granite belongs to A1-type and has similar source to ocean island basalts. The rock is enriched in LREE and contains abundant REE minerals including LREE-phosphates and halides. Minor LREE was also determined in the feldspar and biotite, which shows negligible and negative Eu anomalies, respectively. This indicates that the Zhaibei granite was generated by extreme differentiation of basaltic parent magmas. In contrast, granites associated with ion adsorption HREE ores contain amounts of HREE minerals, and show similar geochemical characteristics with fractionated felsic granites. Note that most Jurassic granitoids in the Nanling region contain no REE minerals and cannot produce REE mineralization. They belong to unfractionated M-, I- and S-type granites. Therefore, accumulation of REE in the weathering profile is controlled by primary REE mineral compositions in the granitoids. Intense fractional crystallization plays a role on REE enrichment in the Nanling granitoid rocks.  相似文献   

10.
The Dong’an gold deposit is a large-sized epithermal gold deposit recently discovered in the Lesser Khingan Range, NE China. Here, we present a detailed study of the petrogenesis, magma source, and tectonic setting of a medium–coarse grained alkali-feldspar granite, the major host rock of the Dong’an gold deposit. The LA–ICP–MS zircon U–Pb dating of the medium–coarse grained alkali-feldspar granite yields an early Jurassic age of 176.3 ± 1.1 Ma (MSWD = 0.62). The whole-rock geochemical data indicate that the samples are felsic, ferroan, alkali-calcic and peraluminous with relatively high alkali (K2O + Na2O) content. They are enriched in LREEs and LILEs (e.g., Rb, Ba, K), but are depleted in HFSEs (e.g., Nb, Ta, P, Ti), especially in P and Ti, showing characteristics of volcanic arc magmas and similarities with the Early–Middle Jurassic granitic rocks in Xing’an Mongolian orogenic belt. Meanwhile, the negative Eu, Nb, Ta, Ti, and P anomalies are consistent with fractional crystallization of plagioclase, Ti-bearing phases (rutile, ilmenite, titanite, etc.) and apatite during magma evolution. The samples have low Nb/Ta ratios (8.65–14.91) and low Mg# values (18–36), which are indicative of crustal derived magmas and no interaction between source magmas and the mantle. In-situ Hf isotopic analyses of the zircons from the medium–coarse grained alkali-feldspar granite yield εHf(t) values of +3.38–+5.68 and two-stage model ages (TDM2) of 772–900 Ma, indicating the magmas formed this intrusion were generated by partial melting of Neoproterozoic basaltic materials in the young lower crust, and the magma source could be derived from a depleted mantle. The medium–coarse grained alkali-feldspar granite most likely formed in the late stage of Toarcian subduction of the Pacific plate, which can be identified on the tectonic setting discrimination diagrams, and the formation of this intrusion was associated with underplating of mantle-derived magmas, which provided heat for crustal partial melting. Similar to the medium–coarse grained alkali-feldspar granite, large amounts of granitic rocks and a series of nonferrous metal hydrothermal deposits (Mo, Cu, Au) formed in northeast China as results of magmatic activities triggered by subduction of the Pacific plate during the Early–Middle Jurassic.  相似文献   

11.
The northwestern region of Peninsular India preserves important records of Precambrian plate tectonics and the role of Indian continent within Proterozoic supercontinents. In this study, we report precise SHRIMP zircon U–Pb ages from granitoids from the Sirohi terrane located along the western fringe of the Delhi Fold Belt in Rajasthan, NW India. The data reveal a range of Neoproterozoic ages from plagiogranite of Peshua, foliated granite of Devala, and porphyritic granite of Sai with zircon crystallization from magmas at 1015 ± 4.4 Ma, 966.5 ± 3.5 and 808 ± 3.1 respectively. The plagiogranite shows high SiO2, Na2O and extremely low K2O, Rb, Ba, comparable with typical oceanic plagiogranites. These rocks possess low LREE and HREE concentrations and a relatively flat LREE–HREE slope, a well-developed negative Eu-anomaly and conspicuous Nb and Ti anomalies. Compared to the plagiogranite, the foliated Devala granite shows higher SiO2 and moderate Na2O, together with high K2O and comparatively higher Rb, Ba, Sr and REE, with steep REE profiles and a weak positive Eu anomaly. In contrast to the plagiogranite and foliated granite, the porphrytic Sai granite has comparatively lower SiO2 moderately higher Na2O, extremely high Y, Zr, Nb and elevated REE. The geochemical features of the granitoids [HFSE depletion and LILE enrichment, Nb- and Ta-negative anomalies], and their plots in the fields of Volcanic Arc Granites and those from active continental margins in tectonic discrimination diagrams suggest widespread Neoproterozoic arc magmatism with changing magma chemistry in a protracted subduction realm. Our results offer important insights into a long-lived active continental margin in NW India during early and mid Neoproterozoic, consistent with recent similar observations on Cryogenian magmatic arcs widely distributed along the margins of the East African Orogen, and challenge some of the alternate models which link the magmatism to extensional tectonics associated with Rodinia supercontinent breakup.  相似文献   

12.
In situ zircon U–Pb ages and Hf isotope data, major and trace elements and Sr–Nd–Pb isotopic compositions are reported for coeval syenite–granodiorites–dacite association in South China. The shoshonitic syenites are characterized by high K2O contents (5.9–6.1 wt.%) and K2O/Na2O ratios (1.1–1.2), negative Eu anomalies (Eu/Eu* = 0.65 to 0.77), enrichments of Rb, K, Nb, Ta, Zr and Hf, but depletion of Sr, P and Ti. The adakitic granodiorite and granodiorite porphyry intrusions are characterized by high Al2O3 contents (15.0–16.8 wt.%), enrichment in light rare earth elements (LREEs), strongly fractionated LREEs (light rare earth elements) to HREEs (heavy rare earth elements), high Sr (438–629 ppm), Sr/Y (29.2–53.6), and low Y (11.7–16.8 ppm) and HREE contents (e.g., Yb = 1.29–1.64 ppm). The calc-alkaline dacites are characterized by LREE enrichment, absence of negative Eu anomalies, and enrichment of LILEs such as Rb, Ba, Th, U and Pb, and depletion of HFSEs such as Nb, Ta, P and Ti.Geochemical and Sr–Nd–Hf isotopic compositions of the syenites suggest that the shoshonitic magmas were differentiated from parental shoshonitic melts by fractional crystallization of olivine, clinopyroxene and feldspar. The parent magmas may have originated from partial melting of the lithospheric mantle with small amount contribution from crustal materials. The adakitic granodiorite and granodiorite porphyry have Sr–Nd–Pb isotopic compositions that are comparable to that of the mafic lower crust. They have low Mg# and MgO, Ni and Cr contents, abundant inherited zircons, low εNd(t) and εHf(t) values as well as old whole-rock Nd and zircon Hf model ages. These granodiorites were likely generated by partial melting of Triassic underplated mafic lower crust. The Hf isotopic compositions of the dacites are relatively more depleted than the Cathaysia enriched mantle, suggesting those magmas were derived from the partial melting of subduction-modified mantle sources. The coeval shoshonitic, high-K calc-alkaline and calc-alkaline rocks in Middle to Late Jurassic appear to be associated with an Andean-type subduction. This subduction could have resulted in the upwelling of the asthenosphere beneath the Cathaysia Block, which induced partial melting of the mantle as well as the mafic lower crust, and formed an arc regime in the coastal South China during Middle to Late Jurassic.  相似文献   

13.
The Hongshi gold deposit is located in the southwestern margin of the Kanggur–Huangshan ductile shear zone in Eastern Tianshan, Northwest China. The gold ore bodies are predominantly hosted in the volcanogenic metasedimentary rocks of the Lower Carboniferous Gandun Formation and the Carboniferous syenogranite and alkali-feldspar granite. The syenogranite and the alkali-feldspar granite yield SHRIMP zircon U–Pb ages of 337.6 ± 4.5 Ma (2σ, MSWD = 1.3) and 334.0 ± 3.7 Ma (2σ, MSWD = 1.1), respectively, indicating that the Hongshi gold deposit is younger than 334 Ma. The granitoids belong to shoshonitic series and are relatively enriched in large ion lithophile elements (Rb, K, Ba, and Pb) and depleted in high field-strength elements (Nb, Ta, P, and Ti). Moreover, these granitoids have high SiO2, Al2O3, and K2O contents, low Na2O, MgO, and TiO2 contents, low Nb/Ta ratios, and slightly positive Eu anomalies. The εHf(t) values of the zircons from a syenogranite sample vary from + 1.5 to + 8.8 with an average of + 5.6; the εHf(t) values of the zircons from an alkali-feldspar granite sample vary from + 5.0 and + 10.1 with an average of + 7.9. The δ34S values of 10 sulfide samples ranged from − 11.5‰ to + 4.2‰, with peaks in the range of + 1‰ to + 4‰. The above-mentioned data suggest that the Hongshi granitoids were derived from the melting of juvenile lower crust mixed with mantle components formed by the southward subduction of the paleo-Tianshan ocean plate beneath the Aqishan–Yamansu island arc during the Early Carboniferous. The Hongshi gold deposit was formed by post-collisional tectonism during the Permian. The granitoids most likely acted as impermeable barriers that prevented the leakage and runoff of ore-bearing fluids. Thus, the granitoids probably played an important role in controlling gold mineralization.  相似文献   

14.
The Jiadanggen porphyry Cu–(Mo) deposit is newly discovered and located in the Eastern Kunlun metallogenic belt of Qinghai Province, China. Here, we present a detailed study of the petrogenesis, magma source, and tectonic setting of the mineralization causative granodiorite porphyry. The new data indicate that the granodiorite porphyry is characterized by high SiO2 (68.21–70.41 wt.%) and Al2O3, relatively high K2O, low Na2O, and low MgO and CaO concentrations, and is high-K calc-alkaline and peraluminous. The granodiorite porphyry has low Mg# (38–46) values that are indicative of no interaction between the magmas and the mantle. The samples that we have examined have low Nb/Ta (9.17–10.3) and Rb/Sr (0.28–0.39) ratios, which are indicative of crustal-derived magmas. Source region discrimination diagrams indicate that the magmas that formed the granodiorite porphyry were derived from melting of a mixed amphibolite source in the lower crust. The samples have ISr values of 0.70954–0.70979, εNd(t) values of − 8.3 to − 7.9, and t2DM ages ranging from 1644 to 1677 Ma. These indicate that the magmas that formed this intrusion were generated by melting of Mesoproterozoic lower crustal material. Higher K(Rb) contents of the samples indicate that the magma source is high potassium basaltic material in the lower crust, which could be derived from an enriched mantle source. LA-ICP-MS zircon U–Pb dating of the granodiorite porphyry yields a late Indosinian age (concordia age of 227 ± 1 Ma; MSWD = 0.31), which is close to the molybdenite Re–Os isochron age (227.2 ± 1.9 Ma), indicating further the close relationship between the granodiorite porphyry and the Cu–(Mo) mineralization. These samples are LREE and LILE (e.g., Rb, K, Ba, and Sr) enriched, and HFSE (e.g., Nb, Ta, P, and Ti) depleted, especially in P and Ti, similar to the characteristics of volcanic arc magmas. This intrusion most likely formed during the later stage of Indosinian deep subduction of oceanic slab. This was associated with underplating of mantle-derived magmas, which provided heat for crustal melting. Similar to the Jiadanggen granodiorite porphyry, Indosinian hypabyssal intermediate-felsic intrusive rocks, formed under subduction tectonism or a transitional regime from subduction to syn-collision, make up the most important targets for porphyry Cu(Mo) deposits in the Eastern Kunlun metallogenic belt.  相似文献   

15.
Extensive Early Cretaceous post-collisional igneous rocks, especially the large volume of granitoids developed in the Dabie orogen. Some of these granitic rocks are spatially, temporally, and genetically associated with economically important molybdenum deposits. The Tangjiaping large-scale (> 0.1 million ton) porphyry Mo deposit is located in the northwest of the Northern Dabie Complex unit. The Mo mineralization is mainly hosted in molybdenite-bearing quartz veinlets and stockworks in the Tangjiaping granite porphyry, which intruded into Proterozoic biotite-plagioclase gneiss and amphibole-plagioclase gneiss. Two alteration zones from the porphyry centre outwards and downwards can be recognized: (1) K-silicate alteration-silicification zone; (2) silicification-phyllic alteration zone. The Tangjiaping ore-bearing granite porphyry occurs as an individual stock with an outcrop of 0.4 km2. LA-ICP-MS zircon U-Pb dating of the Tangjiaping granite porphyry yields crystallization age of 115 ± 1 Ma, which is consistent with the molybdenite Re-Os age of the deposit given by previous studies. The Tangjiaping granitic rocks are metaluminous and belong to high-K calc-alkaline and shoshonitic series. They are relatively enriched in light rare earth elements and have moderately negative Eu anomalies. Geochemical and mineralogical characteristics indicate that the Tangjiaping granite is an A-type granite and was generated by partial melting of intermediate-felsic rocks at pressures of ca. 0.4–0.8 GPa. There are high initial 87Sr/86Sr ratios ranging from 0.707367 to 0.709410 and negative εNd(t) values varying from − 15.0 to − 14.2 for the Tangjiaping granite. In situ zircon Hf isotopic analyses show that the εHf(t) values of zircons from the Tangjiaping granite porphyry vary from − 17.0 to − 6.0. The geochemical data and Sr-Nd-Hf isotopes, coupled with the Neoproterozoic inherited zircon age (652 ± 21 Ma), indicate that the Tangjiaping granite porphyry was most likely derived from partial melting of the Northern Dabie gneiss with some relatively enriched mantle materials involved. The Tangjiaping Mo ore-forming granite porphyry was formed in an extensional setting. The Early Cretaceous asthenospheric upwelling might have played an important role in the formation of the approximately coeval Mo-bearing magmas in the Dabie orogen.  相似文献   

16.
The Jinping terrane is situated in the southern segment of the Ailaoshan ore belt, Sanjiang Tethyan Orogen (SW China). The Paleogene intrusions in Jinping consist of syenite porphyry, fine-grained syenite and biotite granite stocks/dikes, and contain relatively low TiO2 (0.21–0.38 wt%), P2O5 (0.01–0.35 wt%), and high Na2O (2.00–4.62 wt%) and K2O (4.48–7.06 wt%), belonging to high-K alkaline series. Paleogene gold mineralization in Jinping comprises four genetic types, i.e., orogenic, alkali-rich intrusion-related, porphyry and supergene laterite. The NW–NNW-trending faults and their subsidiaries are the major ore-controlling structures. The orogenic Au mineralization, dominated by polymetallic sulfide-quartz veins, occurs in the diorite and minor in Silurian-Devonian sedimentary rocks. It contains a CO2-rich mesothermal fluid system generated from the mixing of mantle-derived fluids with crustal-derived metamorphic fluids, and the ore-forming materials were upper crustal- or orogenic-derived. The alkali-rich intrusion-related Au mineralization is hosted in the Ordovician-Silurian sedimentary rocks and minor in the Paleogene alkaline intrusions, and the Au orebodies occur predominantly in the alteration halos. It contains a CO2-bearing, largely metamorphic-sourced mesothermal fluid system, and the ore-forming materials were derived from the ore-hosting rocks and minor from the alkali-rich intrusions. The porphyry Cu-Mo-Au mineralization occurs in the granite/syenite porphyries and/or along their contact skarn, with the mineralizing fluids being magmatic-hydrothermal in origin. The former two hypogene Au mineralization types in Jinping were mainly formed in the late Eocene (ca. 34–33 Ma) and slightly after the porphyry Cu-Mo-Au mineralization (ca. 35–34 Ma), which is coeval with the regional Himalayan orogenic event. Subsequent weathering produced the laterite Au mineralization above or near the hypogene Au orebodies.  相似文献   

17.
《Gondwana Research》2014,25(1):401-419
This study reports new zircon U–Pb and Hf isotopes and whole-rock elemental and Sr–Nd isotopic data for the gneissic granite and leucogranite from the Nabang metamorphic zone, Yingjiang area (West Yunnan, SW China). The metamorphosed granitoids crystallized during the early Eocene (~ 55–50 Ma) with zircons showing εHf(t) values from + 11 to − 5.3 and crustal model ages of 1.5 to 0.42 Ga, comparable to those of coeval I-type granitoids from the Gangdese batholith, southern Lhasa. The rocks are characterized by metaluminous and weakly peraluminous hornblende-bearing gneissic granites with A/CNK = 0.95–1.09, Na2O > K2O, coupled with low initial Sr isotopic values of 0.7049–0.7070 and high εNd(t) values from + 1.1 to − 7.1. The rocks were derived from crustal materials involving ancient upper crust/sedimentary and juvenile mantle-derived rocks. Together with available data from nearby regions, it is proposed that the early Eocene granitoids in the Nabang and Tengliang area can be correlated to the Gangdese granitoids and represent the southeastward continuation of the magmatic arc resulting from the Neotethyan subduction in southern Tibet. The petrogenesis of early Eocene granitoids in western Yunnan was probably related to the rollback of the subducting Neotethyan slab that caused the remelting of the crustal materials newly modified by the underplated basaltic magma.  相似文献   

18.
Abstract: Five groups of the Phanerozoic granitoids in South Korea can be deduced from their temporal and spatial distributions: (1) Jurassic granitoids in the Gyeonggi massif, (2) Permo-Jurassic granitoids in the Ogcheon belt, (3) Permo-Jurassic granitoids in the Yeongnam massif, (4) Cretaceous granitoids in the Ogcheon belt, and (5) Cretaceous granitoids in the Gyeongsang basin. Though the granitoids of each group generally show calc-alkaline and orogenic natures, the petrological, geochemical and genetical features are different with each other. The Permo-Jurassic granitoids in the Ogcheon belt have lower contents of Al2O3, Fe2O3, CaO, P2O5, but higher of FeO, FeOT, MgO, K2O than those in the Yeongnam massif. From higher feature of K2O, Na2O+K2O and K2O/Na2O, the Ogcheon belt seems to have been located at closer continent side relative to the Yeongnam massif during Permo-Jurassic time. From lower values of Fe2O3/FeO and magnetic susceptibility the granitoids of the Ogcheon belt had been solidified under more reducing environment than those of the Yeongnam massif. The Cretaceous granitoids in the Ogcheon belt have lower contents of TiO2, Fe2O3, FeO, FeOT, CaO and P2O5, but higher of MgO, K2O, Na2O+K2O and K2O/Na2O than those in the Gyeongsang basin. This feature indicates that the Ogcheon belt would correspond to the continental environment of magma genesis during Cretaceous time. Higher values of Fe2O3/FeO and magnetic susceptibility in the Cretaceous granitoids in the Gyeongsang basin suggest that the granitoids had been solidified under highly oxidizing environment. From the particular chemical features of K2O, Na2O+K2O and K2O/Na2O, the Permo-Jurassic granitoids in the Ogcheon belt, the Yeongnam massif as well as the Cretaceous ones in the Gyeongsang basin can be categorized to the continental margin type granite. The Jurassic granitoids in the Gyeonggi massif are possibly of collision type, and the Cretaceous granitoids in the Ogcheon belt of post–orogenic, intra–conti–nent type. The Jurassic granitoids in the Gyeonggi massif had been possibly generated by crustal melting during the collision of Gyeonggi massif to the northern Pyeongnam basin block. The Cretaceous granitoids in the Ogcheon belt had been emplaced at the hinterland of the continental margin during post-orogenic stage of the Honam Shear Zone. The Cretaceous granitoids in the Gyeongsang basin are often compared with Japanese Cretaceous?Paleogene granitoids in their geochemical and genetical natures. For the granitoid composition, the granitoids in the Gyeongsang basin are higher in Fe2O3, Fe2O3/FeO, Na2O, K2O, Na2O+K2O and K2O/Na2O, but lower in Al2O3, FeO, MnO, CaO and P2O5 than the Japanese granitoids. The contents of TiO2, FeOT and MgO are similar in both granitoids. This geochemical contrast would imply that the Cretaceous granitoid magmas in the Gyeongsang basin had been originated at closer place to the continent side under more tensional field, and solidified under more oxidizing environment than the coeval Japanese granitoid magmas.  相似文献   

19.
East Qinling is the largest porphyry molybdenum province in the world; these Mo deposits have been well documented. In West Qinling, however, few Mo deposits have been discovered although granitic rocks are widespread. Recently, the Wenquan porphyry Mo deposit has been discovered in Gansu province, which provides an insight into Mo mineralization in West Qinling. In this paper we report Pb isotope compositions for K-feldspar and sulfides, S isotope ratios for sulfides, the results obtained from petrochemical study and from in situ LA-ICP-MS zircon U-Pb dating and Hf isotopes. The granitoids are enriched in LILE and LREE, with REE and trace element patterns similar to continental crust, suggesting a crustal origin. The Mg# (40.05 to 56.34) and Cr and Ni contents are high, indicating a source of refractory mafic lower crust. The εHf(t) values of zircon grains from porphyritic monzogranite range from ? 2.9 to 0.6, and from granitic porphyry vary from ? 3.3 to 1.9. The zircons have TDM2 of 1014 to 1196 Ma for the porphyritic monzogranite and 954 to 1224 Ma for the granitic porphyry, implying that these granitoids were likely derived from partial melting of a Late Mesoproterozoic juvenile lower crust. The Pb isotope compositions of the granitoids are similar to granites in South China, showing that the magma was sourced from the middle–lower crust in the southern Qinling tectonic unit. The Pb isotopic contrast between the Mo-bearing granitoids and ores shows that the Pb in the ore-forming solution was derived from fractionation of a Triassic magmatic system. δ34S values of sulfides are between 5.02 and 5.66‰, similar to those associated with magmatic-hydrothermal systems. LA-ICP-MS zircon U-Pb dating yields crystallization ages of 216.2 ± 1.7 and 217.2 ± 2.0 Ma for the granitoids, consistent with a previously reported molybdenite Re-Os isochron age of 214.4 ± 7.1 Ma. This suggests that the Mo mineralization is related to the late Triassic magmatism in the West Qinling orogenic belt. In view of these geochemical results and known regional geology, we propose that both granitoid emplacement and Mo mineralization in the Wenquan deposit resulted from the Triassic collision between the South Qinling and the South China Block, along the Mianlue suture. Since Triassic granitoid plutons commonly occur along the Qinling orogenic belt, the Triassic Wenquan Mo-bearing granitoids highlight the importance of the Triassic tectono-magmatic belt for Mo exploration. In order to apply this metallogenic model to the whole Qinling orogen, further study is needed to compare the Wenquan deposit with other deposits.  相似文献   

20.
The Huangyangshan pluton occurs in the Kalamaili region which is situated in the central part of the Central Asian Orogenic Belt, East Junggar, Xinjiang (NW China). The granitoid rocks are composed of medium-grained biotite (richterite, arfvedsonite) alkali-feldspar granite, fine grained arfvedsonite alkali-feldspar granite and microgranular enclaves. The granites have a pronounced A-type affinity: they are metaluminous to weakly peraluminous and calc-alkaline to alkaline in composition with high concentrations of Na2O + K2O varying from 8.4 to 9.2 wt.%, high FeOt/MgO and 10,000 Ga/Al ratios, low abundances of CaO, MgO and TiO2, enrichment in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu), depletion in Sr and Ba. Moreover, they display characteristic tetrad REE patterns and non-CHARAC trace element behavior, which is well demonstrated in highly differentiated rocks with strong hydrothermal interaction. The U–Pb zircon LA-ICP-MS ages of the host rocks and enclaves are 311 ± 5 Ma and 300 ± 6 Ma, respectively. The similar of these two ages suggests that host rocks and enclaves formed at a same time. Furthermore, the time span closely corresponds to known ages of post-collisional A-type granitoids of the Junggar terrane. Geochemical, geochronological and isotopic data (εNd(T) in the range +5.2 to +6.6 and ISr mostly in the range 0.7031–0.7041) suggest that the Huangyangshan intrusions, and the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas in the Late Carboniferous post-collisional tectonic setting (A2 type granite). The magma for the Huangyangshan granites was derived by partial melting of an enriched subcontinental lithospheric mantle (SCLM) that was modified by slab-derived components from an earlier subduction event, this melting resulted from heat supplied from the asthenosphere through an opening created during the break-off of an oceanic slab. This further proves the important contribution of the Late Paleozoic granitic magmatism in terms of vertical crustal growth in northern Xinjiang.  相似文献   

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