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1.
Sudicky EA  Illman WA 《Ground water》2011,49(5):630-648
This article summarizes several of many field-based studies of subsurface contaminant transport conducted over the last 30 years at the Canadian Forces Base (CFB) Borden site. The field research initially consisted of extensive monitoring of a leachate plume from an abandoned landfill and its analytical and numerical modeling. Lessons learned from these initial studies led to the execution and interpretation of a variety of tracer tests involving conservative and reactive/organic solutes tests performed at various scales. The lessons learned from these tracer tests revealed a number of deficiencies in classical theories of contaminant dispersion and reaction processes as they occur in groundwater, and thus spawned a new era of process-oriented research within the hydrogeological community. The extensively monitored tracer tests were followed by controlled spills of organic contaminants to observe their subsurface movement and distribution as well as the emplacement of a variety of contaminant sources in the saturated and unsaturated zones to study the ambient transport of contaminants. The controlled spills and emplaced sources of various contaminants were then utilized for testing various active and passive remediation technologies. These studies have led to fundamental insights and lessons learned that have significantly contributed to research on contaminant transport in both the saturated and unsaturated zones. Over the years, data generated by the University of Waterloo (UW) researchers and their collaborators continues to be examined by various research groups and has led to additional new insights on subsurface transport of various chemicals.  相似文献   

2.
A new probabilistic remediation simulation package, PREMChlor, was used to simulate the effect of contaminant source and plume remediation at a site contaminated by trichloroethylene (TCE). First, the PREMChlor model was calibrated to the plume using a deterministic approach to represent the site conditions prior to remediation activities, which occurred in 1999. The calibrated model was then used in a probabilistic mode to conduct a simulation of the effects of field source and plume remediation activities during the period after 1999. This probabilistic simulation considers uncertainties in seven key parameters: the initial source mass and concentration, the relationship between source mass removal and source concentration, the effectiveness of the source remediation, the groundwater velocity, the background plume degradation rate, and the plume treatment effectiveness. The simulation results compare favorably with the observed data collected after 1999, and show the influence of the remediation efforts on the plume.  相似文献   

3.
Long-term monitoring solutions at contaminated sites are necessary to track plume migration and evaluate the performance of remediation efforts. Electrical resistivity imaging (ERI) can potentially provide information about plume dynamics; however, the feasibility and likelihood of success are seldom evaluated before conducting a field study. Coupling flow and transport models with geoelectrical models provide a powerful way to assess the potential effectiveness of an actual ERI field campaign. We present a coupled approach for evaluating the feasibility of monitoring nitrate migration and remediation using 4D time-lapse ERI at a legacy nuclear waste facility. This kilometer-scale study focuses on depths below the water table (∼70 m). A flow and transport model is developed to perform simulations of nitrate migration and removal via a hypothetical pump-and-treat system. A tracer injection is also simulated at the leading edge of the nitrate plume to enhance the conductivity contrast between the native subsurface and the groundwater fluids. Images of absolute bulk conductivity provide limited information concerning plume migration while time-lapse difference images, which remove the static effects of geology, provide more useful information concerning plume dynamics over time. A spatial moment analysis performed on flow and transport and ERI models matches well during the tracer injection; however, inversion regularization smoothing otherwise limits the value in terms of locating the center of mass. We find that the addition of a tracer enables ERI to characterize plume dynamics during pump-and-treat operations, and late-time ERI monitoring provides a conservative estimate of nitrate plume boundaries in this synthetic study.  相似文献   

4.
Methodology for comparing source and plume remediation alternatives   总被引：2，自引：0，他引：2  
Falta RW 《Ground water》2008,46(2):272-285
It is often difficult at contaminated sites to decide whether remediation effort should be focused on the contaminant source, the dissolved plume, or on both zones. The decision process at these sites is hampered by a lack of quantitative tools for comparing remediation alternatives. A new screening-level mass balance approach is developed for simulating the transient effects of simultaneous ground water source and plume remediation. The contaminant source model is based on a power function relationship between source mass and source discharge, and it can consider partial source remediation at any time after the initial release. The source model serves as a time-dependent mass flux boundary condition to a new analytical plume model, where flow is assumed to be one dimensional, with three-dimensional dispersion. The plume model simulates first-order sequential decay and production of several species, and the decay rates and parent/daughter yield coefficients are variable functions of time and distance. This new method allows for flexible simulation of natural attenuation or remediation efforts that enhance plume degradation. The plume remediation effort may be temporary or delayed in time, limited in space, and it may have different chemical effects on different contaminant species in the decay chain.  相似文献   

5.
A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well.  相似文献   

6.
The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.  相似文献   

7.
The performance of cyclodextrin (CD)‐enhanced push‐pull (PP) and line‐drive (LD) approaches to remediation of a site contaminated with a multicomponent dense nonaqueous phase liquid (DNAPL) present in a surficial sandy aquifer was evaluated in this field study. The treatment techniques were compared to each other and to the projected performance of a conventional water‐flushing system. Performance was assessed based on contaminant mass removed per unit volume of extraction solution and per unit time of operation. As expected, the CD‐enhanced LD and PP approaches to remediation were more efficient than conventional flushing with water. Between the two techniques, the PP approach performed 1.5 to 2 times better than the LD approach, particularly for higher DNAPL saturation of the source zone. This result suggests that forcing the flushing solution directly into and through the DNAPL source zone minimized flow bypassing and consequently resulted in a more efficient transfer of contaminant mass between the DNAPL phase and the flushing solution. Nonuniform treatment zone contaminant concentrations and changes in contaminant composition influenced the treatment performances, but these effects were small and still permitted the comparison of successive tests. Although CD was used as the solubility‐enhancing flushing agent in this study, it is likely that the results can be transferred to other chemically enhanced flushing technologies that use, for example, surfactants or alcohols.  相似文献   

8.
Hadley PW  Newell CJ 《Ground water》2012,50(5):669-678
Groundwater remediation technologies are designed, installed, and operated based on the conceptual models of contaminant hydrogeology that are accepted at that time. However, conceptual models of remediation can change as new research, new technologies, and new performance data become available. Over the past few years, results from multiple-site remediation performance studies have shown that achieving drinking water standards (i.e., Maximum Contaminant Levels, MCLs) at contaminated groundwater sites is very difficult. Recent groundwater research has shown that the process of matrix diffusion is one key constraint. New developments, such as mass discharge, orders of magnitude (OoMs), and SMART objectives are now being discussed more frequently by the groundwater remediation community. In this paper, the authors provide their perspectives on the existing "reach MCLs" approach that has historically guided groundwater remediation projects, and advocate a new approach built around the concepts of OoMs and mass discharge.  相似文献   

9.
Site closure for soil vacuum extraction (SVE) application typically requires attainment or specified soil concentration standards based on the premise that mass flux from the vadose zone to ground water not result in levels exceeding maximum contaminant levels (MCLs). Unfortunately, realization of MCLs in ground water may not be attainable at many sites. This results in soil remediation efforts that may be in excess of what is necessary for future protection of ground water and soil remediation goals which often cannot be achieved within a reasonable time period. Soil venting practitioners have attempted to circumvent these problems by basing closure on some predefined percent total mass removal, or an approach to a vapor concentration asymptote. These approaches, however, are subjective and influenced by venting design. We propose an alternative strategy based on evaluation of five components: (1) site characterization, (2) design. (3) performance monitoring, (4) rule-limited vapor transport, and (5) mass flux to and from ground water. Demonstration of closure is dependent on satisfactory assessment of all five components. The focus of this paper is to support mass flux evaluation. We present a plan based on monitoring of three subsurface zones and develop an analytical one-dimensional vertical flux model we term VFLUX. VFLUX is a significant improvement over the well-known numerical one-dimensional model. VLEACH, which is often used for estimation of mass flux to ground water, because it allows for the presence of nonaqueous phase liquids (NAPLs) in soil, degradation, and a lime-dependent boundary condition at the water table inter-face. The time-dependent boundary condition is the center-piece of our mass flux approach because it dynamically links performance of ground water remediation lo SVE closure. Progress or lack of progress in ground water remediation results in either increasingly or decreasingly stringent closure requirements, respectively.  相似文献   

10.
Measurement and interpretation of mass fluxes in favor of concentrations is gaining more and more interest, especially within the framework of the characterization and management of large-scale volatile organic carbon (VOC) groundwater contamination (source zones and plumes). Traditional methods of estimating contaminant fluxes and discharges involve individual measurements/calculations of the Darcy water flux and the contaminant concentrations. However, taken into account the spatially and temporally varying hydrologic conditions in complex, heterogeneous aquifers, higher uncertainty arises from such indirect estimation of contaminant fluxes. Therefore, the potential use of passive sampling devices for the direct measurement of groundwater-related VOC mass fluxes is examined. A review of current passive samplers for the measurement of organic contaminants in water yielded the selection of 18 samplers that were screened for a number of criteria. These criteria are related to the possible application of the sampler for the measurement of VOC mass fluxes in groundwater. This screening study indicates that direct measurement of VOC mass fluxes in groundwater is possible with very few passive samplers. Currently, the passive flux meter (PFM) is the only passive sampler which has proven to effectively measure mass fluxes in near source groundwater. A passive sampler for mass flux measurement in plume zones with regard to long-term monitoring (several months to a year) still needs to be developed or optimized. A passive sampler for long-term monitoring of contaminant mass fluxes in groundwater would be of considerable value in the development of risk-based assessment and management of soil and groundwater pollutions.  相似文献   

11.
The objective of this study was to characterize the behavior of a groundwater contaminant (trichloroethene, TCE) plume after implementation of a source‐containment operation at a site in Arizona. The plume resides in a quasi‐three‐layer system comprising a sand/gravel unit bounded on the top and bottom by relatively thick silty clayey layers. The system was monitored for 60 months beginning at start‐up in 2007 to measure the change in contaminant concentrations within the plume, the change in plume area, the mass of the contaminant removed, and the integrated contaminant mass discharge (CMD). The concentrations of TCE in groundwater pumped from the plume extraction wells have declined significantly over the course of operation, as have concentrations for groundwater sampled from 40 monitoring wells located within the plume. The total CMD associated with operation of the plume extraction wells peaked at 0.23 kg/d, decreased significantly within 1 year, and thereafter began an asymptotic decline to a current value of approximately 0.03 kg/d. Despite an 87% reduction in contaminant mass and a comparable 87% reduction in CMD for the plume, the spatial area encompassed by the plume has decreased by only approximately 50%. This is much less than would be anticipated based on ideal flushing and mass‐removal behavior. Simulations produced with a simplified three‐dimensional (3D) numerical model matched reasonably well to the measured data. The results of the study suggest that permeability heterogeneity, back diffusion, hydraulic factors associated with the specific well field system, and residual discharge from the source zone are all contributing to the observed persistence of the plume, as well as the asymptotic behavior currently observed for mass removal and for the reduction in CMD.  相似文献   

12.
Interactions between lakes and groundwater are of increasing concern for freshwater environmental management but are often poorly characterized. Groundwater inflow to lakes, even at low rates, has proven to be a key in both lake nutrient balances and in determining lake vulnerability to pollution. Although difficult to measure using standard hydrometric methods, significant insight into groundwater–lake interactions has been acquired by studies applying geochemical tracers. However, the use of simple steady‐state, well‐mixed models, and the lack of characterization of lake spatiotemporal variability remain important sources of uncertainty, preventing the characterization of the entire lake hydrological cycle, particularly during ice‐covered periods. In this study, a small groundwater‐connected lake was monitored to determine the annual dynamics of the natural tracers, water stable isotopes and radon‐222, through the implementation of a comprehensive sampling strategy. A multilayer mass balance model was found outperform a well‐mixed, one‐layer model in terms of quantifying groundwater fluxes and their temporal evolution, as well as characterizing vertical differences. Water stable isotopes and radon‐222 were found to provide complementary information on the lake water budget. Radon‐222 has a short response time, and highlights rapid and transient increases in groundwater inflow, but requires a thorough characterization of groundwater radon‐222 activity. Water stable isotopes follow the hydrological cycle of the lake closely and highlight periods when the lake budget is dominated by evaporation versus groundwater inflow, but continuous monitoring of local meteorological parameters is required. Careful compilation of tracer evolution throughout the water column and over the entire year is also very informative. The developed models, which are suitable for detailed, site‐specific studies, allow the quantification of groundwater inflow and internal dynamics during both ice‐free and ice‐covered periods, providing an improved tool for understanding the annual water cycle of lakes.  相似文献   

13.
Remediation of subsurface contamination requires an understanding of the contaminant (history, source location, plume extent and concentration, etc.), and, knowledge of the spatial distribution of hydraulic conductivity (K) that governs groundwater flow and solute transport. Many methods exist for characterizing K heterogeneity, but most if not all methods require the collection of a large number of small‐scale data and its interpolation. In this study, we conduct a hydraulic tomography survey at a highly heterogeneous glaciofluvial deposit at the North Campus Research Site (NCRS) located at the University of Waterloo, Waterloo, Ontario, Canada to sequentially interpret four pumping tests using the steady‐state form of the Sequential Successive Linear Estimator (SSLE) ( Yeh and Liu 2000 ). The resulting three‐dimensional (3D) K distribution (or K‐tomogram) is compared against: ( 1 ) K distributions obtained through the inverse modeling of individual pumping tests using SSLE, and ( 2 ) effective hydraulic conductivity (Keff) estimates obtained by automatically calibrating a groundwater flow model while treating the medium to be homogeneous. Such a Keff is often used for designing remediation operations, and thus is used as the basis for comparison with the K‐tomogram. Our results clearly show that hydraulic tomography is superior to the inversions of single pumping tests or Keff estimates. This is particularly significant for contaminated sites where an accurate representation of the flow field is critical for simulating contaminant transport and injection of chemical and biological agents used for active remediation of contaminant source zones and plumes.  相似文献   

14.
Exposure from groundwater contamination to aquatic receptors residing in receiving surface water is dependent upon the rate of contaminated groundwater discharge. Characterization of groundwater fluxes is challenging, especially in coastal environments where tidal fluctuations result in transient groundwater flows towards these receptors. This can also be further complicated by the high spatial heterogeneity of subsurface deposits enhanced by anthropogenic influences such as the mixing of natural sediments and backfill materials, the presence of subsurface built structures such as sheet pile walls or even occurrence of other sources of contaminant discharge. In this study, the finite volume point dilution method (FVPDM) was successfully used to characterize highly transient groundwater flows and contaminant mass fluxes within a coastal groundwater flow system influenced by marked tides. FVPDM tests were undertaken continuously for more than 48 h at six groundwater monitoring wells, in order to evaluate groundwater flow dynamics during several tide cycles. Contaminant concentrations were measured simultaneously which allowed calculating contaminant mass fluxes. The study highlighted the importance of the aquifer heterogeneity, with groundwater fluxes ranging from 10−7 to 10−3 m/s. Groundwater flux monitoring enabled a significant refinement of the conceptual site model, including the fact that inversion of groundwater fluxes was not observed at high tide. Results indicated that contaminant mass fluxes were particularly higher at a specific monitoring well, by more than three orders of magnitude, than at other wells of the investigated aquifer. This study provided crucial information for optimizing further field investigations and risk mitigation measures.  相似文献   

15.
Groundwater is a primary source of drinking water worldwide, but excess nutrients and emerging contaminants could compromise groundwater quality and limit its usage as a drinking water source. As such contaminants become increasingly prevalent in the biosphere, a fundamental understanding of their fate and transport in groundwater systems is necessary to implement successful remediation strategies. The dynamics of surface water-groundwater (hyporheic) exchange within a glacial, buried-valley aquifer system are examined in the context of their implications for the transport of nutrients and contaminants in riparian sediments. High conductivity facies act as preferential flow pathways which enhance nutrient and contaminant delivery, especially during storm events, but transport throughout the aquifer also depends on subsurface sedimentary architecture (e.g. interbedded high and low conductivity facies). Temperature and specific conductance measurements indicate extensive hyporheic mixing close to the river channel, but surface water influence was also observed far from the stream-aquifer interface. Measurements of river stage and hydraulic head indicate that significant flows during storms (i.e., hot moments) alter groundwater flow patterns, even between consecutive storm events, as riverbed conductivity and, more importantly, the hydraulic connectivity between the river and aquifer change. Given the similar mass transport characteristics among buried-valley aquifers, these findings are likely representative of glacial aquifer systems worldwide. Our results suggest that water resources management decisions based on average (base) flow conditions may inaccurately represent the system being evaluated, and could reduce the effectiveness of remediation strategies for nutrients and emerging contaminants.  相似文献   

16.
The passive flux meter (PFM) is a permeable down-hole device designed to measure the magnitudes of horizontal groundwater specific discharge and contaminant mass flux in porous media. By means of a geometrical analysis of resident tracer transport inside a PFM, this paper introduces two new PFM designs capable of measuring both the direction and magnitude of horizontal water and contaminant fluxes. One design relies on the detection of a single resident tracer over multiple domains within the PFM cross section to determine the magnitude and direction of water flux. The second PFM configuration uses the detected loss of multiple resident tracers in different sectors of the PFM cross section to generate the same characterization of water flux. Both designs rely on the assumption of linear, instantaneous and reversible tracer sorption.  相似文献   

17.
The groundwater remediation field has been changing constantly since it first emerged in the 1970s. The remediation field has evolved from a dissolved‐phase centric conceptual model to a DNAPL‐dominated one, which is now being questioned due to a renewed appreciation of matrix diffusion effects on remediation. Detailed observations about contaminant transport have emerged from the remediation field, and challenge the validity of one of the mainstays of the groundwater solute transport modeling world: the concept of mechanical dispersion (Payne et al. 2008). We review and discuss how a new conceptual model of contaminant transport based on diffusion (the usurper) may topple the well‐established position of mechanical dispersion (the status quo) that is commonly used in almost every groundwater contaminant transport model, and evaluate the status of existing models and modeling studies that were conducted using advection‐dispersion models.  相似文献   

18.
Most established methods to characterize aquifer structure and hydraulic conductivities of hydrostratigraphical units are not capable of delivering sufficient information in the spatial resolution that is desired for sophisticated numerical contaminant transport modeling and adapted remediation design. With hydraulic investigation methods based on the direct-push (DP) technology such as DP slug tests, DP injection logging, and the hydraulic profiling tool, it is possible to rapidly delineate hydrogeological structures and estimate their hydraulic conductivity in shallow unconsolidated aquifers without the need for wells. A combined application of these tools was used for the investigation of a contaminated German refinery site and for the setup of hydraulic aquifer models. The quality of DP investigation and the models was evaluated by comparisons of tracer transport simulations using these models and measured breakthroughs of two natural gradient tracer tests. Model scenarios considering the information of all tools together showed good reproduction of the measured breakthroughs, indicating the suitability of the approach and a minor impact of potential technical limitations. Using the DP slug tests alone yielded significantly higher deviations for the determined hydraulic conductivities compared to considering two or three of the tools. Realistic aquifer models developed on basis of such combined DP investigation approaches can help optimize remediation concepts or identify flow regimes for aquifers with a complex structure.  相似文献   

19.
Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, represents an environmental challenge with global implications. Mass-transfer limitations due to rate-limited dissolution can lead to long-term aquifer persistence for even small volumetric fractions. The identification of DNAPL source zones located beneath the water table is critical to ultimately achieve site remediation and aquifer restoration. This paper provides a comparison of the advantages and disadvantages of many of the methods being used for detecting and delineating DNAPL contaminant source zones. The objective is to determine which options are best to pursue based on site characteristics, method performance, and method costs. DNAPL characterization methods are grouped into approaches, which include site preparation, characterization, and data-processing activities necessary to design an effective remediation system. We compare the different approaches based on the level of chemical and hydrogeologic resolution, and the need for additional data requirements. Our findings can be used to assist with selection of appropriate site remediation management options.  相似文献   

20.
In situ treatment usually requires contact between an injected reagent and target contaminant to realize mass removal from source zones and plumes. Despite significant site characterization efforts, unknown heterogeneities that exist at all spatial scales often hinder prediction of the distribution of injected reagents. To provide remediation practitioners with additional information on the distribution of injected reagents, a prototype real-time monitoring probe was designed and tested. This new probe comprises a two-wire resistivity circuit, hence the designation dipole resistivity probe (DRP). The low-cost DRPs were built to be attached as arrays to a central stalk, and installed by direct-push techniques. An installed network of multilevel DRPs can be used to detect the arrival, persistence, and relative concentration of a high-conductivity reagent solution in real-time across a zone of interest. Static cell and sandbox experiments were conducted to test and refine the DRP design before field testing. Static cell experimental results indicated that the DRP was sensitive to solution electrical conductivity (EC), and that the probe response and EC relationship is nonlinear and dependent on the fixed resistor used. The choice of fixed resistor can be adjusted to optimize the DRP response over a critical EC range of interest. Under dynamic conditions in the sandbox, the DRP was able to reproduce breakthrough profiles collected by a commercial EC sensor. The results from two field studies demonstrated the utility of the DRPs to generate information regarding the arrival and persistence of reagents in an efficient and cost-effective manner. The first field study used a network of DRPs to monitor the land application of a sodium sulfate solution, and the second field study employed DRPs to monitor the distribution and longevity of a persulfate solution. While additional field testing is warranted, the results presented are encouraging and suggest that this low-cost system can be used to improve our understanding of the detailed migration of injected reagents in treatment zones.  相似文献   

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