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1.
本文描述了花岗岩中榍石的矿物学特征,对其红外光谱与金红石红外光谱对比研究,获得某些谱带的归属,并给出了群论分析;对其穆斯堡尔谱Fe~(3-)的两组对线的归属从结构、成分上进行了讨论.  相似文献   

2.
大别山区石英质玉宝石矿物学特征研究   总被引:1,自引:0,他引:1  
大别山区石英质玉属新近发现的一种石英质玉(简称"大别山玉"),具色彩绚丽、质地细腻温润等特点。利用偏光显微镜、扫描电子显微镜、X射线粉末衍射、化学分析、红外光谱分析等方法,重点对"大别山玉"的矿物组成、化学成分、物理光学性质、微结构、红外吸收光谱等特征进行研究。结果表明,"大别山玉"具较典型的微粒-细粒结构,主要矿物为石英,含少量的绢云母、绿泥石、萤石、黄铁矿及其它粘土矿物等次要矿物,实属石英质玉;其化学成分相对较纯,主成分为SiO2,含少量的Al2O3,CaO,MgO,Fe2O3,FeO,K2O等;其红外反射光谱以Si—O非对称伸缩振动致特征的1177,1104 cm-1谱带、Si—O—Si对称伸缩振动致800,781cm-1分裂谱带以及由Si—O弯曲振动致492 cm-1较强谱带和542 cm-1弱谱带为特征。同时,还对"大别山玉"的结晶度及水的赋存状态一并给予了探讨。  相似文献   

3.
研究了不同程度变生褐帘石及其热处理样品的红外光谱变化特征,提出其变生的红外光谱定量标志──变生反M=■(6-N)(N为750-200Cm-1范围的谱带数)。分析了变生作用中褐帘石晶格内离子基团的变化,结合晶体结构分析,提出褐帘石红外光谱中450、510cm-1附近的两个谱带分别系结构内孤立硅氧四面体SiO4及群体硅氧四面体Si2O7的弯曲振动谱带。  相似文献   

4.
福建马坑铁矿中角闪石的谱学特征及成因意义   总被引:1,自引:0,他引:1  
文章研究了马坑铁矿中角闪石的红外光谱、穆斯堡尔谱及热谱特征,特别是阐述了角闪石的(OH)伸缩振动红外光谱的A、B、C、D振动带随Fe~(2+)和Mg含量变化而产生的规律性变化。探索了谱学参数与Fe_2O_3、Al_2O_3、FeO、MgO、MnO的关系。应用(OH)红外光谱的四个振动带的相对强度和穆斯堡尔谱参数计算了Fe~(2+)和Mg在M_1、M_2、M_3晶位中的分配及占位顺序,进而讨论了角闪石的成因。  相似文献   

5.
界河金矿绿泥石化及其地质意义   总被引:1,自引:0,他引:1  
李莉  齐金忠 《黄金地质》1995,1(2):72-75
界河金矿产于燕山期郭家岭花岗闪长岩中,围岩蚀变发育,并以较强的绿泥石化为特征,通过对绿泥石形态,成分,红外光谱,晶胞参数,热发光和穆斯堡尔谱等特征进行分析,进一步探讨了绿泥石化与金矿化的关系。  相似文献   

6.
绿泥石化是花岗岩型铀矿床蚀变带广泛发育的围岩蚀变类型之一.在酸性热液构造蚀变带中,与赤铁矿化、硅化、水云母化同时产出;在碱性热液构造蚀变带中,与赤铁矿化同时出现,有时还存在方解石化.因此,绿泥石化应属于重要的铀矿找矿线索.为了选择最佳铀矿勘查遥感谱段(童庆禧,1990),为了利用成像光谱技术提取铀矿蚀变带混合光谱所含的蚀变矿物信息,开展高光谱遥感铀矿蚀变带填图,需要掌握铀矿蚀变带端元光谱.本文针对铀矿床绿泥石化蚀变开展矿物学分类研究,提取和分析其诊断性光谱特征.  相似文献   

7.
查福标  谢先德 《矿物学报》1993,13(3):230-236
本文通过观测在不同温度下加热过的硼酸盐矿物的红外光谱,并与喇曼光谱结果进行比较,讨论了红外光谱谱带的归属。结果表明,通过观测不同温度下加热过的样品的谱带特征有助于谱带的归属。  相似文献   

8.
广西阳朔长期出产宝石级磷氯铅矿,迄今未见其矿物学和振动光谱的研究报道。采用能量色散X射线荧光光谱、X射线粉末晶体衍射、红外光谱和拉曼光谱分析了14颗阳朔磷氯铅矿。该矿物为半透明的黄绿色六方柱,相对密度为6.484~7.310,白色条痕,硬度为4,化学成分以铅、磷和氯为主。红外光谱在1 060~920 cm-1和580~540 cm-1区域观察到属于PO43-的伸缩和弯曲振动带,平行和垂直光轴的谱带差异明显;部分样品观察到AsO43-振动弱带,说明结构中有少量PO43-被替代。拉曼光谱观察到916/940 cm-1属于PO43-伸缩振动强带、位于390/414/542/572 cm-1系列弯曲振动带和160~262 cm-1晶格振动带。这些谱带随着测试方向不同而变化,反映出结构中的PO4  相似文献   

9.
“绿龙晶”(俗称)为一种产自俄罗斯的绿泥石玉,目前普遍认为其矿物组成为斜绿泥石。本次研究用“绿龙晶”样品具有独特的深绿色至灰绿色,呈鳞片状至叶片状结构,密度为2.61~2.62g/cm^3,折射率约为1.57,摩氏硬度约为2.5,其主要矿物组成为绿泥石的亚种叶绿泥石。通过在显微镜下薄片观察发现,叶绿泥石具有靛蓝色、锈褐色和紫色异常干涉色,近平行消光。电子探针结果表明,该“绿龙晶”样品的主要化学成分为SiO2和MgO,其次为Al2O3和FeOT;计算其晶体化学式并根据Fe^2+/R^2+和Si的原子数量进行投影,恰好落于叶绿泥石的区域范围。在其X射线衍射图谱中出现了叶绿泥石的14.5320,7.2156,4.7897,3.5972A处的特征衍射峰;其红外光谱中,高频区3637,3465cm^-1处的吸收谱带、中频区1000cm^-1左右分裂的1048,1001,967cm^-1吸收峰和低频区444cm^-1处的强吸收谱带显示了叶绿泥石的红外光谱特征。  相似文献   

10.
近年来红外光谱技术作为一种绿色、快速、无损、精确探测矿物的技术手段而倍受关注,针对斑岩型矿床蚀变矿物高度叠加、蚀变分带界线不明显、细粒蚀变矿物多、黏土蚀变矿物多等特征,该技术在蚀变矿物识别和勘探信息解读等方面优势突出。本文应用红外光谱技术对云南普朗斑岩铜矿区钻孔ZK1801岩心进行矿物识别和蚀变分带划分的研究,识别出钾硅酸盐化带、绿帘石-绿泥石化带、绿泥石-伊利石化带、石英-伊利石化带和泥化带。研究表明:普朗铜矿整个钻孔的蚀变矿物主要有石英、钾长石、绢云母、绿泥石、绿帘石、高岭石、蒙脱石、伊利石等;根据矿化特征,发现铜矿体广泛赋存在钾硅酸盐化带和绿帘石-绿泥石化带中,与矿化关系密切的蚀变矿物"石英+钾长石+绢云母"和"绿帘石+绿泥石",可以作为普朗矿床勘查的标型蚀变矿物组合;研究区广泛发育的绢云母Al—OH波长随钻孔深度增加而逐渐从2210~2205nm减小到2202~2198nm, Al—OH波长2210~2205nm(长波绢云母)与矿化关系密切,可以作为普朗矿床勘查的指示信息。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
15.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)  相似文献   

17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,  相似文献   

18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)  相似文献   

19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-  相似文献   

20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with  相似文献   

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