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1.
硼具有两种稳定同位素10B和11B,其在自然界的丰度分别是19.90%和80.10%。自然界硼同位素组成变化很大, δ11B变化可达90‰以上(－30‰～＋60‰)。硼同位素的分析精度优于0.2‰,因此被广泛应用于多种地质过程的示踪研究。近年来,硼元素的提取、分离纯化和仪器测定技术均取得了可喜的进展,分析精度不断提高,为硼同位素地球化学研究奠定了良好的基础。本文从样品分解、化学分离和仪器测定等方面对硼同位素分析测试方法进行了归纳总结。 相似文献
2.
An Evaluation of Methods for the Chemical Decomposition of Geological Materials for Trace Element Determination using ICP-MS 总被引：3，自引：0，他引：3
Zongshou Yu Philip Robinson Peter McGoldrick 《Geostandards and Geoanalytical Research》2001,25(2-3):199-217
Complete dissolution is essential to obtain accurate analytical results using ICP-MS. In this study, decomposition techniques (i.e. acid digestions using Savillex Teflon vials, a high pressure digestion system and microwave oven, a combined lithium tetraborate fusion - HF/HNO3 acid decomposition and sodium peroxide sinter) for the total dissolution of different types of geological reference materials have been investigated. Savillex Teflon vial HF/HNO3 digestion is effective for basaltic samples. The high pressure HF/HClO4 digestion (PicoTrace TC-805 digestion system, Bovenden, Germany) allows dissolution of basalts and ironstones. Granites and magnetite-rich samples can be dissolved using a high pressure HF/H2 SO4 method. Geological samples cannot be effectively attacked by microwave acid digestion. A combined lithium tetraborate fusion - HF/HNO3 acid digestion method allows complete dissolution of many different types of geological materials; however, this method precludes the determination of volatile elements due to the high fusion temperature (1000 °C). A sodium peroxide sinter method at 480 °C has the potential for the rapid determination of Y, Sc and REE in different types of geological materials. However, the lack of ultra-pure reagents precludes the use of lithium tetraborate fusion and sodium peroxide sinter methods for the measurement of geological samples with low trace element abundances. 相似文献
3.
《Chemical Geology》2002,182(2-4):323-334
An optimized procedure for the separation of boron from natural river samples and an improved mass spectrometry determination of boron isotopic ratio are presented. The chemical procedure, based on the use of the boron-specific resin Amberlite IRA 743, is especially efficient in separating boron from natural organic matter-rich samples like river waters.The properties of Amberlite IRA 743 have been investigated. The two factors important in determining the boron affinity for the resin are: the pH value and the ionic strength of the solution from which B is to be extracted. A logarithmic relationship between B partition coefficients and pH values is found. High ionic strength significantly lowers the fixation of B onto the Amberlite resin.The knowledge of the factors controlling the affinity of the resin Amberlite IRA 743 for boron enables us to design a simple and miniaturized chemical separation procedure characterized by (i) three chromatographic steps using, respectively, 50, 10 and 3 μl of resin, (ii) no evaporation step between each column, and (iii) final separation of boron from residual organic matter by sublimation of boric acid at 75 °C.Boron isotopic ratios are measured using an improved cesium metaborate technique, with graphite and mannitol. Adequate loading conditions enable us to obtain typical signal intensities of 5×10−12 A for 250 ng of boron. No in-run isotopic fractionation is observed, the external reproducibility for standards processed through the entire chemical procedure, as well as for samples, corresponds to 0.35‰ (±2σ). According to this precision, a slight, but reproducible isotopic fractionation of 0.4‰ is observed for standards processed through the entire chemical procedure whose origin is discussed, but is still unclear. 相似文献
4.
Experimental and analytical procedures devised for measurement of rare earth element (REE) abundances using a secondary ion
mass spectrometer (ion microprobe) are described. This approach is more versatile than the conventional techniques such as
neutron activation analysis and isotope dilution mass spectrometry by virtue of its high spatial resolution that allows determination
of REE abundances in small domains (10-20 micron) within individual mineral phases. The ion microprobe measurements are performed
at a low mass-resolving power adopting the energy-filtering technique (Zinner and Crozaz 1986) for removal and suppression
of unresolved complex molecular interferences in the REE masses of interest. Synthetic standards are used for determining
various instrument specific parameters needed in the data deconvolution procedure adopted for obtaining REE abundances. Results
obtained from analysis of standards show that our ion microprobe may be used for determining REE abundances down to ppm range
with uncertainties of ∼ 10 to 15%. Abundances of rare earth and several other refractory trace elements in a set of early
solar system objects isolated from two primitive carbonaceous chondrites were determined using the procedures devised by us.
The results suggest that some of these objects could be high temperature nebular condensates, while others are products of
melting and recrystallization of precursor nebular solids in a high temperature environment. 相似文献
5.
灰岩样品的主要成分为碳酸钙,而镁、钾、钠、铝、钛、铁、锰的含量非常低,测试的灵敏度要求很高。该文采用一次溶矿电感耦合等离子体法直接测试灰岩中的镁、钾、钠、铝、钛、铁、锰。实验表明：在5％的盐酸介质中测试镁、钾、钠、铝、钛、铁、锰能取得很好的效果。通过测试国家标准样品,与国家标准值相比较,分析结果基本一致,准确度和精密度均令人满意,镁、钾、钠、铝、钛、铁、锰元素的相对标准偏差≤0．07％。钙元素的标准偏差≤0．15％。 相似文献
6.
Kateryna Klochko George D. Cody Przemyslaw Dera 《Geochimica et cosmochimica acta》2009,73(7):1890-368
Understanding the partitioning of aqueous boron species into marine carbonates is critical for constraining the boron isotope system for use as a marine pH proxy. Previous studies have assumed that boron was incorporated into carbonate through the preferential uptake of tetrahedral borate B(OH)4−. In this study we revisit this assumption through a detailed solid state 11B magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopic study of boron speciation in biogenic and hydrothermal carbonates. Our new results contrast with those of the only previous NMR study of carbonates insofar as we observe both trigonal and tetrahedral coordinated boron in almost equal abundances in our biogenic calcite and aragonite samples. In addition, we observe no strict dependency of boron coordination on carbonate crystal structure. These NMR observations coupled with our earlier re-evaluation of the magnitude of boron isotope fractionation between aqueous species suggest that controls on boron isotope composition in marine carbonates, and hence the pH proxy, are more complex that previously suggested. 相似文献
7.
Horst R. Marschall Rainer Altherr Katalin Gméling Zsolt Kasztovszky 《Mineralogy and Petrology》2009,95(3-4):291-302
High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H2O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B?/Be and Cl?/Be ratios correlate with H2O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B?/Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl?/Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H2O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies. 相似文献
8.
本文初步建立了一种用硼特效树脂和阴、阳混和离子交换树脂相结合进行有孔虫中硼的分离和同位素测定的方法。该方法适用低硼含量 (纳克级 )的微体古生物中的硼的分离和同位素测定 ,分离过程不产生同位素分馏 ,满足了正热电离质谱法测定硼同位素的要求。 相似文献
9.
Mercury inhomogeneity was found between bottles of the same standard for each of the six U.S.G.S. rock standards tested. Variations between bottles amounted to at least a factor of 2 for four of the six standards. Caution is suggested when using these standards as mercury accuracy checks and as estimators of mercury geochemical abundances or cycles. 相似文献
10.
The non-LTE sodium abundances of 100 stars with metallicities ?3<[Fe/H]<0.3 are determined using high-dispersion spectra with high signal-to-noise ratios. The sodium abundances [Na/Fe] obtained are close to the solar abundance and display a smaller scatter than values published previously. Giants (logg<3.8) with [Fe/H]g>3.8) with metallicities ?2<[Fe/H]相似文献
11.
近年来,随着核探测与分析技术的日趋成熟,使复杂γ谱的获取、解析达到了在线测量的要求,从而使在线PGNAA(中子活化瞬发γ射线分析)技术获得了飞速的发展。它可对一些工业生产过程中的全物料进行在线测量,其分析精度、可靠性等皆能满足在线元素含量分析的需要,因而显示出巨大的发展潜力和广阔的市场前景。这里介绍了基于PGNAA技术的在线分析系统的基本原理、组成和发展,并概述了它在水泥、煤炭等行业的应用情况。 相似文献
12.
This brief contribution presents new boron isotopic data for a set of proposed borosilicate reference minerals, most of which are described in the companion paper by Dyar et al.2001 . The results for a variety of minerals (tourmalines, danburite, prismatine, serendibite, ferroaxinite and a Li mica) show that it is generally possible to reproduce the 11 B/10 B ratio within ± 0.5 per mil with replicate chemistry and mass spectrometry over long time spans. Because the accuracy of boron isotopic analysis is commonly determined by reference to secondary standards, it is suggested that some of the samples used in this study be adopted for interlaboratory comparisons and for quality control on boron isotopic analyses produced by a variety of analytical methods. 相似文献
13.
14.
The abundances of 19 chemical elements in the atmospheres of five stars belonging to three globular clusters have been determined by applying the model-atmospheremethod to 430.0–790.0 nm spectra obtained with the échelle spectrometer of the 6-m telescope of the Special Astrophysical Observatory. The abundances of silicon, calcium, iron-peak elements, copper, zinc, and neutron-capture elements follow the abundance patterns for halo stars. The abundance of sodium in M 10 giants provides evidence that different mixing mechanisms operate in halo and cluster stars or that light elements are enriched in different ways in the pre-stellar matter from which some globular clusters and halo stars were formed. 相似文献
15.
C. J. L. Wilson 《Contributions to Mineralogy and Petrology》1977,65(2):171-181
Fission and particle track methods have been used to study uranium and lithium/boron distributions in muscovite and biotite schists. The results show that uranium and lithium/boron have a non-uniform distribution within grain boundaries and strained crystal lattice structures of the micas. Uranium redistribution is attributed to; (1) hydrothermal or metamorphic fluids that have redistributed the uranium together with lithium/boron by diffusion and infiltration through planar and lattice defects within the mica aggregate, (2) meteoric fluids that postdate the hydrothermal or metamorphic fluid and are also responsible for the introduction of iron and manganese concentrations within planar defect structures. 相似文献
16.
Ten U.S. Geological Survey rock standards have been analyzed for trace elements by instrumental neutron activation using a low flux reactor and Ge detectors. Results compare favorably with the current working values for all elements except Mo. REE values that have been determined are generally slightly lower than accepted values. Data obtained for rocks that have very low trace element concentrations (e.g., BIR-1) will aid in refining the working values for these standards. 相似文献
17.
Twenty one basaltic flows of known mineralogical and chemical composition from the Deccan of western India have been analyzed for nine rare-earth elements (REE), together with Hf, Ta and Th by instrumental neutron activation methods. The flows, which are tholeiites and transitional alkali basalts, are relatively enriched in the Light REE and have total REE abundances systematically related to their bulk petrochemistry. The results are compared with REE abundances of basalts from other provinces. 相似文献
18.
Boron isotope systematics in large rivers: implications for the marine boron budget and paleo-pH reconstruction over the Cenozoic 总被引：5，自引：0，他引：5
The chemical composition of the oceans and long-term climate changes are believed to be linked. Reconstruction of seawater pH evolution is desirable as pH may be related to atmospheric pCO2, and hence to climate evolution. Boron isotopes in oceanic carbonates have been suggested to be a proxy for oceanic paleo-pH reconstruction. Nevertheless, the calculation of paleo-pH values over geological periods requires a precise knowledge of the boron isotopic composition of the oceans when calcite precipitated. We present the systematics of boron isotopic composition of the world's main rivers. We deduce a continental boron flux to the oceans of 38×1010 gB/year with a mean isotopic composition of +10‰. These results lead to a balanced boron budget in the oceans and allow the development of a model for the marine boron secular evolution over the past 100 Myr. It is shown that the oceanic boron cycle is mainly controlled by the boron continental discharge and the boron uptake from the oceans during low temperature alteration of oceanic crust. However, the recent important increase of the clastic sediment supply, linked to the Himalayan erosion, impacts the oceanic boron budget by enhancing significantly the boron uptake by adsorption on sediments. We predict a boron isotopic composition in the oceans lower during the Cenozoic and slightly higher during the Cretaceous than today. The modelled values for the marine boron isotopes follow the variations of boron isotopes in carbonates over the Cenozoic era provided by previous studies, suggesting that the variations of the seawater pH may not have been important on this time scale. If this is the case, it involves that buffering mechanisms occur in the oceans to maintain seawater pH at a roughly constant value against past atmospheric pCO2 variations. 相似文献
19.
Toshihiko Yajima Hideo Higuchi Hiroshi Nagasawa 《Contributions to Mineralogy and Petrology》1972,35(3):235-244
The abundances of rare earth elements in 5 each of aphyric volcanic rocks of pigeonitic and hypersthenic rock series from Izu-Hakone region have been determined by neutron activation analysis. Pigeonitic rock series show rare earth patterns with relative depletion of lighter rare earths (low lanthanum type) and large increase in rare earth abundances with differentiation. Hypersthenic rock series show higher lanthanum abundances (high lanthanum type) compared with pigeonitic rock series. The differences in rare earth patterns between two rock series are compatible with the theory of independent magmatic generation of these two series. Variation of rare earth patterns in both series have been examined by a model of magmatic differentiation based on the observed rare earth partition coefficients. 相似文献
20.
Hydrochemical characteristics and groundwater quality assessment in Tirupur Region, Coimbatore District, Tamil Nadu, India 总被引：3，自引：0，他引：3
Groundwater samples from 62 locations have been collected from Tirupur region viz. Avinashi, Tirupur and Palladam taluks of
Coimbatore District. The extensive agricultural industrial activities and urbanization resulted in the contamination of the
aquifer. To study the contamination of groundwater, water samples were collected in an area of 180 km2 and analysed for major cations and anions. Most of the locations are contaminated by higher concentration of EC, TDS, K and
NO3. Major hydro chemical facies were identified using Piper trilinear diagram. Based on US salinity diagram, most of the samples
fall in the field of C3S1, indicating high salinity and low sodium water, which can be used for almost all types of soil with
little danger of exchangeable sodium. Majority of the samples are not suitable for domestic purposes and far from drinking
water standards. However, PI values indicates that groundwater is suitable for irrigation. 相似文献