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1.
At present, there is growing interest in using low cost, commercially available materials for the adsorption of heavy metals. The major advantages of adsorption technologies are its effectiveness in reducing the concentration of heavy metal ions to very low levels and the use of inexpensive adsorbent materials. In this review, agricultural and forest waste adsorbents were used to remove Pb2+ ions in wastewater treatment, and their technical feasibilities were reviewed in studies mainly from 2000 to 2010. They all were compared with each other by metal binding capacities, metal removal performances, sorbent dose, optimum pH, temperature, initial concentration and contact time. Although commercial activated carbon is widely used in wastewater treatment applications, it has high costs. The use of agricultural by-products as adsorbent material to purify heavy metal contaminated water has become increasingly popular through the past decade because they are less expensive, biodegradable, abundant and efficient. Instead of activated carbon, this study was focused on the inexpensive materials such as agricultural and forest waste. It was shown that these alternative adsorbents had sufficient binding capacity to remove Pb2+ ions from wastewater.  相似文献   

2.
Treatment options for wastewater effluents from pharmaceutical companies   总被引：4，自引：2，他引：2  
In recent years, concerns about the occurrence and fate of active pharmaceutical ingredients, solvents, intermediates and raw materials that could be present in water and wastewater including pharmaceutical industry wastewater has gained increasing attention. Traditional wastewater treatment methods, such as activated sludge, are not sufficient for the complete removal of active pharmaceutical ingredients and other wastewater constituents from these waters. As a result, complementary treatment methods such as membrane filtration, reverse osmosis and activated carbon are often used in conjunction with the traditional methods for treatment of industrial wastewater. Most of the literature published to date has been on the treatment of municipal wastewater. However, there is a growing body of research that looks at the presence of active pharmaceutical ingredients in industrial wastewater, the treatment of these wastewaters and the removal rates. This article, reviews these treatment methods and includes both traditional methods and advanced oxidation processes. The paper concludes by showing that the problem of pharmaceuticals in wastewaters cannot be solved merely by adopting end of pipe measures. At source measures, such as replacement of critical chemicals, reduction in raw material consumption should continue to be pursued as the top priority.  相似文献   

3.
Authorities have been applying very strict regulations for the treatment of industrial wastewater recently because of the threatening level of the environmental pollution faced. Industrial wastewater containing heavy metals is a threat to the public health because of the accumulation of the heavy metals in the aquatic life which is transferred to human bodies through the food chain. Therefore, recently, researchers have been oriented toward the practical use of adsorbents for the treatment of wastewater polluted by heavy metals. The aim of this research was to determine the retention capacity of compost for copper, zinc, nickel and chromium. For this purpose, experiments in batch-mixing reactors with initial metal concentrations ranging from 100 to 1,000 mg/l were carried. It was also observed that compost could repeatedly be used in metal sorption processes. The experiments conducted indicated that compost has high retention capacities for copper, zinc and nickel, but not for chromium. Thus, compost has been approved as a potential sorbent for copper, zinc and nickel and may find place in industrial applications. Thus, solid waste which is another source of significant environmental pollution will be reduced by being converted into a beneficial product compost.  相似文献   

4.
In most countries of the world, groundwater and surface water are at a serious risk of pollution due to chemicals used in agricultural activities. The present study examined whether such a risk exists in Eskipazar, Turkey and the surrounding area, which covers a surface area of 696 km2. Nitrate pollution (NO3) was observed in waters discharging from the Örencik Formation, consisting of loose conglomerate, sandstone, mudstone, siltstone, and claystone levels; from the Yörük member of the Örencik Formation consisting of limestone, from areas where the Örencik Formation and Yörük member are located together, and from alluvium. Agricultural is practiced in these areas, and the waters discharging from these formations are used as drinking water and for domestic purposes. In particular, periodically varying levels of pollutants, such as B, Pb, Hg, Se were detected in wells drilled in Örencik Formation featuring a high NO3 concentration. The concentrations of S, Cr, Mn, Fe, Cu, Zn, Ga, Br, Sr, Y, I, Ba, and U in these waters are also slightly higher than other cold waters in the study area. In addition to the NO3 pollution, high levels of Ca and SO4 pollution was observed at a well drilled in alluvium. In addition, some trace element concentrations identified in the wells drilled in the Örencik Formation were higher than the average values at geothermal and/or mineral springs in the study area. The study area has an adequate sewage system and has no sources of pollution, such as mineralization, industrial center, waste disposal area, etc. Therefore, it is believed that the main causes of NO3 and trace element pollution are fertilizers and pesticides used in agricultural activities. Water–rock interaction, usage period of fertilizers and pesticides, amount of precipitation, groundwater level, usage of elements by plants, mobility of elements, pH value of the environment, redox potential, adsorption/desorption, biochemical processes, etc. are thought to be the causes of the periodical variation of some trace element concentrations observed in these waters.  相似文献   

5.
水环境污染的修复技术   总被引：8，自引：0，他引：8  
朱宛华 《地学前缘》2001,8(1):143-150
由于人口增加 ,经济建设发展 ,人民生活水平提高 ,需水量也日益增长。中国水资源紧缺 ,而水污染又加重了水资源危机。水资源及水污染的修复技术的探讨有利于改善人类的生存环境。文中叙述了中国水资源紧缺、地下水超采引起的环境地质灾害 ,提倡节约用水 ,降低万元产值耗水量 ,提高单位水资源的投入产出率 ,开发节水型农业体系。建议以流域为单位 ,实行统一管理调配 ,利用地下水开采所腾出库容 ,拦蓄洪水及将处理后的污水回灌地下 ,以减少灾害 ,增加水资源量。文中还综述了地面水污染、水质富营养化、海水古咸水入侵 ,酸雨影响地下水水质及垃圾堆放场下淋滤液对地下水的污染 ;探讨了用絮凝沉淀、好氧厌氧生物处理工艺、脱氮除磷工艺、膜分离技术及高浓度有机有毒废水等在水污染治理方面的修复技术 ;探讨了对地下水中病原微生物、重金属离子、溶解有机物、硬度、三氮的截、坝、投、抽、排等的修重技术。  相似文献   

6.
The method of principal component analysis was applied to systematical research on the soil multi-media environment, including soil, surface water, ground water, waterbody sediment and agricultural crops, as well as pollution-inducing wastewater, mullock (or waste ore) and slag in the periphery of a large-sized Pb-Zn mining and smelting plant in a karst area of Guangxi Zhuang Autonomous Region. The results revealed that soils in the area studied have been heavily polluted by Cd, Zn, Pb and Hg, and the levels of these metals in the samples of agricultural crop greatly exceed the standards. The above-mentioned pollutants exist in all soil-multi-media environments. The mullock, slag, wastewater, surface water, ground water, soil, and agricultural crops constitute a composite ecological chain. Therefore, the improper disposal of mullock and slag, and the use of polluted wastewater for agricultural irrigation are the main causes of soil pollution. Heavy metals in the soil have three transition progresses: point (improved soil with slag, ground water inflow plot), linear (river transition) and non-point transition (regional pollution by slag) patterns, and the tailing yard is the most important locus for heavy metals to release into the environment.  相似文献   

7.
湖南水口山及周边是湖南省重金属污染较为严重的地区之一,龙王山金矿床是该区中部的一个重要金矿床.为调查该矿床废石堆污染状况、是否为周边环境的污染源、污染途径、重金属迁移能力和潜在的危害,对矿区FS17废石堆进行了自然淋滤水和24 m浅钻系统取样,开展重金属元素总量分析,利用单因子指数法和内梅罗综合污染指数法对其重金属污染程度进行污染评价,采用四步改良BCR提取法分析废石堆中8种重（类）金属元素（Pb、Zn、Cd、Cu、Cr、Ni、As和Fe）的赋存形态,并利用迁移指数量化废石堆重金属元素迁移能力;发现废石堆中Cd、Cu、Pb、As、Zn、Ni重金属元素严重超标,且在垂向上分布极不均匀;其自然淋滤水样中重金属元素Cd、Ni、Zn、Cu也严重超标;废石堆浅层重金属元素潜在迁移能力顺序为:Cd＞Ni≈Zn＞Cu＞Pb＞As＞Cr＞Fe,深层重金属元素迁移能力顺序为:Cd＞Zn＞Cu＞Ni＞Cr＞Pb＞As＞Fe,浅层重金属元素的迁移性大于深层;说明该废石堆重金属元素含量高,是周围环境重要污染源,酸性废水排放为其释放污染元素的主要途径;Cd、Cu、Zn、Ni迁移能力强,是周围环境的主要污染元素;Pb、Ni、As的迁移性在深层明显降低,可以通过埋深来削弱其迁移性,而Cr不会对周边环境产生污染.   相似文献   

8.
Impact of agriculture on surface water in Ireland Part I. General   总被引：1，自引：0，他引：1  
The inland freshwaters of Ireland are generally of good quality, a condition at least partly attributable to the relatively small population and industrial base, which are mainly located in coastal areas. The wastes generated by agricultural activities greatly exceed those resulting from domestic and industrial activities. However, the bulk of these agricultural wastes are attributable to grazing livestock and are not likely to lead to pollution of waters. The disposal of manure slurries from intensive rearing operations and silage making are the main agricultural operations which have been implicated in pollution incidents, e.g., fish kills and lake eutrophication. Contamination of surface waters with nitrate and pesticides is not a significant problem at this stage, which reflects the relatively low usage of artificial fertilizers and biocides in Ireland. It is suggested that, in the long term, the main effect of agriculture on Irish surface waters will be eutrophication.  相似文献   

9.
Agro-industrial wastewaters are known by high strength of organic pollutants that cause an adverse effect on the water bodies. Wastewater management becomes a major task, leads environmental regulations to be stricter worldwide. Increased disposal of untreated/partially treated industrial wastewaters are major environmental problems in Ethiopia. In Ethiopia, industries most commonly dispose their untreated wastewater straight into the nearby rivers. Somewhat, constructed wetlands are used by some industries for treatment of wastewaters. The objective of this review paper was to summarize the characteristics and recent research efforts done on anaerobic treatment of some selected agro-industrial wastewaters and innovative technologies used for cogeneration of byproducts. Many developed countries designed cost effective approaches for agro-industrial wastewater management. The full-scale anaerobic treatment system in China generates 40,000 m3 biogas daily for 20,000 households from agro-industrial wastes. Likewise, the Brewery, Addis Ababa, Ethiopia used full-scale anaerobic treatment technology and produce average methane yield of 487 Nm3/day. The estimated maximum methane production potential of Kera, Luna slaughterhouses, and Ada milk factory were 4.5599LCH4, 0.1878LCH4, and 0.9952LCH4, respectively. These indicate that they can be potential sources of biogas production. Limitations of the brewery are burning of the produced energy and some quantified parameters being become above national standards while meat processing and diary industries are discharging their wastewater without treatment into the rivers. We devised the brewery to use the produced energy properly and extend its treatment to achieve the national standards using integrated sequencing batch reactor. Similarly, slaughterhouse and diary industries should install anaerobic–aerobic integrated treatment techniques.  相似文献   

10.
Levels of heavy metals are found in soils and waters of the major tributary valleys of the Jordan Valley. Heavy metal content in soils irrigated by treated waste water were measured for a 40 km reach of Zarqa River. Soil samples from eight different sites along the upper course of this river were analyzed to determine the concentration of selected heavy metals (CO, Cr, Cu, Pb, Ni, Zn). Silt forms the major component of the soils with an average of 54%. Clay fractions show an increase with depth from 17 to 41%. Trends in particle size distribution and metal contents were compared across sample sites. Samples contained moderate to considerable levels of Pb and Ni. Concentrations of Cu and Cr ranged between 33–59 and 65–90 ppm, respectively. These values represent a slight to moderate class of pollution. The concentration of Cr shows a decrease with depth and distance from the waste water plant. Cu, Zn, and Ni show increasing concentrations with depth but Pb and CO do not. The concentrations of the measured heavy metals increases near the waste water treatment plant but decreases with distance from the plant due to precipitation in the stream bed and dilution with stream water. This decline in metal content with distance from the treatment plant suggests that most metals reaching floodplain soils may derive from the same source. Although current metal concentrations are low to moderate, floodplain surface soils in this area should be regarded as a potential source for future heavy metal pollution downstream.  相似文献   

11.
环境矿物材料治理镉（Cd^2＋）污染研究进展   总被引：4，自引：0，他引：4  
近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。  相似文献   

12.
The reuse of nutrients and organic matter in wastewater sludge via on agricultural lands application is a desirable goal. However, trace or heavy metals present in sludge pose the risk of human or phytotoxicity from land application. The aim of this research is possibility of ground water pollution of south of Tehran because of ten years irrigation with Ni, Cd and Pb borne waste water. For this purpose, 6 soil samples from southern parts of Tehran city and 2 ones from Zanjan city without lime and organic matter were selected. The soils differed in their texture from sandy to clayey. Each soil sample in duplicate and uniformly packed into PVC columns. Soil samples were irrigated with Cd, Pb and Ni-added wastewater. After irrigating, the columns were cut and the soils separated from sectioned pieces and their heavy metal concentrations (Pb, Cd and Ni) were measured by atomic absorption spectrophotometer by use of HNO3 4N solution. Because of high sorption capacity of these elements by soils, these metals were accumulated in surface layer of the soils. Movement in the soils without lime and organic matter were as low as other samples. Ni has had the most accumulation or the least vertical movement, and Pb the opposite ones.  相似文献   

13.
为了解吉林省典型废水的化学需氧量(COD)与总有机碳(TOC)间的相关关系及其形成机制,在对吉林省典型废水的ρ(COD)与ρ(TOC)进行测定的基础上,分析了各类废水ρ(COD)与ρ(TOC)的相关关系,研究了其形成作用和有机组分的挥发性与可氧化特征对其的影响。结果表明：所研究废水水样的ρ(COD)与ρ(TOC)间均存在显著的线性相关关系(α≤0.050),各类废水ρ(COD)/ρ(TOC)为1.711~12.280;废水ρ(COD)与ρ(TOC)的相关关系主要由废水的有机化学成分决定,其中废水有机组分的元素组成起主导作用,有机组分的挥发性和可氧化特征对废水ρ(COD)与ρ(TOC)的相关性和比值均存在影响。  相似文献   

14.
The aim of this study is to understand the effects of pollution of anthropogenic origin on water quality in Yalvac Basin, part of the Egirdir Lake catchment. Surface discharge from the basin to the lake is 63 m3/year and underground discharge is 114 m3/year. Possible water pollution is categorized into domestic, industrial and agricultural origin. Domestic and industrial wastewaters, including effluents from leather tanneries are discharged, without being purified, into Yalvac Stream, which flows into Egirdir Lake directly or via the drainage canal. Surface waters flowing into the lake are used in winter for irrigation of agricultural areas. In agricultural areas natural and synthetic fertilizers and pesticides are used extensively. Lake Egirdir is used as a source of drinking water. Sampling sites were established for surface and underground waters, taking into account the known point sources of pollution. These sites were sampled in May and October of 2002, and analysed chemically. Cr3+ and Pb2+ concentrations exceed standard limits, meaning that pollution caused by effluent from the tanneries is adversely affecting the water quality in the lake.  相似文献   

15.
Water quality in the Northern part of Mellegue-Medjerda watershed (East Algeria) has been adversely affected by important pollutants discharged into the Medjerda wadi without, in most cases, any treatment. Chemical and physical degradation are due to agricultural and industrial practices and domestic wastewaters. Over a three-month period, a study of the low-flow water quality characteristics throughout Medjerda wadi was undertaken. Longitudinal profiles of water quality were constructed using data from fourteen sites. All sewage, agricultural, and industrial inputs were included. Analyzed properties were nutrients (NO3 −, NO2 −, NH4 +, and PO4 3−), Biochemical oxygen demand after five days (BOD5), chemical oxygen demand (COD), and dissolved oxygen (DO). Along Medjerda wadi, all values change because of conditions specific to each sampling station. Nitrate was the most important form of nitrogen-element load (94%). Its concentration reached 34.3 mg L−1 at OM4 point, downstream of domestic wastewater discharges. The spatial evolution of the organic pollution index (OPI) shows that the wastewater effluent constitutes the main source of pollution. Indeed, water quality goes from a moderate pollution state at some sampling stations not or slightly affected by wastewaters discharges to a very strong pollution state (OPI of about 1.75) downstream of the domestic effluents inputs of Souk-Ahras city.  相似文献   

16.
松花江上游表层沉积物中重金属元素时空分布特征   总被引：1，自引：0，他引：1  
松花江是我国七大河流之一,研究其底泥重金属元素的时空分布特征对流域的水环境治理具有重要意义。本文对松花江（哈达山至松花湖段）底泥（表层沉积物）中元素As、Hg、Cr、Cd、Pb的分布特征进行了研究,并利用地累积指数分析了这些元素的污染状况。结果表明：研究区底泥几乎未受到As、Cr和Pb的污染,但多数地段内出现了Cd和Hg的污染,尤其是元素Hg,在个别地段的污染程度达到了极强;与10年前相比,一些重金属的污染得到了明显改善,但吉林市区段内Hg的污染仍非常严重。污染样品空间分布特征表明,松花江吉林市区段可能有来自工农业废水的重金属污染。  相似文献   

17.
Physicochemical characteristics of wastewater from one of the paper mills near Nanjangud and the differential accumulation of heavy metals in parts of coconut trees growing in the area irrigated directly by the wastewaters of a paper mill were investigated. The total dissolved and suspended solids of wastewater were 1,136.9 mg/l and 2,185.4 mg/l, respectively. Biological oxygen demand (BOD) expands and COD is beyond the tolerance limit proposed by Indian standards. The concentrations of heavy metals like Cu, Pb, Zn, Ni, Co, and Cd in coconut water, root, and leaf are higher than the limits suggested by World Health Organization. Survival of coconut trees irrigated by polluted waters indicates tolerance to toxic heavy metals. Since coconut forms part of human food chain, accumulation of toxic heavy metals may lead to organic disorders.  相似文献   

18.
Groundwater pollution due to industrial effluents from textile units around Pali city area is the major concern to the local villagers and the district administration. Indiscriminate discharge of these effluents in the past two decades caused severe damage to the agricultural land and groundwater resources within 3 km buffer zone of the Bandi river. Remote Sensing and GIS techniques are found to be better tools in assessing the damage in agricultural crops during 1997 and 2006 with the help of high resolution satellite images. Groundwater fluctuation trend with annual rainfall pattern during 1985 and 2005 indicate good recharge in the study area. Detailed analysis of groundwater quality parameters (TDS, Cl and SO4) and heavy metals (Cu, Pb, Zn, Fe, Cd and Cr) for 1997–98 indicates maximum concentration around Chatelao village and Dholera Jagir in the downstream direction of Bandi river. However, temporal analysis of groundwater samples collected in January, 2009 shows marginal decrease in concentration of TDS, Cl, SO4, Pb and Cu in both groundwater as well as river effluents. Slight improvement in water quality especially heavy metals in the last 12 years (1998–2009) may be attributed to the appropriate measures (treatment of wastewater and solid waste disposal) taken by the establishment of three Common Effluent Treatment Plants (CETP) in Pali city area. However, a few stringent actions may be taken to avoid direct discharge of the effluents into Bandi river.  相似文献   

19.
The present study monitored textile factory, distillery, and domestic wastewaters and investigated the effects of blending on the physicochemical properties of these wastes. Findings revealed that distillery wastewaters had the highest values of all tested parameters, including heavy metals, biodegradable organics, and nutrients. Biological and chemical oxygen demands in the textile wastewater were higher than domestic wastewater, while total phosphorus, total nitrogen, and sulfate were higher in the domestic wastewater. Likewise, while higher mean concentrations of zinc, copper, iron, and manganese were found in the domestic wastewater, the rest studied heavy metals did not show statistical differences (p < 0.05). This study concluded that blending improves biological treatability and effectively neutralizes the alkaline textile, acidic distillery, and domestic wastewaters at volumetric ratios of 3:1:18, respectively. This methodology will help to avoid the use of chemicals for neutralization and can be a useful entry point to establish sustainable wastewater management strategy in the developing countries. The results suggest the need for inclusion of the tested nine heavy metals in the Ethiopian standards for discharge from the distillery and domestic effluents.  相似文献   

20.
对湘中桃江锰矿废矿堆的废石进行了主量元素、稀土元素、微量元素和重金属元素的地球化学分析。野外观察及分析结果表明:组成废矿堆的岩石主要是赋矿围岩中奥陶统黑色页岩和原生碳酸锰矿石。这些废石富含Cu、Pb、Zn、Cr、Tl、Sb、U等重金属元素。废石暴露地表而遭受风化分解,导致Sc、V、Cr、U、Cd、Th等重金属元素淋滤释出,在废石样品中均表现出不同程度的迁移特征,且以V、Cd、U的迁移性最为强烈。此外,黑色页岩中Ni、Cu、Zn、Pb、Tl、Sb也明显发生淋失。这些重金属元素如Cd、Tl等毒性极强,进入矿区周围不断积聚,便可能对环境造成严重的影响。故对区内分布的废矿堆作为重金属污染源应高度重视。  相似文献   

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