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1.
The intensive mussel culture carried out in the past 40 years in the Rias of Vigo and Arousa (Galicia-NW Spain) has led to substantial changes in the ecology and geochemistry of the seabed in these areas. Organic C enrichment of the seabed has generated strongly reducing conditions that directly affect the geochemistry of Fe and S. In the present study a total of six sediment cores were collected from the seabed under mussel rafts, and two different layers were distinguished: the biodeposit generated by the mussels, and the sediment situated immediately below this. Samples of each were analyzed to determine the pH, redox potential, sulphate and chloride in the interstitial water, as well as total percentage of organic C (TOC), N and S. Sequential extraction of the samples differentiated six fractions of Fe: exchangeable, carbonate, ferrihydrite, lepidocrocite, goethite and pyrite. The contents of total Fe, Fe associated with silicates, Fe soluble in 1 M HCl and AVS-Fe were also determined. In general, both the biodeposit and the sediment were anoxic (Eh < 100 mV) and there were no significant differences between the two in the total Fe or in the Fe associated with silicates, which appears to indicate that the input of Fe to the system did not vary greatly. However, there were significant differences between the sediment and the biodeposit in terms of the forms of Fe in each layer. The concentrations of pyrite in the biodeposit (0.37 ± 0.25 μmol g−1) were high but significantly lower than in the sediment (1.10 ± 0.20 μmol g−1), and there remained large quantities of reactive-Fe that were susceptible to pyritisation. In contrast, in the sediment, the reactive-Fe was intensively pyritised, and judging from the ratio of TOC–DOP, it limited synthesis of pyrite. Furthermore, a plot of the concentration of pyrite-S against TOC revealed an excess of ∼15% of pyrite-S, which is explained by the partial decoupling of pyrite formation from organic matter accumulation, caused by the formation of pyrite from the H2S generated by the anaerobic oxidation of methane. The latter process also appears to favour, although to a lesser extent, the precipitation of Ca carbonate, with incorporation of Fe.  相似文献   

2.
The consequences of two upwelling events in mid- (MW) and late (LW) winter on biogeochemical and phytoplankton patterns were studied in the Pontevedra Ria and compared with the patterns measured under typical winter conditions and under a summer upwelling event. Thermohaline patterns measured during the mid-winter upwelling event (MW-up) revealed the intrusion of saltier seawater (35.9) into the ria associated with the Iberian Poleward Current (IPC). During the late-winter upwelling event (LW-up), the seawater which had welled up into the ria showed characteristics of the Eastern North Atlantic Central Water mass (ENACW). In both cases the measured water residence time (4 days during MW-up and 10 days during LW-up) was related to both meteorological and fluvial forcing. This residence time contrasts with that of summer upwelling (7 days) and with that estimated under unfavorable upwelling atmospheric conditions (2–4 weeks). During MW-up, the ria became poor in nutrients due to continental freshwater dilution, associated with the shorter residence time of the water, and the intrusion of IPC, which is a water body poor in nutrient salts: 2.9 μM of nitrate, 0.1 μM of phosphate and 1.5 μM of silicate. During this event, the ria exported 3.4 molDIN s−1, compared with 6.9 molDIN s−1 in non-upwelling conditions. Phytoplankton showed a uniform distribution throughout the ria, as during unfavorable upwelling conditions, and was characterized by the dominance of diatoms, mainly Nitzschia longissima and Skeletonema costatum. During LW-up, a nutrient depletion in the photic layer also occurred, but as a result of a phytoplankton spring bloom developing at this time. The ria was a nutrient trap where 4.1 molDIN s−1 were processed by photosynthesis. This budget is three times higher than the one under non-upwelling conditions. In contrast with the MW-up, which had no effect on primary production, during LW-up the ria became more productive, although not as productive as during a summer upwelling event (9.9 molDIN s−1). The taxonomic composition of the phytoplankton community did not change noticeably during LW-up and the summer upwelling, with the same species present and changing only in relative proportions. Diatoms were always the dominant microphytoplankton community, with Pseudonitzschia pungens, Thalassionema nitzschioides and several species of Chaetoceros as characteristic taxons.  相似文献   

3.
Concentrations of heavy metals (Co, Cr, Cu, Fe, Ni, Pb and Zn), particulate organic (POC) and nitrogen (PON), particulate inorganic carbon (PIC) and opal content were measured in 35 surface sediment samples taken in the Ferrol Ria (Galicia, NW Spain). This ria is a semi-enclosed embayment receiving inputs from industrial and urban effluents. The restricted water exchange between the ria and the shelf has led to a significant accumulation of contaminants within the embayment. Two main factors controlled the metal distribution and concentrations in the bay: (1) contamination point sources and (2) distribution of the organic-rich sediments. Zn, Cu and, to a lesser extent Pb, were the metals most contaminated in the bay, with average enrichment factors (AEF)—defined as the mean metal concentration in the bay divided by the background value reported for this ria—of 4.7, 5.5 and 2.7, respectively. The highest concentrations for these metals were observed in the vicinity of the point sources. Values found for Zn, Cu and Pb are comparable to other industrialized coastal areas in the world. For Ni, Fe, Cr and Co a negligible to low contamination was found (AEF = 1–2), with the highest concentrations found in the organic-rich sediments.  相似文献   

4.
Water column samples have been collected in the outer channel of the Ferrol Ria (NW Spain) during four occasions over a tidal cycle. The objective was to study the exchange of dissolved and particulate Cd, Cu, Pb and Zn and particulate Al, Fe and Si between the ria and the adjacent coastal waters. This study provides the first extensive dataset on dissolved and particulate metal concentrations in the water column of a Galician ria. Typical concentrations of dissolved Cd (96 ± 31 pM), Cu (8 ± 4 nM), Pb (270 ± 170 pM) and Zn (21 ± 10 nM) were similar than in other European Atlantic shelf and coastal waters. The fraction of metals in the particulate phase followed the trend: Pb > Cu Zn > Cd. The outgoing water from the ria was enriched in dissolved and particulate Cu, Pb and Zn compared with incoming waters, whereas Cd concentrations were similar for both waters. The suspended particulate matter was composed of a mixture of marine and continental material. The latter end-member was found to arise from the metal-rich ria bed sediments, which is diluted by the dominant metal-poor marine end-member. The net output flux of Cu from the channel is balanced by the freshwater inputs to the ria, and the net Zn flux gave a positive output to coastal waters. For Pb, the net flux to the coastal waters is less than that input from the rivers, as a result of its particle reactivity and deposition in sediments. On the contrary, a net input flux of dissolved Cd from coastal waters was observed, highlighting the oceanic source of this metal in the Galician rias. Results from the budget calculations are in agreement with the differential geochemical behavior of these elements in coastal waters.  相似文献   

5.
Hydrographic observations were made in Otsuchi Bay on the Sanriku ria coast, Japan, to provide clear images of the baroclinic circulation extending over the bay together with the associated intrusion of lower-layer water (bottom water) from outside the bay. In summer, a prominent baroclinic circulation with flow speeds \({>} 0.1\ \text{ m }\ \text{ s }^{-1} \) extends over the greater part of the bay. A main pycnocline (thermocline), which separates the upper and lower layers, is located at a depth of 15–40 m in and around the bay. The direction of the lower-layer flow (inflow into and outflow from the bay) is opposite to that of the upper-layer flow, which are baroclinically coupled to each other. Moreover, with regard to the lower-layer flow, the inflow tends to occur mainly through the northwestern part of the bay mouth, whereas the outflow tends to occur mainly through the southeastern part. The inflow and outflow alternate on time scales of several to a few tens of hours, and the flow directions are sometimes related to the tidal ones, although the relationship is not applied persistently. In winter, the baroclinic circulation is considerably weaker than in summer, because the stratification breaks down.  相似文献   

6.
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7.
Spring blooms of phytoplankton composed of centric diatoms developed in late February, March, and April in Otsuchi Bay on Sanriku ria coast, Japan. During this period, associated with prolonged seasonal west wind (>1 day), intense exchange of waters occurred between inside and outside the bay: outflow of nearsurface brackish water over inflow of oceanic water at depth. This circulation interrupted formation of the blooms, and transported phytoplankton populations seaward. By such water movements, a significant amount of nutrients in the bay was carried out, otherwise replenished into the bay, depending on water masses located outside the bay. Owing to irregular features of wind events, a bloom lasted from several days to a week. From February to April, supply of nutrients seemed to be replete except for the latter half of the bloom period, and estimates of the critical depth exceeded the depth of the bottom consistently. Thus, net growth of phytoplankton was expected throughout the observation period, and potentially blooms could be formed. However, the blooms were only formed under calm weather. We hypothesize that the exchange of waters dilutes populations in the bay, and that formation of the bloom, that is, accumulation of biomass depends on a balance between the growth of phytoplankton and the dilution of bay water.  相似文献   

8.
The wind-induced water exchange between the ria of Ferrol (NW Spain) and the adjacent shelf is analyzed by means of a three-dimensional hydrodynamic model (MOHID2000). Since thermohaline measurements indicate that the estuary can be considered vertically homogeneous a barotropic version of the model has been used. Real in situ wind measurements have been used for model calibration and further analysis. The approach to study the wind effect on water exchange through the ria strait consisted in subtracting the signal calculated with only tidal forcing (Ts) from the one with wind and tidal forcing (WTs). This shows the existence of a residual circulation, with water flowing in wind direction along surfaces layers and a counter current flowing in the opposite direction at bottom layers. The flux across the strait of Ferrol has shown to increase linearly on wind strength, with a correlation larger than 96% and reaching values close to 20 m3 s−1 under real wind forcing.  相似文献   

9.
The Ria of Vigo, one of the classical rias of SW Europe, is an environment of high production of organic matter naturally induced by the Galician upwelling. The organic matter is partly supplied by small rivers but mainly by sewage plants along the ria shoreline; jointly they contribute 725 t y−1 of POC, of which 72% is of anthropogenic origin. The freshwater flux is equivalent to a supply of 5 g m−2 yr−1 of allochtonous POC to the ria floor. However the rate of accumulation of POC is dominated by the order of magnitude higher supply of autochthonous material from the net primary production. The present accumulation rate of organic matter (49-58 gPOC m−2 yr−1) is lower than the average supply, estimated from the sedimentary record, to the ria since the middle of the nineteen Century (>60 gPOC m−2 yr−1). This difference may be due to anthropogenic activity or changes in the upwelling pattern. The composition of the organic matter in the sediment reflects the relative importance of the various sources (terrestrial-marine). While terrestrial woody materials dominate the inner ria, phytoplankton remains dominate the remainder of the ria. Rock-Evaluation analysis indicates the inner ria is the site of deposition of gas-prone material and it is inferred that the outer ria of oil-prone organic matter. The controls on the accumulation of POC in the rias show many differences to those found in estuaries affected by anthropogenic activities e.g. agriculture and increasing human population.  相似文献   

10.
Copper concentrations were measured in the sediments and dissolved phase of the water column in the Lérez Estuary (Pontevedra Ria, Galicia), NW Spain, and in the freshwater-sewage inputs to the estuary. Dissolved copper fluxes in the estuary were quantified. Results show that the freshwater end-member in the Lérez Estuary has minimal copper contamination ([Cu](Dissolved)=7+/-4 nM, Sediment Enrichment Factor=1) and the source of dissolved copper inputs is localized in the saline end-member ([Cu](Dissolved)=20-55 nM, Sediment Enrichment Factor=6-7). A non-conservative behaviour of dissolved copper showing a net addition during estuarine mixing was observed. The budgetary calculations and the copper sediment distribution suggest that the major copper input to the estuary-ria system is located at the Marín-Placeres transect, playing an important role in the net addition of copper within the estuarine mixing. The importance of upwelling in the renewal of the Galician coastal waters and dilution of continental inputs is discussed.  相似文献   

11.
Flow fields in Shizugawa Bay on the Sanriku ria coast, which faces the Pacific Ocean, were investigated using hydrographic observations for the purpose of understanding oceanographic conditions and the process of water exchanges in the bay after the 2011 earthquake off the Pacific coast of Tohoku. In spring to summer, density-driven surface outflow is part of estuarine circulation and is induced by a pressure gradient force under larger longitudinal gradients in density along with lower salinity water in the innermost part of the bay, regardless of wind forcing. In winter to summer, another density-driven current with a thermal structure is induced by a pressure gradient force under the smaller longitudinal density gradients in calm wind conditions. Particularly in winter, Tsugaru Warm Current water can be transported in the surface layer inside the bay. Wind-driven bay-scale circulation with downwind and upwind currents in the surface and deeper layers, respectively, is induced by strong longitudinal wind forcing under the smaller longitudinal density gradients, irrespective of season. Particularly in fall to spring, this circulation can cause the intrusions of oceanic water associated with Oyashio water and Tsugaru Warm Current water in the deeper layer. These results suggest that wind- and density-driven currents can produce the active exchange of water from inside and outside the bay throughout the year.  相似文献   

12.
Real-time monitoring of wind and surface waves in Otsuchi Bay, Iwate, Tohoku, Japan, commenced in October 2012, using a mooring buoy with an ultrasonic anemometer and a single-mode GPS wave sensor. Wind and wave data are distributed hourly in real time via the Internet along with a chart of their time series. We analyzed data monitored in the first 3 months in order to assess the variability and occurrence of wind and waves and to elucidate the main reasons for wave variation in Otsuchi Bay. The monitoring data revealed that surface waves in the bay were predominantly affected by swells propagated from the northeastern offshore region and that the wave height was significantly correlated with the component of wind velocity toward Otsuchi Bay in the northeastern offshore region that faces the bay mouth. The offshore wind field was expected to provide information useful for predicting coastal waves in a ria bay in Sanriku such as Otsuchi Bay. However, it should be emphasized that the horizontal distribution of the offshore wind field which has a significant effect on the surface waves in a ria bay depends heavily on the topographic shape of the bay.  相似文献   

13.
本文基于南大洋环流研究最新资料，从资料来源、动力模式以及有待解决的问题几个方面较详细地阐述南大洋环流动力学研究动态。  相似文献   

14.
选取长江口外赤潮多发区沉积物柱状样,在高分辨率测年基础上,通过有机碳、有机碳同位素(δ13C)、生物硅、绿素等多项指标的分析获得了调查海区古生产力的变化信息。并结合近几十年来营养盐浓度及组成结构的变化探讨了海洋浮游藻类组成结构的变化在海洋古环境中的记录。柱状样年代可追溯到20世纪40年代初。δ13C值在柱中的分布为-26.15×10-3~-19.5×10-3,表明有机碳为陆源与海生的混合。生物标志物在柱状样中的分布可大致分为三个阶段,50年代以前含量均较低;50年代至80年代含量均增加,表明海洋浮游藻类活动强烈且以硅藻为主,与此阶段长江口营养盐浓度迅速增加相对应;80年代以后,生物硅的含量下降至整个柱中最低水平,绿素有所降低,但高于50年代前的水平,而有机碳含量增加,表明在该时段硅藻生物量降低,其他藻类生物量有所增加,这与长江口营养盐氮盐持续增加而硅酸盐逐年降低、氮与磷的含量比值、磷与硅的含量比值迅速增大有关。沉积记录还表明此阶段陆源有机碳的贡献增强。  相似文献   

15.
This paper analyses the global tendency of the sea level rise (SLR) and its long term influence on the sea level upstream drainage cascade based on the example of the level’s variation in the Vistula Lagoon of the Baltic Sea compared to the other lagoons and coastal regions of the southeastern part of the Baltic Sea. A steady positive trend in the water level variations was revealed; its magnitude varies significantly depending on the time period. In general, during the 100–150 year period, the rate of the SLR in the lagoons and coastal areas of the Baltic Sea (1.7–1.8 mm per year) is close to the SLR rate in the World Ocean. In the second half of the 20th century, the increased rate of the SLR in the lagoons and marine areas became stronger (up to 3.6 mm per year in the Vistula Lagoon and in 1959–2006 in the sea and exceeded the rate of global ocean SLR). It dramatically increased at the end of the last century both in the lagoons and in the sea (up to 10.0–15.0 mm per year). This is the response not only to the global climate warming but it is likely that it is also a response to the changes of the climate driving forces that influence the regimes of the local wind and precipitation in the catchment.  相似文献   

16.
A numerical experiment on the reproduction of the variability in the state of North Atlantic water in 1948–2007 with a spatial resolution of 0.25° has been performed using the global ocean model developed at Institute of Numerical Mathematics, Russian Academy of Sciences (INM RAS), and the Shirshov Institute of Oceanology (IO RAS) (the INM–IO model). The data on the state of the atmosphere, radiation fluxes, and bulk formulas of the CORE-II protocol are used as boundary conditions. Five successive 60-year calculation cycles have been performed in order to obtain the quasi-equilibrium state of a model ocean. For the last 20 years, the main elements of large-scale ocean circulation have been analyzed and compared with the WOA09 atlas data and the results of other models.  相似文献   

17.
近30年来莱州湾滨海湿地景观格局变化特征研究   总被引：1，自引：0，他引：1  
基于莱州湾滨海湿地特征以及野外实地观测数据,利用landsat遥感影像手段,揭示1990-2018年莱州湾滨海湿地景观格局变化特征,并结合景观指数分析莱州湾滨海湿地异质性。结果表明,1990-2018年间,莱州湾滨海湿地呈现人工滨海湿地面积增加而天然滨海湿地面积减少的趋势。截至2018年莱州湾滨海湿地面积总计1954 km2,其中天然滨海湿地面积约811 km2,人工滨海湿地面积约1143 km2,分别占42%和58%,滨海湿地向建设用地转化的趋势明显。斑块数量(NP)、景观形状指数(LSI)等景观指数值逐年增加,表明莱州湾景观格局变化明显且破碎化程度加重。莱州湾滨海湿地不同岸段之间景观格局变化的驱动机制不完全一样,造成其破碎化程度加重的自然驱动力有河口冲淤、降水量变化等;人工驱动力主要为城市建设、港口码头、集约用海区建设、养殖业和制盐业的开发利用等。以期对莱州湾滨海湿地生态系统退化原因、合理利用和优化土地空间布局、采取有效措施保护及恢复滨海湿地提供一定的技术支持。  相似文献   

18.
1Introduction Besidestheprecipitationandriverdischarges,the watersinthePacificOceanandtheAtlanticOceanare thesourcesoftheArcticOceanwater.TheAtlantic waterenterstheArcticOceanviatheFramStraitand theBarentsSea.Foritsdenserfeatureduetohigh salinity,mostofitsinkstothenorthofSvaldbardand circulatesinallthedeepbasinsintheArcticOcean, formingthedeepandbottomwatersoftheArcticO- cean(Aagaardetal.,1985;Rudelsetal.,1999).The BeringStraitistheonlychannelforthePacificwater toflowintotheArcticOce…  相似文献   

19.
Field data in the Oman ophiolite show that the Moho transition zone (MTZ), which is on average 300 m thick above mantle diapirs, reduces to 50 m away from diapirs, with a sharp transition at the outskirts of the diapirs. We show here that this reduction is dominantly due to compaction of a dunitic mush present above diapirs in the MTZ, with upward injection of a wehrlitic magma in the crust, and, to a lesser extent, due to tectonic stretching. In order to explain the fraction of wehrlites injected into the crust, which is in the range of 25%, it is necessary that mantle upwelling is active, with a mantle flow velocity away from diapirs several times faster than the spreading velocity. If this velocity exceeds 5 times the ridge spreading-rate, a significant part of the MTZ may be entrained down into the mantle, flowing away from the diapir as tabular dunites.  相似文献   

20.
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