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1.
The specific catalytic effect of a silica grain on the formation of methanol via the sequential addition of H atoms to CO adsorbed on the surface is investigated. A negatively charged defect on a siliceous edingtonite surface is found to reduce the gas phase barriers for the H + COads and H + H2C=Oads reactions by 770 and 399 K, respectively, when compared to the same reactions in the gas phase. The catalytic effect of negatively charged surface sites could also be applicable to the hydrogenation of other adsorbed unsaturated species. However, the activation energies on the surface defect are still too large (1150 and 2230 K) for CH3OH to form efficiently at 10–20 K in the interstellar medium via a classical mechanism. It is therefore suggested that quantum mechanical tunnelling through the activation barrier is required for these hydrogen addition reactions to proceed at such temperatures. The calculations show that because the adsorption energies of CO and H2C=O on the negatively charged defect are substantial, CH3OH may form efficiently during the warm-up period in star-forming regions.  相似文献   

2.
We report the discovery of high-velocity dense gas from a bipolar outflow source near NGC 2068 in the L1630 giant molecular cloud. CO and HCO+ J =3→2 line wings have a bipolar distribution in the vicinity of LBS 17-H with the flow orientated roughly east–west and perpendicular to the elongation of the submillimetre dust continuum emission. The flow is compact (total extent ∼0.2 pc) and contains of the order of 0.1 M⊙ of swept-up gas. The high-velocity HCO+ emission is distributed over a somewhat smaller area <0.1 pc in extent.
A map of C18O J =2→1 emission traces the LBS 17 core and follows the ambient HCO+ emission reasonably well, with the exception of the direction towards LBS 17-H where there is a significant anticorrelation between the C18O and HCO+. A comparison of beam-matched C18O and dust-derived H2 column densities suggests that CO is depleted by up to a factor of ∼50 at this position if the temperature is as low as 9 K, although the difference is substantially reduced if the temperature is as high as 20 K. Chemical models of collapsing clouds can account for this discrepancy in terms of different rates of depletion on to dust grains for CO and HCO+.
LBS 17-H has a previously known water maser coincident with it but there are no known near-infrared, IRAS or radio continuum sources associated with this object, leading to the conclusion that it is probably very young. A greybody fit to the continuum data gives a luminosity of only 1.7 L⊙ and a submillimetre-to-bolometric luminosity ratio of 0.1, comfortably satisfying the criteria for classification as a class 0 protostar candidate.  相似文献   

3.
The formation of H2 on a pristine olivine surface [forsterite (010)] is investigated computationally. Calculations show that the forsterite surface catalyzes H2 formation by providing chemisorption sites for H atoms. The chemisorption route allows for stepwise release of the reaction exothermicity and stronger coupling to the surface, which increases the efficiency of energy dissipation. This suggests that H2 formed on a pristine olivine surface should be much less rovibrationally excited than H2 formed on a graphite surface. Gas-phase H atoms impinging on the surface will first physisorb relatively strongly  ( E phys= 1240 K)  . The H atom can then migrate via desorption and re-adsorption, with a barrier equal to the adsorption energy. The barrier for a physisorbed H atom to become chemisorbed is equal to the physisorption energy, therefore there is almost no gas-phase barrier to chemisorption. An impinging gas-phase H atom can easily chemisorb  ( E chem= 12 200 K)  , creating a defect where a silicate O atom is protonated and a single electron resides on the surface above the adjacent magnesium ion. This defect directs any subsequent impinging H atoms to chemisorb strongly (39 800 K) on the surface electron site. The two adjacent chemisorbed atoms can subsequently recombine to form H2 via a barrier (5610 K) that is lower than the chemisorption energy of the second H atom. Alternatively, the adsorbed surface species can react with another incoming H atom to yield H2 and regenerate the surface electron site. This double chemisorption 'relay mechanism' catalyzes H2 formation on the olivine surface and is expected to attenuate the rovibrational excitation of H2 thus formed.  相似文献   

4.
The chemical desorption of an adsorbed CO molecule in the vicinity of H2-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H2. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H2 formation energy in the vicinity of H2-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H2-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (1013 s) and that for H2 forming in the vicinity of an adsorbed CO molecule (more than 2×1013 s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.  相似文献   

5.
Determining temperatures in molecular clouds from ratios of CO rotational lines or from ratios of continuum emission in different wavelength bands suffers from reduced temperature sensitivity in the high-temperature limit. In theory, the ratio of far-infrared (FIR), submillimetre or millimetre continuum to that of a 13CO (or C18O) rotational line can place reliable upper limits on the temperature of the dust and molecular gas. Consequently, FIR continuum data from the COBE /Diffuse Infrared Background Experiment (DIRBE) instrument and Nagoya 4-m  13CO  J = 1 → 0  spectral line data were used to plot  240 μm/13CO  J = 1 → 0  intensity ratios against 140/240 μm dust colour temperatures, allowing us to constrain the multiparsec-scale physical conditions in the Orion A and B molecular clouds.
The best-fitting models to the Orion clouds consist of two components: a component near the surface of the clouds that is heated primarily by a very large scale (i.e. ∼1 kpc) interstellar radiation field and a component deeper within the clouds. The former has a fixed temperature and the latter has a range of temperatures that vary from one sightline to another. The models require a dust–gas temperature difference of 0 ± 2 K and suggest that 40–50 per cent of the Orion clouds are in the form of dust and gas with temperatures between 3 and 10 K. The implications are discussed in detail in later papers and include stronger dust–gas thermal coupling and higher Galactic-scale molecular gas temperatures than are usually accepted, and an improved explanation for the N (H2)/ I (CO) conversion factor. It is emphasized that these results are preliminary and require confirmation by independent observations and methods.  相似文献   

6.
Solid CO2 is observed to be an abundant interstellar ice component towards both quiescent clouds and active star-forming regions. Our recent models of gas–grain chemistry, appropriate for quiescent regions, severely underproduce solid CO2 at the single assumed gas density and temperature. In this paper, we investigate the sensitivity of our model results to changes in these parameters. In addition, we examine how the nature of the grain surface affects the results and also consider the role of the key surface reaction between O and CO. We conclude that the observed high abundance of solid CO2 can be reproduced at reasonable temperatures and densities by models with diffusive surface chemistry, provided that the diffusion of heavy species such as O occurs efficiently.  相似文献   

7.
C18O J  = 2–1, C17O J  = 2–1 and [C  I ] 3P1–3P0 emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.  相似文献   

8.
We present J , H and K -band spectroscopy of Cygnus A, spanning 1.0–2.4 μm in the rest-frame and hence several rovibrational H2, H recombination and [Fe  ii ] emission lines. The lines are spatially extended by up to 6 kpc from the nucleus, but their distinct kinematics indicate that the three groups (H, H2 and [Fe  ii ]) are not wholly produced in the same gas. The broadest line, [Fe  ii ] λ 1.644, exhibits a non-Gaussian profile with a broad base (FWHM≃1040 km s−1), perhaps because of the interaction with the radio source. Extinctions to the line-emitting regions substantially exceed earlier measurements based on optical H recombination lines.
Hard X-rays from the quasar nucleus are likely to dominate the excitation of the H2 emission. The results of Maloney, Hollenbach & Tielens are thus used to infer the total mass of gas in H2 v=1–0 S(1)-emitting clouds as a function of radius, for gas densities of 103 and 105 cm−3, and stopping column densities N H=1022–1024 cm−2. Assuming azimuthal symmetry, at least 2.3×108 M⊙ of such material is present within 5 kpc of the nucleus, if the line-emitting clouds see an unobscured quasar spectrum. Alternatively, if the bulk of the X-ray absorption to the nucleus inferred by Ueno et al. actually arises in a circumnuclear torus, the implied gas mass rises to ∼1010 M⊙. The latter plausibly accounts for 109 yr of mass deposition from the cluster cooling flow, for which within this radius.  相似文献   

9.
We present submillimetre observations of the   J = 3 → 2  rotational transition of 12CO, 13CO and C18O across over 600 arcmin2 of the Perseus molecular cloud, undertaken with the Heterodyne Array Receiver Programme (HARP), a new array spectrograph on the James Clerk Maxwell Telescope. The data encompass four regions of the cloud, containing the largest clusters of dust continuum condensations: NGC 1333, IC348, L1448 and L1455. A new procedure to remove striping artefacts from the raw HARP data is introduced. We compare the maps to those of the dust continuum emission mapped with the Submillimetre Common-User Bolometer Array (SCUBA; Hatchell et al.) and the positions of starless and protostellar cores (Hatchell et al.). No straightforward correlation is found between the masses of each region derived from the HARP CO and SCUBA data, underlining the care that must be exercised when comparing masses of the same object derived from different tracers. From the 13CO/C18O line ratio the relative abundance of the two species  ([13CO]/[C18O]∼ 7)  and their opacities (typically τ is 0.02–0.22 and 0.15–1.52 for the C18O and 13CO gas, respectively) are calculated. C18O is optically thin nearly everywhere, increasing in opacity towards star-forming cores but not beyond  τ18∼ 0.9  . Assuming the 12CO gas is optically thick, we compute its excitation temperature, T ex (around 8–30 K), which has little correlation with estimates of the dust temperature.  相似文献   

10.
We report the first detection of CO in the bulge of M31. The 12CO (1–0) and (2–1) lines are both detected in the dust complex D395A/393/384, at 1.3 arcmin (∼0.35 kpc) from the centre. From these data and from visual extinction data, we derive a CO luminosity to reddening ratio (and a CO luminosity to H2 column density ratio) quite similar to that observed in the local Galactic clouds. The (2–1) to (1–0) line intensity ratio points to a CO rotational temperature and a gas kinetic temperature of >10 K. The molecular mass of the complex, inside a 25-arcsec (100 pc) region, is 1.5×104 M⊙.  相似文献   

11.
We explore possibilities of collapse and star formation in Population III objects exposed to the external ultraviolet background (UVB) radiation. Assuming spherical symmetry, we solve self-consistently radiative transfer of photons, non-equilibrium H2 chemistry and gas hydrodynamics. Although the UVB does suppress the formation of low-mass objects, the negative feedback turns out to be weaker than previously suggested. In particular, the cut-off scale of collapse drops significantly below the virial temperature T vir∼104 K at weak UV intensities ( J 21≲10−2) , owing to both self-shielding of the gas and H2 cooling. Clouds above this cut-off tend to contract highly dynamically, further promoting self-shielding and H2 formation. For plausible radiation intensities and spectra, the collapsing gas can cool efficiently to temperatures well below 104 K before rotationally supported and the final H2 fraction reaches ∼ 10−3.
Our results imply that star formation can take place in low-mass objects collapsing in the UVB. The threshold baryon mass for star formation is ∼ 109 M⊙ for clouds collapsing at redshifts z ≲3 , but drops significantly at higher redshifts. In a conventional cold dark matter universe, the latter coincides roughly with that of the 1 σ density fluctuations. Objects near and above this threshold can thus constitute 'building blocks' of luminous structures, and we discuss their links to dwarf spheroidal/elliptical galaxies and faint blue objects. These results suggest that the UVB can play a key role in regulating the star formation history of the Universe.  相似文献   

12.
We have found a bar of shocked molecular hydrogen (H2) towards the OH(1720 MHz) maser located at the projected intersection of supernova remnant (SNR)  G359.1–0.5  and the non-thermal radio filament known as the Snake. The H2 bar is well aligned with the SNR shell and almost perpendicular to the Snake. The OH(1720 MHz) maser is located inside the sharp western edge of the H2 emission, which is consistent with the scenario in which the SNR drives a shock into a molecular cloud at that location. The spectral line profiles of 12CO, HCO+ and CS towards the maser show broad-line absorption, which is absent in the 13CO spectra and most probably originates from the pre-shock gas. A density gradient is present across the region and is consistent with the passage of the SNR shock, while the H2 filament is located at the boundary between the pre-shock and post-shock regions.  相似文献   

13.
The collapse of marginally Jeans-unstable primordial gas clouds in the presence of a UV radiation field is discussed. Assuming that the dynamical collapse proceeds approximately in an isothermal self-similar fashion, we investigate the thermal evolution of the collapsing central core until H2 cooling dominates photoheating and the temperature drops to below 104 K. Consequently, the mass of the cooled core is evaluated as M cool=3.6×106 M⊙ ( I 21/1)−0.32. This scale depends only on the incident UV intensity, and provides a lower limit to the mass of collapsed objects in the UV radiation field.  相似文献   

14.
A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C2 and CO, and predicts a column density of 91010 cm2 for HCO+.  相似文献   

15.
To better understand the environment surrounding CO emission clumps in the Keyhole Nebula, we have made images of the region in H2 1–0 S(1) (2.122-μm) emission and polycyclic aromatic hydrocarbon (PAH) emission at 3.29 μm. Our results show that the H2 and PAH emission regions are morphologically similar, existing as several clumps, all of which correspond to CO emission clumps and dark optical features. The emission confirms the existence of photodissociation regions (PDRs) on the surface of the clumps. By comparing the velocity range of the CO emission with the optical appearance of the H2 and PAH emission, we present a model of the Keyhole Nebula whereby the most negative velocity clumps are in front of the ionization region, the clumps at intermediate velocities are in it and those which have the least negative velocities are at the far side. It may be that these clumps, which appear to have been swept up from molecular gas by the stellar winds from η  Car, are now being overrun by the ionization region and forming PDRs on their surfaces. These clumps comprise the last remnants of the ambient molecular cloud around η Car.  相似文献   

16.
Maps are presented of 3 P 1→3 P 0[C  i ] and J =2→1 C18O line emission from the interstellar molecular cloud G35.2−0.74N. The maps are interpreted with reference to a previous model for the structure of the cloud in which opposing jets from a central object, embedded in a rotating interstellar disc, precess and drive a bipolar molecular outflow. The C18O emission traces the rotating interstellar disc, but the [C  i ] emission shows several features. An unresolved component is observed which probably results from dissociation of CO in the centre of the disc by UV radiation from the central source. Background [C  i ] emission is also observed which shares the rotation of the disc on larger scales. The C  i /CO ratio in these components is typically a few per cent. High-velocity [C  i ] emission, where C  i /CO is high (>0.1–0.4), is observed between the CO molecular outflow and the cavity exacavated by the jet. This material has probably been accelerated by the jet but dissociated by far-UV radiation propagating through the cavity. The C  i /CO ratio falls as the shocked outflow later sweeps up CO.  相似文献   

17.
Near-infrared images in H2 line emission and submillimetre maps in CO J  = 3–2 emission illustrate the remarkable association between a molecular bow shock and the redshifted molecular outflow lobe in W75N. The flow lobe fits perfectly into the wake of the bow, as one would expect if the lobe represented swept-up gas. Indeed, these observations strongly support the 'bow shock' entrainment scenario for molecular outflows driven by young stars.   The characteristics of the bow shock and CO outflow lobe are compared with those of numerical simulations of jet-driven flows. These models successfully reproduce the bulge and limb-brightening in the CO outflow, although the model H2 bow exhibits more structure extending back along the flow axis. We also find that the size of the flow, the high mass fraction in the flow at low outflow velocities (low γ values) and the high CO/H2 luminosity ratio indicate that the system is evolved. We also predict a correlation, in evolved systems, between outflow age and the CO/H2 luminosity ratio.  相似文献   

18.
We have computed optical absorption-line profiles of CH+ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C+(H2, H)CH+. Whilst CH+ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH+3(e−, H2)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH+ and CH line profiles is found to be no more than approximately 2 km s−1, which is smaller than has previously been assumed. We also investigate OH and HCO+, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.  相似文献   

19.
CO isotopes are able to probe the different components in protostellar clouds. These components, core, envelope and outflow have distinct physical conditions, and sometimes more than one component contributes to the observed line profile. In this study, we determine how CO isotope abundances are altered by the physical conditions in the different components. We use a 3D molecular line transport code to simulate the emission of four CO isotopomers, 12CO   J = 2 → 1, 13CO J = 2 → 1  , C18O   J = 2 → 1  and C17O   J = 2 → 1  from the Class 0/1 object L483, which contains a cold quiescent core, an infalling envelope and a clear outflow. Our models replicate James Clerk Maxwell Telescope (JCMT) line observations with the inclusion of freeze-out, a density profile and infall. Our model profiles of 12CO and 13CO have a large linewidth due to a high-velocity jet. These profiles replicate the process of more abundant material being susceptible to a jet. C18O and C17O do not display such a large linewidth as they trace denser quiescent material deep in the cloud.  相似文献   

20.
Compact regions of enhanced HCO+ and NH3 emission have been detected close to a number of Herbig–Haro objects. An interpretation of these detections is the following: a transient clump within the molecular cloud has been irradiated by the shock that generates the Herbig–Haro object. The irradiation releases icy mantles from the grains within the transient clump and initiates a photochemistry. On the basis of this picture, we have developed an extensive chemical model which predicts that a wide range of species, other than NH3 and HCO+, should also be detectable. These include CH3OH, H2S, C3H4, H2CO, SO, SO2, H2CS and NS. The chemical effects should last ∼  104 yr  .  相似文献   

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