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1.
The Ca–Mg relationship in groundwaters strongly points to the overall dolomitization and local albitization. The Mg/Ca ratios reveal two trends by which saline waters develop: increase of Mg/Ca ratio by evaporation and decreasing Mg/Ca ratios due to dolomitization and albitization. Br/Cl vs. Na/Cl ratios demonstrate that albitization does not play a major role which leaves dolomitization to be the main source for decreasing Mg/Ca ratios in saline waters. In the eastern and southern Region of Lake Kinneret, salinization occurs by mixing with a Ca/Mg molar ratio <1 brine (Ha’On type). Along the western shoreline of the Lake, a Ca/Mg > 1 dominates, which developed by the albitization of plagioclase in abundant mafic volcanics and the dolomitization of limestones. The most saline groundwater of the Tabgha-, Fuliya-, and Tiberias clusters could be regional derivatives of at least two mother brines: in diluted form one is represented by Ha’On water, the other is a Na-rich brine of the Zemah type. Additionally, a deep-seated Ca-dominant brine may ascend along the fractures on the western side of Lake Kinneret, which is absent on the eastern side. Groundwaters of the Lower Jordan Valley are chemically different on both sides of the Jordan River, indicating that the exchange of water is insignificant. All saline waters from the Dead Sea and its surroundings represent a complex mixture of brines, and precipitation and local dissolution of halite and gypsum. Many wells of the Arava/Araba Valley pump groundwater from the Upper Cretaceous limestone aquifer, the origin of the water is actually from the Lower Cretaceous Kurnub Group sandstones. Groundwater drawn from the Quaternary alluvial fill either originates from Kurnub Group sandstones (Eilat 108, Yaalon 117) or from altered limestones of the Judea Group. The origin of these waters is from floods flowing through wadis incised into calcareous formations of the Judea Group. On the other hand, as a result of step-faulting, hydraulic contact is locally established between the Kurnub- and the Judea Groups aquifers facilitating the inter-aquifer flow of the confined Kurnub paleowater into the karstic formations of the Judea Group. Two periods of Neogene brine formation are considered: the post-Messinan inland lagoon resulting in drying up of the Sdom Sea and the evaporation of the Pleistocene Samra Lake, which went further through the stage of Lake Lisan to the present Dead Sea. For the first period, major element hydrochemistry suggests that the saline waters and brines in the Jordan-Dead Sea–Arava Valley transform evolved from the gradual evaporation of an accumulating mixture of sea-, ground-, and surface water. Due to the precipitation of carbonates, gypsum, and halite, such an evaporating primary water body was strongly enriched in Mg, Br, and B and shows high molar ratios of Br/Cl, B/Cl, and Mg/Ca but low Na/Cl ratios. The development of the Br/Cl ratio is chemically modelled, showing that indeed brine development is explicable that way. Along with the evaporation brine, evaporites formed which are leached by infiltrating fresh water yielding secondary brines with Na/Cl ratios of 1. When primary brines infiltrated the sub-surface, they were subjected to Mg–Ca exchange in limestones (dolomitization) and to chloritization and albitization in basic igneous rocks turning them into Ca-Cl brines. These tertiary brines are omnipresent in the Rift. The brines of the late Lisan and Dead Sea were generated by evaporating drainage waters, which leached halite, gypsum, and carbonates from the soil and from the sub-surface. All these brines are still being flushed out by meteoric water, resulting in saline groundwaters. This flushing is regionally enhanced by intensive groundwater exploitation. In variable proportions, the Neogene and late Lisan Lake and Recent Dead Sea brines have to be considered as the most serious sources of salinization of groundwaters in the Rift. Deep-seated pre-Sdom brines cannot strictly be excluded, but if active they play a negligible role only. An erratum to this article can be found at  相似文献   

2.
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3.
Yemen is a semi-arid country with very limited water resources. Sana’a Basin is located in the central part of Yemen and is the major source of water for drinking and irrigation. High abstraction rates in Sana’a Basin rising from 21.1 million (M) m3 in 1972 to 227.7?Mm3 in 2006, have led to a major decline in water levels and deterioration in groundwater quality. Effective management of groundwater resources in Sana’a Basin can be aided by modelling. FEFLOW was used to build a groundwater flow model for the basin and the model was calibrated under transient conditions for the period 1972–2006. The water balance for transient conditions of the Sana’a Basin in 2006 indicated that the total annual inflow was 116.9?Mm3, and the total annual outflow was 245.8?Mm3. Three scenarios for potential groundwater extraction for the period 2006–2020 are presented. The first represents the present status based on the 2006 extraction rates without introducing any management measures. The second is based on maximum domestic, agricultural and industrial consumption of water resources. The third simulates the effect of water-resource augmentation, i.e. the increase of groundwater recharge, and maximizes sustainability by reducing water consumption. Identified areas of the basin require prompt management action.  相似文献   

4.
Managing environmental problems in Cuban karstic aquifers   总被引：1，自引：0，他引：1  
The study area is located along the Dead Sea Rift, the climate is considered arid in its southern margin near the Dead Sea, which is the lowest water reservoir found on the globe (412 m BSL), to semiarid in its northern part. During the last few decades, the water resources became depleted limiting the natural development of the agricultural settlements, which are the most common type of communities in the region. Previous studies suggested that a large amount of freshwater is lost as the result of salinization processes, which occur when fresh groundwater from the mountain aquifers, flow into the saline clastic Neogene aquifer complex. In order to comprehend this complex system, a detailed outlining of the regional hydrogeological system is essential. Since there are no boreholes, which penetrate the aquiferous rock sequences within the Rift, it was necessary to interpolate a large variety of data from several fields of geosciences. The methods applied included geological mapping, geophysical modeling based on interpretation of seismic profiles and geochemical modeling based on chemical and isotopic analysis of runoff, sediments and groundwater. The combined modeling based on results from the different types of analyses implied to several conclusions relevant to the regional water management policy: (1) groundwater becomes saline as it flows from the margins of the Rift to its center. Therefore, it is recommended to exploit it along the foothills of the rift escarpment. (2) Geophysical modeling indicated that the foothills and the Karstic mountain aquifer extend into the subsurface of the valley and can be farther exploited (up to 15 mm3 per annum) by relatively shallow wells. (3) Several mechanisms of groundwater salinization were deciphered: (a) the dense vertical faulting systems act as potential conduits for saline water, which flow-up from deep-seated sources and penetrate into the fresh aquifers. (b) Fresh groundwater in the clastic aquifer complex is rare, furthermore, two evaporates bodies were encountered (Auja and Zaharat el Qurein), also acting as sources for fresh water salinization. (c) Although the quantity of runoff recharge to the Jordan Valley aquifer complex is negligible, the increase in its salt-content (TDS) turns this negligible freshwater recharge to a significant contributor of salts.  相似文献   

5.
Increasing water demands,especially in arid and semi-arid regions,continuously exacerbate groundwater as the only reliable water resources in these regions.Samalqan watershed,Iran,is a groundwater-based irrigation watershed,so that increased aquifer extraction,has caused serious groundwater depletion.So that the catchment consists of surface water,the management of these resources is essential in order to increase the groundwater recharge.Due to the existence of rivers,the low thickness of the alluvial sediments,groundwater level fluctuations and high uncertainty in the calculation of hydrodynamic coefficients in the watershed,the SWAT and MODFLOW models were used to assess the impact of irrigation return flow on groundwater recharge and the hydrological components of the basin.For this purpose,the irrigation operation tool in the SWAT model was utilized to determine the fixed amounts and time of irrigation for each HRU(Hydrological Response Unit)on the specified day.Since the study area has pressing challenges related to water deficit and sparsely gauged,therefore,this investigation looks actual for regional scale analysis.Model evaluation criteria,RMSE and NRMSE for the simulated groundwater level were 1.8 m and 1.1%respectively.Also,the simulation of surface water flow at the basin outlet,provided satisfactory prediction(R2=0.92,NSE=0.85).Results showed that,the irrigation has affected the surface and groundwater interactions in the watershed,where agriculture heavily depends on irrigation.Annually 11.64 Mm3 water entered to the aquifer by surface recharge(precipitation,irrigation),transmission loss from river and recharge wells 5.8 Mm3 and ground water boundary flow(annually 20.5 Mm3).Water output in the watershed included ground water extraction and groundwater return flow(annually 46.4 Mm3)and ground water boundary flow(annually 0.68 Mm3).Overally,the groundwater storage has decreased by 9.14 Mm3 annually in Samalqan aquifer.This method can be applied to simulate the effects of surface water fluxes to groundwater recharge and river-aquifer interaction for areas with stressed aquifers where interaction between surface and groundwater cannot be easily assessed.  相似文献   

6.
Groundwaters were collected around the Spence porphyry copper deposit, Atacama Desert, northern Chile, to study water-porphyry copper ore bodies interaction and test hypotheses regarding transport of metals through thick overburden leading to the formation of soil geochemical anomalies. The deposit contains 400 Mt of 1% Cu and is completely buried by piedmont gravels of Miocene age. Groundwaters were recovered from the eastern up hydraulic gradient (upflow) margin of the Spence deposit, from within the deposit, and for two kilometers down flow from the deposit. Water table depths decrease from 90 m at the upflow margin to 30 m 1.5 km down flow. Groundwaters at the Spence deposit are compositionally variable with those upflow of the deposit characterized by relatively low salinities (900-7000 mg/L) and Na+-SO42−-type compositions. These waters have compositions and stable isotope values similar to regional groundwaters recovered elsewhere in the Atacama Desert of Northern Chile. In contrast, groundwaters recovered within and down flow of the deposit range in salinity from 10,000 to 55,000 mg/L (one groundwater at 145,000 mg/L) and are dominantly Na+-Cl−-type waters. Dissolved sulfate values are, however, elevated compared to upflow waters, and δ34SCDT decreases into the deposit (from >4‰ to 2‰), consistent with increasing influence of sulfur derived from oxidation of sulfide minerals within the deposit. The increase in salinity and conservative tracers (Cl−, Br−, Li+, and Na+) and the relationship between oxygen and hydrogen isotopes suggests that in addition to water-rock reactions within the deposit, most of the compositional variation can be explained by groundwater mixing (with perhaps a minor role for evaporation). A groundwater-mixing scenario implies a deeper, more saline groundwater source mixing with the less saline regional groundwater-flow system. Flow of deeper, more saline groundwater along pre-existing structures has important implications for geochemical exploration and metal-transport models.  相似文献   

7.
Formation water samples from deep drillings in southern Israel fall into three regional groups, each of which shows distinct chemical and isotopic characteristics. Waters from the Mediterranean coastal plain appear to be of marine lagoonal origin; some of these brines are associated with occurrences of oil. In the mountain region the top part of the sedimentary sequence has been flushed by fresher waters, apparently during Pleistocene time. In Jurassic and deeper-lying formations one encounters concentrated brines of seawater origin, with low Na/Ca ratios, which have undergone a process of ultrafiltration. In the Rift Valley proper, magnesium-rich brines have invaded the deeper formations, and are evidently of continental lake origin.The absence of oil occurrences in association with the CaCl2 brines of the inland locations is interpreted as being due mainly to loss of oil as a result of the tectonic events associated with the formation of the Jordan Rift Valley.  相似文献   

8.
One of the most important processes leading to the deterioration of groundwater in Israel is the migration of brines penetrating into fresh groundwater bodies. Such manifestations occur at an ever increasing frequency and in unexpected locations. The hydrochemistry of these processes reveals the possibility of involvement of several types of brines. The distribution and the hydrostratigraphic sequence of the brines is correlated with the evolution of paleoenvironments during the geological history of the region. Several major phases of brine and evaporite formation are discerned: The earliest phase occurred in the Paleozoic–Early Mesozoic (Yam Suf–Ramon–Lower Arad Groups) during which brines were generated by dissolution of evaporites. The second major phase in the evolution of brines occurred during the Mio-Pliocene. In the western areas of the country, the brines were generated mainly by the post-Messinian ingression of seawater which dissolved evaporites and reacted with the invaded rock sequence. In the Rift and in adjoining areas, the dominant brine was the final product of the evaporation of an inland marine lagoon (the Sdom Sea) which penetrated into an environment prevalently built of previously formed rocks and, particularly of clastic beds filling at that time, the nascent rift. From this evaporating lagoon precipitated evaporates, the dissolution of which produced brines. A further step in the hydrochemical evolution in the Rift was the creation of the Lisan Lake, which became progressively saline, probably as the result of dissolution and flushing of salts derived from the previous hypersaline Sdom Sea. The contemporary phase in the Rift is characterized by an ongoing process of flushing-out of residual brines and dissolution of evaporites by currently recharged fresh water. Throughout the geological history of the area, four major periods of flushing stand out. These occurred between the Triassic and the Jurassic, at the end of the Jurassic, as the result of the Oligocene uplift and as part of the Messinian event. As the result of these processes, the rock-sequences were flushed off previously formed brines and evaporites and were “made ready” for following generations of liquids.  相似文献   

9.
In recent years, voices in Jordan became lauder to exploit the fresh to brackish deep groundwater overlain by fresh groundwater bodies. In this article the implications of such a policy on the existing fresh water bodies are worked out through studying the sources of salinity in the different aquifer systems and the potentials of salinity mobilization by artificial changes in the hydrodynamic regimes. It is concluded that extracting the groundwater of deep aquifers overlain by fresh water bodies, whether the deep groundwater is fresh to brackish, brackish or salty, is equivalent to extracting groundwater from the overlying fresh groundwater bodies because of the hydraulic connections of the deep and the shallow aquifers’ groundwaters. The consequences are even more complicated and severe because exploiting the deep groundwater containing brackish or salty water will lead to refilling by fresh groundwater leaking from the overlying aquifers. The leaking water becomes salinized as soon as it enters the pore spaces of the emptied deep aquifer matrix and by mixing with the deep aquifer brackish or saline groundwater. Therefore, the move to exploit the deep groundwater is misleading and damaging the aquifers and is unjust to future generation's rights in the natural wealth of Jordan or any other country with similar aquifers’ set-up. In addition, desalination produces brines with high salinity which cannot easily be discharged in the highlands of Jordan (with only very limited access to the open sea) because they will on the long term percolate down into fresh water aquifers.  相似文献   

10.
The time domain electromagnetic (TDEM) geophysical method was employed to detect saline groundwater bodies within and in the close margins of the Arava Rift Valley. The Arava Valley aquifers are known to occupy fresh to saline groundwater. The lateral subsurface inflow to the Arava from west and east is characterized by fresh to brackish waters. The results of the present study indicate that salination of groundwater is controlled by both present day and ancient base levels, namely by the Dead Sea in the north and by the Gulf of Elat in the south. The configuration obtained by the TDEM survey exhibits interfaces and palaeo-interfaces between fresh to brackish waters and underlying seawater or diluted seawater intruded inland from both base levels as well as brines intruded from the northern base level. The central Arava structural and hydrological divide seems to escape seawater or brine encroachment at least to the considerable depth of the TDEM measurements.  相似文献   

11.
The Minqin Basin is at the lower reach of the Shiyang River of Gansu province in northwest China. Dramatic decline in groundwater level has resulted from over-abstraction of groundwater since the late 1950s to satisfy increasing irrigation and other demands. Severe water shortage led to environmental degradation. To better understand the spatial–temporal variation of groundwater levels and to evaluate the groundwater resources in the region, a three-dimensional regional groundwater flow model was built and calibrated under transient condition. The MODFLOW program was used and the research area was discretized as a square network with cell size of 400 × 400 m. The model showed that the aquifer was under destructive stress, with a groundwater resource deficit of 260 million cubic meters per year (Mm3/year) on average. Since the inflow of surface water from the upstream basin has declined to about 100–150 Mm3/year in recent decades, the irrigation return flow had become the main recharge and accounted for 60.6% of total recharge; meanwhile, abstraction by pumping wells took 99.2% from the total groundwater discharge.  相似文献   

12.
Modeling of groundwater flow for Mujib aquifer, Jordan   总被引：4，自引：0，他引：4  
Jordan is an arid country with very limited water resources. Groundwater is the main source for its water supply. Mujib aquifer is located in the central part of Jordan and is a major source of drinking water for Amman, Madaba and Karak cities. High abstraction rates from Mujib aquifer during the previous years lead to a major decline in water levels and deterioration in groundwater quality. Therefore, proper groundwater management of Mujib aquifer is necessary; and groundwater flow modeling is essential for proper management. For this purpose, Modflow was used to build a groundwater flow model to simulate the behavior of the flow system under different stresses. The model was calibrated for steady state condition by matching observed and simulated initial head counter lines. Drawdown data for the period 1985–1995 were used to calibrate the transient model by matching simulated drawdown with the observed one. Then, the transient model was validated by using drawdown data for the period 1996–2002. The results of the calibrated model showed that the horizontal hydraulic conductivity of the B2/A7 aquifer ranges between 0.001 and 40m/d. Calibrated specific yield ranges from 0.0001 to 0.15. The water balance for the steady state condition of Mujib aquifer indicated that the total annual direct recharge is 20.4 × 106m3, the total annual inflow is 13.0 × 106 m3, springs discharge is 15.3 × 106 m3, and total annual outflow is 18.7 × 106 m3. Different scenarios were considered to predict aquifer system response under different conditions. The results of the sensitivity analysis show that the model is highly sensitive to horizontal hydraulic conductivity and anisotropy and with lower level to the recharge rates. Also the model is sensitive to specific yield  相似文献   

13.
The Bet She’an and Harod Valleys in Israel are regional recipients and mixing zones for groundwater draining from a multiple aquifer system, which includes carbonate and basalt aquifers and deep-seated pressurized brines. The aquifers drain through two types of outlets, distinct and mixed. The latter type is mainly conditioned by the occurrence of fault-blocks related to the Jordan Rift system, which act as connecting media between the aquifers and facilitate interaquifer flow. Conjoint application of rare earth element distribution and water isotopes enables detection of the local areas replenishment by rainfall infiltration and, in connection with the position of wells or springs, the identification of groundwater flow paths. Once stationary equilibria are established changes of REY composition between REY in groundwater and their surface adsorption, are negligible. In areas with little soil coverage and vegetation even recharge over young Tertiary and diagenetic Cretaceous limestones is distinguishable by their REY distribution patterns. Groundwater recharged over Tertiary limestones show higher REY abundance and more significant Ce anomalies than those derived from the Cretaceous limestones. Weathering of alkali olivine basalts leads to REY patterns in groundwater depleted in the middle REE. The improved knowledge of the hydrological systems is thought to be useful for regional hydrogeological modeling and for designing rational water management schemes.  相似文献   

14.
The chemical and isotopic (87Sr/86Sr, δ11B, δ34Ssulfate, δ18Owater, δ15Nnitrate) compositions of water from the Lower Jordan River and its major tributaries between the Sea of Galilee and the Dead Sea were determined in order to reveal the origin of the salinity of the Jordan River. We identified three separate hydrological zones along the flow of the river:
(1)
A northern section (20 km downstream of its source) where the base flow composed of diverted saline and wastewaters is modified due to discharge of shallow sulfate-rich groundwater, characterized by low 87Sr/86Sr (0.7072), δ34Ssulfate (−2‰), high δ11B (∼36‰), δ15Nnitrate (∼15‰) and high δ18Owater (−2 to-3‰) values. The shallow groundwater is derived from agricultural drainage water mixed with natural saline groundwater and discharges to both the Jordan and Yarmouk rivers. The contribution of the groundwater component in the Jordan River flow, deduced from mixing relationships of solutes and strontium isotopes, varies from 20 to 50% of the total flow.
(2)
A central zone (20-50 km downstream from its source) where salt variations are minimal and the rise of 87Sr/86Sr and SO4/Cl ratios reflects predominance of eastern surface water flows.
(3)
A southern section (50-100 km downstream of its source) where the total dissolved solids of the Jordan River increase, particularly during the spring (70-80 km) and summer (80-100 km) to values as high as 11.1 g/L. Variations in the chemical and isotopic compositions of river water along the southern section suggest that the Zarqa River (87Sr/86Sr∼0.70865; δ11B∼25‰) has a negligible affect on the Jordan River. Instead, the river quality is influenced primarily by groundwater discharge composed of sulfate-rich saline groundwater (Cl-=31-180 mM; SO4/Cl∼0.2-0.5; Br/Cl∼2-3×10-3; 87Sr/86Sr∼0.70805; δ11B∼30‰; δ15Nnitrate ∼17‰, δ34Ssulfate=4-10‰), and Ca-chloride Rift valley brines (Cl-=846-1500 mM; Br/Cl∼6-8×10-3; 87Sr/86Sr∼0.7080; δ11B>40‰; δ34Ssulfate=4-10‰). Mixing calculations indicate that the groundwater discharged to the river is composed of varying proportions of brines and sulfate-rich saline groundwater. Solute mass balance calculations point to a ∼10% contribution of saline groundwater (Cl−=282 to 564 mM) to the river. A high nitrate level (up to 2.5 mM) in the groundwater suggests that drainage of wastewater derived irrigation water is an important source for the groundwater. This irrigation water appears to leach Pleistocene sediments of the Jordan Valley resulting in elevated sulfate contents and altered strontium and boron isotopic compositions of the groundwater that in turn impacts the water quality of the lower Jordan River.
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15.
 High radon fluxes in the seismically active Dead Sea Rift seem to be affected by the hydrological system and the different salinities of groundwater bodies involved. The time domain electromagnetic (TDEM) method was employed to delineate those different bodies and the configuration of the interfaces between them. The present hydrological system and the related brines and interfaces are controlled by the Dead Sea base level, presently at 408 m below MSL. TDEM measurements detect low resistivity (<1 ohm/m) units representing brines and the interface between them as well as the overlying fresher water bodies. In addition, high resistivity (freshwater) units are also detected, underlying the brines, related herein to a multiple hydrological system. Low-resistivity brines, detected above the present base level, are interpreted herein as yet unflushed ones which correspond to a former higher base level. Higher sequences, below historical (sixteenth century) base levels, are already devoid of brines, which gives an indication as to the rate of flushing. Received: 3 June 1996 / Accepted: 23 July 1996  相似文献   

16.
The adsorption rate constants of Ra and Th were estimated from empirical data from a freshwater lake and its feeding saline springs. We utilized the unique setting of Lake Kinneret (Sea of Galilee, northern Israel) in which most of the Ra and Th nuclides are introduced into the lake by saline springs with high 226Ra activities and a high 224Ra/228Ra ratio of 1.5. The mixing of the Ra enriched saline waters and freshwater in the lake causes the 224Ra/228Ra ratio to drop down to 0.1 in the Kinneret due to preferential adsorption of 228Th. These conditions constitute a “natural experiment” for estimating adsorption rates. We developed a simple mass-balance model for the radionuclides in Lake Kinneret that accurately predicted the Ra isotope ratios and the 226Ra activity in the lake. The model is comprised of simultaneous equations; one for each radionuclide. The equations have one input term: supply of radionuclides from the saline springs; and three output terms: adsorption on particles in the lake, radioactive decay and outflow from the lake. The redundancy in the analytical solutions to the mass balance equations for the relevant nuclides constrained the values of Ra and Th adsorption rate constants to a very narrow range. Our results indicate that the adsorption rate constant for Ra is between 0.005 d−1 and 0.02 d−1. The rate constant for Th is between 0.5 d−1 and 1 d−1, about fifty to a hundred times higher. The estimated desorption rate coefficient for Ra is about 50-100 times larger than its adsorption rate constant. The mass-balance equations show that the residence times of all Ra isotopes (226Ra, 228Ra,223Ra, 224Ra) and of 228Th in the lake are about 95, 92, 14, 6 and 1 d, respectively. These residence times are much shorter than the residence time of water in the lake (about 5.5 y). The steady state activity ratios in Lake Kinneret depend mainly on the adsorption rate constants, decay constants, the outflow rate from the lake and the activity ratios in the saline springs. The activity ratios are independent of the saline springs flow rate.  相似文献   

17.
The discovery of layered, SO4-rich sediments on the Meridiani Planum on Mars has focused attention on understanding the formation of acid–saline lakes. Many salt lakes have formed in southern Australia where regional groundwaters are characterized by acidity and high salinity and show features that might be expected in the Meridiani sediments. Many (but not all) of the acid–saline Australian groundwaters are found where underlying Tertiary sediments are sulfide-rich. When waters from the formations come to the surface or interact with oxidised meteoric water, acid groundwaters result. In this paper examples of such waters around Lake Tyrrell, Victoria, and Lake Dey-Dey, South Australia, are reviewed. The acid–saline groundwaters typically have dissolved solids of 30–60 g/L and pH commonly <4.5. Many contain high concentrations of Fe and other metals, leached from local sediments. The combination of acidity and salinity also releases Ra. Around salt-lakes, these acidic waters often emerge at the surface in marginal spring zones where the low density (ρ ∼ 1.04) regional water flows out over the denser (ρ ∼ 1.16) lake brines. In the spring zones examined, large amounts of Fe are commonly precipitated. In a few places minerals of the alunite-jarosite family are formed which can trap many other metals, including Ra. The studied groundwater systems were discovered by U exploration programs following up radiometric anomalies related to this Ra. Evaporation concentrates the lesser soluble salts (gypsum and some halite) on the surface of the lakes. The lake brines contain most of the more soluble salts and form a column within the porous sediments which is held in place by hydrostatic forces around the salt-lake. These brines are near-neutral in pH.  相似文献   

18.
Changes in the climatic conditions during the Late Quaternary and Holocene greatly impacted the hydrology and geochemical evolution of groundwaters in the Great Lakes region. Increased hydraulic gradients from melting of kilometer-thick Pleistocene ice sheets reorganized regional-scale groundwater flow in Paleozoic aquifers in underlying intracratonic basins. Here, we present new elemental and isotopic analyses of 134 groundwaters from Silurian-Devonian carbonate and overlying glacial drift aquifers, along the margins of the Illinois and Michigan basins, to evaluate the paleohydrology, age distribution, and geochemical evolution of confined aquifer systems. This study significantly extends the spatial coverage of previously published groundwaters in carbonate and drift aquifers across the Midcontinent region, and extends into deeper portions of the Illinois and Michigan basins, focused on the freshwater-saline water mixing zones. In addition, the hydrogeochemical data from Silurian-Devonian aquifers were integrated with deeper basinal fluids, and brines in Upper Devonian black shales and underlying Cambrian-Ordovician aquifers to reveal a regionally extensive recharge system of Pleistocene-age waters in glaciated sedimentary basins. Elemental and isotope geochemistry of confined groundwaters in Silurian-Devonian carbonate and glacial drift aquifers show that they have been extensively altered by incongruent dissolution of carbonate minerals, dissolution of halite and anhydrite, cation exchange, microbial processes, and mixing with basinal brines. Carbon isotope values of dissolved inorganic carbon (DIC) range from −10 to −2‰, 87Sr/86Sr ratios range from 0.7080 to 0.7090, and δ34S-SO4 values range from +10 to 30‰. A few waters have elevated δ13CDIC values (>15‰) from microbial methanogenesis in adjacent organic-rich Upper Devonian shales. Radiocarbon ages and δ18O and δD values of confined groundwaters indicate they originated as subglacial recharge beneath the Laurentide Ice Sheet (14-50 ka BP, −15 to −13‰ δ18O). These paleowaters are isolated from shallow flow systems in overlying glacial drift aquifers by lake-bed clays and/or shales. The presence of isotopically depleted waters in Paleozoic aquifers at relatively shallow depths illustrates the importance of continental glaciation on regional-scale groundwater flow. Modern groundwater flow in the Great Lakes region is primarily restricted to shallow unconfined glacial drift aquifers. Recharge waters in Silurian-Devonian and unconfined drift aquifers have δ18O values within the range of Holocene precipitation: −11 to −8‰ and −7 to −4.5‰ for northern Michigan and northern Indiana/Ohio, respectively. Carbon and Sr isotope systematics indicate shallow groundwaters evolved through congruent dissolution of carbonate minerals under open and closed system conditions (δ13CDIC = −14.7 to−11.1‰ and 87Sr/86Sr = 0.7080-0.7103). The distinct elemental and isotope geochemistry of Pleistocene- versus Holocene-age waters further confirms that surficial flow systems are out of contact with the deeper basinal-scale flow systems. These results provide improved understanding of the effects of past climate change on groundwater flow and geochemical processes, which are important for determining the sustainability of present-day water resources and stability of saline fluids in sedimentary basins.  相似文献   

19.
The Bet She’an and Harod Valleys are regional recipients and mixing zones for groundwater draining to these valleys from a multiple aquifer system. This aquifer system includes two different carbonate aquifers, several groundwater-bearing basalt flows and deep-seated pressurized brine, the upflow of which causes salinization of fresh groundwater bodies. These aquifers drain through two groups of springs. Due to lack of information on the subsurface structure of the valley the flow-paths of groundwater feeding the springs, the initial distribution of salinities along the valley and particularly, the inflow-paths of the brines, have never been understood but were assumed to be fault-controlled. The interpretation of seismic profiles and analysis of gravity anomalies revealed the subsurface structure of the valley and namely the occurrence of a dense network of faults which branch out from those delineating the Jordan-Dead Sea Rift. The faults formed a series of uplifted and down-warped horst-and-graben structures. By joint analysis of structural, hydrological and geochemical evidence, it occurs that groundwater flow-paths leading to the springs emerging in the middle of the Bet She’an Valley are determined by structural elements such as major faults and fault-controlled structures. The penetration of the pressurized Ca-chloride Rift brines and their inflow into fresh groundwater bodies occurs prevalently along the faults outlining the western margins of the Dead Sea Rift Valley and at their intersection with outbranching NW–SE-striking faults.  相似文献   

20.
Stable isotopes (H, O, C) were determined for ground and surface waters collected from two relatively undisturbed massive sulfide deposits (Halfmile Lake and Restigouche) in the Bathurst Mining Camp (BMC), New Brunswick, Canada. Additional waters from active and inactive mines in the BMC were also collected. Oxygen and hydrogen isotopes of surface and shallow groundwaters from both the Halfmile Lake and Restigouche deposits are remarkably uniform (− 13 to − 14‰ and − 85 to − 95‰ for δ18OVSMOW and δ2HVSMOW, respectively). These values are lighter than predicted for northern New Brunswick and, combined with elevated deuterium excess values, suggest that recharge waters are dominated by winter precipitation, recharged during spring melting. Deeper groundwaters from the Restigouche deposit, and from active and inactive mines have heavier δ18OVSMOW ratios (up to − 10.8‰) than shallow groundwaters suggesting recharge under warmer climate or mixing with Shield-type brines. Some of the co-variation in Cl concentrations and δ18OVSMOW ratios can be explained by mixing between saline and shallow recharge water end-members. Carbon isotopic compositions of dissolved inorganic carbon (DIC) are variable, ranging from − 15 to − 5‰ δ13CVPDB for most ground and surface waters. Much of the variation in the carbon isotopes is consistent with closed system groundwater evolution involving soil zone CO2 and fracture zone carbonate minerals (calcite, dolomite and siderite; average = − 6.5‰ δ13CVPDB). The DIC of saline Restigouche deposit groundwater is isotopically heavy (∼+ 12‰ δ13CVPDB), indicating carbon isotopic fractionation from methanogenesis via CO2 reduction, consistent with the lack of dissolved sulfate in these waters and the observation of CH4-degassing during sampling.  相似文献   

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