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1.
Efrat Farber Ittai Gavrieli Thomas D. Bullen Ran Holtzman Uri Shavit 《Geochimica et cosmochimica acta》2004,68(9):1989-2006
The chemical and isotopic (87Sr/86Sr, δ11B, δ34Ssulfate, δ18Owater, δ15Nnitrate) compositions of water from the Lower Jordan River and its major tributaries between the Sea of Galilee and the Dead Sea were determined in order to reveal the origin of the salinity of the Jordan River. We identified three separate hydrological zones along the flow of the river:
- (1)
- A northern section (20 km downstream of its source) where the base flow composed of diverted saline and wastewaters is modified due to discharge of shallow sulfate-rich groundwater, characterized by low 87Sr/86Sr (0.7072), δ34Ssulfate (−2‰), high δ11B (∼36‰), δ15Nnitrate (∼15‰) and high δ18Owater (−2 to-3‰) values. The shallow groundwater is derived from agricultural drainage water mixed with natural saline groundwater and discharges to both the Jordan and Yarmouk rivers. The contribution of the groundwater component in the Jordan River flow, deduced from mixing relationships of solutes and strontium isotopes, varies from 20 to 50% of the total flow.
- (2)
- A central zone (20-50 km downstream from its source) where salt variations are minimal and the rise of 87Sr/86Sr and SO4/Cl ratios reflects predominance of eastern surface water flows.
- (3)
- A southern section (50-100 km downstream of its source) where the total dissolved solids of the Jordan River increase, particularly during the spring (70-80 km) and summer (80-100 km) to values as high as 11.1 g/L. Variations in the chemical and isotopic compositions of river water along the southern section suggest that the Zarqa River (87Sr/86Sr∼0.70865; δ11B∼25‰) has a negligible affect on the Jordan River. Instead, the river quality is influenced primarily by groundwater discharge composed of sulfate-rich saline groundwater (Cl-=31-180 mM; SO4/Cl∼0.2-0.5; Br/Cl∼2-3×10-3; 87Sr/86Sr∼0.70805; δ11B∼30‰; δ15Nnitrate ∼17‰, δ34Ssulfate=4-10‰), and Ca-chloride Rift valley brines (Cl-=846-1500 mM; Br/Cl∼6-8×10-3; 87Sr/86Sr∼0.7080; δ11B>40‰; δ34Ssulfate=4-10‰). Mixing calculations indicate that the groundwater discharged to the river is composed of varying proportions of brines and sulfate-rich saline groundwater. Solute mass balance calculations point to a ∼10% contribution of saline groundwater (Cl−=282 to 564 mM) to the river. A high nitrate level (up to 2.5 mM) in the groundwater suggests that drainage of wastewater derived irrigation water is an important source for the groundwater. This irrigation water appears to leach Pleistocene sediments of the Jordan Valley resulting in elevated sulfate contents and altered strontium and boron isotopic compositions of the groundwater that in turn impacts the water quality of the lower Jordan River.
2.
We present a visco-elastic bubble growth model, accounting for viscous and elastic deformations and for volatile mass transfer
between bubbles and melt. We define the borders between previous bubble growth models accounting for incompressible viscous
melt, and our new model accounting also for elastic deformation; this is done by a set of end-member analytical solutions
and numerical simulations. Elastic deformation is most prominent for magma of small vesicularity, where the growth regime
depends on the shear modulus. For high shear modulus, bubble growth is slow and follows an exponential law in a viscous growth
regime, while for low shear modulus bubbles quickly follow a square-root diffusive solution. Our model provides all the elastic
components (stresses, strains and strain rates) required for defining criteria for failure and magma fragmentation. We suggest
two failure criteria, a stress related one based on the internal friction and the Mohr-Coulomb failure theory, and a strain
related one based on fibre elongation experiments. We argue that both criteria are equivalent if we consider their shear modulus
dependency and its effect on magma rheology. Last, we apply our model to the process of bubble nucleation. In the incompressible
case, following nucleation, growth is slow and leads to long incubation times during which bubbles may be dissolved back into
the melt. The elastic response in magmas with low shear modulus results in a short incubation time, increasing the probability
of survival. The above effects emphasize the significance of visco-elasticity for the dynamic processes occurring in magmas
during volcanic activity. 相似文献
3.
An increase in salinity and change from oxic to anoxic conditions are observed in the Upper subaquifer of the Judea Group
in the Kefar Uriyya pumping field at the western foothills of the Judea Mountains, Israel. Hydrogeological data indicate that
the change, which occurs over a distance of only a few kilometers, coincides with a transition from confined to phreatic conditions
in the aquifer. The deterioration in the water quality is explained as a result of seepage of more saline, organic-rich water
from above, into the phreatic "roofed" part of the aquifer. The latter is derived from the bituminous chalky rocks of the
Mount Scopus Group, which confine the aquifer in its southeastern part. In this confined part, water in perched horizons within
the Mount Scopus Group cannot leak down and flow westward while leaching organic matter and accumulating salts. However, upon
reaching the transition area from confined to phreatic conditions, seepage to the Judea Upper subaquifer is possible, thereby
allowing it to be defined as a leaky aquifer. The incoming organic matter consumes the dissolved oxygen and allows bacterial
sulfate reduction. The latter accounts for the H2S in the aquifer, as indicated by sulfur isotopic analyses of coexisting sulfate and sulfide. Thus, from an aquifer management
point of view, in order to maintain the high quality of the water in the confined southeastern part of the Kefar Uriyya field,
care should be taken not to draw the confined-roofed transition area further east by over pumping.
Electronic Publication 相似文献
4.
Gypsum precipitation kinetics were examined from a wide range of chemical compositions , ionic strengths (4.75-10 m) and saturation state with respect to gypsum (1.16-1.74) in seeded batch experiments of mixtures of Ca2+-rich Dead Sea brine and -rich seawater. Despite the variability in the experimental solutions, a single general rate law was formulated to describe the heterogeneous precipitation rate of gypsum from these mixtures:
5.
Gypsum as a monitor of the paleo-limnological–hydrological conditions in Lake Lisan and the Dead Sea
A. Torfstein I. Gavrieli A. Katz Y. Kolodny M. Stein 《Geochimica et cosmochimica acta》2008,72(10):2491-2509
The isotopic composition and mass balances of sources and sinks of sulfur are used to constrain the limnological–hydrological evolution of the last glacial Lake Lisan (70–14 ka BP) and the Holocene Dead Sea. Lake Lisan deposited large amounts of primary gypsum during discrete episodes of lake level decline. This gypsum, which appears in massive or laminated forms, displays δ34S values in the range of 14–28‰. In addition, Lake Lisan’s deposits (the Lisan Formation) contain thinly laminated and disseminated gypsum as well as native sulfur which display significantly lower δ34S values (−26 to 1‰ and −20 to −10‰, respectively). The calculated bulk isotopic compositions of sulfur in the sources and sinks of Lake Lisan lacustrine system are similar (δ34S ≈ 10‰), indicating that freshwater sulfate was the main source of sulfur to the lake. The large range in δ34S found within the Lisan Formation (−26 to +28‰) is the result of bacterial sulfate reduction (BSR) within the anoxic lower water body (the monimolimnion) and bottom sediments of the lake.
Precipitation of primary gypsum from the Ca-chloride solution of Lake Lisan is limited by sulfate concentration, which could not exceed 3000 mg/l. The Upper Gypsum Unit, deposited before ca. 17–15 ka, is the thickest gypsum unit in the section and displays the highest δ34S values (25–28‰). Yet, our calculations indicate that no more than a third of this Unit could have precipitated directly from the water column. This implies that during the lake level decline that instigated the precipitation of the Upper Gypsum Unit, significant amounts of dissolved sulfate had to reach the lake from external sources. We propose a mechanism that operated during cycles of high-low stands of the lakes that occupied the Dead Sea basin during the late Pleistocene. During high-stand intervals (i.e., Marine Isotopic Stages 2 and 4), lake brine underwent BSR and infiltrated the lake’s margins and adjacent strata. As lake level dropped, these brines, carrying 34S-enriched sulfate, were flushed back to the shrinking lake and replenished the water column with sulfate, thereby promoting massive gypsum precipitation.
The Holocene Dead Sea precipitated relatively small amounts of primary gypsum, mainly in the form of thin laminae. δ34S values of these laminae and disseminated gypsum are relatively constant (15 ± 0.7‰) and are close to present-day lake composition. This reflects the lower supply of freshwater to the lake and the limited BSR activity during the arid Holocene time and possibly during former arid interglacials in the Levant. 相似文献
6.
I. Gavrieli Alan Matthews J. B. Holland 《Contributions to Mineralogy and Petrology》1996,125(2-3):251-262
The hydrothermal reaction between grossular and 1 molar manganese chloride solution was studied at 2 kbar and 600 °C at various
bulk Ca/(Ca+Mn) compositions:
Ca3Al2Si3O12+3Mn2+(aq) ⇔ Mn3Al2Si3O12+3Ca2+(aq)
The reaction products are garnets of the spessartine-grossular solid-solution series which discontinuously armour the dissolving
grossular grains. The first garnet to crystallize is spessartine rich (X
gt
Mn≥0.95), reflecting the high Mn content of the solution, but as the reaction proceeds more calcium-rich garnets progressively
overgrow the initial products. The armouring product layer is detached from the dissolving grossular, which allows the progressive
overgrowth to occur on both its external and internal surfaces and results in the development of a two directional Ca/(Ca+Mn)
zoning pattern in the product grains. The compositional changes in the run products are consistent with attainment of heterogeneous
equilibrium between the external rims of the spessartine-grossular garnets and the bulk solutions in runs of duration ≥24
hours. Plots of ln KD versus X
gt
Ca maxima show linear variations that are not consistent with the ideal mixing that has been proposed for spessartine-grossular
garnets at temperatures of 900 to 1200 °C. The data rather fit a regular solution model with the parameters ΔG° (600 °C, 2 kbar)=−8.0±0.8 kJ/mol and w
gt
CaMn=2.6±2.0 kJ/mol. Existing solubility measurements and thermodynamic data from other Ca and Mn silicates support the calculated
data. Grossular activities calculated using the w
gt
CaMn parameter indicate that even in manganese-rich metapelites pressure estimates calculated using the garnet-plagioclase-Al2SiO5-quartz barometer will not be increased by more than 0.2 kbar.
Received: 18 January 1995/Accepted: 4 June 1996 相似文献
7.
Ants of the speciesMessor arenariusandM. ebeninusare known as common granivores in the deserts of the Middle East and North Africa. The relationship between the spatial distribution of nests of these ant species and the distribution of vegetation was examined in the Negev highlands. Using the method of nearest neighbour analysis, it was found that nests ofM. arenariusare evenly dispersed while the dispersion of nests ofM. ebeninusdoes not differ from a random distribution. It is suggested that in desert surroundings there is a connection between the distribution pattern of nests of harvester ants and their foraging type. It seems that nests of individually foraging ants are usually evenly dispersed while nests of trunk-trail foraging ants are usually distributed in a random or aggregated dispersion. 相似文献
8.
Concurrent Salinization and Development of Anoxic Conditions in a Confined Aquifer,Southern Israel 
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下载免费PDF全文 An ancient, brackish, anoxic, and relatively hot water body exists within the Yarqon‐Tanninim Aquifer in southern Israel. A hydrogeological‐geochemical conceptual model is presented, whereby the low water quality is the outcome of three conditions that are met simultaneously: (1) Presence of an organic‐rich unit with low permeability that overlies and confines the aquifer; the confining unit contains perched horizons with relatively saline water. (2) Local phreatic/roofed conditions within the aquifer that enable seepage of the organic‐rich brackish water from above. The oxidation of the dissolved organic matter in the seeping water consumes the dissolved oxygen and continues through bacterial sulfate reduction, with H2S as a product. These exothermic reactions result in some heating. (3) The seeping water comprises a relatively large portion of the water volume. In the presented case study, the latter condition first developed in the Late Pleistocene following climate change, which led to a dramatic decline in recharge. Consequently, water flow in the local basin has nearly ceased, as evident by old water ages, specific isotopic composition, and nearly equipotential water levels. The continuous seepage from above into the almost stagnant water body has resulted in degraded water quality. Seepages of organic‐rich brackish water exist at other sites throughout the aquifer but have limited impact on the salinity and redox conditions due to the dynamic water flow, which flushes the seeping water, that is, the third condition is not met. The coexistence of the above three conditions may explain the development of anoxic and saline groundwater in other aquifers worldwide. 相似文献
9.
The Dead Sea brine is supersaturated with respect to gypsum (Ω = 1.42). Laboratory experiments and evaluation of historical data show that gypsum nucleation and crystal growth kinetics from Dead Sea brine are both slower in comparison with solutions at a similar degree of supersaturation. The slow kinetics of gypsum precipitation in the Dead Sea brine is mainly attributed to the low solubility of gypsum which is due to the high Ca2+/SO42− molar ratio (115), high salinity (∼280 g/kg) and to Na+ inhibition.Experiments with various clay minerals (montmorillonite, kaolinite) indicate that these minerals do not serve as crystallization seeds. In contrast, calcite and aragonite which contain traces of gypsum impurities do prompt precipitation of gypsum but at a considerable slower rate than with pure gypsum. This implies that transportation inflow of clay minerals, calcite and local crystallization of minerals in the Dead Sea does not prompt significant heterogeneous precipitation of gypsum. Based on historical analyses of the Dead Sea, it is shown that over the last decades, as inflows to the lake decreased and its salinity increased, gypsum continuously precipitated from the brine. The increasing salinity and Ca2+/SO42− ratio, which results from the precipitation of gypsum, lead to even slower kinetics of nucleation and crystal growth, which resulted in an increasing degree of supersaturation with respect to gypsum. Therefore, we predict that as the salinity of the Dead Sea brine continues to increase (accompanied by Dead Sea water level decline), although gypsum will continuously precipitate, the degree of supersaturation will increase furthermore due to progressively slower kinetics. 相似文献
10.