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1.
本文利用目前有关含鲜方解石以及水－碳酸钙系统的研究成果，对水－含磷方解石系统的模型化作了初步的尝试；然后以该系统为核心，拓展出了一个包括气候、水文及不化学等影响因素在内的湖泊综合模型，并运用该湖泊模型定量化地探讨了湖泊中常见的由气候季节性变化所控制的，由交替富含碳酸盐和碎屑物的层系所构成的韵律沉积现象，展示了该类湖粕的水化学演化进程，证明了韵律中的碳酸直轲在每年的夏季形成。 相似文献
2.
湖泊沉积物—水界面铁—锰循环研究新进展 总被引：18，自引：2，他引：18
通过云贵高原深水湖泊沉积物－水界面铁－锰循环研究，揭示了湖泊铁－锰循环不仅受氧化还原边界层化学界面的控制，而且受沉积物－水地质界面的制约；有机质生物氧化和硫酸盐还原构成界面铁－锰循环的重要机制并产生亚扩散层屏蔽效应；铁－锰循环伴随有微量金属元素地球化学形态的改变，从而影响其迁移行为；气候剧烈变化所中断的铁－锰循环，形成铁－锰富集层的古环境记录。 相似文献
3.
4.
青藏高原秋里南木湖盐类沉积韵律 总被引：4，自引：0，他引：4
盐类沉积韵律对研究湖泊环境及气候变迁有重要意义。对青藏高原秋里南木湖发现的芒硝、粘土和原生硼砂的韵律沉积进行了沉积速率和沉积韵律的分析。从物质来源、地貌和气候变化3个方面讨论了韵律形成的机制。在此基础上，利用矿物组成、年代、孢粉资料讨论了沉积物所反映的气候环境变化。结果表明，充足的物源和封闭的地貌环境是沉积韵律形成的物质条件，气候变化是主要外部动力。沉积韵律所反映的气候环境变化为：20.6~20.5 ka BP无芒硝，植被发育，气候相对温暖湿润；20.5~11.4 ka BP芒硝层很厚，植被类型过渡至以蒿为主的荒漠草原，气候干冷。其中，20.5~17.5 ka BP气候极端干旱寒冷，17.5~17.1 ka BP，15.9~15.2 ka BP和14.1~13.4 ka BP气温回升；11.4~10.1 ka BP芒硝层很薄，植物种类丰富，气候显著变暖；10.1~7.5 ka BP芒硝层厚度增加，木本植物花粉进一步降低，盘星藻消失，气候变冷；7.5~4.97 ka BP芒硝层厚度减小，但厚薄不一，植被过渡到以蒿为主的典型草原，气候相对暖湿，但冷暖交替频繁，其中7.0~6.2 ka BP蒿含量下降，湿生植物含量增加，气候冷湿，6.2~5.2 ka BP耐干旱、盐碱植物增加，禾本科消失，湖水盐度增加，气候冷干。 相似文献
5.
碳酸盐溶解,沉淀控制下的反应—迁移模型研究 总被引：1，自引：0，他引：1
以碳酸盐岩中方解石，白云石和石膏的溶解和沉淀化学反应为基础，阐述了反应模型和水流模型，建立了化学动力学方程－水流方向的关系，并且采用解法－数值法混合解法求解济南岩溶区的反应－模型，计算该区的化学反应速率常数和水动力参数。 相似文献
6.
江汉平原江陵湖泊沉积物粒度特征及气候环境意义 总被引：4，自引：0，他引：4
以江汉平原江陵湖泊沉积物为研究对象,结合沉积物岩性、粒度组成、孢粉和有机碳同位素等,分析了江陵湖泊沉积物粒度组成特征及该区域近9 000 a来的气候环境变化。研究发现,江陵湖泊沉积物记录了该区湖泊水体逐渐减小直至消亡的过程,气候环境变化大致可分为以下5个阶段：（1）8 900～6 300 a B.P.为水体较深、面积较大的开阔湖阶段,气候暖湿;（2）6 300～4 700 a B.P.为面积较小、水体较浅的潴水湖阶段,气候干旱;（3）4 700～3 400 a B.P.为面积更小、水体更浅的洼地湖阶段,气候偏暖偏湿;（4）3 400～2 500 a B.P.为湖沼泥炭发育阶段,气候暖湿;（5）2 500 a B.P.以来,由湖泊及湖沼堆积转化为洪水漫滩堆积,古云梦泽开始萎缩,气候变干。江陵湖泊沉积物粒度所记录的区域气候干湿变化与国内邻近区域（特别是鄱阳-洞庭湖区）显示出较好的一致性,沉积物粒度研究是恢复区域古降水等气候环境变化的有效途径。 相似文献
7.
陕西洛川黄土中碳酸盐的某些地球化学特征 总被引：9，自引：0，他引：9
本文对陕西洛川黄土中的碳酸盐从矿物成分、化学成分和同位素组成进行了系统研究，建立了确定黄土中原生方解石和次生方解石含量的方法，并提出了黄土气候地层研究的两个地球化学指标。研究表明，洛川黄土中的碳酸盐主要是次生方解石，是由原生方解石在成土过程中溶解转变而成的。 相似文献
8.
日本本州岛中部的远野砂岩型铀矿区地层由中新统下部的湖相沉积岩（１８￣２２Ｍａ）和上部的海相（１５￣１６Ｍａ）沉积岩组成。方解石和黄铁矿是该地层中的主要成岩蚀变产物。湖相和海相的方解石和黄铁矿的特征差别很大。湖相沉积物中方解石的δ＾１３Ｃ值低（－１９‰￣－６‰ＰＤＢ），而海相地层中的δ＾１３Ｃ值高（－１１‰￣＋３‰）。这意味着海相碳酸盐在上部海相沉积岩上所起的作用较大，下部湖相地层中方解石的碳既来源 相似文献
9.
王承书 《沉积与特提斯地质》1992,12(2):62-68
一、澳大利亚南部两个咸火山口湖的现代及全新世碳酸盐沉积学 967 Basin湖是位于澳大利亚维多利亚西部火山平原地区中心的两个相邻火山口湖。这两个湖均为咸水并呈碱性。西Basin湖为局部混合湖,而东Basin湖为暖单对流湖。这两个Basin湖的现代离岸湖底沉积物的碳酸盐矿物组合均以白云石和方解石为主,西Basin湖含少量水碳镁石和菱镁矿;东Basin湖含少量一水方解石。方解石、水碳镁石、菱镁矿和一水方解石为内源成因,来源于湖泊水柱内或沉积物-水界面处的原生无机沉淀。方解石为介形壳生物沉淀。 相似文献
10.
SWB—1型便携式湖泊沉积物—界面水取样器的研制 总被引：35，自引：1，他引：34
在湖泊环境的研究中,采到保持原状的沉积物－水界面样品是一项基本工作。根据国外有关资料,在前期研制的沉积物－水界面采样装置的基础上,研制成功了一种新型湖泊沉积物－水界面取样器。本取样器由部分组成,即连接构件、配重、悬挂密封机构和取样管。取样器是靠自重插入湖泊沉积层,悬挂密封机构将样品封闭于取样管内。本取样器能在深水湖泊中取到３０￣５０ｃｍ的湖底沉积物柱及１０￣３０ｃｍ的界面水柱。整个取样器重量轻（只 相似文献
11.
Holocene carbonate sedimentation in Lake Manitoba, Canada 总被引：1，自引：0，他引：1
W. M. LAST 《Sedimentology》1982,29(5):691-704
The carbonate mineral suite of the modern offshore bottom sediment of the South Basin of Lake Manitoba consists mainly of high magnesian calcite and dolomite with minor amounts of low-Mg calcite and aragonite. The high-Mg calcite is derived from inorganic precipitation within the water column in response to supersaturation brought about by high levels of organic productivity in the basin. Both dolomite and pure calcite are detrital in origin, derived from erosion of the surrounding carbonate-rich glacial deposits. Aragonite, present only in trace amounts in the offshore sediments, is bioclastic in origin. The upward increase in the amount of magnesian calcite in the post-glacial sediment record is attributed to increasing photosynthetic utilization of CO2 in the lake. Stratigraphic variation in the amount of magnesium incorporated into the calcite lattice is interpreted as reflecting a variable magnesium input to the lake from ground water and surface runoff, and possibly variable calcium removal in the precipitating lake water. The effects of long-term chemical weathering at the source and size segregation explain the changes in dolomite content throughout the section. 相似文献
12.
João Paulo B. Gomes Rodrigo B. Bunevich Sandra N. Tonietto Daisy B. Alves Julice F. Santos Fiona F. Whitaker 《Sedimentology》2020,67(5):2282-2309
Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits. 相似文献
13.
沉积物岩芯的碳酸盐、石膏等蒸发盐含量和矿物组成的证据显示了新疆巴里坤湖末次间冰期以来一直是一个水位变化频繁的浅水盐湖,有时甚至为间歇式的湖泊,约在34000aB.P.前后巴里坤湖沉积相发生了显著的变化,34000aB.P.之前为泥坪-湖滨相沉积,34000aB．P．之后为成湖相沉积。尽管我们对巴里坤湖34000aB．P．前后的沉积相变难以理解,但是长期处于浅水状态的巴里坤湖沉积物中蒸发盐的含量和矿物组成仍然与气候变化密切相关。在泥坪-湖滨相形成的碳酸盐中白云石相对的增加是地表强烈蒸发的结果。以石膏为主的蒸发盐含量增加是温度和降水增加所致,而其含量减少则是冰川前进致使补给水矿化度降低造成的。这使我们获得了该区古气候变化并不服从于冰期与雨期同步模式的信息。 相似文献
14.
ABSTRACT A small, closed, lacustrine system developed during the restraining overstep stages of the Oligocene As Pontes strike‐slip basin (Spain). The increase in basin accommodation and the headward spread of the drainage, which increased the water input, triggered a change from shallow, holomictic to deeper, meromictic conditions. The lower, shallow, lacustrine assemblage consists of mudstone–carbonate cycles recording lacustrine–palustrine ramp deposition in a saline lake. High Sr content in some early diagenetic calcites suggests that aragonite and calcite made up the primary carbonate muds. Early dolomitization took place together with widespread pedogenic activity. The upper, deep, freshwater, lacustrine assemblage includes bundles of carbonate–clay rhythmites and fine‐grained turbidite beds. Primary calcite and diagenetic siderite make up the carbonate laminae. The Mg content of the primary carbonates records variations in Mg/Ca ratios in lacustrine waters. δ18O and δ13C covariance trends in calcite reinforce closed drainage conditions. δ18O data indicate that the lake system changed rapidly from short‐lived isotopically light periods (i.e. from seasonal to pluriannual) to longer steady‐state periods of heavier δ18O (i.e. from pluriannual to millennial). The small δ13C changes in the covariant trends were caused by dilute inflow, changing the contributions of dissolved organic carbon in the system and/or internal variations in lacustrine organic productivity and recycling. In both shallow and deep carbonate facies, sulphate reduction and methanogenesis may account, respectively, for the larger negative and positive δ13C shifts recorded in the early diagenetic carbonates (calcite, dolomite and siderite). The lacustrine system was very susceptible to high‐frequency, climatically forced water balance variations. These climatic oscillations interfered with the low‐frequency tectonic and morphological changes in the basin catchment. This resulted in the superposition of high‐order depositional, mineralogical and geochemical cycles and rhythms on the lower order lacustrine infill sequence. 相似文献
15.
抚仙湖是我国面积、蓄水量最大的高原湖泊之一。通过对抚仙湖FXH-B2钻孔岩芯296 cm沉积物的矿物组成和碳酸盐含量分析,结合岩芯XRF扫描数据和AMS^14C年代的测定,探讨了抚仙湖湖泊沉积物中碳酸盐含量与方解石矿物及沉积物Ca元素相对含量之间的关系及其环境指示意义,在对比和参考水下地形测量、地球物理勘探、水质和地球化学监测和不同部位钻孔岩芯的分析结果的基础上,重建了抚仙湖全新世以来气候和湖泊水位的变化。结果指示,抚仙湖碳酸盐含量与方解石的XRD信号强度、沉积物Ca元素的XRF扫描数据之间存在很高的相关性,沉积物中碳酸盐类物质主要为方解石(其他碳酸盐类矿物相对含量极微甚至可以忽略不计),沉积物中Ca元素主要来自碳酸盐,因此其含量由碳酸盐、即方解石矿物含量决定。沉积物中碳酸盐含量的变化可以用沉积物中Ca元素XRF扫描结果进行表示。由于抚仙湖处于亚热带季风气候区,以10月至次年4月降水量极少而蒸发强烈为特点的干季和以5月至9月降水为主的湿季所形成的干湿变化控制了湖泊演化的主要过程,区域气候变化是湖泊演化和水位变化的主要动力。结合湖泊沉积碳酸盐稳定同位素δ^18O和δ^13C、有机质含量及其同位素δ^13C、抚仙湖北部边缘水下侵蚀地形测量、地球物理勘探和沉积地层年代的确定和讨论,明确了抚仙湖沉积碳酸盐含量指示湖泊水位的变化,并重建了抚仙湖过去约12 ka以来水位变化的历史。结果显示,在约12 cal.ka B.P.至2.2 cal.ka B.P.期间的湖泊水位变化主要经历了波动式降低的过程,其中4.37~2.2 cal.ka B.P.期间高CaCO3含量、偏正的碳酸盐δ^18O、δ^13C值指示抚仙湖一度出现低于现代湖面约30 m左右的低水位,可能记录了抚仙湖流域极端的干旱时期,在2.2~2.0 cal.ka B.P.期间抚仙湖水位经历了快速升高的变化事件,期间湖水位快速上升达到现代湖水水位,揭示了印度季风控制区区域降水的特殊性和气候变化的突发性。 相似文献
16.
Stoichiometric solubility constants of calcite in initially supersaturated solutions of various magnesium to calcium concentration ratios but identical ionic strength were determined at 25°C and one atmosphere total pressure.The thermodynamic solubility constant of calcite is used with ion pairing equations to interpret the data reported in this study. Results indicate that even though magnesian calcites, rather than pure calcite, precipitate from seawater solutions containing magnesium ions, the incorporation of MgCO3 in the calcite crystal lattice does not extensively alter the equilibrium calcium carbonate activity product.The equilibrium activity of the ionic species in solution and the composition of magnesian calcite overgrowths precipitated from solutions of similar composition are used to calculate the solubility of magnesian calcites. The values for magnesian calcite solubilities obtained by this approach are lower than those obtained from the dissolution kinetics of biogenic carbonates. 相似文献
17.
Travertine formation in Plitvice National Park, Yugoslavia: chemical versus biological control 总被引：5，自引：1，他引：5
Hydrochemical studies of the Plitvice Lakes and their tributaries (Croatia/Yugoslavia) were coupled with micromorphological investigations on carbonate lake sediments and recent travertines. Karst springs discharge water from aquifers in Triassic and Jurassic dolomites and limestones and collect in lakes, which are ponded behind accreting travertine dams. Waters at springs have a high CO2 partial-pressure (greater than 7000 ppm) and are slightly undersaturated with respect to calcite (saturation index less than —0·03). CO2 partial pressure is quickly reduced in swift running streams, leading to very high supersaturation with carbonate minerals (saturation indices between 0·74 and 0·53). Calcite deposition, however, is restricted to the lake bottoms (formation of lake marl) and to the tufa dams. The annual carbonate precipitating capacity of the system based on water balance and downstream loss of dissolved ions is estimated to be on the order of 10 000 t CaCO3 as cascade deposits (tufa dams) or as micrite in lakes behind the travertine dams. The initial stages of travertine formation as a result of morphological, biological, and chemical factors are (i) moss settling on small ridges in the creek courses, (ii) epiphytes (diatoms and cyanobacteria) settling on the moss surface, (iii) micrite particles resuspending from lake bottoms and being trapped on mucous excretions from bacteria and diatoms, and (iv) inorganic calcite precipitating as sparite at nucleation sites provided by these crystal seeds. Geochemical studies of the lake marl and tufa dams show that amino acids are dominated by aspartic acid. Carbohydrates come from structural polysaccharides of diatoms. The sticky excretions, rich in aspartic acid, are necessary for the initiation of calcite precipitation. They may be a response of algal and bacterial metabolism to environmental stress by either nutrient depletion or high calcium concentrations in ambient waters. The formation of tufa and micrite (lake marl) appears to be initiated by localized biological factors and is not governed by mere calcite supersaturation of the water. Oligotrophy may be an essential precondition for the formation of fresh water carbonate deposits. 相似文献
18.
HENRY T. MULLINS SHERWOOD W. WISE ANNE F. GARDULSKI EDWARD J. HINCHEY PHILIP M. MASTERS D.I. SIEGEL 《Sedimentology》1985,32(4):473-494
Previous studies on early submarine diagenesis of periplatform carbonates have implied that these originally polymineralic (aragonite, magnesian calcite, calcite) sediments are susceptible to early diagenesis only in current-swept open seaways or where surficially exposed by erosion on the seafloor. It has also been proposed that while in the shallow subsurface, periplatform oozes retain their original mineralogy for at least 200,000–400,000 yr and remain unlithified for tens of millions of years. Evidence is reported here for extensive calcitization and selective lithification of periplatform oozes of late Pleistocene age in two piston cores collected from water depths of ～ 1,000 m north of Little Bahama Bank. It is shown that shallow (<30 m) subsurface diagenesis can significantly alter the original mineralogy of periplatform oozes to predominantly calcite in less than 440,000 yr, and that cementation by calcite can produce chalk-ooze sequences within the same time-frame. Periplatform oozes that originally contain a high percentage of bank-derived magnesian calcite appear to have a higher diagenetic potential than those originally low in magnesian calcite. Shallow subsurface calcitization and fithification greatly reduce the diagenetic potential of periplatform carbonates, and chalk-ooze sequences apparently can persist for tens of millions of years and to burial depths of at least 300 m. Shallow subsurface diagenesis, at water depths > 1,000 m, proceeds via dissolution of magnesian calcite and aragonite and reprecipitation of calcite as allochem fillings, exterior overgrowths and cement. It is speculated that density-driven ‘Kohout convection‘, where seawaters under-saturated with respect to magnesian calcite and aragonite and saturated/supersaturated with respect to calcite flow through the margins of carbonate platforms, is the primary driving mechanism for shallow subsurface diagenesis. Removal of Mg during early stages of deep seafloor and shallow subsurface diagenesis should increase the Mg content of interstitial waters which is likely to increase the ‘dolomitizing potential’ of Kohout convection fluid flow. 相似文献
19.
The formation and subsequent reactions of magnesiancalcite overgrowths on calcite were investigated bymeans of closed system seeded precipitationexperiments. These experiments demonstrated that(1) thin overgrowths of magnesian calcite are precipitatedon calcite seeds suspended in seawater;(2) the solubilities of the coatings increase outward from theseed crystals as a linear function of the log ofrelative coating thickness;(3) during the period ofthese experiments (up to 5.5 months), the magnesiancalcite coatings continued to increase in thickness,but became less soluble in composition. Thestabilization reaction, referred to asrecrystallization, can be described by the followingequation:Cax Mg(1-x) CO3 + [z + y(x + z)]Ca2++ 2yHCO3- ]= (1 + y)Ca(x + z)Mg(1 - x -z)CO3 + [z + y(x + z - 1)]Mg2++ y CO2 + yH20;]4) recrystallization rate is dependent on solutionsaturation state, with a reaction order of 3.2 forartificial seawater and 4.0 for natural seawater; and(5) by the cessation of the closed system experiments,overgrowth compositions approached that of the stablecalcite (a few mol % MgCO3).Armoring of suspended carbonate particles in thesurface oceans with magnesian calcite overgrowthswould provide an effective barrier to release of theoceanic supersaturation with respect to calcite. Thicknesses of such coatings would be limited by therecrystallization rate of the magnesian calcite. Estimates based on the recrystallization ratesdetermined in this work indicate coatings on the orderof 0.02 µm in thickness could form on particles asthey sink through the mixed layer. According to thesecalculations, the total amount of carbon precipitatedannually in magnesian calcite overgrowths iscomparable to the riverine flux of dissolved carbon tothe oceans. Field observations of severalinvestigators indicate the likely presence ofmagnesian calcite coatings on planktonic particles,and provide evidence for possible recrystallization ofbiogenic magnesian particles in the marineenvironment. 相似文献
20.
Carbon and Oxygen Isotopic Composition of Surface‐Sediment Carbonate in Bosten Lake (Xinjiang,China) and its Controlling Factors 总被引：1，自引：1，他引：0
Steffen MISCHKE ZHENG Mianping Alexer PROKOPENKO GUO Fangqin FENG Zhaodong 《《地质学报》英文版》2009,83(2):386-395
Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ13C) values of the carbonate sediment (?1‰ to ?2‰) have no relation to the oxygen isotope composition of the carbonate (δ18O) values (?7‰ to ?8‰), with both isotopes showing a low variability. The carbonate content is low (<20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ13C values between approximately +0.5‰ and +3‰, and δ18O values between ?1‰ and ?5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg–calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg–calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate. 相似文献