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1.
The paper is devoted to studying the mineral composition and magnetic properties, mainly at the cryogenic temperatures, of the Middle–Late Devonian basalts from North Timan. The magnetic minerals in these basalts are dominated by intermediate-composition titanomagnetites (TM25–TM30) which demonstrate unusual magnetic properties in a wide temperature range. At room temperature, a low coercive force coexists with relatively high Mrs/Ms ratios. At cryogenic temperatures, the dependences of magnetic susceptibility on the temperature and frequency of the applied field are characteristic of this titanomagnetite composition, whereas the remanent saturation magnetization acquired at 2 K is destroyed at significantly lower temperatures compared to the synthetic analogs. The obtained results again highlight the necessity of studying the low-temperature properties of titanomagnetite samples with a controlled composition and grain size.  相似文献   

2.
The grain size dependence of the ratio of saturation remanent magnetization to saturation magnetization (J R :J S ), weak field susceptibility (X 0), thermoremanent magnetization (TRM) and its stability against AF demagnetization are interpreted in terms of nucleation theory. It is concluded that each of these parameters exhibits grain size dependence due to two effects. The first is the increasing difficulty with which domain walls are neucleated as grain size decreases. The second is an intrinsic grain size dependence of the parameters in multidomain particles.  相似文献   

3.
We test the possibility of using the pseudo-Thellier method as a means of determining absolute paleointensity. Thellier analysis of anhysteretic remanent magnetization (ARM) and pseudo-Thellier analysis of thermoremanent magnetization (TRM) have been carried out on a large collection of sized synthetic magnetites and natural rocks. In all samples, the intensity of TRM is larger than that of ARM and the ratio R (=TRM/ARM) is strongly grain size dependent. The best-fit slope (bTA) from pseudo-Thellier analysis of TRM shows a linear correlation with R. The ratio bTA/R yielded approximately correct paleointensities, although uncertainties are larger than in typical Thellier-type determinations. For single-domain and multidomain magnetites, alternating field and thermal stabilities of ARM and TRM are fairly similar. However, for ∼0.24 μm magnetite, ARM is both much less intense and less resistant to thermal demagnetization than TRM, reflecting different domain states for the two remanences and resulting in severely non-linear Arai plots for Thellier analysis of ARM.  相似文献   

4.
Early in the history of planetary evolution portions of Martian crust became magnetized by dynamo-generated magnetic field. A lateral distribution of the secondary magnetic field generated by crustal remanent sources containing magnetic carriers of certain grain size and mineralogy is able to produce an ambient magnetic field of larger intensity than preexisting dynamo. This ambient field is capable of magnetizing portions of deeper crust that cools through its blocking temperatures in an absence of dynamo. We consider both magnetite (Fe3O4) and hematite (α-Fe2O3) as minerals contributing to the overall magnetization. Analysis of magnetization of magnetic minerals of various grain size and concentration reveals that magnetite grains less than 0.01 mm in size, and hematite grains larger than 0.01 mm in size can become effective magnetic source capable of magnetizing magnetic minerals contained in surrounding volume. Preexisting crustal remanence (for example ∼250 A/m relates to 25% of multi-domain hematite) can trigger a self-magnetizing process that can continue in the absence of magnetic dynamo and continue strengthening and/or weakening magnetic anomalies on Mars. Thickness of the primary magnetic layer and concentration of magnetic carriers allow specification of the temperature gradient required to trigger a self-magnetization process.  相似文献   

5.
This paper reports the alternating field demagnetization characteristics of glass–ceramic magnetite assemblages carrying weak-field thermoremanent magnetization (TRM), weak-field anhysteretic remanent magnetization (ARM), and saturation remanence (Jrs). Average grain sizes vary from less than 0.1 μm to approximately 100 μm, and hysteresis parameters indicate that these assemblages encompass single-domain (SD) through truly multidomain (MD) behavior. In all assemblages, weak-field TRM and weak-field ARM are more stable to alternating field demagnetization than is (Jrs). This response is especially remarkable in the 100 μm assemblage, which otherwise displays truly MD behavior. Although the SD samples pass the Lowrie–Fuller test for SD behavior, calculations presented here show that populations of noninteracting, uniaxial SD grains should behave in just the opposite sense to that reported originally by Lowrie and Fuller. This discrepancy could indicate that SD, glass–ceramic magnetite populations are more affected by magnetic interactions than would be expected for magnetite crystals that nucleated individually from a silicate matrix. This interpretation is supported by the SD assemblages failing the ‘Cisowski' test: that is, the curves for acquisition and AF demagnetization of (Jrs) intersect well below the 50% mark. However, a second and intriguing explanation of the SD-like results obtained from all samples is that alternating field demagnetization characteristics reflect a strong dependence of local energy minimum domain state, and its associated stability, on the state of magnetization.  相似文献   

6.
Summary The paper deals with the magnetic properties of the natural minerals haematite, ilmenite and pyrrhotite. The natural remanent magnetization Jn, the volume susceptibility , the specific magnetization of saturation so, the Curie temperature , the A.C. demagnetization of natural remanent magnetization, the thermal demagnetization Jn, the temperature dependence of the specific magnetization of saturation, and several other parameters were determined for the individual sets of minerals. Since natural minerals can and do contain various heterogeneous and isomorphic admixtures, their magnetic properties may change depending on the content and type of these admixtures. Therefore, all the investigations of the magnetic properties described in this paper were carried out with extensive sets of minerals, representing various Czechoslovak and world localities. A number of interesting results were obtained from the executed experiments, e.g., the different stability of the natural remanent magnetization of haematite with respect to A.C. demagnetization, the presence and type of heterogeneous inclusions in ilmenite, the phase changes connected with the -transition in natural pyrrhotites, etc. The types of distributions of the investigated values of the magnetic properties were also determined.  相似文献   

7.
The pseudo-single-domain (PSD) intensity and stability of thermoremanent magnetization (TRM) in multidomain magnetite grains 0.05–15 μm in size are attributed to residual magnetic moments not removed by demagnetization. Barkhausen discreteness in domain wall positions is a possible source of such moments, but the observed grain size and applied field dependences of TRM in the lower PSD range are more convincingly explained by a new theory (F.D. Stacey and S.K. Banerjee, 1974) in which the moments of domain walls and the surface terminations of domain walls play a central role. The magnitudes of PSD moments and the average number of moments per grain required by this theory are deduced from low-field (0–25 Oe) TRM measurements on magnetite grains of controlled sizes between 0.04 and 0.22 μm. The predicted maximum PSD moment is about equal to the saturation moment in grains ≤ 0.1 μm in size but is only 10% of the saturation moment in 0.22-μm grains. Since blocking temperature and hysteresis data independently suggest two-domain structure in 0.22-μm grains and wall-like domain structure in smaller grains, the predicted PSD moments are quantitatively reasonable.  相似文献   

8.
An electric furnace with oxygen-fugacity control was constructed. Oxygen partial pressure inside the furnace is controlled by flowing H2 and CO2 gas mixtures in different ratios. The system is set up inside a three-layer permalloy shield and a solenoid coil to produce an axial magnetic field. Oxygen fugacities are directly measured by an yttriadoped zirconia probe. The difference between the predicted and measured values of fugacities was small at 1,200°C, but a substantial discrepancy was observed at 780°C. Thermoremanent magnetization (TRM) was produced in various gas mixtures by heating the samples of recent basaltic lavas of Oshima (Japan) and Hawaii to 600 or 800°C for 1 h and cooling in a 0.4-Oe field. In general, the TRM is larger when produced in an oxidizing atmosphere and smaller in a reducing atmosphere. Alternating field demagnetization shows that the coercivity is also increased (decreased) when the TRM is acquired in oxidizing (reducing) conditions. However, these properties depend also on the previous heat treatments of the samples.  相似文献   

9.
The use of magnetic susceptibility as a proxy for the relative degree of industrial pollution of soils and sediments is only qualitative and complications arise when unmixing the contributions from different sources. Detailed characterization of anthropogenic magnetic phases is needed in order to discriminate the input from different sources. The present study investigates magnetic fractions from fly ashes from different thermoelectric power plants and lagooned ash from metal works in Bulgaria, to further our knowledge of potential sources. Thermomagnetic analysis of saturation magnetization (Ms) and magnetic susceptibility (K) revealed a low-substituted magnetite-like phase in power-plant fly ashes and magnetite/maghemite phases in lagooned ash. Magnetic hysteresis measurements on single spherules from the wastes are combined with subsequent SEM/EDX examination of the same grains, allowing for the grain size dependence of the hysteresis parameters to be directly obtained for the studied anthropogenic phases. The results suggest that the structure-sensitive magnetic parameters for the lagooned ash show stronger size dependence compared to the published data for synthetic crushed magnetites, which is due to the complex internal structure and stress level in the anthropogenic phases formed under fast cooling conditions. Moreover, the Day plot for the studied single grains shows the presence of different correlation lines for fly ashes and the lagooned ash, i.e. it discriminates between the sources.  相似文献   

10.
Electron microprobe and reflected light microscopic examinations confirm the presence of composite grains of ferrian ilmenite with Xilm = 0.53 and titanomagnetite with Xusp = 0.13 in a dacite with self-reversed TRM. A parallel TRM component associated with titanomagnetite and a reversed component associated with self-reversing ferrian ilmenite are the principal NRM components. A subordinate, parallel component is associated with ferrian ilmenite which is not magnetically coupled to an “χ-phase”. The natural self-reversing properties are mainly a consequence of the dacite's high quenching temperature, calculated at 862–864°C using the Fe—Ti oxide geothermometer, and are most consistent with the self-reversal mechanism proposed by Lawson et al. [9].The conduction of thermal demagnetization and TRM induction tests in air had a much greater effect on the Fe—Ti oxides than did natural cooling, and resulted in significant oxidation with the consequent modification of some magnetic properties and the formation of another reversed TRM component. The subdivision of titanomagnetite grains by oxidation along fractures decreased its effective grain size and caused an apparent increase in its magnetic intensity, in addition to a slight increase in its resistance to alternating field demagnetization. The χ-phase associated with the reversed NRM component, with 0.42 > Xilm 0.31, became Fe-enriched during the earlier stages of heat treatment. It is suggested that after heating at 600°C for two hours or more, this χ-phase exsolves as titanohematite with Xilm < 0.33. The ferrian ilmenite host is consequently enriched in Ti, and another χ-phase much closer in composition to the host generates a reversed TRM component with Tb < 200°C.  相似文献   

11.
A high-resolution mineral magnetic investigation has been carried out on the Jingbian loess/paleosol sequence at the northern extremity of the Chinese Loess Plateau. Results show that the magnetic assemblage is dominated by large pseudo-single domain and multidomain-like magnetite with associated maghemite and hematite. Variations in the ratios of SIRM100mT/SIRM, SIRM100mT/SIRM30mT and SIRM100mT/SIRM60mT (SIRM is the saturation isothermal remanent magnetization; SIRMnmT represents the residual SIRM after an n mT alternating field demagnetization) have been used to document regional paleoclimate change in the Asian interior by correlating the mineral magnetic record with the composite δ18O record in deep-sea sediments. The long-term up-section decreasing trend in those ratios in both loess and paleosol units has been attributed to a long-term decrease in the relative contributions of eolian hematite during glacial extrema and of pedogenic hematite during interglacial extrema, respectively, which reveals a long-term decreasing trend in chemical weathering intensity in both glacial-stage source region (the Gobi and deserts in northwestern China) and interglacial-stage depositional area (the Loess Plateau region). We further relate this long-timescale variation to long-term increasing aridification and cooling, during both glacial extrema in the dust source region and interglacial extrema in the depositional area, over the Quaternary period. Changes in those ratios are most likely due to Quaternary aridification and cooling driven by ongoing global cooling, expansion of the Arctic ice-sheet, and progressive uplift of the Himalayan–Tibetan complex during this period.  相似文献   

12.
Thermal remanent magnetization (TRM) and anhysteretic remanent magnetization (ARM) components were imposed on natural rock samples. The artificial laboratory components had different directions and the blocking temperature and/or coercivity spectra were overlapping. Two methods, principal component analysis (PCA) by Kirschvink and analytical modelling of demagnetization data (by Stupavsky and Symons, S&S) were used to resolve these components. The PCA technique calculated lines fitted to the demagnetization path with ASD = 10° (angular standard deviation), and the S&S method used four types of intensity decay curves for calculated components.

Both methods (PCA and S&S) resolved perfectly the one-component case. The two- or three-component case results strongly depended on spectra overlapping, and on the angles between component directions and magnetic minerals in samples. Principal component analysis gave more reliable results for separated spectra of TRM and thermally cleaned samples, whereas the S&S technique was more efficient for the case of strong spectra overlapping of ARM components and the alternative current field (AF) demagnetization method. Remarkable anisotropy of RM was observed which influences the results for the haematite-bearing samples.  相似文献   


13.
Magnetite, haematite, and to a minor extent maghaemite are recognised in the Cretaceous and Paleocene red pelagic limestones at Gubbio. The magnetite is detrital (or biological), whereas the haematite grew during diagenesis from a goethitic precursor. Thermal and AF demagnetization of samples collected from close to reversal boundaries indicate that the various magnetization components do not record the polarity reversal at exactly the same stratigraphic level. In the few tens of centimetersbelow a recorded geomagnetic reversal, defined by the magnetite magnetization, some of the haematite grains are magnetized in the post-reversal field. The blocking temperature spectra of this haematite fraction (with post-reversal magnetization) are found to shift toward higher temperatures as the reversal boundary is approached. The blocking temperature spectra reflect the grain size spectra of the haematite, which we interpret as arising by the continual nucleation of grains down to a certain burial depth where the conditions are no longer conducive to further haematite growth. The depth below reversal boundaries to which haematite with post-reversal magnetization can occur, is estimated to be about 60 cm (after compaction), and is equivalent to a time of about 105 years for these particular sediments. A detailed study of the magnetization components at reversal boundaries indicates that the first diagenetic growth of haematite through the single-domain critical volume occurs prior to the mechanical fixation of the detrital (or biological) magnetite. Subsequently the diagenetic haematite grains do not rotate in response to the ambient geomagnetic field polarity as easily as the magnetite, because of their occurrence as pigmentary coatings on larger non-magnetic grains.  相似文献   

14.
Single crystals of approximate composition Fe2.4Ti0.6O4 were prepared from which spherical samples of diameters 1–2 mm were obtained. The measured values of the Königsberger ratio, the ratio of saturation remanence to saturation magnetization and a Lowrie-Fuller test showed that they were multidomain in character. The temperature variation of the coercive force and saturation magnetization was measured between room temperature and the Curie point. The field dependence of intensity of acquired thermoremanent magnetization (TRM) was determined. The predictions of some of the theoretical models for multidomain TRM, which, of necessity, apply to simplifications of real materials (either natural or synthetic), compare favourably with the results of the present study. The validity of the assumptions made in this comparison is discussed.  相似文献   

15.
We report normalized AF demagnetization curves of anhysteretic remanences (ARM's) produced by 1-, 10- and 40-Oe steady fields and of saturation isothermal remanence (IRMs) in a suite of dispersed, unannealed magnetite powders with median sizes of 2, 4, 6, 10 and 14 μm (pseudo-single-domain or PSD size range) and 100 μm (multidomain or MD size). Interpreted in the light of the domain structure test first proposed by Lowrie and Fuller [12], the relative stability trend of curves for the 2 μm sample is of single-domain (SD) type, the 1-Oe ARM being most resistant to demagnetization followed by the 10-Oe and 40-Oe ARM's and IRMs. For the 100-μm sample, the trend is exactly reversed and is of MD-type. In the 4–14 μm samples, hitherto undescribed transitional trends between SD-type and MD-type occur. At 6 μm, 1-Oe, 10-Oe and 40-Oe ARM's preserve an SD-type trend but for all AF's > 75 Oe, IRMs is more resistant than any of these remanences. At 10 μm, this trend is unmistakable, and only at 14 μm do the 1-Oe, 10-Oe and 40-Oe ARM curves merge. We conclude (1) that the Lowrie-Fuller test distinguishes between small MD grains enhanced by PSD remanence and large MD grains lacking PSD remanence, rather than between SD and MD structures per se, and (2) that in the PSD transition region from 6 to 14 μm in magnetite, IRMs changes over to MD-type relative stability around 6 μm, whereas 10-Oe and 40-Oe ARM's achieve an MD-type trend around 14 μm, in accord with the predicted field dependence of the PSD threshold size.Our theoretical interpretation assumes that the intrinsic (internal field) coercive force spectra of weak-field and strong-field remanences are identical but that the observed (external field) spectrum is shifted to lower fields as a result of the internal demagnetizing field — NJr of the remanence Jr. The effect is slight for weak-field Jr's but substantial for IRMs. Since all coercivities, high as well as low, are shifted, the result of the Lowrie-Fuller test is determined simply by the shape of the intrinsic coercivity spectrum or the corresponding AF demagnetization curve. Depending on the model of self-demagnetization used, either subexponential or sublinear AF decay curves of weak-field remanence will automatically lead to an MD-type trend, whereas by either model the decay curves that characterize SD and PSD remanences (decaying slowly initially and then more rapidly) will always produce and SD-type trend.  相似文献   

16.
In this work, we investigate the correlation between some magnetic parameters and the level of contamination by heavy metals in urban soils from Morelia city, western Mexico. The magnetic study was carried out on 98 urban soils samples belonging to distinct land uses. Most of analyzed samples contain ferrimagnetic minerals as the responsible for magnetization, most probably corresponding to the titanomagnetites/ titanomaghemites solid solutions. This is inferred from the susceptibility vs. temperature measurements and the isothermal remanent magnetization (IRM) experiments. These measurements also indicate that most of samples are almost completely saturated before 300 mT. Additionally, the S-200 values (S-200 = IRM-200/ SIRM, where IRM-200= Back-field of 200 mT after magnetic saturation) are between 0.7 and 1.0, characteristic of low coercivity magnetic minerals. The averaged saturation isothermal remanent magnetization (SIRM) curves can be used as an indicator of pollution level, as these curves show different saturation values according to the level of contamination by heavy metals: Cu, Ni, Cr and Sr. These associations of (titano)magnetite with heavy metals were observed by Scanning Electron Microscope revealing some complex aggregates rather than commonly detected spherules.  相似文献   

17.
Parallel studies on rock magnetic properties, petrology and mineralogy were conducted on 16 eclogite samples from the ZK703 hole and magnetic susceptibilities and densities of 41 eclogite samples with different degree of retrograde metamorphism (from fresh eclogite to fully-retrograded eclogite) from the Chinese Continental Scientific Drilling (CCSD) near the ZK703 hole, located at Donghai, southern Sulu ultrahigh-pressure metamorphic belt, eastern China. Results show: (1) that the high-field slopes obtained from the hysteresis loops (the paramagnetic fraction χpara) and density have a positive correlation with the volume concentration of garnet + omphacite, a typical mineral assemblage used to semi-quantify the degree of retrograde metamorphism. The low-field slopes obtained from hysteresis loops (the ferrimagnetic susceptibility fraction χferri), saturation isothermal remanent magnetization Mrs and saturation magnetization Ms have a positive correlation with the volume concentration of symplectite, a mineral related to retrograded metamorphism. Therefore they could be potential indicators for quickly semi-quantifying the degree of retrograde metamorphism of the eclogite units. (2) The dominant magnetic carriers in retrograded eclogites are magnetite particles in pseudo-single domain grain size region. (3) The P–T conditions during the retrograde (decompressional) process could first increase the concentration of magnetite, which can reach up to 3% for extensively retrograded eclogite and then was dissolved for fully-retrograded eclogite. Therefore, change in the magnetite contents during the retrograde process is the major factor controlling the magnetism of retrograde eclogites.  相似文献   

18.
ARM (anhysteretic remanence)/SIRM (saturation isothermal remanence) and TRM (thermoremanence)/SIRM were measured as a function of the concentration (volume fraction) of single-domain magnetite (3 × 10?6 ? C ? 2 × 10?2), ARM/SIRM increases with decreasing concentration, showing that there is magnetic interaction between fine particles. The role of magnetic interaction in TRM acquisition is also important at higher concentrations of magnetite (C ? 0.1%), where the value of TRM/SIRM increases with decreasing concentration. It is only for concentrations ofC ? 0.1% that the value of TRM/SIRM is fairly constant and interactions among magnetite grains seem to be ignored. The ratio TRM/ARM decreases from seven to almost unity as the concentration of magnetite decreases.  相似文献   

19.
Experiments comparing anhysteretic remanence (ARM) and thermoremanence (TRM) in samples containing natural and synthetic magnetite, whose mean particle sizes range from single domain to multidomain, show that ARM and TRM are very similar (but not identical) in their stabilities with respect to alternating field (AF) demagnetization, temperature cycles in zero field to below magnetite's isotropic temperature near 130°K, and stability with respect to spontaneous decay in zero field. Therefore, for magnetites, ARM can be used to model (with reasonable success) these stability properties of TRM. The field dependence of the acquisition of ARM and TRM shows that the low field susceptibility ratio, χARM/χTRM, has a particle size dependence, increasing from 0.1 for certain submicron particles to 2.0 for large multidomain crystals. Even for samples whose remanence is predominantly carried by submicron particles χARM/χTRM is highly variable, 0.11 ≤ χARM/χTRM ≤ 0.50. Therefore, ARM paleointensity methods which do not take into account the large variability in and the particle size dependence of χARM/χTRM are subject to order-of-magnitude uncertainties.  相似文献   

20.
Gega lake, in southeastern Tibet, was formed by the blocking of Yarlung Tsangpo gorge by a glacier and is a well-known example of geomorphological damming. However, the evolution of the damming process at the site is still not understood in detail. Here, we use measurements of multiple magnetic parameters of the sediments from the Yusong (YS) 3 section, which is well-dated by optically stimulated luminescence, to provide a detailed history of the late stage of Gega dammed lake since 17.0 ka. Low-frequency field magnetic susceptibility (χlf) increases upwards gradually from 25 to 79?×?10?8 m3/kg above 5.5 m, but other magnetic properties, such as frequency-dependent magnetic susceptibility (χfd % and χfd), susceptibility of anhysteretic remanent magnetization (χARM), and saturation isothermal remanent magnetization (SIRM) did not show a similar degree of enhancement. The magnetic grain size indicators of χARM/χlf, χARM/SIRM, and χlf/SIRM all indicate a trend of increasing magnetic grain size from the 5.5 m to the top of section; however, the bulk sediment grain size decreases gradually within the same interval. The total organic carbon is very low (0.2–0.7%), and thus, it is unlikely that the sedimentary environment is sufficiently strongly reducing to lead to the dissolution of magnetic minerals. Therefore, we infer that the coarsening-upwards of the magnetic grain size, and the increasing magnetic susceptibility from 5.5 m, reflect the gradual preferential preservation of magnetic minerals, caused by the deepening of the lake. Thus, we interpret the magnetic record of the section as reflecting the gradual deepening of the late stage of Gega ice-dammed lake. Last, the abrupt disappearance of the lake may have resulted in an outburst flood.  相似文献   

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