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1.
黑云母是花岗岩中常见的造岩矿物,其化学成分可以用于判断岩体形成时的物理化学条件、岩石成因类型及构造环境。本文利用电子探针(EMPA)对武当隆起西段牌楼花岗岩中的黑云母进行了成分分析,结果发现这些黑云母Al~Ⅵ原子数较低(0.128～0.395),而Ti原子数适中(0.236～0.267),属于铁叶云母,并且均具富Fe贫Mg的特征,Fe~(2+)/(Fe~(2+)+Mg)值为0.985～0.989。岩相学观察和化学成分分析结果显示,牌楼二长花岗岩中的黑云母为岩浆成因,结晶温度为640～710℃,寄主岩体的固结压力为0.9～1.7 GPa,log f_(O_2)变化于-18.1～-17.4之间,指示其形成于低氧逸度环境中。岩浆的氧逸度较低可能是导致牌楼岩体不能形成Cu、Au和Mo矿化的决定因素,而缺乏Sn矿化可能与熔体温度较低有关。综合黑云母化学成分和岩石地球化学特征,认为牌楼似斑状二长花岗岩为A型花岗岩,侵位于非造山的伸展构造背景。  相似文献   

2.
诸广棉花坑铀矿床围岩是中粒斑状二云母花岗岩和中粗粒斑状黑云母花岗岩,本文通过对其中的黑云母进行了岩相学观察和详细的矿物化学分析以探讨黑云母的形成条件及其成岩成矿意义。电子探针分析结果表明,本区黑云母富铁贫镁,属于铁叶黑云母,指示诸广花岗岩体为过铝质岩系,起源于地壳。黑云母结晶的温度为650~700℃,logfO2为-15~-16,压力为159~247MPa,对应的侵位深度为5.2~7.2km。与非产铀花岗岩对比,本区岩浆具有相对较低的温度和氧逸度。  相似文献   

3.
山东西部莱芜－淄博地区的中生代雪野碳酸岩中发育有大量罕见的反环带云母，云母的电子探针分析表明，云母斑晶的核心为黑云母，过渡带和边缘是金云母，基质中云母为金云母，核心黑云母与过渡带的金云母界限清晰，成分突变以及核心黑云母的溶蚀结构表明，核心黑云母和过渡带与边缘带金云母不是同一岩浆体系结晶的产物，核心黑云母可能是碳酸岩岩浆捕获的外来黑云母，过渡带与边缘带金云母同基质中金云母具有相似的化学成分，从过渡带到边缘带，金云母的Mg(Mg Fe)逐渐降低，反映了碳酸岩岩浆的不断结晶演化过程，TiO2的不断降低，一方面是由于岩浆的分异结晶，另一方面则是岩浆上升期间去气作用导致岩浆内CO2／H2O值降低所致。云母斑晶从过渡带向边缘带Al2O3含量逐渐减少，表明碳酸岩浆自过渡带云母结晶后没有富Al的圈岩物质加入。  相似文献   

4.
西华山钨矿为华南地区最重要的钨矿产区之一,其形成与西华山复式岩体的岩浆演化过程密切相关。随着岩浆演化,西华山钨矿区花岗岩的云母成分发生变化,三八面体云母和二八面体云母分别按"富铁黑云母→铁叶云母→黑鳞云母"和"白云母/多硅白云母→富锂多硅白云母"的方向演化。Li主要通过"Fe2++Mg→AlⅥ+Li"置换方式进入云母晶格,在岩浆演化过程中云母的Li含量逐渐升高。F在云母-熔体间的分配系数随着云母的Mg#(Mg#=100Mg/(Mg+Mn+Fe))降低而减小,因此岩浆演化过程中云母的F含量未明显升高,有利于熔体富集F并演化至更高程度。另外,西华山成矿花岗岩的云母因受到流体交代作用而普遍发育环带结构。环带结构云母的边部与核部相比具有明显较低的Li、F,属于多硅白云母,而出现与多硅白云母共存的方解石表明交代作用流体富含CO2。因此,西华山含矿花岗岩在岩浆演化过程中存在含CO2、相对贫Li和F流体的加入。西华山花岗岩中云母成分的变化还指示体系的氧逸度曾发生变化,即从高氧逸度环境转变为氧逸度相对较低的环境,有利于钨矿的形成。  相似文献   

5.
芙蓉锡矿田骑田岭复式岩体主要由早阶段角闪石黑云母花岗岩和晚阶段黑云母花岗岩组成.电子探针分析结果表明角闪石黑云母花岗岩中的黑云母属于铁黑云母,黑云母花岗岩中的黑云母属于铁叶云母.相对于黑云母花岗岩,角闪石黑云母花岗岩中黑云母的MgO、TiO2含量偏高,Al2O3含量偏低.矿物化学研究结果显示,角闪石黑云母花岗岩中黑云母的结晶温度、氧逸度(logfO2)分别为680℃～740℃、-16.00～-15.31,黑云母花岗岩中黑云母的结晶温度、氧逸度分别为530℃～650℃、-19.20～-17.50.从角闪石黑云母花岗岩到黑云母花岗岩,岩浆结晶温度和氧逸度逐渐降低.与花岗岩有关的共存流体性质的研究发现,与角闪石黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2O/fHCl)fluid,log(fHF/fHCl)fiuid值分别为4.22～4.39,2.78～3.24,-1.82～-1.73,而与黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2OfHCl)fluid,log(fHF/fHCl)fluid值分别为3.27～3.53,2.85～3.22,-0.75～-0.22,可见与两种岩石类型共存热液流体的性质存在明显差异,且热液中Cl、Sn含量变化与岩浆结晶分异指数呈正相关关系.骑田岭岩体从角闪石黑云母花岗岩到黑云母花岗岩,随着岩浆的演化.岩浆结晶期后分异出的热液流体向富Cl和Sn方向演化.芙蓉锡矿田的成矿流体应主要来源于黑云母花岗岩岩浆结晶期后分异出的岩浆热液.  相似文献   

6.
岩背花岗岩黑云母矿物化学研究及其对成矿意义的指示   总被引：4，自引：0，他引：4  
对岩背火山-斑岩型锡矿含黄玉黑云母花岗岩和含黄玉花岗斑岩中黑云母矿物化学研究表明,含黄玉黑云母花岗岩中的黑云母属于富铁黑云母,含黄玉花岗斑岩中的黑云母属于铁叶云母。含黄玉花岗斑岩的成岩温度为720℃~730℃,logfO2为-15.5~-15.7;含黄玉黑云母花岗岩的成岩温度为510℃~550℃,logfO2为-19.2~-18.7。含黄玉花岗斑岩成岩温度、氧逸度高于含黄玉黑云母花岗岩成岩温度和氧逸度。与含黄玉花岗斑共存热液流体log(fH2O/fHCl)fluid值为4.29~4.99,与含黄玉黑云母花岗岩共存热液流体log(fH2O/fHCl)fluid值为3.15~3.67。因此,相对于含黄玉黑云母花岗岩,含黄玉花岗斑岩岩浆演化过程中分异出的流体富F和Sn,即岩背含黄玉花岗斑岩岩浆演化过程分异出的原始流体以富F和Sn为特征,结合有关岩背Sn矿成矿流体的研究结果,进一步揭示出岩背Sn矿成矿流体为岩背含黄玉花岗斑岩岩浆演化过程分异出的岩浆热液,相对于含黄玉黑云母花岗岩,含黄玉花岗斑岩与锡成矿关系更密切。  相似文献   

7.
叶茂  赵赫  赵沔  舒珣  张若曦  杨水源 《岩石学报》2017,33(3):896-906
灵山花岗岩体在平面上为一环状分布的侵入体,中心为角闪石黑云母花岗岩,外围为黑云母花岗岩。在角闪石黑云母花岗岩中分布有大量的暗色镁铁质微粒包体。黑云母是大多数中酸性火成岩中比较重要的一种镁铁质矿物,它能很好地反映寄主岩浆的属性和成岩时的物理、化学条件,因此,本文对这两种花岗岩及镁铁质微粒包体中的黑云母开展了系统的岩相学观察和电子探针化学组成研究,探讨灵山岩体的物质来源、成岩条件和岩浆的混合作用过程。研究结果表明两种花岗岩体的黑云母具有不同化学成分,而暗色镁铁质微粒包体中黑云母的化学成分则变化较大。三种黑云母均在低氧逸度条件下晶出。两种花岗岩中的黑云母均富Fe贫Mg,属于铁质黑云母,含铁系数[(Fe~(3+)+Fe~(2+))/(Fe~(3+)+Fe~(2+)+Mg~(2+))]分别为0.65~0.70,0.72~0.78,FeOT/MgO均接近7.04。MF值[2×Mg/(Fe~(2+)+Mg+Mn)]分别为0.64~0.76和0.48~0.60,指示两种花岗岩的物质来源都是以壳源为主。镁铁质微粒包体中黑云母的MF值变化范围比较大,为0.63~1.06,为铁质黑云母到镁质黑云母,暗示包体岩浆经历过不同程度的岩浆混合作用。镁铁质微粒包体中部分黑云母与角闪石黑云母花岗岩中黑云母的结晶条件相似,而部分则有明显差异,推测是由于基性的镁铁质包体岩浆注入到酸性的花岗岩浆是一个连续多阶段的过程。  相似文献   

8.
诸广矿区与铀矿化关系密切的碱交代作用广泛发育,碱交代岩与围岩(正常花岗岩)对比,Na2O、K2O明显增高,Al2O3、Fe2O3也增高;SiO2明显降低,FeO、MgO、CaO也降低,表明K2O和Na2O被带入。矿物化学成分分析得出诸广碱交代岩的长石主要为钠长石与钾长石;绿泥石主要属铁镁绿泥石和蠕绿泥石;黄铁矿有的含铀量较高,据Fe/S值属硫亏损型,据S/Se值属岩浆热液矿床范畴;云母属白云母及少量铁白云母;铀矿物和含铀矿物的UO2含量以沥青铀矿较高,钍石较低,铀矿石的蚀变矿物和造岩矿物有的也含微量铀。碱交代作用既释放矿质又为矿质沉淀创造空间,碱交代岩既提供铀源又是一种有利的成矿围岩。  相似文献   

9.
为了探讨花岗岩的萤石成矿专属性特征,在系统搜集前人成果基础上,对南岭东段北部产萤石花岗岩和非产萤石花岗岩开展了元素地球化学测试和黑云母电子探针分析(EPMA)与对比。结果表明:产萤石花岗岩主要为黑云母花岗岩,属于高钾钙碱性系列,副矿物组合中常见萤石;加里东期、印支期和燕山期的花岗岩均具有形成萤石矿床的可能性,以燕山早期花岗岩的潜力最大。与非产萤石花岗岩相比,产萤石花岗岩具较高的Mo含量和较低的Th/U比值;其黑云母主要为铁质黑云母和铁叶云母,比非产萤石花岗岩的黑云母(主要为铁白云母和铁叶云母)更富TiO2、MgO、Cl、F而贫Al2O3、FeO+Fe2O3;黑云母的F与Cl含量呈正相关,而与Al2O3含量呈负相关;产萤石花岗岩形成于相对高温、低压和高氧逸度的环境,岩浆来源主要为地壳,但有少量幔源,与钨多金属矿床关系较为密切。  相似文献   

10.
巴塘措莫隆含锡花岗岩自阿冬－措莫隆及其自早－晚单元，在岩石学、岩石化学、地球化学、稀土元素等方面，都具有典型“序列－单元”的规律演化；锡矿化与晚单元体浅角黑云二长－钾长花岗岩关系最密切。岩石主成矿元素和相关伴生元素：Ｓｎ及（Ｓｎ＋Ｗ＋Ｂｉ和Ｌｉ及（Ｌｉ＋Ｒｂ＋Ｂｅ＋Ｔａ）分别大于世界花岗岩维氏值３倍和２－３倍；富挥发分Ｂ，Ｆ；黑云母Ｓｎ的高丰度为含锡花岗岩的特征反映，锡矿主要产于矽卡岩化和云英岩化  相似文献   

11.
Biotites from unaltered Sn granites in southeastern Australia are highly ferroan, Fe/(Fe+Mg+Mn) >0.75, whereas biotites from barren granites are less Ferich, Fe/(Fe+Mg+Mn)<0.65. Similar distinctions between Sn-specialized and barren granites can be observed in the other phyllosilicates, especially chlorite. Biotites and muscovites from Sn granites have greater Be, Cs, (F), Li, Mo, Rb, Sc, Sn, Tl, (Y) and Zn and lesser Ba abundances than corresponding micas from barren granites in the same district. Alteration of barren granites also results in similar enrichments in micas. Of these elements, Sn and Zn, because of their abundance and retention during degradation of biotite to chlorite, are the best trace element discriminants between barren granites and Sn granites/altered granites, with the Sn content of phyllosilicates being a better indicator than Zn. Rutile inclusions within phyllosilicates from unaltered Sn granites have Nb2O5 contents up to 26%. The Ta content tends to increase with Nb content but especially high Ta contents occur in the rutile inclusions of granites that give rise to pegmatitic deposits. The rutile inclusions in Sn granites may also have substantial Sn and W contents. The rutiles of barren granites have low Nb, Ta, Sn and W contents but Sn and W increase with alteration. Together, the ratio Fe/(Fe+Mg+Mn) and Sn contents in phyllosilicates and rutile compositions can be used to identify the Sn mineralization potential of a granite.  相似文献   

12.
漳州地区白垩至纪I型和A型花岗岩中黑云母的矿物学特征   总被引：1，自引：0，他引：1  
漳州地区白垩纪花岗岩由Ｉ型和Ａ型花岗岩组成，本文对该地区两类花岗岩中黑云母的矿物化学、矿物物理特征进行了系统研究。发现在两类花岗岩中的黑云母矿物学特征存在重大差别，如Ａ型花岗岩中黑云母更富铝、铁、氟及水而贫镁、硅，形成温度及氧逸度较低等。在Ａ型花岗岩中的黑云母穆斯堡尔谱也与Ｉ型不同，四极分裂（Ｑ．Ｓ）较高，且Ｆｅ￣（２＋）在Ｍ＿２位，Ｆｅ（３＋）在Ｔ位占位率也较高。两类花岗岩中的黑云母化学成分随岩浆演化也呈现不同的变化规律。黑云母的矿物学特征可提供花岗岩成因类型的有益信息。  相似文献   

13.
Abstract. The Cornubian Batholith comprises six major and several smaller bodies of S‐type granite in southwestern England. These late‐Variscan granites comprise two‐mica granites, and much less abundant Li‐mica granites that are restricted to one of the major bodies (St Austell) and smaller bodies. Some of these intrusive rocks are associated with major Sn mineralization. This paper is concerned with the geochemistry of the two‐mica granites, which are felsic, strongly peraluminous, and have a high total alkali content and low Na:K. Rocks with very similar compositions to these granites occur elsewhere, including the Variscan granites of continental Europe, and in southeastern Australia. In detail all of the major plutons of this batholith have distinctive compositions, except for Bodmin Moor and Carnmenellis which cannot be discriminated from each other compositionally. A comparison with experimental data shows that the granites attained their major element composition under conditions of crystal‐liquid equilibrium, with the final melt being saturated in H2O, at temperatures close to 770d?C and pressures about 50 MPa. That temperature estimate is in good agreement with values obtained from zircon saturation thermometry. The specific minimum‐temperature composition excludes the possibility of widespread transfer of elements during hydrothermal alteration. Minor elements that are relatively very abundant are Li, B, Cs and U, while F, Ga, Ge, Rb, Sn, Ta, W and Tl are quite abundant and P is high for felsic rocks. Sr, Ba, and the trace transition metals Sc to Zn, are low, but not as low as they commonly are in very felsic granites. These trace element abundances, and the EL2O‐saturation, resulted from the fractional crystallization of a melt derived by the partial melting of feldspathic greywackes in the crust. The Cornubian granites have compositions very similar to the more felsic rocks of the Koetong Suite of southeastern Australia, where a full range of granites formed at the various stages of magmatic fractionation postulated for the Cornubian granites, can be observed. The operation of fractional crystallization in the Cornubian granites is confirmed by the high P abundances in the feldspars, with P contents of the plagioclase crystals correlating with Ab‐con‐tent Most of the granites represent solidified melt compositions but within the Dartmoor pluton there is a significant component of granites that are cumulative, shown by their higher Ca contents. The Cornubian plutons define areas of high heat flow, of a magnitude which requires that fractionated magmas were transported laterally from their sources and concentrated in the exposed plutons. The generation of these granite plutons therefore involved magmatic fractionation during the stages of partial melting, removal of unmelted material from that melt, and fractional crystallization. During the later stages of those processes, movement of those magmas occurred on a crustal scale.  相似文献   

14.
黑云母作为花岗岩中含量最高的暗色矿物,其成分特征对指示岩石成因与成矿起着重要作用。云南个旧卡房锡多 金属矿床的形成与花岗质岩浆活动密切相关,卡房花岗岩包含有大量黑云母,通过电子探针测试方法,对该花岗岩中的 黑云母成分进行了系统的研究。结果显示,黑云母为富铁黑云母,具有富硅、铁、铝、钾、钛,贫锰、镁、钙、钠等特 征,含铁指数为0.67~0.83。黑云母的成分特征暗示其结晶温度为500~708 ℃,结晶压力为202~538 MPa,对应的结晶深度为 7.64~20.35 km,表明卡房花岗岩形成于中低温环境、属于中深成相。综合研究认为,卡房锡矿田花岗岩具有高铁指数以及 氧逸度由高到低变化趋势等特征是锡成矿的有利条件,可以作为在本区寻找锡矿的重要标志。  相似文献   

15.
华南富氟花岗岩高磷和低磷亚类型对比   总被引：10，自引：3，他引：7  
黄小龙  王汝成 《地质论评》1998,44(6):607-617
根据全岩Ｐ２Ｏ５含量的多寡可将华南富氧花岗岩分为高磷亚类和低磷亚类,它们之间具较大的地球化学差异。高磷亚类以低硅、强过铝和低的ＲＥＥ总量为特征,而低磷亚类则相反。在长石、云母等矿物化学成分上这两亚类花岗岩也有所差异。高磷亚类花岗岩中磷以长石中结构磷和磷铝锂石形式存在,而低磷亚类花夺中的磷则主要存在于磷灰石等磷酸盐矿物中。  相似文献   

16.
High- and Low-Temperature I-type Granites   总被引：4，自引：0，他引：4  
Abstract: I– and S-type granites differ in several distinctive ways, as a consequence of their derivation from contrasting source rocks. The more mafic granites, whose compositions are closest to those of the source rocks, are most readily classified as I– or S–type. As granites become more felsic, compositions of the two types converge towards those of lowest temperature silicate melts. While discrimination of the two is therefore more difficult for such felsic rocks, that in no way invalidates the twofold subdivision. If felsic granite melts undergo fractional crystallisation, the major element compositions are not affected to any significant extent, but the concentrations of trace elements can vary widely. For some trace elements, fractional crystallisation causes the trace element abundances to diverge, so the I– and S– type granites are again easily separated. Such fractionated S-type granites can be distinguished, for example, by high P and low Th and Ce, relative to their I-type analogues. Our observations in the Lachlan Fold Belt show that there is no genetic basis for subdividing peraluminous granites into more mafic and felsic varieties, as has been attempted elsewhere. The subdivision of felsic peraluminous granites into I– and S-types is more appropriate, and mafic peraluminous granites are always S–type. In a given area, associated mafic and felsic S-type granites are likely to be closely related in origin, with the former comprising both restite-rich magmas and cumulate rocks, and the felsic granites corresponding to melts that may have undergone fractional crystallisation after prior restite separation. We propose a subdivision of I-type granites into two groups, formed at high and low temperatures. The high-temperature I–type granites formed from a magma that was completely or largely molten, and in which crystals of zircon were not initially present because the melt was undersaturated in zircon. In comparison with low-temperature I–type granites, the compositions extend to lower SiO2 contents and the abundances of Ba, Zr and the rare earth elements initially increase with increasing SiO2 in the more mafic rocks. While the high-temperature I–type granite magmas were produced by the partial melting of mafic source rocks, their low-temperature analogues resulted from the partial melting of quartzofeldspathic rocks such as older tonalites. In that second case, the melt produced was felsic and the more mafic low-temperature I–type granites have that character because of the presence of entrained and magmatically equilibrated restite. High temperature granites are more prospective for mineralisation, both because of that higher temperature and because they have a greater capacity to undergo extended fractional crystallisation, with consequent concentration of incompatible components, including H2O.  相似文献   

17.
最近,花岗岩混合成了花岗岩研究的热点,国内外许多学者探讨了花岗岩混合问题,并尝试用不同端元组分不同比例的混合来解释花岗岩的地球化学变化。本文从花岗岩与玄武岩的对比出发,探讨了花岗岩混合的可能性和局限性。作者认为,花岗岩混合的现象是普遍存在的,但是次要的和局部的。岩浆混合的能力或能干性(competence of mixing)主要取决于岩浆的黏性和温度,而黏性又与硅氧四面体有关。相对于玄武岩,花岗岩的SiO_2含量高,温度低,因此,花岗质岩浆的混合能干性很低。玄武质岩浆的混合是mixing(以化学混合为主),而花岗质岩浆的混合通常只是mingling(以机械混合为主),只有在少数情况下才能达到mixing的程度,例如,埃达克岩与地幔混合形成的高镁安山岩或高镁埃达克岩。许多人认为,花岗岩中的暗色微粒包体是花岗质岩浆混合作用最显著、最直接证据。研究表明,花岗岩中的暗色微粒包体大多是闪长质成分的,其初始成分大多是玄武质的。因此,暗色微粒包体不是花岗质岩浆混合作用最显著、最直接证据,而是玄武质岩浆混合能力强过花岗质岩浆的证据。与玄武质岩浆的起源比较,花岗质岩浆从一开始熔融就是不均一的,这源于源区的不均一及熔融过程的复杂性。花岗质岩浆原始均一性的假定是不可能的。花岗岩成分的变化以及在哈克图解中成分点的"连续谱系",主要是由源区不均一性引起的,混合和分异可能有一定的作用,但毕竟是次要的。花岗质岩浆从源区生成、迁移、直至在地表喷出或在浅部定位的全过程,是一个不断均一化和不均一化的过程。但是,由于花岗质岩浆的黏性大,上述过程及岩浆演化的程度和规模都受到限制,也限制了岩浆混合的程度和规模。许多人仅从花岗岩地球化学成分的变化来研究花岗岩的成因,而很少考虑花岗岩物理性质对岩浆演化的制约。对比玄武岩与花岗岩,我们认为,地球化学方法在花岗岩中应用的范围和程度可能远远不及玄武岩,我们应当重新考虑花岗岩的地球化学应用问题。  相似文献   

18.
黑云母是花岗质岩石中常见的造岩矿物,其成分可以有效指示花岗岩形成的物理化学条件和岩石成因。巴斯铁列克矿床是近年来在新疆阿尔泰造山带南缘发现的首例二叠纪矽卡岩型钨多金属矿床。矿区出露多种类型二叠纪含钨花岗岩。为理清花岗质岩体之间、岩体与钨多金属矿化之间的关系,文章采用电子探针测定了黑云母花岗岩、二长花岗岩、二云母花岗岩和钾长花岗岩中的黑云母成分。结果表明,所有黑云母具有富铁、高铝、贫镁特征,含铁指数(Fe2+/(Mg+Fe2+))为0.66~0.80,二云母花岗岩属铁质黑云母而黑云母花岗岩、二长花岗岩和钾长花岗岩属铁叶黑云母。所有岩石是具有A型特征的I型花岗岩。不同类型岩石中黑云母的成分差异与岩浆来源、分异演化程度有关。二云母花岗岩中黑云母的w(MgO)与结晶温度最高,与黑云母平衡流体的log(fHF/fHCl)值（-1.13~-1.25）最低,log(fH2O/fHF)值（4.64~4.96）最高,母岩浆相对富Cl;黑云母花岗岩中log(fHF/fHCl)值最高,log(fH2O/fHF)最低,与二长花岗岩是同一岩浆房不同演化阶段的产物,与二云母花岗岩和钾长花岗岩属不同的岩浆体系,母岩浆相对富F元素。黑云母花岗岩与W矿化关系更密切。  相似文献   

19.
Partial melting has been shown to be an important mechanism for intracrustal differentiation and granite petrogenesis. However, a series of compositional differences between granitic melt from experiments and natural granites indicate that the processes of crustal differentiation are complex. To shed light on factors that control the processes of crustal differentiation, and then the compositions of granitic magma, a combined study of petrology and geochemistry was carried out for granites (in the forms of granitic veins and parautochthonous granite) from a granulite terrane in the Tongbai orogen, China. These granites are characterized by high SiO2 (>72 wt%) and low FeO and MgO (<4 wt%) with low Na2O/K2O ratios (<0.7). Minerals in these granites show variable microstructures and compositions. Phase equilibrium modelling using P–T pseudosections shows that neither anatectic melts nor fractionated melts match the compositions of the target granites, challenging the conventional paradigm that granites are the crystallized product of pure granitic melts. Based on the microstructural features of minerals in the granites, and a comparison of their compositions with crystallized minerals from anatectic melts and minerals in granulites, the minerals in these granitoids are considered to have three origins. The first is entrained garnets, which show comparable compositions with those in host granulites. The second is early crystallized mineral from melts, which include large plagioclase and K-feldspar (with high Ca contents) crystals as well as a part of biotite whose compositions can be reproduced by crystallization of the anatectic melts. The compositions of other minerals such as small grained plagioclase, K-feldspar and anorthoclase in the granites with low Ca contents are not well reconstructed, so they are considered as the third origin of crystallized products of fractionated melts. The results of mass balance calculation show that the compositions of these granites can be produced by mixing between different proportions of crystallized minerals and fractionated melts with variable amounts of entrained minerals. However, the calculated modal proportions of different crystallized minerals (plagioclase, K-feldspar, biotite and quartz) in the granites are significantly different from those predicted by melt crystallization modelling. Specifically, some rocks have lower modes of biotite and plagioclase, whereas others show lower K-feldspar modes than those produced by melt crystallization. This indicates that the crystallized minerals would be differentially separated from the primary magmas to form the evolved magmas that produce these granites. Therefore, the crystal entrainment and differential melt-crystal separation make important contributions to the composition of the target granites. Compared with leucogranites worldwide, the target granites show comparable compositions. As such, the leucogranites may form through the crystal fractionation of primary granitic magmas at different extents in addition to variable degrees of partial melting.  相似文献   

20.
The Middle Miocene Tsushima granite pluton is composed of leucocratic granites, gray granites and numerous mafic microgranular enclaves (MME). The granites have a metaluminous to slightly peraluminous composition and belong to the calc‐alkaline series, as do many other coeval granites of southwestern Japan, all of which formed in relation to the opening of the Sea of Japan. The Tsushima granites are unique in that they occur in the back‐arc area of the innermost Inner Zone of Southwest Japan, contain numerous miarolitic cavities, and show shallow crystallization (2–6 km deep), based on hornblende geobarometry. The leucocratic granite has higher initial 87Sr/86Sr ratios (0.7065–0.7085) and lower εNd(t) (?7.70 to ?4.35) than the MME of basaltic–dacitic composition (0.7044–0.7061 and ?0.53 to ?5.24), whereas most gray granites have intermediate chemical and Sr–Nd isotopic compositions (0.7061–0.7072 and ?3.75 to ?6.17). Field, petrological, and geochemical data demonstrate that the Tsushima granites formed by the mingling and mixing of mafic and felsic magmas. The Sr–Nd–Pb isotope data strongly suggest that the mafic magma was derived from two mantle components with depleted mantle material and enriched mantle I (EMI) compositions, whereas the felsic magma formed by mixing of upper mantle magma of EMI composition with metabasic rocks in the overlying lower crust. Element data points deviating from the simple mixing line of the two magmas may indicate fractional crystallization of the felsic magma or chemical modification by hydrothermal fluid. The miarolitic cavities and enrichment of alkali elements in the MME suggest rapid cooling of the mingled magma accompanied by elemental transport by hydrothermal fluid. The inferred genesis of this magma–fluid system is as follows: (i) the mafic and felsic magmas were generated in the mantle and lower crust, respectively, by a large heat supply and pressure decrease under back‐arc conditions induced by mantle upwelling and crustal thinning; (ii) they mingled and crystallized rapidly at shallow depths in the upper crust without interaction during the ascent of the magmas from the middle to the upper crust, which (iii) led to fluid generation in the shallow crust. The upper mantle in southwest Japan thus has an EMI‐like composition, which plays an important role in the genesis of igneous rocks there.  相似文献   

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