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1.
The vacuum-encapsulation laser 40Ar39Ar technique allows extremely small (10−6 g) samples of fine-grained materials such as diagenetic clays to be dated. Here we show that the method can be extended to higher-grade clay minerals. The integration of transmission electron microscopic (TEM) characterization with 40Ar39Ar dating of vacuum encapsulated samples permits the resolution of the timing of metamorphic growth/cooling from the time of diagenesis. We have applied this technique to well characterized Lower Paleozoic slates and K-bentonites from the Welsh Basin, which span the transition from anchizonal to epizonal grade, which had been previously studied using RbSr and SmNd dating.

TEM observations of epizonal K-bentonites and slate showed that illite in these samples is of 2M1 polytype, of muscovite-like composition, and oriented parallel to cleavage, suggesting that they are of metamorphic origin. Total gas ages (equivalent to conventional KAr ages) for encapsulated epizonal K-bentonites and slate (340–408 Ma) are considerably variable. The Ar retention ages (calculated from 39Ar and 40Ar atoms retained in the sample after irradiation) are more consistent (383–411 Ma). The 39Ar recoil losses are minor for illites from whole rock samples of epizonal K-bentonites but very significant for clay separates of epizonal slate. Plateaus in age spectra were observed in epizonal K-bentonites and slate. The plateau ages (414–421 Ma) and retention ages (383–411 Ma) can be correlated with the onset of Acadian metamorphism and culmination of uplift and inversion of the Welsh Basin, respectively. These ages are significantly younger than the 450 Ma ages previously reported for diagenetic clays using the same method, suggesting that diagenetic history has been lost in these epizonal K-bentonites and slate.

TEM observations of anchizonal slates showed that there are two modes of illite. The first mode is similar to that observed in epizonal samples, suggesting a metamorphic origin. The second mode consists of the 1Md polytype, has typical diagenetic illite composition, and is oriented parallel to bedding, suggesting a diagenetic origin. Total gas ages for encapsulated anchizonal slates vary considerably (361–422 Ma). The retention ages are more consistent (413–432 Ma) than the total gas ages. The 39Ar recoil losses are more significant than those for epizonal K-bentonites and slate. Plateaus in age spectra are generally not observed. However, the consistent retention ages for the anchizonal slates correspond to the plateau ages for the epizonal samples, and are inferred to represent the onset of Acadian metamorphism.

These data, when combined with our previously published results for diagenetic shales, suggest that thermal conditions near the boundary of anchizonal and epizonal grades are necessary to completely reset Ar systems in shales and slates.  相似文献   


2.
Single crystal 40Ar/39Ar dating of K-feldspars from silicic volcanic rocks containing xenocrysts often yields a spectrum of ages slightly older than those of juvenile sanidine phenocrysts. In contrast, feldspars from thin, low-volume units of the Tertiary (14 Ma) McCullough Pass Tuff define discrete age populations at 14 Ma, 15 Ma, and 1.3 Ga, reflecting the time of eruption, xenocrysts from an older ignimbrite exposed in the caldera wall, and Proterozoic basement K-feldspars, respectively. Conductive cooling and diffusion modelling suggests preservation of such discrete populations is likely only when xenocrystic material is incorporated into the magma very near or at the surface, or is engulfed in thin, rapidly cooled pyroclastic flows during emplacement. Incorporation of xenocrysts into the subvolcanic magma chamber, into thick rhyolite domes or lava flows, or into large, welded ignimbrite sheets will result in partial or total resetting of the K/Ar isotopic system. Similarly, petrographic evidence such as exsolution lamellae may be homogenized under these conditions but not in thin ignimbrites. Extremely low diffusion rates for disordering of the Al–Si tetrahedral siting of basement feldspars suggests that they will retain their ordered structural state given rhyolitic magma temperatures. Thus, even when petrographic and K/Ar isotopic evidence for xenocrystic contamination is obscured, it may be preserved in the form of Al–Si ordering.  相似文献   

3.
A detailed 40Ar/39Ar study, of mineral separates from the Jurassic Atlantic Continental Tholeiites (JACT) of Guyana (French Guyana and Surinam, South America), and Guinea (West Africa) related to the initial opening of the Central Atlantic, has been carried out. In French Guyana, plateau ages of 196.0 ± 5.7 Ma and 196.1 ± 7.5 Ma were obtained on single, small amphibole grains from NNW—SSE trending dykes. In Guinea, single biotite grains from intrusive formations from the Kakoulima and Fouta Djalon areas yielded plateau ages of 200.4 ± 0.2 Ma and 194.8 ± 0.5 Ma, concordant with high temperature apparent ages on other biotites. The bulk plagioclase samples display disturbed age spectra due to alteration and excess argon. However, intermediate temperature, weighted mean plagioclase ages are similar in both regions of Guyana and Guinea, ranging from 200.2 ± 2.4 Ma to 188.7 ± 1.9 Ma, partly in agreement with the amphibole and biotite data.

These data, combined with previous 40Ar/39Ar and U/Pb results from the northern part of the Central Atlantic margins, indicate intense magmatic activity distributed over a large area from Iberia to Liberia (ca. 4500 km long) for a short period of time (204-195 Ma, perhaps less for the bulk of the magmatism) during the initial break-up of Pangea continent. These data do not support an initiation of the magmatism from a radial volcano-tectonic system centred in the south of the region, as suggested by May [1], and the initial break-up seems to affect the whole Central Atlantic during a period of 9 Ma.  相似文献   


4.
An evaluation of the precision and resolution of the unspiked K–Ar dating method is presented with particular regard to the statistical significance of ages that are measured near or at the detection limit of the technique. Near-zero (historical) ages can be measured by the unspiked K–Ar technique with a precision that is essentially controlled by the precision with which the 40Ar/36Ar of the sample can be resolved from the present-day atmospheric value of 295.5. The best analytical precision on the isotopic ratio is ±0.05% (1σ) by this technique, which currently limits the lower detection limit of unspiked K–Ar ages to samples featuring at least 0.14% of radiogenic 40Ar. The corresponding youngest resolvable K–Ar age depends on the K content and atmospheric contamination of the sample. Total-fusion analysis of high-K refractory minerals like sanidine is not practicable via K–Ar, and the lowest resolvable age for medium-K samples more amenable to complete fusion is around 1.5 ka (on a single-run basis). It is argued that near-zero age measured with a probability density straddling or narrowing the time-origin cannot be handled without accounting for the non-negativity constraint imposed by the physical requirement of a positive age. The pertinent equations are derived both for the single-run case and for the case of independent replicates made on a single sample. We show that pooled K–Ar replicates can theoretically reduce the nominal uncertainty of individual unspiked ages (typically ±1.5 ka, 2σ) to a value that is close to the smallest 40Ar/39Ar isochron age uncertainty achievable on sanidine in the 0–2 ka range (±0.2 ka, 2σ). However, this performance is obtained at the cost of prohibitively large-sample statistics (n≥15) for medium-K feldspars datable via K–Ar. Coupled with the inability of the K–Ar approach to obviate the problems of excess/fractionated 40Ar and/or xenocrystic contamination, this makes the 40Ar/39Ar technique the method of choice for dating historical events by the K–Ar scheme.  相似文献   

5.
Emerald, occurring in K-metasomatic rocks developed at the contact of the Carnaíba leucogranite with serpentinite (Bahia State, Brazil), has been dated using an original 40Ar/39Ar procedure. It combines step heating and spot fusion experiments on two types of phlogopite crystals: (1) bulk samples and individual grains extracted from the enclosing K-metasomatic host rocks; and (2) syngenetic solid inclusions precipitated along growing zones of the emerald host crystals. The second procedure uses in situ laser probe experiments on rock sections. In spite of the huge amounts of excess 40Ar detected in adjacent emerald, we could measure reliable ages of 1951 ± 8 Ma and 1934 ± 8 Ma for the Trecho Velho and Braulia occurrences, respectively. Spot fusion data had higher discrepancy than the step heating data, but minute crystals of phlogopite included in emeralds bearing excess argon do not reveal excess argon. A muscovite belonging to the same granite hydrothermal complex gave a plateau age of 1976 ± 8 Ma, which may correspond to a higher closure temperature of the KAr system during the cooling of the whole pluton and associated hydrothermal halo.

These accurate measurements lead to the following conclusions: (1) direct emerald dating is possible; (2) in spite of a polyphase history during the Transamazonian orogenesis (2 Ga), combined step heating and spot fusion experiments give a better precision for granite-related emerald mineralization than the scattered ages obtained by Rb-Sr and K-Ar methods; (3) the late-Transamazonian tectonothermal retrograde event which probably caused the dispersion of previous Rb-Sr and K-Ar data is not revealed by our procedure; (4) the emerald mineralization and K-metamorphism appear to be linked with the thermal history of the leucogranite; (5) in addition to its use in polyphase crustal domains, accurate 40Ar/39Ar dating is of major interest in the field of metallogenic models, even, for instance, for mineralizations characterized by disturbed isotopic systems, which record effects as excess argon.  相似文献   


6.
We have sampled a sequence of 107 lava flows in the Waianae series on Oahu, Hawaii, in two separate stretches. The first (51 flows) at Kaena Point extends from sea level to an altitude of 190 m, and the second (56 flows) follows the Satellite Tracking Station road from 218 m to 360 m above sea level. Thermal and af demagnetization yield very similar results, and reveal only normal polarities. K/Ar dating at five different horizons combined with the paleomagnetic results indicate that the sequence was emplaced entirely in the normal polarity interval between the Upper Mammoth and the Lower Kaena polarity transitions (3.22–3.11 Ma). Some of the flows are serially correlated. Filtering does not, however, drastically affect the final results. Inclinations are shallower than those expected from a centered dipole field. Although large (13°), the inclination anomaly is consistent with results from other sites at the same latitude. The scatter of the VGPs about the geographic pole is consistent with available data from other regions at similar latitudes. The scatter of the directions is also consistent with the predictions of recent statistical models of paleosecular variation. Therefore, these results do not support the hypothesis of a Pacific dipole window.  相似文献   

7.
We present 39Ar–40Ar dating of phengite, muscovite and paragonite from a set of mafic and metasedimentary rocks sampled from the high-pressure (HP) metaophiolites of the Voltri Group (Western Alps) and from clasts in the basal layer conglomerates from the Tertiary molasse which overlie the high-pressure basement. The white mica-bearing rocks display peak eclogitic and blueschist-facies parageneses, locally showing complex greenschist-facies replacement textures. The internal discordance of age spectra is proportional to the chemical complexity of the micas. High-Si phengites from eclogite clasts record a 39Ar–40Ar age of ca. 49 Ma for the eclogite stage and ca. 43 Ma for the blueschist retrogression; phengites from a blueschist basement sample yield an age of ca. 40 Ma; low-Si muscovite from a metasediment dates the formation of the greenschist paragenesis at ca. 33 Ma. Our data indicate that the analyzed samples reached high-pressure conditions at different times over a time-span of c.a. 10 Ma. Subduction was continuing during exhumation and blueschist retrograde re-equilibration of higher-pressure, eclogite-facies rocks. This process kept the isotherms depressed, allowing the older HP-rocks to escape thermal re-equilibration. Our results, added to literature data, fit a tectonic model of a subduction–exhumation cycle, with different tectonic slices subducted at different times from Early Eocene until the Eocene–Oligocene boundary.  相似文献   

8.
We carried out an integrated paleomagnetic, rock-magnetic and paleointensity study of Miocene volcanic succession from the trans-Mexican volcanic belt (TMVB) north of Guadalajara. A total of 37 consecutive basaltic lava flows (326 oriented standard paleomagnetic cores) were collected at Lazo locality. Continuous susceptibility measurements with temperature and hysteresis experiments yield in most cases reasonably reversible curves with Curie points close to that of pseudo-single-domain magnetite. Two geomagnetic reversals were observed in the 300 m thick composite section. Paleosecular variation was lower than the one observed in general during Miocene. It appears that the volcanic units have been emplaced during a relatively short time span of about 1 Ma. The mean paleomagnetic directions obtained from this study do not differ significantly from that expected for the middle Miocene. The mean paleomagnetic direction calculated from all data is I=31.1°, D=354.6°, k=124 and 95=2.1°, N=37. Seventy-two samples with apparently preserved primary magnetic mineralogy and without secondary magnetization, mostly belonging to reverse polarity chron were pre-selected for Thellier paleointensity determination. The flow-mean paleointensity values are ranging from 22.4±3.4 to 53.8±6.0 μT and the corresponding virtual dipole moments (VDMs) are ranging from (5.4±0.8) to (12.0±1.4)×1022 A m2. This corresponds to mean value of (7.7±2.2)×1022 A m2, which is close to present day geomagnetic field strength. Altogether, our data suggest the existence of relatively high geomagnetic field strength undergoing low fluctuations.  相似文献   

9.
New U–Pb age-data from zircons separated from a Northland ophiolite gabbro yield a mean 206Pb/238U age of 31.6 ± 0.2 Ma, providing support for a recently determined 28.3 ± 0.2 Ma SHRIMP age of an associated plagiogranite and  29–26 Ma 40Ar/39Ar ages (n = 9) of basalts of the ophiolite. Elsewhere, Miocene arc-related calc-alkaline andesite dikes which intrude the ophiolitic rocks contain zircons which yield mean 206Pb/238U ages of 20.1 ± 0.2 and 19.8 ± 0.2 Ma. The ophiolite gabbro and the andesites both contain rare inherited zircons ranging from 122–104 Ma. The Early Cretaceous zircons in the arc andesites are interpreted as xenocrysts from the Mt. Camel basement terrane through which magmas of the Northland Miocene arc lavas erupted. The inherited zircons in the ophiolite gabbros suggest that a small fraction of this basement was introduced into the suboceanic mantle by subduction and mixed with mantle melts during ophiolite formation.

We postulate that the tholeiitic suite of the ophiolite represents the crustal segment of SSZ lithosphere (SSZL) generated in the southern South Fiji Basin (SFB) at a northeast-dipping subduction zone that was initiated at about 35 Ma. The subduction zone nucleated along a pre-existing transform boundary separating circa 45–20 Ma oceanic lithosphere to the north and west of the Northland Peninsula from nascent back arc basin lithosphere of the SFB. Construction of the SSZL propagated southward along the transform boundary as the SFB continued to unzip to the southeast. After subduction of a large portion of oceanic lithosphere by about 26 Ma and collision of the SSZL with New Zealand, compression between the Australian Plate and the Pacific Plate was taken up along a new southwest-dipping subduction zone behind the SSZL. Renewed volcanism began in the oceanic forearc at 25 Ma producing boninitic-like, SSZ and within-plate alkalic and calc-alkaline rocks. Rocks of these types temporally overlap ophiolite emplacement and subsequent Miocene continental arc construction.  相似文献   


10.
This study reports the results of the first40Ar/39Ar combined induction furnace and laser probe dating of phengites from the Mulhacen HP/LT metamorphic complex in the Betic Cordilleras, southern Spain. Laser step heating and spot fusion analyses on different halves of a split single grain were made with a continuous laser probe. Spot fusion analysis resulted in ages of about 30–31 Ma in the core and ages as low as 25–26 Ma in the rim. Laser step heating on the other half of the grain gave a spectrum with apparent ages increasing from about 25 Ma to 29.5 Ma. The age spectrum and the decreasing ages towards the rim of the grain may imply that resetting essentially occurred by volume diffusion of radiogenic40Ar due to late stage reheating resulting from extensional tectonics. Ages around 30 Ma in the core of the grain are interpreted as minimum estimates of the cooling age of the main tectono-metamorphic phaseD2.

Induction furnace step heating on phengite separates from mica schists and one gneiss resulted in two types of age spectra. Type I spectra show monotonously rising apparent ages from14.5 ± 1.9 Ma to20.7 ± 0.2 Ma, and in a second sample from16.9 ± 0.7 to29.7 ± 0.2 Ma. Type II spectra are characterized by plateaus of14.4 ± 0.1 Ma (the gneiss sample),17.3 ± 0.1 Ma and17.6 ± 0.1 Ma. Type II spectra show low temperature apparent ages significantly below the plateau age, implying resetting subsequent to initial cooling. Modelling of the age spectra demonstrated that the plateau ages are possibly the result of strong resetting (75–85% of argon loss) of an older isotope system. Total fusion of a number of phengite single grains from marbles taken close to type II mica schists yielded ages of15.4 ± 1.2 Ma and17.0 ± 0.7 Ma. The observed repeated resetting is coeval with major volcanic activity in basins adjacent to the metamorphic ranges, pointing to a resetting by advective fluid transport related to volcanism.  相似文献   


11.
A rock magnetic and paleomagnetic investigation was performed on some selected, radiometrically dated lava flows from the Mascota Volcanic Field (MVF), western Trans- Mexican Volcanic Belt. A set of rock-magnetic experiments and standard paleomagnetic analysis were carried out on 19 sites spanning the time interval from 2268 to 72 kyr. The paleomagnetic directions are anchored to absolute radiometric ages while no such information was available in previous studies. This makes possible to correctly evaluate the fluctuation of Earth’s magnetic field from Pliocene to Pleistocene and reveal the firm evidence of possible Levantine excursion. Both Ti-poor and Ti-rich titanomagnetites seem to carry the remanent magnetization with Curie temperatures ranging from 350°C to 537°C. Thirteen flows correspond to the Brunhes chron, one of them exhibits transitional directions, while the remaining six sites belong to the Matuyama chron. New and existing dataset for MVF were used to estimate the paleosecular variation parameters. The selected data include 35 Plio-Quaternary lava flows. After excluding the poor quality data, as well as the transitional directions, the mean paleodeclination is 356.1° and oaleoinclination 39.9°, which agree well with the geocentric axial dipole (GAD) and the expected paleodirections for the Plio-Pleistocene, as derived from the reference poles for the stable North America. The corresponding mean paleomagnetic poles are paleolongitude 226.7° and paleolatitude 86.0°. The virtual geomagnetic pole scatter for the MVF is 15.2°, which is consistent with the value expected from model G at latitude of 20° (this model provides an interpretation of the paleosecular variation at different latitudes for the time of interest). The combined paleomagnetic data, supported by positive reversal test, indicate no paleomagnetically detectable vertical-axis rotations in the study area. The evidence of one transitional directions was detected, which may correspond to the Levantine excursion (360-370 kyr) or unnamed event between 400-420 kyr.  相似文献   

12.
Paleocene volcanic rocks in West Greenland and Baffin Island were among the first products of the Iceland mantle plume, forming part of a larger igneous province that is now submerged beneath the northern Labrador Sea. A 40Ar/39Ar dating study shows that volcanism commenced in West Greenland between 60.9 and 61.3 Ma and that 80% of the Paleocene lava pile was erupted in 1 million years or less (weighted mean age of 60.5±0.4 Ma). Minimum estimates of magma production rates (1.3×10−4 km3 year−1 km−1) are similar to the present Iceland rift, except for the uppermost part of the Paleocene volcanic succession where the rate decreases to <0.7×10−4 km3 year−1 km−1 (rift). The timing of onset of volcanism in West Greenland coincides with the opening of the northern Labrador Sea and is also strikingly similar to the age of the oldest Tertiary volcanic rocks from offshore SE Greenland and the British–Irish province. This is interpreted as manifesting the impact and rapid (>1 m/year) lateral spreading of the Iceland plume head at the base of the Greenland lithosphere at 62 Ma. We suggest that the arrival, or at least a major increase in the flux, of the Iceland mantle plume beneath Greenland was a contributing factor in the initiation of seafloor spreading in the northern Labrador Sea. Our study has also revealed a previously unrecognised Early Eocene volcanic episode in West Greenland. This magmatism may be related to movement on the transform Ungava Fault System which transferred drifting from the Labrador Sea to Baffin Bay. A regional change in plate kinematics at 55 Ma, associated with the opening of the North Atlantic, would have caused net extension along parts of this fault. This would have resulted in decompression and partial melting of the underlying asthenosphere. The source of the melts for the Eocene magmatism may have been remnants of still anomalously hot Iceland plume mantle which were left stranded beneath the West Greenland lithosphere in the Early Paleocene.  相似文献   

13.
Eighty-nine basaltic lava flows from the northwest wall of Haleakala caldera preserve a concatenated paleomagnetic record of portions of the Matuyama-Brunhes (M-B) reversal and the preceding Kamikatsura event as well as secular variation of the full-polarity reversed and normal geomagnetic field. They provide the most detailed volcanic record to date of the M-B transition. The 24 flows in the transition zone show for the first time transitional virtual geomagnetic poles (VGPs) that move from reverse to normal along the Americas, concluding with an oscillation in the Pacific Ocean to a cluster of VGPs east of New Zealand and back finally to stable polarity in the north polar region. All but one of the 16 Kamikatsura VGPs cluster in central South America. The full-polarity flows, with 40Ar/39Ar ages spanning a total of 680 kyr, pass a reversal test and give an average VGP insignificantly different from the rotation axis, with standard deviation consistent with that for other 0-5 Ma lava flows of similar latitude. Precise 40Ar/39Ar dating consisting of 31 incremental heating experiments on 12 transitional flows yields weighted mean ages of 775.6±1.9 and 900.3±4.7 ka for the M-B and Kamikatsura transitional flows, respectively. This Matuyama-Brunhes age is ∼16 kyr younger than ages for M-B flows from the Canary Islands, Tahiti and Chile that were dated using exactly the same techniques and standards, suggesting that this polarity transition may have taken considerably longer to complete and been more complex than is generally believed for reversals.  相似文献   

14.
This study presents the chronological evolution of the upper amphibolite facies Orue Unit in NW Namibia. Metasedimentary and meta-igneous rocks of the Orue Unit were investigated using the Pb–Pb stepwise leaching technique on garnet and rutile, U–Pb multi-grain analysis on rutile, Sm–Nd–Lu–Hf leaching technique on garnet, SHRIMP analysis on zircon and Ar–Ar dating on amphibole. Each of these techniques pertains to different processes that occurred before, during, or after the metamorphic peak. Our age data can be integrated with petrological constraints to provide a more complete understanding of the metamorphic cycle. Our pre-peak metamorphic zircon ages, peak metamorphic garnet ages and peak to late peak metamorphic amphibole 39Ar–40Ar ages bracket the upper amphibolite facies metamorphic event including hydration or dehydration processes into a time span of only ca. 20 Ma. The age data obtained by peak metamorphic mineral analyses cluster around 1340–1320 Ma. Based on age data and field observation, we interpret the upper amphibolite facies metamorphism as a large-scale regional mid-crustal event. Spot analyses of inherited zircon cores obtained by SHRIMP reflect the sedimentary origin of the respective rocks of the Orue Unit and derivation from Palaeoproterozoic protoliths. The metamorphic rocks south of the anorthositic Kunene Intrusive Complex (KIC) have previously been ascribed to the Palaeoproterozoic Epupa Complex at the SW margin of the Congo craton and were thus thought to be older than the Mesoproterozoic KIC. Our data show that the high-grade metamorphic overprint took place 30–50 Ma after emplacement of the KIC. Rutile growth ages of 1248 Ma in one sample reflect fluid activity which seems to be a local phenomenon since there is no other evidence of geological activity throughout the Orue Unit at that time. The rutile ages predate the emplacement of satellite intrusions in that area by 30 Ma and there is no causal relation between these two events.  相似文献   

15.
Primitive basaltic single eruptions in the Big Pine Volcanic Field (BPVF) of Owens Valley, California show systematic temporal–compositional variation that cannot be described by simple models of fractional crystallization, partial melting of a single source, or crustal contamination. We targeted five monogenetic eruption sequences in the BPVF for detailed chemical and isotopic measurements and 40Ar/39Ar dating, focusing primarily on the Papoose Canyon sequence. The vent of the primitive (Mg# = 69) Papoose Canyon sequence (760.8 ± 22.8 ka) produced magmas with systematically decreasing (up to a factor of two) incompatible element concentrations, at roughly constant MgO (9.8 ± 0.3 (1σ) wt.%) and Na2O. SiO2 and compatible elements (Cr and Ni) show systematic increases, while 87Sr/86Sr systematically decreases (0.7063–0.7055) and εNd increases (− 3.4 to − 1.1). 187Os/188Os is highly radiogenic (0.20–0.31), but variations among four samples do not correlate with other chemical or isotopic indices, are not systematic with respect to eruption order, and thus the Os system appears to be decoupled from the dominant trends. The single eruption trends likely result from coupled melting and mixing of two isotopically distinct sources, either through melt-rock interaction or melting of a lithologically heterogeneous source. The other four sequences, Jalopy Cone (469.4 ± 9.2 ka), Quarry Cone (90.5 ±17.6 ka), Volcanic Bomb Cone (61.6 ± 23.4 ka), and Goodale Bee Cone (31.8 ± 12.1 ka) show similar systematic temporal decreases in incompatible elements. Monogenetic volcanic fields are often used to decipher tectonic changes on the order of 105–106 yr through long-term changes in lava chemistry. However, the systematic variation found in Papoose Canyon (100–102 yr) nearly spans that of the entire volcanic field, and straddles cutoffs for models of changing tectonic regime over much longer time-scales. Moreover, ten new 40Ar/39Ar ages combined with chemistry from all BPVF single eruption sequences show the long-term trend of BPVF evolution comprises the overlapping, temporal–compositional trends of the monogenetic vents. This suggests that the single eruption sequences contain the bulk of the systematic chemical variation, whereas their aggregate compositions define the long-term trend of volcanic field evolution.  相似文献   

16.
The paleosecular variation (PSV) and polarity transitions are two major features of the Earth’s magnetic field. Both PSV and reversal studies are limited when age of studied units is poorly constrained. This is a case of Central and western Mexico volcanics. Although many studies have been devoted to these crucial problems and more than 200 paleomagnetic directions are available for the last 5 Ma, only few sites were dated directly. This paper presents new paleomagnetic results from seventeen independent cooling units in the Michoacán-Guanajuato Volcanic Field (MGVF) in western Mexico. Twelve sites are directly dated by 40Ar/39Ar or K-Ar methods and span from 2.78 to 0.56 Ma. The characteristic paleodirections are successfully isolated for 15 lava flows. The mean paleodirection (inclination I and declination D) obtained in this study is I = 28.8°, D = 354.9°, and Fisherian statistical parameters are k = 28, α95 = 7.3°, N=15, which corresponds to the mean paleomagnetic pole position Plat = 83.9°, Plong = 321.6°, K = 34, A95 = 6.6°. The paleodirections obtained in present study compiled with those, previously reported from the MGVF, are practically undistinguishable from the expected Plio-Quaternary paleodirections. The paleosecular variation is estimated through the study of the scatter of the virtual geomagnetic poles giving SF = 15.9 with SU =21.0 and SL = 12.7 (upper and lower limits respectively). These values agree reasonably well with the recent statistical Models. The oldest sites analyzed (the Santa Teresa and Cerro Alto) yield normal polarity magnetizations as expected for the cooling units belonging to the Gauss geomagnetic Chron. The interesting feature of the record comes from lava flows dated at about 2.35 Ma with clearly defined normal directions. This may point out the possible existence of a normal polarity magnetization in the Matuyama reversed Chron older than the Reunion and may be correlated to Halawa event interpreted as the Cryptochron C2r.2r-1. Another important feature of the geomagnetic record obtained from the MGVF is the evidence of fully reversed geomagnetic field within Bruhnes Chron, at about 0.56 Ma corresponding to the relative paleointensity minimum of global extent found in marine sediments at about 590 ka.  相似文献   

17.
Two alkaline syenite plutons, the Tieshan and Yangfang plutons, have recently been recognized within NE-trending fault zones in eastern Cathaysia, South China. The rocks are very enriched in K2O (6.28–9.39 wt.%), rare earth elements (REE; particularly light REE) and large ion lithophile elements, but are relatively low in high field strength elements. Isotopically, they are characterized by high initial 87Sr/86Sr (0.7093 to 0.7123) and low Nd(t) values (−5.64 to −10.63). The geochemical data suggest that the alkaline syenites most likely formed via fractional crystallization of enriched mantle-derived magmas. Sensitive High-Resolution Ion Microprobe zircon U–Pb dating indicates that these two intrusions have Late Permian (254±4 Ma) and Early Triassic (242±4 Ma) crystallization ages, respectively. Our data suggest that a tectonic regime dominated by transtension probably existed from at least the latest Permian into the Triassic and was responsible for the formation of the Tieshan and Yangfang alkaline syenites. When combined with previous paleomagnetic, structural, and sedimentology data, we suggest that the transtension along the NE-trending strike-slip fault zones was related to oblique subduction of the Pacific plate underneath South China.  相似文献   

18.
We report isotope analyses of helium, neon, argon, and xenon using different extraction techniques such as stepwise dynamic and static crushing, and high-resolution stepwise heating of three mantle xenoliths from Réunion Island. He and Ne isotopic compositions were similar to previously reported Réunion data, yielding a more radiogenic composition when compared to the Hawaiian or Icelandic mantle plume sources. We furthermore observed correlated 129Xe/130Xe and 136Xe/130Xe ratios following the mantle trend with maximum values of 6.93 ± 0.14 and 2.36 ± 0.06, respectively. High-resolution argon analyses resulted in maximum 40Ar/36Ar ratios of 9000–11,000, in agreement with maximum values obtained in previous studies. We observed a well-defined hyperbolic mixing curve between an atmospheric and a mantle component in a diagram of 40Ar/36Ar vs. 20Ne/22Ne. Using a mantle 20Ne/22Ne of 12.5 (Ne–B) a consistent 40Ar/36Ar value of 11,053 ± 220 in sample ILR 84-4 was obtained, whereas extrapolations to a higher mantle 20Ne/22Ne ratio of 13.8 (solar wind) would lead to a much higher 40Ar/36Ar ratio of 75,000, far above observed maximum values. This favours a mantle 20Ne/22Ne of about 12.5 considered to be equivalent to Ne–B. Extrapolated and estimated 40Ar/36Ar ratios of the Réunion, Iceland, Loihi, and MORB mantle sources, respectively, tend to be linearly correlated with air corrected 21Ne/22Ne and show the same systematic sequence of increasing relative contributions in radiogenic isotopes (Iceland–Loihi–Réunion–MORB) as observed for 4He/3He. In general, He–Ne–Ar isotope systematics of the oceanic mantle can be explained by following processes: (i) different degree of mixing between pure radiogenic and pure primordial isotopes generating the MORB and primitive plume (Loihi-type) endmembers; (ii) relatively recent fractionation of He relative to Ne and Ar, in one or both endmembers; (iii) after the primary fractionation event, different degrees of mixing between melts or fluids of MORB and primitive plume affinity generate the variety of observed OIB data, also on a local scale; (iv) very late-stage secondary fractionation during magma ascent and magma degassing leads to further strong variation in He/Ne and He/Ar ratios.  相似文献   

19.
We report detailed rock-magnetic and paleomagnetic directional data from 35 lava flows (302 standard paleomagnetic cores) sampled in the Central-Northern region of Uruguay in order to contribute to the study of the paleosecular variation of the Earth’s magnetic field during early Cretaceous and to obtain precise Cretaceous paleomagnetic pole positions for stable South America. The average unit direction is rather precisely determined from 29 out of 35 sites. All A95 confidence angles are less than 8°, which points to small within-site dispersion and high directional stability. Normal polarity magnetizations are revealed for 19 sites and 10 are reversely magnetized. Two other sites yield well defined intermediate polarities. The mean direction, supported by a positive reversal test is in reasonably good agreement with the expected paleodirection for Early Cretaceous stable South America and in disagreement with a 10° clockwise rotation found in the previous studies. On the other hand, paleomagnetic poles are significantly different from the pole position suggested by hotspot reconstructions, which may be due to true polar wander or the hotspot motion. Our data suggest a different style of secular variation during (and just before) the Cretaceous Normal Superchron and the last 5 Ma, supporting a link between paleosecular variation and reversal frequency.  相似文献   

20.
Fresh basalt glasses from the North Chile Ridge (NCR) in the southeastern Pacific have Ne isotopic compositions distinctly different from typical mid-ocean ridge basalts (MORB). In a three-isotope plot of 20Ne/22Ne vs. 21Ne/22Ne, the NCR data define a correlation line with a slope smaller than that of the MORB correlation line, i.e. their Ne composition is more nucleogenic than that of MORB. 3He/4He ratios are slightly lower than the MORB average, whereas in a few stepwise heating fractions very high 40Ar/36Ar ratios up to 28,000 are found. One model to explain the data assumes contamination of the NCR mantle source by material from the continental or oceanic crust, but in addition to difficulties with quantitatively reconciling the noble gas patterns with such a model it seems unable to account for some geochemical characteristics of NCR basalts reported earlier [Bach et al., Earth Planet. Sci. Lett. 142 (1996) 223–240], such as depletions in highly incompatible elements and unradiogenic Sr isotope compositions. Therefore we favor the scenario of a mantle source which was depleted and degassed previously, possibly as a residue from mantle melting beneath the southern East Pacific Rise that was transported to the NCR and melted again. The time during which such a depleted reservoir would have to be separated from the MORB mantle is estimated at 10–100 Ma based on U/Th–Ne systematics, in reasonable agreement with the time scale deduced from the formation history of the NCR and the temporal evolution of the southeast Pacific.  相似文献   

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