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1.
为研究汉中盆地地下水的水化学特征及成因,在丰水期共采集56件潜水样品,综合运用数理统计、相关性分析、Piper三线图、Gibbs模型和离子比等方法,分析了汉中盆地地下水的水文地球化学特征、各化学参数的空间变化规律、主要离子的控制因素及来源。结果表明,汉中盆地地下水阳离子以Ca2+为主,阴离子以HCO3为主。从离子空间变化规律上来看,K+波动最为剧烈,且从中下游开始逐渐降低,Cl-和Na+变化规律一致,呈波动变化;HCO3-、Ca2+、Mg2+以及SO42-的从中上游至中下游含量逐步降低,至下游含量增加;TDS值为128.5~590 mg/L,平均值为282.67 mg/L,在中下游含量明显增加;pH平均值为7.17,为弱碱性,在中上游波动剧烈,至下游逐渐降低。地下水水化学类型以HCO3–Ca和HCO  相似文献   

2.
贺兰山以北乌兰布和沙漠地下水水化学特征演化规律研究   总被引:5,自引:0,他引:5  
党慧慧  董军  岳宁  董阳  郭映  魏国孝 《冰川冻土》2015,37(3):793-802
乌兰布和沙漠对中国西北部干旱地区气候变化和水文循环过程研究具有指示意义, 以水文地球化学运移为导向, 通过分析33个地下水样, 探讨了该区地下水的补给与演化过程. 结果表明: 巴彦乌拉山浅层地下水水化学类型为Cl--HCO3--SO42--Na+; 从吉兰泰盐湖至乌兰布和沙漠, 主要水化学类型变化浅层地下水为Cl--HCO3--Na+到Cl--HCO3--SO42--Na+, 深层地下水为HCO3--Cl--Na+再到HCO3--Cl--Na+或HCO3--Cl--Ca2+. Gibbs图表明, 研究区地下水的水化学特征主要受蒸发浓缩作用影响和岩石风化作用控制, 大气降雨机制影响甚微. 主要离子相关关系图及饱和指数表明, 岩盐、芒硝、钠长石、方解石、白云石、石膏等矿物的风化溶解是该区地下水主要离子来源. 此外, 氯碱指数和Ca/Na的指示, 说明阳离子交换作用也是形成该地区地下水水化学组分的重要机制.  相似文献   

3.
地下水水文地球化学特征及其成因的认识可为地下水环境及饮用水安全提供重要依据。本文以车马碧水库引水隧洞近场区为研究对象,在现场水文地质调查和分析基础上,选取33组水样进行水化学测试,并从中抽取22组水样进行氢氧同位素测定。利用Piper三线图、Gibbs模型图、离子比例分析和因子分析等方法,确定研究区地下水离子组分来源。结果表明:大气降水是研究区内地下水的主要补给来源。地下水和地表水受含水层岩性影响,主要水化学类型分别为HCO3-Ca·Mg型、HCO3-Ca型;支洞水由于受人类活动影响较大,阴离子由HCO3-型变为SO42-型。水-岩作用在各离子来源中占主导作用,K++Na+和Cl-主要来源于盐岩和硅酸盐的溶解作用,Ca2+、Mg2+、HCO3-、SO42-主要来...  相似文献   

4.
大同盆地地下水砷异常及其成因研究   总被引:14,自引:0,他引:14       下载免费PDF全文
大同盆地是中国典型的原生高砷地下水分布区。笔者对大同盆地高砷地下水的分布特征、水化学演化过程、砷的来源以及控制高砷地下水形成的地球化学过程等近期研究成果进行了总结。盆地周边石炭—二叠纪煤系地层是盆地高砷环境的主要原生物源,含水层系统中铁磁性矿物为砷的主要载体,盆地内富含有机质的湖相沉积物是次生富砷介质。在盆地中心,地下水径流受阻,蒸发成为主要的排泄方式,浓缩作用使得地下水中TDS含量增大。在富含有机质的地层中,有机质在细菌或微生物作用下不断发生分解,使得地下水环境呈还原性。在高pH、低Eh条件下,由于铁锰氧化物或氢氧化物等水合物或粘土矿物对砷的吸附性降低,一部分被吸附的砷从这些矿物表面解吸;同时部分铁锰氧化物可被还原为低价态可溶性铁锰,从而使与其结合的砷也得以释放进入地下水中。在还原条件下,水中的SO24-和有机碳可被还原成H2S和CH4等低价态化合物,尽管生成的硫化物达到一定浓度时可与水中的亚铁离子和砷反应生成FeAsS沉淀,降低了地下水中砷含量,但由于地下水中Fe和硫酸盐含量有限,Fe普遍含量较低,硫酸盐耗尽后,CH4生成细菌就会成为主导力量,砷就会继续在地下水中积聚。此外,由于pH的升高,还可引起其他不同的酸根离子的解吸,如磷酸根、钒酸根、铀酰和钼酸根等也趋向于在溶液中积累,这些被吸附的阴离子以竞争吸附方式,进一步促进砷的解吸。  相似文献   

5.
针对沁水盆地煤层气开采对地下水环境的影响问题,基于统计学方法对采集的129件水样进行分析,系统评价了地下水与煤层气排采水之间的关系。Piper三线图对各含水层地下水和煤层气排采水水化学特征的分析表明,沁水盆地区域地下水常见离子以HCO3-、SO42-、Ca2+、Mg2+为主,煤层气排采水水化学类型以HCO3-、Cl-、Na+为主,与地下水水化学类型差异大。箱式图结果表明:煤层气排采水中F-平均质量浓度远高于区域地下水中的,可选取F-作为煤层气排采水的示踪剂;沁水盆地未出现地下水F-质量浓度大范围升高现象,仅柿庄区块南部水样(1027-4、1027-5)和郑庄区块(1030-3)东南部水样地下水出现高F-质量浓度。通过聚类分析评价地下水和煤层气排采水之间的F-质量浓度关系,结果显示:柿庄区块南部煤层气排采水F-质量浓度与Na+、HCO3-、Fe3+质量浓度相关性好,水样1027-4同时出现Na+、HCO3-、Fe3+偏高现象;郑庄区块东南部煤层气排采水F-与NO3-质量浓度相关性好,但1030-3未出现NO3-质量浓度偏高现象。结果表明:沁水盆地煤层气开采未造成大范围地下水污染,但柿庄区块南部局部地区浅层地下水混入煤层气排采水。  相似文献   

6.
吕琳  李伟  刘元晴  宋绵  邓启军  郑一迪 《中国岩溶》2023,(1):149-160+181
以太行山北段金龙洞岩溶泉为研究对象,通过数理统计.、离子比值及饱和指数等方法,分析泉水水化学和同位素动态特征、水中主要离子来源及演化、水-岩相互作用过程等内容。结果显示:(1)金龙洞泉补给来源为大气降水,泉流量对其响应程度高,泉流量较小时,水中主要离子含量相对高,水化学类型为HCO3·SO4-Ca·Mg型,泉流量大时,水中离子含量低,水化学类型为HCO3-Ca、HCO3·SO4-Ca型,泉流量增加引起的稀释作用对离子含量影响明显;(2)控制泉水水化学特征的主要因素为溶滤作用和稀释作用,且Ca2+、Mg2+、HCO3-主要来源于碳酸盐岩溶解,SO42-、Na+、K+、Sr主要来源于安山岩中长石、黄铁矿等矿物的风化溶解,NO3-则来源于人类活动;(3)降水集中期,泉...  相似文献   

7.
铜铁矿区周边地下水硫酸盐污染是生态环境研究关注的热点问题,精确识别硫酸盐来源及迁移途径对于矿区周边地下水污染防控和供水安全至关重要.利用水化学与硫同位素耦合分析,结合矿区水文地质条件和潜在污染源分布,探讨了区内地下水硫酸盐污染特征、来源及迁移途径.区域内地下水包括松散岩类孔隙水、碳酸盐岩裂隙岩溶水及岩浆岩风化裂隙水,水化学类型主要为HCO3·SO4-Ca型,水化学组分主要来源于硅酸岩、碳酸盐岩和硫酸盐矿物的溶解以及硫化物氧化;地下水中SO42-含量范围为44.4~2 089.0 mg/L,高值区主要分布在洪山溪尾矿库、矿渣堆存处及矿业生产区附近;地下水中δ34S-SO42-在2.6‰~31.5‰之间,反映其SO42-具有多源性.地下水中SO42-的主要来源包括含水层中石膏矿物的溶解和黄铁矿等含硫矿物氧化输入,高含量的SO4  相似文献   

8.
为查清济南市新旧动能转换先行区浅层地下水NO3-污染问题,对研究区7种污染源类型64件浅层地下水样品水质结果进行统计分析后认为:受人类活动影响,地下水中NO3-含量的高低往往与几种特定的水化学类型存在对应关系。4类主要污染源类型浅层地下水NO3-含量一般顺序为:垃圾渗滤液>禽畜养殖>生活污水>农业种植。垃圾渗滤液下渗导致的NO3-污染对应的主要地下水化学类型为HCO3·Cl-Na·Mg型,粪便渗滤液及尿液下渗主要对应产生HCO3·SO4-Na·Mg型、生活污水入渗对应产生HCO3·Cl-Na·Ca型,农业种植区主要对应HCO3-Na·Ca型。离子相关性分析表明,NO3-含量与Ca2+、Cl-存在相关关系。研究区以农业种植为主,大量氮素化肥和石灰等土壤改良剂的使用是导致浅层地下水NO3-与Ca2+相关的主要因素。NO3-与Cl-在地下水中同属较稳定离子,由长期的人类活动排放、入渗积累或蒸发浓缩富集,是一个地区人类活动密集程度和历史长度的综合反映,提出了NO3-与Cl-质量浓度联合评价地下水污染的基本方法。  相似文献   

9.
北方典型内陆盆地高砷地下水的水化学特征及处理技术   总被引:1,自引:0,他引:1  
赵凯  郭华明  高存荣 《现代地质》2015,29(2):351-360
我国高砷地下水分布广泛,是受砷污染最严重的地区之一,严重危害居民身体健康,开发经济、高效、环境友好的高砷地下水修复治理技术极具必要性。以大同盆地、呼包平原、河套平原和银川平原为代表性研究区域,归纳总结了北方干旱、半干旱地区典型高砷地下水区水化学特征。通常情况下,高砷地下水的pH值较高,共存阴离子(HCO-3、SO2-4和Cl-)浓度较大,溶解性有机碳含量较高,并且As(Ⅲ)为主要砷形态。开展了针对北方典型高砷地下水特定水化学环境特点(如pH值、共存阴阳离子以及溶解性有机物等)的改性天然菱铁矿除砷性能研究。结果表明,改性天然菱铁矿对溶液pH值具有良好的缓冲能力,其除砷性能基本不受pH值、共存阴离子、Ca/Mg阳离子及以腐殖酸为代表的溶解性有机物等典型高砷地下水水化学特征因素的影响,表明吸附剂对砷具有良好的吸附选择性。另外,改性天然菱铁矿对As(Ⅲ)的去除效果优于对As(V)的去除效果,因此,利用改性天然菱铁矿作为反应介质材料,将其应用于处理主要以As(Ⅲ)形式存在的高砷地下水具备良好的发展前景。  相似文献   

10.
陈倩  钟金先  李长顺 《现代地质》2012,26(3):607-613
通过对四川盆地大量浅层风化带裂隙水水化学数据的描述性分析、相关分析、因子分析,结合盆地地质-水文地质条件,分析和研究了浅层风化带裂隙水化学成分分布特征及形成作用。结果表明:区内浅层风化带裂隙水中主要阴阳离子为HCO3-和Ca2+,HCO3-、Ca2+、Mg2+在地下水中含量相对稳定,尤其是HCO3-绝对含量较大,相对含量差别不大;Na++K+、SO42-、Cl-在地下水中含量变化较大,是随环境因素变化的敏感因子;水化学成分特征的形成受大气降水和含水系统中岩石矿物成分的影响;总溶解固体值TDS<1 g/L的淡水在区内大面积分布,TDS值总体呈现出由盆地边缘向盆地中心的递增关系,表明溶滤作用由盆地周围向盆地中心的递增特点,但局部地区TDS值受大气降雨的影响。  相似文献   

11.
To better understand the sources and mobilization processes responsible for arsenic enrichment in groundwater in the central part of Datong Basin where serious arsenic poisoning cases have been reported, hydrochemical characteristics of the groundwater and the geochemical and mineralogical features of the aquifer sediments were studied. The aqueous arsenic levels are strongly depth-dependent in the study area and the high arsenic concentrations are found at depths between 15 m and 60 m, with a maximum up to 1820 μg/L. The hydrochemical characteristics of high arsenic groundwater from the Datong Basin indicate that the mobilization of arsenic is related to reductive dissolution of Fe oxides/oxyhydroxides and/or desorption from the Fe oxides/oxyhydroxides at high pH (above 8.0). The bulk chemical results of sediments show the arsenic and iron are moderately correlated, suggesting that arsenic is associated with iron-bearing minerals. Results of sequential-extraction experiment show that solid-phase arsenic is similarly distributed among the different pools of reservoir in the aquifer sediments. Strongly adsorbed arsenic and co-precipitated arsenic are its dominant species in the solid-phase. Geochemical studies using chemical analysis, X-ray diffraction and scanning electron microscopy on magnetically separated fractions demonstrate that iron oxides/oxyhydroxides with residual magnetite and chlorite, illite, iron oxides/oxyhydroxides-coated quartz and feldspar, and ankerite are the dominant carriers of arsenic in the sediments. The major processes of arsenic mobilization are probably linked to desorption of As from Fe oxides/oxyhydroxides and reductive dissolution of Fe-rich phases in the aquifer sediments under reducing and alkaline conditions.  相似文献   

12.
江汉平原东北部地区高铁锰地下水成因与分布规律   总被引:1,自引:0,他引:1       下载免费PDF全文
肖港地区位于江汉平原东北部,属于大别山连片贫困区和贫水区,地下水资源较贫乏,且地下水水质不佳,水中铁锰离子含量普遍超过了国家饮用水标准。为查明高铁锰地下水成因及空间分布规律,服务区内地下水开发利用及安全供水问题,系统采集区内岩石、土壤和地下水样品,测试岩土与地下水中铁锰的含量,分析地下水中铁锰含量与含水层沉积物的铁锰含量、地下水的氧化还原条件和酸碱度之间的关系。结果表明:江汉平原东北部地区地下水中铁锰超标现象普遍存在,其中锰的超标率大于铁,第四系孔隙潜水超标最严重,铁锰最大浓度分别达到44.88 mg/L和19.21 mg/L。研究区岩土中铁锰氧化物为地下水中铁锰提供了物质来源,弱酸性、强还原环境为沉积物中铁锰的溶解释放提供了有利条件,总体上从研究区东西两侧(补给、径流区)向中部第四系孔隙潜水含水层(排泄区),沿地下水流向Eh值、pH值逐渐减小,铁锰含量逐渐增大,形成北北东向带状分布的高铁锰地下水区。  相似文献   

13.
Groundwater in some deep wells of Maydavood aquifer, southwestern Iran, contains relatively high concentrations of arsenic. Detailed hydrochemical analysis of these groundwaters (with ICP-OES instrument) showed that concentrations of iron, manganese, nickel, and vanadium are also high in them and concentrations of total arsenic in 81% of deep wells are greater than World Health Organization’s permissible value (10 ppb). XRF analysis of surrounding geological formations and aquifer sediments proposed that original source of arsenic in aquifer material can be attributed to minerals from Asmari Formation. It appears that a key mechanism for arsenic mobilizing to deep wells is microbial biodegradation of petroleum related organic matters (PROMs), which exist in aquifer sediments and originates from the bedrock of the aquifer (Gachsaran Formation). This process is followed by microbially mediated reductive dissolution of arsenic-bearing iron/manganese oxyhydroxides/oxides and further by nickel and vanadium mobilizing to groundwater. According to hydrogeochemical conditions and cluster analysis, water wells in Maydavood aquifer are divided to four subgroups: the wells with mildly reducing condition (subgroup I), moderately reducing condition (subgroup II), reducing condition (subgroup III), and high reducing condition (subgroup IV). Affected wells to arsenic are belonged to subgroups III and IV.  相似文献   

14.
Arsenic concentrations surpassing potability limit of 10 μg/L in the groundwater supplies of an extensive area in the Duero Cenozoic Basin (central Spain) have been detected and the main sources of arsenic identified. Arsenic in 514 samples of groundwater, having mean values of 40.8 μg/L, is natural in origin. Geochemical analysis of 553 rock samples, assaying arsenic mean values of 23 mg/kg, was performed. Spatial coincidence between the arsenic anomaly in groundwater and the arsenic lithogeochemical distribution recorded in the Middle Miocene clayey organic-rich Zaratan facies illustrates that the rocks of this unit are the main source of arsenic in groundwater. The ferricretes associated to the Late Cretaceous–Middle Miocene siliciclastics also constitute a potential arsenic source. Mineralogical study has identified the presence of arsenic in iron oxides, authigenic pyrite, manganese oxides, inherited titanium–iron oxides, phyllosilicates and organomineral compounds. Arsenic mobilization to groundwater corresponds to arsenic desorption from iron and manganese oxides and from organic matter.  相似文献   

15.
Natural arsenic(As)contamination of groundwater which provides drinking water and/or irrigation supplies remains a major public health issue,particularly in South and Southeast Asia.A number of studies have evaluated various aspects of the biogeochemical controls on As mobilization in aquifers typical to this region,however many are predicated on the assumption that key biogeochemical processes may be deduced by sampled water chemistry.The validity of this assumption has not been clearly established even though the role of sorption/desorption of As and other heavy metals onto Fe/Mn(hydr)oxides is an important control in As mobilization.Here,selective chemical extractions of sand-rich and clay-rich sediments from an As-affected aquifer in Kandal Province,Cambodia,were undertaken to explore the potential role of partial re-equilibrium through sorption/desorption reactions of As and related solutes(Fe,Mn and P)between groundwater and the associated solid aquifer matrix.In general,groundwater As is strongly affected by both pH and Eh throughout the study area.However,contrasting sorption behaviour is observed in two distinct sand-dominated(T-Sand)and clay dominated(T-Clay)transects,and plausibly attributed to differing dominant lithologies,biogeochemical and/or hydrogeological conditions.Sorption/desorption processes appear to be re-setting groundwater As concentrations in both transects,but to varying extents and in different ways.In T-Sand,which is typically highly reducing,correlations suggest that dissolved As may be sequestered by sorption/re-adsorption to Fe-bearing mineral phases and/or sedimentary organic matter;in T-Clay Eh is a major control on As mobilization although binding/occlusion of Fe-bearing minerals to sedimentary organic matter may also occur.Multiple linear regression analysis was conducted with groups categorised by transect and by Eh,and the output correlations support the contrasting sorption behaviours encountered in this study area.Irrespective of transect,however,the key biogeochemical processes which initially control As mobilization in such aquifers,may be "masked" by the re-setting of As concentrations through in-aquifer sorption/desorption processes.  相似文献   

16.
针对地下水资源过量开采而出现的绿洲水文生态问题,以贺兰山西麓具有典型特征的内蒙古腰坝绿洲为研究对象,分开采期、非开采期对地下水进行系统取样分析,综合运用描述性统计、相关性分析、离子比例系数和Piper三线图示法,全面系统地研究了地下水水化学的时空变异特征与演变规律。研究结果表明:①季节变化对潜水和承压水水化学类型空间变异性影响较小,潜水水文化学性质受外界因素干扰较大,承压水受外界因素干扰较少;②蒸发浓缩、阳离子交换和人为混合是控制研究区潜水水质演变的主要水文化学过程;③潜水子系统总溶解固体较高,水化学类型变化也较复杂,主要从HCO3·SO4.Cl-Na·Mg·Ca型向Cl·SO4·HCO3-Mg·Na、Cl·SO4-Na·Mg型演化。承压水水化学类型比较单一,主要以低矿化度的HCO3-Na·Mg·Ca型为主。  相似文献   

17.
在研究咸阳地区地质和地热背景条件基础上,探讨了地热水的主要化学成分特征和形成机制。分析结果表明:热水属深循环高温高氟高矿化热水;水化学类型以Cl-Na、Cl·HCO3-Na、HCO3-Na、HCO3·SO4-Na、SO4·HCO3-Na、HCO3·Cl·SO4-Na等类型为主,地热水与渭河北岸断裂及其次级断裂关系密切。  相似文献   

18.
渭北岩溶水的化学特征及其地质背景   总被引:3,自引:0,他引:3  
渭北东、西部岩溶水的化学特征各不相同。这种不同,是由于含水介质的差异而造成的。东部岩溶水的含水介质为中奥陶统的滨海相、潮间泻湖相与广海陆棚相的灰岩夹膏盐地层,水化学类型为HCO3·SO4、SO4·HCO3或SO·4HCO3·Cl型,矿化度一般为1g/L左右;西部岩溶水的含水介质以中、上奥陶统浅海相或浅海深海相的灰岩、白云质灰岩、粒状灰岩为主,水化学类型为单一的HCO3型,矿化度一般为0.5g/L左右。  相似文献   

19.
The Hutuo River alluvial-proluvial fan is located in North China Plain, and groundwater is the main source of water supply for agriculture and domestic water. Shijiazhuang depression funnels due to the long-term excessive exploitation are the bottleneck of the regional economic development. Analyzing the chemical characteristics of groundwater under the condition of strong human activities, can provide a scientific basis for further study of strong groundwater mining area environmental change. 143 groups of shallow groundwater samples are collected during the period of 2007-2008. In this paper, the hydrochemical characteristics of groundwater in the Hutuo River Plain area are analyzed systematically, using hydrogeochemical theory, combined with statistical methods and hydrochemical methods. Results are shown as follows: HCO_3~- and Ca~(2+) are major anion and cation. The variation coefficients of K~+, Ca~(2+), Mg~(2+) and HCO_3~- between 0.25 and 0.52, which means small and stable relatively. The variation coefficient of are Na~+, NO_3~-, Cl-, SO2-4 were large(0.89-1.01). They are sensitive and vulnerable to environmental change affect. Due to the impact of human activities, from the top to the edge of the alluvial-proluvial fan, the hydrochemical types of groundwater change from single to multiple, followed by HCO_3~-Ca·Mg, HCO_3·SO_4-Ca·Mg, HCO_3·SO_4·Cl-Ca·Mg, HCO_3·Cl-Ca·Mg and other types.  相似文献   

20.
经过野外现场调查和取样分析及室内研究得知南阳油田地下水已遭受不同程度的有机物污染,且污染范围可能进一步向油田南部扩散。根据近似地下水流线方向上地下水中总油质量浓度和Fe,Mn等无机组分的变化势态,结合含水介质化学分析结果,发现硫酸盐、Fe和Mn可作为地下水有机污染和地球化学标志物。在含水介质中Fe和Mn质量浓度较高的地方,地下水有机污染物降解速度快,含水介质中Fe和Mn的氧化物和氢氧化物的还原作用导致了含水层介质中Fe和Mn的缺乏和地下水中溶解Fe和Mn的积聚;在含水介质中Fe和Mn质量浓度低的地方,地下水中的有机物质量浓度并没有降低,相应地地下水中溶解Fe和Mn的质量浓度也很低。同时,由于有机污染物的存在使地下水中硫酸盐被还原,导致城下水中硫酸盐质量浓度偏低,且地下水中Fe对有机物污染的敏感性比Mn强。  相似文献   

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