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1.
The Bayana Basin forms the eastern most limit of north Delhi fold belt covering parts of northeastern Rajasthan. The deposition
of sediments took place during middle Proterozoic in fluvial and shallow marine environments. The rocks are mainly clastics
and include conglomerate, sandstone and shale. During mechanical compaction rearrangement of grains took place and point and
long contacts were formed. The sandstones are cemented by iron oxide, silica, carbonate and barite. The porosity has developed
due to dissolution of iron, carbonate cement and feldspar grains. Dissolution of quartz along grain boundaries and silica
rich compaction pore water seems to be the main source of silica. These observations suggest progressive compaction which
initiated at the sediment water interface and continued till deep burial diagenesis in a rapidly subsiding basin. 相似文献
2.
M. Kennedy 《Australian Journal of Earth Sciences》2013,60(3):217-228
Parts of the Late Proterozoic to Cambrian sequence along the northeastern margin of the Amadeus Basin were deposited under the influence of salt movement within the underlying Bitter Springs Formation. Later folding during the Devonian Alice Springs Orogeny and subsequent erosion has exposed salt‐influenced structures to provide a rare opportunity to observe the effects of diapiric growth on local facies and structure. Such effects are commonly only seen in seismic section. Salt withdrawal led to normal faulting and syn‐sedimentary thickening of adjacent units. The Undoolya Sequence, a previously undescribed 710 m section, was deposited within a salt‐withdrawal basin adjacent to a proposed diapiric structure. Periods of salt mobilization are recorded by syn‐depositional thickening and localized unconformities within units flanking the diapiric structure. This structure is representative of the influence salt movement had on deposition in the northeastern Amadeus Basin during the Late Proterozoic. 相似文献
3.
JIANGUO WANG DAIZHAO CHEN DAN WANG DETIAN YAN XIQIANG ZHOU QINGCHEN WANG 《Sedimentology》2012,59(3):809-829
The Ediacaran–Cambrian transition was one of the most critical intervals in Earth history. During this interval, widespread chert was precipitated, commonly as a stratal wedge in carbonates, along the southern margin of the Yangtze Platform, South China. The chert wedge passes into a full chert succession further basinward to the south‐east. Four lithotypes of chert are identified across the marginal zone in western Hunan: mounded, vein, brecciated and bedded chert. The mounded chert is characterized by irregular to digitiform internal fabrics, generally with abundant original vesicles and/or channels that mostly are lined by botryoidal chalcedony cements with minor quartz and barite crystals. The host chert (or matrix) of these mounds is dominated by amorphous cryptocrystalline silica, commonly disseminated with pyrite. The vein chert, with minor quartz locally, generally cross‐cuts the overlying dolostone and chert horizons and terminates under the mounded and/or bedded chert bodies. The brecciated chert commonly occurs as splayed ‘intrusions’ or funnel‐shaped wedges and cross‐cuts the topmost dolostones. The bedded chert, the most common type, generally is thin to medium‐bedded and laminated locally; it is composed of amorphous silica with minor amounts of black lumps. Microthermometry of fluid inclusions from vein and void‐lining minerals (mainly quartz and barite) revealed homogenization temperatures from 120 to 180°C for the trapped primary fluids. Compositionally, these chert deposits generally are pure, with SiO2 > 92 wt%, and only minor Fe2O3 and Al2O3 contents, most of which show positive Europium anomalies in rare earth element patterns, especially for the mounded chert. All these data suggest that the marginal zone chert deposits resulted from a low‐temperature, silica‐rich hydrothermal system, in which the mounded chert was precipitated around the releasing vents, i.e. as silica chimneys. The vein and splayed brecciated chert, however, was formed along the syndepositional fault/fracture conduits that linked downward, while the bedded chert was precipitated in the quieter water column from the fallout of hydrothermal plumes onto the sea floor. These petrological and geochemical data provide compelling evidence and a new clue to the understanding of the extensive silica precipitation; rapid tectono‐depositional and oceanic changes during the Ediacaran–Cambrian transition in South China. 相似文献
4.
During the Cenozoic numerous shallow epicontinental evaporite basins formed due to tectonic movements in the Northern Province of the Central Iran Tectonic Zone (the Great Kavir Basin). During the Miocene, due to sea‐level fluctuations, thick sequences of evaporites and carbonates accumulated in these basins that subsequently were overlain by continental red beds. Development of halite evaporites with substantial thickness in this area implies inflow of seawater along the narrow continental rift axis. The early ocean basin development was initiated in Early Eocene time and continued up to the Middle Miocene in the isolated failed rift arms. Competition between marine and non‐marine environments, at the edge of the encroaching sea, produced several sequences of both abrupt and gradual transition from continental wadi sediments to marginal marine evaporites in the studied area. These evaporites show well‐preserved textures indicative of relatively shallow‐brine pools. The high Br content of these evaporites indicates marine‐derived parent brines that were under the sporadic influence of freshening by meteoric water or replenishing seawater. However, the association of hopper and cornet textures denotes stratified brine that filled a relatively large pool and prevented rapid variations in the Br profile. Unstable basin conditions that triggered modification of parent brine chemistry prevailed in this basin and caused variable distribution patterns for different elements in the chloride units. The presence of sylvite and the absence of Mg‐sulphate/chlorides in the paragenetic sequence indicate SO4−depleted parent brine in the studied sequence. Petrographic examinations along with geochemical analyses on these potash‐bearing halites reveal parental brines which were a mixture of seawater and CaCl2‐rich brines. The source of CaCl2‐rich brines is ascribed to the presence of local rift systems in the Great Kavir Basin up to the end of the Early Miocene. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
5.
M. R. Walter J. H. Shergold M. D. Muir P. D. Kruse 《Australian Journal of Earth Sciences》2013,60(5-6):305-312
In the Desert Syncline of the southern Georgina Basin there is an Early and Middle Cambrian sequence unconformably overlying late Proterozoic sediments. Stratigraphic drilling and subsequent palaeontological studies have allowed the documentation of the sequence across the Proterozoic‐Cambrian unconformity. Earliest Cambrian green shales are bioturbated and contain distinctive acritarchs. These are overlain, probably unconformably, by sandstone with Diplocraterion burrows, in turn succeeded by archaeocyathan dolostone. Ordian and Templetonian (Middle Cambrian) shales and carbonates unconformably overlie the Early Cambrian sequence. The stratigraphic sequence is very similar to that in the Amadeus Basin and the Adelaide Geosyncline. 相似文献
6.
Activity coefficient for aqueous silica in saline waters and brines from the Paris Basin was calculated using Pitzer's specific interaction model. Quartz and chalcedony are the only reported authigenic silica minerals in the Dogger aquifer of the Paris Basin (France). However, the measured silica concentrations fall between those of these two phases. The silica concentrations measured in Dogger fluids seem to be controlled by a microcrystalline quartz phase with a grain size computed to be about 20 nm. Studies have shown that pressure can preserve small grain size for a long time at the geological scale. The effective mechanism of pressure action is probably linked to the fact that pressure simultaneously favours dissolution at the grain-contact inducing a quartz supersaturation and prohibits the increase in size of reprecipitated microcrystalline quartz grains. This hypothesis is supported by other studies reported in the literature. The proposed model, which incorporates silica mineralogy and a precise calculation of aqueous silica activity, allows us to explain measured silica concentrations in the deep sedimentary solutions of the Dogger aquifers. In the Keuper brines, silica solubility can in most cases be explained by an equilibrium with either chalcedony or quartz. Another application of the present work is shown by an example, where we examined the importance of precisely evaluating the activity coefficient in basin characterisation, as the goal of reservoir characterisation is to describe the spatial distribution of petrophysical parameters such as porosity, permeability, and saturations. 相似文献
7.
The Formation and Distribution of the Marine Hydrocarbon Source Rock in the Tarim Basin, NW China 总被引：8，自引：7，他引：1
There are significant differences in type and distribution between marine source rock and continental source rock. According to the iithology, the Cambrian-Ordovician source rock in the Tarim basin is divided into two types： the carbonate source rock and the mud source rock. The two sets of source rocks are developed mainly in three sets of formations, Lower-Middle Cambrian carbonate source rock and mud source rock, Lower-Middle Ordovician mud source rock and Upper Ordovician lime mud source rock. The stratigraphic and areal distributions of the source rocks are controlled by the altitude and the sedimentary facies respectively. The mud source rock is developed in slope-semi deep sea environment. The source rock developed in the slope sedimentary environment is related with the anoxic environment and the one developed in semi deep sea has a close relationship with the up-flowing sea water. The carbonate source rock is developed mainly in platform slope of highstand systems tract and it is usually intimately associated with the salt rock. The Lower-Middle Cambrian carbonate source rock is developed mainly in the Bachu, Tazhong, Tangguzibasi and Yingmaili areas. The Lower-Middle Cambrian mud source rock is mainly developed in the areas east of the line of Kunan 1-Tadong 1. The Lower-Middle Ordovician mud source rock is developed mainly in the east slope of the Manjiaer depression. The carbonate source rock of Early Ordovician is developed mainly in the platform slope of highstand systems tract, such as the south margin of Tabei, the north slope of Tazhong, the Bachu area and Keping area. 相似文献
8.
早寒武世全球广泛发育的黑色岩系记录了重要海洋环境信息。为了解决该时期黑色岩系成因模式和沉积环境问题,本文选取南秦岭淅川—内乡地区下寒武统水沟口组黑色岩系为研究对象,通过剖面详测、薄片鉴定、电子探针和主微量元素等岩石学-地球化学分析方法,对其物质来源、形成机制和沉积环境进行分析。研究表明:水沟口组黑色岩系普遍具有海相硅质岩典型特征—微晶石英结构,并具有与海水一致的稀土标准化曲线和低的总稀土值,指示其形成于海水环境;电子探针下发现黑色岩系富含与热液有关的重晶石、萤石矿物,和与生物相关的磷灰石、黄铁矿矿物,同时黑色岩系成因判别图解中绝大部分样品落入生物成因区域,少数落入热液成因内,指示硅质来源以生物成因硅为主并含少量热液硅;样品高V/(V+Ni)、Ni/Co比值和氧化还原敏感元素(Mo、U、V等)不同程度富集指示较强的还原环境,结合黑色岩系形成环境判别图得出该套岩系形成于大陆边缘—深海盆地区域内还原—缺氧的滞流水体环境。综上得出水沟口组黑色岩系形成时洋底热液活动频繁,深部流体上涌带来大量营养物质使得浅海生物繁盛,海水中硅在生物作用和热液影响下促使硅质胶体颗粒化学沉淀,并随洋流在远离热液中心的大陆边缘位置沉积成岩。早寒武世还原—缺氧性质海水和微生态系统有助于硅质沉淀,而微生物富硅作用促进了黑色岩系形成。 相似文献
9.
朱创业 《沉积与特提斯地质》1999,19(5):47-52
陕甘宁盆地马家沟组可划分出３ 个层序,每个层序均由海侵体系域及高位体系域所组成,海平面变化是控制层序形成的主要因素。此外,盆地基底构造对层序地层的分布也具有重要的影响,在盆地中部发育浅水层序,在盆地西部及南部则发育较深水层序。在盆地中部浅水层序的高位体系域中,生储盖组合最佳,具有较好的勘探前景 相似文献
10.
A. P. Gartrell 《Australian Journal of Earth Sciences》2013,60(2):231-244
The extensional architecture of the Northern Carnarvon Basin can be explained in terms of changes in lithospheric rheology during multiphase extension and lower crustal flow. Low‐angle detachments, while playing a minor role, are not considered to have been the primary mechanism for extension as suggested in previous models. Early extension (Cambrian‐Ordovician) in the Northern Carnarvon Basin is characterised by low‐angle detachment structures of limited regional extent. These structures have a spatial association with a Proterozoic mobile belt on the margin of the Pilbara Craton. Thermo‐mechanical conditions in the mobile belt may have predisposed the highly deformed crust to thin‐skinned extension and detachment development. Permo‐Carboniferous extension generated an extensive wide rift basin, suggesting ductile rheologies associated with intermediate lithospheric temperatures and crustal thickness. Thick Upper Permian to Upper Triassic post‐rift sequences and marked thinning of the lower crust occurred in association with only a small amount of extension in the upper crust. This observation can be reconciled by considering outward lower crustal flow, from beneath the basin towards the basin margin, following extension. Strong mid‐crustal reflectors, which occur over large areas of the Northern Carnarvon Basin, probably represent a boundary between flow and non‐flow regimes rather than detachment fault surfaces as in previous models. Crustal thinning and thermal decay following Permo‐Carboniferous extension contributed to the increased strength and brittle behaviour of the lithosphere. Consequently, Late Triassic to Early Cretaceous extension resulted in the development of far more localised narrow rift systems on the margins of the preceding wide rift basin. Diapiric intrusions are associated with the narrow rift basin development, resulting from either remobilisation of ductile lower crustal rock or the initial formation of sea‐floor spreading centres. 相似文献
11.
The upper Millstone Grit strata (Yeadonian, Namurian) of North Wales have been studied using sedimentological facies analysis and sequence stratigraphy. These strata comprise two cyclothems, each containing prodelta shales (Holywell Shale) that pass gradationally upwards into delta‐front and delta‐plain deposits (Gwespyr Sandstone Formation). The deltas formed in shallow water (<100 m), were fluvial‐dominated, had elongate and/or sheet geometries and are assigned to highstand systems tracts. Two delta complexes with distinctive sandstone petrographies are identified: (1) a southerly derived, quartzose delta complex sourced locally from the Wales‐Brabant Massif, and (2) a feldspathic delta complex fed by a regional source(s) to the north and/or west. The feldspathic delta complex extended further south in the younger cyclothem. A multistorey braided‐fluvial complex (Aqueduct Grit, c. 25 m thick) is assigned to a lowstand systems tract, and occupies an incised valley that was eroded into the highstand feldspathic delta complex in the younger cyclothem. A candidate incised valley cut into the highstand feldspathic delta complex in the older cyclothem is also tentatively identified. Transgressive systems tracts are thin (<5 m) and contain condensed fossiliferous shales (marine bands). The high‐resolution sequence stratigraphic framework interpreted for North Wales can be readily traced northwards into the Central Province Basin (‘Pennine Basin’), supporting the notion that high‐frequency, high‐magnitude sea‐level changes were the dominant control on stratigraphic architecture. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
12.
Noel P. James Margaret J. Seibel Robert W. Dalrymple David Besson Olivier Parize 《Sedimentology》2014,61(2):497-534
The Saumane‐Venasque compound palaeovalley succession accumulated in a strongly tide‐influenced embayment or estuary. Warm‐temperate normal marine to brackish conditions led to deposition of extensive cross‐bedded biofragmental calcarenites. Echinoids, bryozoans, coralline algae, barnacles and benthic foraminifera were produced in seagrass meadows, on rocky substrates colonized by macroalgae and within subaqueous dune fields. There are two sequences, S1 and S2, the first of which contains three high‐frequency sequences (S1a, S1b and S1c). Sequence 1 is largely confined to the palaeovalley with its upper part covering interfluves. Each of these has a similar upward succession of deposits that includes: (i) a basal erosional surface that is bored and glauconitized; (ii) a discontinuous lagoonal lime mudstone or wackestone; (iii) a thin conglomerate generated by tidal ravinement; (iv) a transgressive systems tract series of cross‐bedded calcarenites; (v) a maximum flooding interval of argillaceous, muddy quartzose, open‐marine limestones; and (vi) a thin highstand systems tract of fine‐grained calcarenite. Tidal currents during stages S1a, S1b and S1c were accentuated by the constricted valley topography, whereas basin‐scale factors enhanced tidal currents during the deposition of S2. The upper part of the succession in all but S1c has been removed by later erosion. There is an overall upward temporal change with quartz, barnacles, encrusting corallines and epifaunal echinoids decreasing but bryozoans, articulated corallines and infaunal echinoids increasing. This trend is interpreted to be the result of changing oceanographic conditions as the valley was filled, bathymetric relief was reduced, rocky substrates were replaced as carbonate factories by seagrass meadows and subaqueous dunes, and the setting became progressively less confined and more open marine. These limestones are characteristic of a suite of similar cool‐water calcareous sand bodies in environments with little siliciclastic or fresh water input during times of high‐amplitude sea‐level change wherein complex inboard antecedent topography was flooded by a rising ocean. 相似文献
13.
鄂尔多斯地区西部和南部奥陶纪海槽边缘沉积特征与天然气成藏潜力分析 总被引：8，自引：0，他引：8
鄂尔多斯地区自中—晚元古代至早古生代继承性地发育区域性海相沉积,大体经历了中—晚元古代大陆裂谷及拗拉槽、寒武纪陆表海台地、奥陶纪局限海台地及构造转换等三个主要演化阶段。分析认为,奥陶纪在盆地西部和南部存在对天然气成藏较为有利的海槽/台地边缘沉积相带。中—上奥陶统平凉组—背锅山组是盆地西部和南部下古生界天然气成藏的主要烃源层;奥陶系礁滩体岩性圈闭是最主要的圈闭类型。盆地西部的天环北段和南部的麟游北为两个近期天然气勘探的有利目标。 相似文献
14.
This study examines the sedimentary response to a tectonically driven relative sea‐level fall that occurred in the Neuquén Basin, west‐central Argentina, during the late Early Valanginian (Early Cretaceous). At this time the basin lay behind the emergent Andean magmatic arc to the west. Following the relative sea‐level fall, sedimentation was limited to the central part of the Neuquén Basin, with the deposition of a predominantly clastic, continental to shallow marine wedge on top of basinal black shales. This lowstand wedge is called the Mulichinco Formation and consists of a third‐order sequence that lasted about 2 Myr and contains high frequency lowstand, transgressive, and highstand deposits. Significant variations in facies, depositional architecture, and internal organization of the sequence occur along depositional strike. These variations are attributed mainly to tectonic and topographic controls upon sediment flux, basin gradient, fault tilting, and shifting of the depocentre through time. These controls were ultimately related to asymmetrically distributed tectonic activity that was greater towards the magmatic arc in the west. The superposition of fluvial deposits directly upon offshore facies provides unequivocal evidence for a sequence boundary at the base of the Mulichinco Formation. However, the Mulichinco sequence boundary is marked by shallow, low erosional relief and widespread fluvial deposition. The surface lacks prominent valleys traditionally associated with sequence boundaries. This non‐erosive sequence boundary geometry is attributed to the ramp‐type geometry of the basin and/or rapid uplift that limited stratigraphic adjustment to base‐level fall. Significant along‐strike facies changes and a low‐relief sequence boundary are attributes that may be common in tectonically active, semi‐enclosed basins (e.g. shallow back‐arc basins, foreland basins). 相似文献
15.
FABRIZIO BERRA 《Sedimentology》2007,54(4):721-735
In the Concarena‐Pizzo Camino Massif (Lombardy Basin, Southern Alps, Italy) the lateral transition from Ladinian‐Carnian carbonate platforms to coeval intraplatform basins is preserved. The succession records the sedimentological evidence of a sea‐level fall on a flat‐topped platform with a narrow marginal reef rim and its effects in the adjacent deeper‐water basin. Repeated high‐frequency exposures of the platform top are recorded by a peritidal–supratidal succession that overlies subtidal inner platform facies of the former highstand system tract (HST). On the slope and in the basin, the sea‐level fall is recorded by a few metre thick succession of bioclastic packstones. These facies directly lie on coarse clinostratified breccia bodies (slope facies of the former HST) or on resedimented, well‐bedded, dark laminated limestones (basinal facies of the HST). This facies distribution indicates that during the sea‐level fall carbonate production on the platform top decreased rapidly and that sedimentation in the basin was mainly represented by condensed facies. Microfacies record an enrichment, during low stand, in pelagic biota (packstones with radiolarians and spiculae), whereas the occurrence of platform‐derived, shallow‐water materials is limited to thin lenses of reworked and micritized Fe‐rich oolites and bioclasts (mainly pelecypods and echinoderms). The facies association in the Concarena‐Pizzo Camino Massif demonstrates that a highly‐productive carbonate factory was almost completely turned off during the emergence of the platform top at a sequence boundary, leading to low‐stand starvation in the basin. The reconstruction of the stratigraphic evolution of the Concarena‐Pizzo Camino carbonate platform therefore represents a significant case history for the study of the behaviour of ancient carbonate systems during a fall in sea‐level, independent of its origin (eustatic or tectonic). 相似文献
16.
Primary aragonite and high‐Mg calcite in the late Cambrian (Furongian). Potential evidence from marine carbonates in Oman 
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下载免费PDF全文 Transient aragonite seas occurred in the early Cambrian but several models suggest the late Cambrian was a time of calcite seas. Here, evidence is presented from the Andam Group, Huqf High, Oman (Gondwana) that suggests a transient Furongian (late Cambrian) aragonite sea, characterized by the precipitation of aragonite and high‐Mg calcite ooids and aragonite isopachous, fibrous, cements. Stable carbon isotope data suggest that precipitation occurred just before and during the SPICE (Steptoean Positive Carbonate Isotope Excursion). Aragonite and high‐Mg calcite precipitation can be accounted for if mMg:Ca ratios were around 1.2 given the very high atmospheric CO2 at that time and if precipitation occurred in warm waters associated with the SPICE. This, together with reported occurrences of early Furongian aragonite ooids from various locations in North America (Laurentia), suggests that aragonite and high‐Mg calcite precipitation from seawater may have been more than just a local phenomenon. 相似文献
17.
The Tarim Basin has experienced three tectonic evolutionary phases from the Cambrian to Ordovician: (1) Regional extension from the late Neoproterozoic to Mid-Early Cambrian, (2) Relatively weak regional compression from the Late Cambrian to Mid-Early Ordovician, and (3) Regional compression during the Late Ordovician. Intra-platform tectonic and sedimentary characteristics indicate a clear linkage to the tectonic evolution of the basin margin during early Paleozoic time. During the Cambrian, small intra-platform rift-related depressions formed during an extensional setting. During the Mid-Early Ordovician, a transition from extension to compression caused formation of the Tazhong and Tabei paleo-uplifts and major unconformities T74 (base of the Late Ordovician). The evolving paleo-geomorphology led to differentiation of sedimentary facies, and numerous intra-platform shoals formed during deposition of the Early Ordovician Yingshan Formation. During the Late Ordovician, regional compression began, which changed the platform margin slopes into four slopes that surrounded the three isolated island uplifts of Tabei, Tazhong, and Tangnan in the Late Ordovician. Simultaneously, the basin margin dynamic conditions also changed the relative sea level and filling pattern of the basin. In the Early and Middle Cambrian, the Tarim Basin mainly developed a progradational ramp-type platform due to relative sea level fall. From the Late Cambrian to Early Ordovician the relative sea level began to rise, resulting in an aggradational—retrograding rimmed margins-type platform. In the Late Ordovician, along with a further rise in relative sea level, the basin mainly developed isolated platform. 相似文献
18.
Silicification of sulphate evaporites and their carbonate replacements in Eocene marine sediments, Tunisia: two diagenetic trends 总被引：1，自引：0，他引：1
Samples of chert nodules, diagenetic carbonates and evaporites (gypsum/anhydrite) collected from the gypsiferous limestones of the Kef Eddour Member (Ypressian‐Priabonian) near Metlaoui and Sehib (Tunisia) show selective silicification with great variety in the silicified by‐products. Based on δ13C values, which support an organic origin for the carbon, carbonates replaced evaporites microbially through bacterial sulphate reduction. Observations and results suggest two scenarios for chert formation that are related to the rate and timing of diagenetic carbonate replacement of the evaporites (anhydrite/gypsum). In the absence of early diagenetic carbonate phases, silica with δ18O values from +25 to +28·6‰ [standard mean ocean water (SMOW)] replaced the outer parts of anhydrite nodules at pH < 9. In contrast, pore‐fluid pH values > 9 in the innermost parts of the anhydrite nodules prevented silica precipitation. The record of this chemical barrier is preserved in the microquartz rims and geode features that formed in the inner parts of the nodules after dissolution of the anhydrite nucleus. The microbial diagenetic replacement of evaporites (bacterial sulphate reduction) by carbonates (calcite, aragonite and dolomite) favoured silica replacement of carbonates rather than evaporites. Silica, with δ18O signature of +21 to +26‰ (SMOW), replaced carbonates on a volume‐for‐volume basis, yielding a more siliceous groundmass, and accounting for 90–95% of the nodules. The relatively higher δ18O values of quartz replacing anhydrite can be explained by a diagenetic fluid in equilibrium with mixed (meteoric/marine) to marine water. The lower δ18O values of the quartz that replaced the diagenetic carbonates are ascribed to flushing by meteoric water in a later diagenetic stage. The silica supply for chert formation could be derived from the reworked bio‐siliceous deposits (diatomites) to the west of the basin [vestiges of an opal‐CT precursor undetectable by X‐ray diffraction (XRD) were revealed by δ29Si magic‐angle‐spinning nuclear magnetic resonance investigations], diagenesis of the extraformational and overlying clay‐rich beds (the host limestones are clay‐poor as shown by XRD measurements), and minor volcanogenic and hydrothermal contributions during early diagenetic stages. 相似文献
19.
玛瑙是一种隐晶质硅质岩石,主要由玉髓以及少量蛋白石、斜硅石和微晶石英等组成.其在世界各地分布广泛,质地坚硬细腻、色彩鲜艳多样、纹理交错、造型千姿百态,是一种平凡而美丽的宝石.本文结合国内外最新研究进展,对玛瑙矿物的结构、水含量和成因机制进行了综合评述.玛瑙以纹带构造为特征,其内部纹带花纹和化学组成呈韵律性变化,并在不同观察尺度表征出来.因此,玛瑙也被定义为条带状玉髓.然而,多数玛瑙实际上是由纤维状玉髓、同心环带状玉髓、水平条带状玉髓、微晶石英和自形石英晶体等组成,它们的相对含量与玛瑙的产地和形成过程密切相关.X射线衍射和电子背散射衍射(EBSD)测量数据揭示,玛瑙中的硅质矿物多发生定向生长,其中微晶石英a轴倾向于垂直韵律环带,c轴则近似平行韵律环带.傅立叶变换红外光谱(FTIR)测量表明,玛瑙含有少量分子水和羟基水,并且总水含量随着硅质矿物结晶度提高而降低.至今实验室仍然无法合成玛瑙,还不清楚玛瑙纹带构造的形成机制和过程.一种代表性假设认为,玛瑙中的纹带源于硅质热液沉淀作用或者硅胶原位结晶作用.但是,最近研究发现玛瑙纹带中共生矿物的结晶度、晶体取向和含水量具有系统差异,揭示其形成过程可能与成岩序列密切相关.将实验岩石学与定量显微结构观察以及多种矿物微区分析测试手段有机结合,深入研究玛瑙环带内部微量元素、水含量和晶体取向数据,获得其系统性变化特征及其内部联系,可以为玛瑙成因机制和形成过程研究提供重要数据支撑和关键性的约束条件. 相似文献
20.
Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO4 content. 相似文献