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1.
Clinopyroxene transforms to triple chain silicate, double chain silicate (amphibole) and sheet silicate (talc) in the metasomatic process of the Akatani ore deposit. The triple chain silicate is contained in fibrous amphibole-like phase (“amphibole”). It is of electron microscopic size of 1,000 Å at maximum width in b-direction, and is a calciferous analogue of clinojimthompsonite. Various kinds of fine textures formed in metasomatic reaction process were found in clinopyroxenes. A large amount of triple chains and a small amount of double chains were transformed from single chains in the host clinopyroxene, maintaining topotactic relation. The kinetics of the structural change of biopyriboles at the Akatani ore deposit was discussed from the viewpoint of the mode of occurrence of triple and double chain silicates. The nucleation of triple chain structure slab with one triple chain width is apt to occur rather than the nucleation of double chain structure slab with width of two double chains in clinopyroxene host. Various fine textures in clinopyroxenes and amphibole-like phase were interpreted as corresponding to the propagation of metasomatic reactions.  相似文献   

2.
The Agnew nickel sulfide deposit is spatially associated with a lenticular body of ultramafic rocks which shows a concentric zonation in metamorphic mineralogy. Olivine + tremolite + chlorite + cummingtonite ±enstatite assemblages occur at the margin of the ultramafic lens, giving way to olivine + anthophyllite, olivine + talc and olivine + antigorite assemblages successively inwards. These rocks are interpreted as having crystallized from komatiitic lavas, and exhibit a spectrum of compositions from those of original flow tops to pure olivine adcumulates. The relative modal abundances of metamorphic olivine, tremolite and chlorite reflect original proportions of cumulus olivine and komatiite liquid in the protolith. Peak metamorphic conditions are estimated at 550° C, based on garnet-biotite thermometry, at a maximum pressure of 3 kb. This temperature falls within the narrow range over which metamorphic olivine may co-exist with enstatite, anthophyllite, talc or antigorite depending upon the fugacity of water in the metamorphic fluid. The observed mineralogical zonation is therefore attributed to infiltration by CO2-rich fluids, generated by decarbonation of talc-carbonate rocks formed during pre-metamorphic marginal alteration of the ultramafic lens. Metamorphic fluids were essentially binary mixtures of water and CO2, with minor H2S having a maximum partial pressure less than 1 percent of total pressure. Enstatite-bearing assemblages formed in the presence of CO2-rich fluids at fluid: rock volume ratios close to one, while anthophyllite, talc and antigorite bearing assemblages formed in the presence of progressively more water-rich fluids at progressively lower fluid-rock ratios.  相似文献   

3.
碾子沟金红石矿床蚀变作用的基本特征及其与成矿的关系   总被引：4，自引：1，他引：3  
矿区蚀变岩分为细晶直闪(片)岩、粗晶直闪(片)岩、绿泥片岩及滑石(片)岩4大类;一般绿泥片岩位于蚀变带边部,滑石(片)岩位于中部,直闪(片)岩位于二者之间;含矿岩石主要为直闪(片)岩、次为滑石(片)岩,绿泥片岩富含铁质矿物。蚀变作用过程划为细晶直闪石化、粗晶直闪石化、绿泥石化、滑石化及斜长石化5个阶段,前4个阶段分别形成了上述4类蚀变岩,后一阶段仅形成了矿物细脉;形成金红石的主要为滑石化、次为粗晶直闪石化及细晶直闪石化,斜长石化形成的甚微。高温热液使深部及围岩中的钛向成矿部位富集,蚀变过程中铁与钛的分离及滑石化在直闪(片)岩等上的叠加,是主要成矿作用。据蚀变岩分布规律分析,碾子沟地区应有较好成矿远景。  相似文献   

4.
碾子沟金红石矿床基本地质特征   总被引：4，自引：4，他引：0  
碾子沟金红石矿区地层主要为上太古界变粒岩、斜长角闪片岩及榴闪岩 ;岩浆岩主要为晋宁期基性岩 ;构造主要为断裂。矿区蚀变岩发育 ,主要为细晶直闪片岩、粗晶直闪岩、中细晶滑石岩及细晶绿泥片岩。矿体呈似纺锤状、似板状及透镜状。矿石类型有浅褐色细晶直闪石型片状矿石、灰白色粗晶直闪石型块状矿石、灰绿色或灰白色中细晶滑石型块状矿石、黑色中细晶角闪石型片状矿石及灰绿色巨晶直闪石型块状矿石等 5种。以前 3种为主 ,矿石品位一般 2 %～ 15 %。矿床规模为大型 ,矿床为变质蚀变成因。  相似文献   

5.
Reactions which occur at the lower boundary of the hornblende-hornfels facies and in the so-called pyroxene-hornfels facies were experimentally investigated for an ultrabasic rock at 500, 1000 and 2000 bars H2O pressure.The starting material used was a mixture of natural chlorite, talc, tremolite and quartz such that its composition, except for surplus quartz, corresponded to that of an ultrabasic rock. The atomic ratio Fe2++Fe2+/Mg+Fe3++Fe3+ in the system was 0.16.The lower boundary of the hornblende-hornfels facies was defined by the formation of the orthorhombic amphibole anthophyllite and hornblende according to the following idealized reaction: chlorite+talc+tremolite+quartz hornblende+anthophyllite+H2O In effect, this reaction consists of the two bivariant reactions: chlorite+tremolite+quartz hornblende+anthophyllite+H2O talc+chlorite anthophyllite+quartz+H2OThe equilibrium temperatures obtained for the two reactions in the given system are practically the same and are as follows: 535±10°C at 500 bars H2O pressure 550±20°C at 1000 bars H2O pressure 560±10°C at 2000 bars H2O pressure 580±10°C at 4000 bars H2O pressureAt 2000 bars and higher temperatures within the hornblende-hornfels facies, anorthite is formed in addition to hornblende and anthophyllite, probably according to the following reaction: hornblende1+quartz hornblende2+anthophyllite+anorthite+H2O; because of the formation of anorthite it is to be expected that the hornblende in this case is poorer in aluminium than the hornblende at 500 and 1000 bars. Winkler (1967) suggests renaming the pyroxene-hornfels facies as K-feldspar-cordierite-hornfels facies which, in turn, is subdivided into a lower-temperature orthoamphibole subfacies without orthopyroxene and a higher-temperature orthopyroxene subfacies without orthoamphibole. The orthopyroxene subfacies itself may in its lower temperature part still carry hornblende which finally disappears in the higher temperature part.The appearance of orthopyroxene characterizes the transition from the orthoamphibole to the orthopyroxene subfacies of the K-feldspar-cordierite hornfels facies. The following reaction takes place at pressures lower than 2000 bars: hornblende1+anthophyllite hornblende2+enstatite+anorthite+H2OSince at 2000 bars an Al-poor hornblende already exists in the hornblende-hornfels facies, it is very likely that here only anthophyllite breaks down to give enstatite+quartz+H2O.The equilibrium temperatures for these reactions which give rise to enstatite are: 650±10°C at 250 bars H2O pressure 690±10°C at 500 bars H2O pressure 715±10°C at 1000 bars H2O pressure 770±10°C at 2000 bars H2O pressureOnly after an increase in temperature to about 710°C at 500 bars and about 770°C at 1000 bars does hornblende in the system investigated here break down completely according to the reaction: hornblende = enstatite+anorthite+diopside+H2OExcept at very small H2O-pressures (see Fig. 3), there exists, therefore, a region within the orthopyroxene subfacies where hornblende, enstatite and anorthite coexist. As a result we have, as mentioned above, a lower-temperature and a higher-temperature part of the orthopyroxene subfacies, and it is only in the latter part that the parageneses correspond to the pyroxene-hornfels facies as stated by Eskola (1939).Summing up, the starting material consisting of chlorite, talc, tremolite plus quartz remains unchanged in the albite-epidote-hornfels facies; this gives rise in the hornblende-hornfels facies to the paragenesis hornblende+anthophyllite, or — at higher pressures — to hornblende+anthophyllite+anorthite. For the particular composition of the starting material, however, no reactions take place at the transition of the hornblende-hornfels facies to the orthoamphibole subfacies of the K-feldspar-cordierite-hornfels facies as this transition is typified by the breakdown of muscovite in the presence of quartz. However, at the end of the orthoamphibole subfacies the breakdown of anthophyllite, by which orthopyroxene is formed, heralds the onset of the orthopyroxene subfacies. In this subfacies — at greater than about 300 bars — hornblende is still present and coexists with enstatite and anorthite, but with rising temperature hornblende breaks down to give way to the paragenesis enstatite+anorthite+diopside. The experimentally determined parageneses confirm known petrographic occurrences.

Für die Förderung dieser Arbeit danken wir der Deutschen Forschungsgemeinschaft vielmals. Der Dank von Choudhuri gilt dem Akademischen Auslandsamt der Universität Göttingen für ein Stipendium, das ihm den Abschluß seiner Studien an der Universität Göttingen ermöglichte.  相似文献   

6.
Although the general criteria for recognition and environmental interpretation of different carbonate facies are well‐established, a predictive understanding of the areal extent and spatial patterning of facies bodies and why they might organize into facies belts or facies mosaics is poorly constrained. To explore patterns and process dynamics of facies on isolated carbonate platforms, quantitative analysis of thematic maps derived from remote sensing images of 27 Holocene atolls of the Paracel and Spratly chains in the South China Sea explores variability within and among platforms. On these systems, most annular shelf‐margin reefs are less than 500 m wide on both chains; inboard of the reefs, reef sand aprons range up to 500 m (Spratlys) and 1000 m (Paracels) wide. Around individual platforms, Spratly Chain sand apron widths are wider to the north‐west, whereas apron widths in the Paracel Chain are more symmetrical; collectively, data indicate log‐normal width‐exceedance probability distributions. Platform‐interior patch reefs include area‐exceedance probability distributions and gap size distributions (lacunarity) consistent within chains, but distinct between the chains. To understand the processes underlying distinct distributions, simulations explored distinct growth scenarios. Results suggest that differences may represent distinct process classes: proportional growth processes with multiplicative random effects (reef sand aprons – belts), versus non‐linear, size‐proportional growth of randomly aged and distributed elements (patch reefs – mosaics). The probabilistically distinct sizes and spatial patterns of geomorphic elements within these general process classes are interpreted to represent ‘variations on themes’ related to the different impacts of tropical storms, winter cold fronts and circulation in each chain. The results highlight fundamentally different growth patterns impacting the sizes and distribution of facies belts and mosaics on isolated carbonate platforms. Because these types of bodies ultimately construct stratigraphy, the themes could be applied to understand and predict variability in the architecture of subsurface reservoir analogues.  相似文献   

7.
According to the author's hypothesis (Korzhinskiy, 1937, 1940), rock metamorphism is caused by concentrated aqueous solutions saturated generally by CO2, so that partial pressures PH2O and PCO2 in both progressive and retrogressive metamorphism, are determined by temperature and depth. Consequently, diagrams can be drawn of parageneses of hydrous and carbonate minerals, as functions of T and p, as illustrated in Figure 4 for the system MgO-Si02-H20-CO2.

In the system Mg0-Si02-H20, two reactions without participation of water are possible, as demonstrated by comparing natural metamorphic and experimental mineral syntheses (Bowen and Tuttle, 1950): 1) anthophyllite =talc + enstatite, discussed by N. L. Bowen and 0. F. Tuttle (1950) and H. S. Yoder (1954). Under experimental conditions (PH2O=Ps, where Ps is the rock pressure), anthophyllite is unstable; it is stable under conditions of metamorphism (PH2O < Ps ), except for the deepest (wollastonite-free) facies (Korzhinskiy, 1945); 2) talc+ forsterite=enstatite+serpentine. The left side of this reaction is stable under experimental conditions (pH20=Ps ); the right side, under conditions of natural metamorphism (pH20<Ps; see Figure 2).

In the latter reaction all dehydration reactions proceed at temperatures lower than those of the experiment (Bowen and Tuttle, 1950). The upper critical point of the stability of anthophyllite is less than 500°C., which is the maximum temperature for the stability of serpentine, as follows from Figure 2.

In low-temperature metamorphism, all magnesium silicates are carbonatized (fig. 4), provided that the solutions' criculation is adequate. —Auth. English summ.  相似文献   

8.
Amorphous gels and oxides corresponding to Ca2Mg5Si8O23 in bulk composition have been reacted to phase assemblages containing tremolitic amphibole using routine hydrothermal methods in the pressure/temperature range from 1–22 kbar and 600–875° C. The products have been characterized by X-ray diffraction, optical microscopy and high-resolution electron microscopy. The nature of the amphibole microstructure and the types of intergrown biopyriboles vary markedly as a function of synthesis temperature and pressure, reflecting different amphibole growth mechanisms. At P(H2O)<10 kbar, within or very near the stability field of fale, amphibole forms by topotactic reaction from this metastably crystallized, intermediate phase; chain multiplicity faults (CMFs) with m3 are numerous; the bulk compositional shift in the disordered amphibole crystals is compensated in the run product by coexisting diopside. At P(H2O)10 kbar, but still in the talc stability field, amphibole grows topotactically from and also nucleates preferentially on metastable diopside by a dissolution/regrowth process; the two phases form fine ( 100 Å) lamellar intergrowths with almost no CMFs with m3, and the compositional shift induced by armoured diopside relics is compensated by discrete talc. The same lamellar amphibole/diopside microstructure is observed at temperatures above the talc stability field and at all pressures investigated, but the compositional shift is compensated by enstatite+quartz. Varying the experimental parameters (run duration; H2O content) does not significantly affect the above observations. For the wide range of pressures and temperatures investigated, the synthetic amphiboles of the present study appear to correspond very closely to end-member tremolite. The observed product assemblages and apparent compositional shifts of the amphibole, equivalent in Ca/Mg ratio to as much as 11 mol% magnesiocummingtonite component, can be explained by the incorporation of CMFs in this phase. We argue that CMF-induced shifts in Ca/Mg ratios also play a significant role for the 10 mol% magnesiocummingtonite component commonly assumed in analogous experiments in the present literature. The genuine magnesiocummingtonite solid-solution component may be much less than 10 mol%. Empirical high-resolution transmission electron microscopy observations of preferential corrosion structures at crystal terminations suggest that, to a first approximation, structurally disordered tremolites exhibit the reaction behaviour of mechanical mixtures down to the unit-cell scale. The thermodynamic properties of synthetic tremolite, even in small intergrown lamellae within disordered crystals, should therefore closely approach those of discrete, ideal tremolite single crystals, in accord with the converging agreement shown by recent comparative experimental studies on the phase relationships of natural and synthetic tremolite.  相似文献   

9.
Talc specimens heated to 700–1450° C were examined with an analytical high-resolution transmission electron microscope. Neither the amphibole-like structure nor the MPP structure (M = mica, P = pyroxene-layer), proposed by Avgustinik and Vigdergauz (1948) and Sueno et al. (1980), was found. On the contrary, a disordered pyribole structure was observed. This pyribole showed a structure disordered in terms of chain widths, with single and double chains predominant. A local MPP structure with 4–6 repeated units of (21) sequence was generally observed in a disordered region. The electron diffraction data were consistent with maximum symmetry A2/m for the proto-MPP structure. A HRTEM study of the fine structures associated with the depolymerization of talc was the basis of a structural model proposed for the depolymerization of biopyriboles. In this model, a pair of (010) faults with a displacement of 1/2 (a+c) took an important role. The acceptor and donor regions model was also discussed.  相似文献   

10.
Ultramafic rocks in contact to gneisses in the Mt. Hochwart HP mélange (Eastern Italian Alps) preserve a series of metasomatic mineral zones. A phlogopitite with minor tremolite and accessory zircon and apatite forms close to the gneiss (Zone 1). Zone 2 consists of tremolite, phlogopite and anthophyllite followed by Zone 3 with anthophyllite plus minor chlorite and talc. Zone 3 grades into an amphibole–garnet peridotite lens. This reaction zone has been generated by infiltration of hydrous fluids at T of 660–700 °C and P < 1.2 GPa, which occurred during exhumation of coupled continental crust and mantle peridotites.The reaction zone between a trace element-rich (gneiss) and a trace element depleted reservoir (peridotite) allows assessment of local trace element mobility in aqueous fluids. We present the results of in situ LA-ICP-MS trace element analysis of minerals from the reaction zone. Phlogopite is the main host for Large Ion Lithophile Elements (LILE) and contributes significantly to the Li, Ti, Nb, Ta, Pb and Sc budget. Anthophyllite is the main host for Li whereas all other trace elements including Rare Earth Elements (REE) are preferentially incorporated into tremolite. Combined with the abundance of these minerals over the contact zone, the mineral trace element data suggests that the LILE and REE were mobile on a small scale of a few centimetres only. Limited mobility of Ta, which is generally regarded as barely mobile in fluids, is documented in elevated contents of Ta in anthophyllite coupled with low Nb/Ta. The high Li content in minerals throughout the reaction zone suggests that Li was the most mobile element.The studied metasomatic zones mirror geochemical processes occurring in subduction zones at the slab–mantle interface. Phlogopite crystallization at the slab–mantle interface is an efficient mechanism to filter LILE from the aqueous fluid. Thus, such reaction zones, forming at temperatures < 660–700 °C, likely prevents that the typical slab signature with enriched LILE is transported by aqueous fluids over long distances in the mantle wedge. However, if coupled to the downgoing slab, phlogopite- and tremolite-rich rocks from such reaction zones might be able to act as carriers of trace elements and water into deeper parts of the subduction zone.  相似文献   

11.
 Transmission electron microscopy (TEM) results show there is a series of periodically and nonperiodically interstratified structures composed of berthierine and chlorite layers in low-temperature “chlorite” that is one of the alteration products of granulite-facies Archean ironstone from the eastern border of the Beartooth Mountains, Montana. An antiphase domain structure suggests that the interstratified structures are intermediate transformation products formed by reaction from berthierine (serpentine structure) to chlorite. Periodically interstratified structures consisting of chlorite (C) and serpentine-like (S) (or berthierine) layers include (CS), (CCS), (CCCS), (CCCCS), and (CCCCCCS). The layer sequences in interstratified chlorite-berthierine are indicative of the reaction mechanisms that produce the interstratified structures (e.g., crystallization from solution or solid-state transformation). The reaction from berthierine to chlorite is crystallographically much like a cell-preserved phase transformation, even though it is highly reconstructive. Berthierine can be considered a polymorph of the Fe-rich chlorite mineral chamosite, with berthierine as the los-temperature phase. Interstratification and integrowths in the chlorite-berthierine series may be common phenomena in low-temperature layer silicates resembling chlorite. Although such relations are difficult to recognize from chemical analyses or powder X-ray diffraction patterns, they can be observed readily with TEM method. Received: 25 April 1995/Accepted 5 April 1996  相似文献   

12.
Anthophyllite or another species of Mg‐amphibole commonly occurs in an intervening zone between the higher grade orthopyroxene zone and lower grade talc zone in progressively metamorphosed peridotites. However, the anthophyllite zone is absent in some of the thermally metamorphosed peridotite complexes in SW Japan despite the existence of the other zones. A comparative study presented here reveals similarities in rock composition and metamorphic pressure–temperature conditions at high‐grade zones between the metaperidotite complexes, and differences in the following respects. The metaperidotite complex that contains an anthophyllite zone has less abundant magnetite and olivine that is more homogeneous than the complex where the anthophyllite zone is absent. It is likely that the degree of cation diffusion in olivine crystals depends on duration of heat retention in metaperidotites during thermal metamorphism, which is supported by the variation in mineralogy of intrusive rocks and pelitic hornfelses surrounding the metaperidotites, and by calculations based on a simplified model of thermal conduction. The long duration of heat retention looks to be a necessary condition for the formation of anthophyllite crystals, which have a sluggish nucleation rate. In addition, the circulation of reducing fluids during prolonged metamorphism likely promoted the decomposition of magnetite and the growth of anthophyllite, into which iron is preferentially distributed. This study cautions about kinetic controls and redox conditions for anthophyllite formation in metaperidotites.  相似文献   

13.
The Synthesis and Stability of Anthophyllite   总被引：1，自引：1，他引：0  
The pure magnesium orthorhombic amphibole, anthophyllite, hasbeen synthesized and its upper and lower stability limits havebeen established by reversible hydrothermal experiments. Thesynthetic mineral has refractive indices nx=1?587?0?001, ny=1?602?0?005,nz=1?613?0?001, and unit-cell dimensions of a0=18?61?0?02 ?,b0=18?01?0?06 ?, c0=5?24?0?01 ?. The mineral is stable overa narrow temperature range in the presence of the phase H2O.At a PH2O of 1,000 bars the upper stability limit is 745??10?C and the lower stability limit is 667??8? C. Rate studies indicate that anthophyllite can nucleate at temperaturesabove its upper stability limit by disintegration of talc sheetsinto strips of double chains. The activation energy for thisprocess is 150?30 kcal mol–1. Application of the data to rocks of the Balmat area, New York,suggests that the equilibrium pressure of water during the metamorphismwas significantly less than the total pressure. The data indicatethat monomineralic zones of anthophyllite in ultramafic rocksare due to the presence of a steep gradient in the activityof H2O, or a steep gradient in temperature, or both, acrossthe zones.  相似文献   

14.
Along with eclogitized gabbro and gabbronorite bodies, boudinaged metaultramafites such as garnet-pyroxene rocks and orthopyroxenites were revealed in the Archean plagiogneiss strata of the Gridino complex. The garnet-pyroxene rock crope out as a boudin on Vysokii Island. The early stage of the rock evolution is documented by inclusions of diabantite (Fe-Si chlorite), a mineral that occurs in metasomatized peridotites. Diabantite was found in all rock-forming minerals in paragenesis with mineral phases enriched in REE (Ce, Nd, La, etc.), U, and Th. The confinement of ore phases to the inclusion rims and the development of two systems of cracks, radial and concentric, around the inclusions in pyroxenes point to the transformation of the inclusions after their trapping. Thermobarometric studies of the crystal cores revealed that the anhydrous paragenesis garnet + orthopyroxene + clinopyroxene, which replaced the chlorite-bearing rock, formed at ~690 ºC and ~17 kbar. The rims of the rock-forming minerals reflect isothermal decompression to ~12 kbar, which was followed by decompression cooling to ~650 ºC and ~9 kbar with the formation of regressive amphibole-garnet-pyroxene paragenesis. The giant-grained orthopyroxenites compose chains of boudinaged bodies on Izbnaya Luda Island. The orthopyroxene crystals host abundant amphibole, quartz, biotite, and pyrite inclusions pointing to amphibolite metamorphism at the early stage of the rock evolution. There are two types of amphibole: magnesian hornblende and anthophyllite. The hornblende is a primary mineral, whereas the low-temperature anthophyllite forming rims around the quartz inclusions was produced at the regressive stage of metamorphism. There are no indicators of the PT-conditions of the peak metamorphism in the orthopyroxenite. The reaction enstatite + quartz + H2O = anthophyllite allows deciphering water activity of anthophyllite formation, a ≤ 0.5.  相似文献   

15.
Kornerupine, (□,Fe,Mg)(Mg,Fe,Al)9(Si,Al,B)5 (O,OH,F)22, has been reported with talc in rocks from six localities worldwide, but only at Chilapila Hill in the Lufilian Arc, Zambia do textural relationships imply that kornerupine (Krn) equilibrated with talc (Tlc) during a prograde metamorphic event at T≈ 640 °C, P≈ 13 kbar; a prograde Krn + Tlc assemblage has also been reported from Mautia Hill, Tanzania (P ≤ 13 kbar). In order to estimate possible constraints on the stability range for the kornerupine + talc paragenesis in nature, we constructed a P-T diagram in the model system MgO-Al2O3-SiO2-H2O (MASH) for seven phases quartz (Qtz), B-free kornerupine sensu stricto, anthophyllite (Ath), chlorite (Chl), cordierite (Crd), kyanite (Ky), and talc. The minimum pressure for Krn + Tlc + Ky stability in MASH is close to that for Ky + Tlc stability, i.e., 6–8 kbar, at T≤ 780 °C. However, in the natural system, B2O3 and Na2O are major constituents in Krn and orthoamphibole (Oam), respectively, and dravitic tourmaline (Tur) is widespread. The critical assemblage alternative to Krn + Tlc in nature is Tur + Oam. The upper pressure limit of Tur + Ath is determined by the upper pressure for anthophyllite: 7.7–10.5 kbar at 682–794 °C in the MgO-SiO2-H2O system (Chernosky et al. 1985, Am Mineral 70:223–236), and is undoubtedly higher in the presence of Na2O, CaO, and Al2O3. At three of the six localities, talc is a retrograde phase; nonetheless, it possibly equilibrated with kornerupine on the retrograde path or during a later metamorphic event at P-T conditions appropriate for Ky + Tlc. At the sixth locality (Mulvoj, southwestern Pamir Mountains, Tajikistan), Krn is found in the same thin section as talc and kyanite and all three minerals formed during a prograde metamorphic event at T≥ 650 °C, P near 7 kbar. However, Krn is restricted to a lens 4 to 6 mm thick of phlogopite + anthophyllite + Tur and it does not touch either talc or kyanite. A reaction relating the Mulvoj and Chilapila Hill (Krn + Tlc + Ky + Qtz + Tur) parageneses is calculated from compositions in the Mulvoj rock to be 0.40Tur + 2.55Ath + 1.33H2O + 0.27F = Krn + 2.16Tlc + 0.36B2O3 + 0.02Rutile + 0.19Na2O + 0.17CaO. Given the difference in metamorphic pressures estimated for Mulvoj and Chilapila Hill, Krn + Tlc is inferred to be favored by increasing pressure as well as by low Na2O and CaO contents. Some FeO, F, Fe2O3, and BeO are present in measurable amounts in at least one of the phases in the Mulvoj and Chilapila Hill whiteschists (e.g., Krn contains 0.24–0.67 wt% BeO), but the effect of these constituents is subordinate to that of Na2O, CaO and B2O3. The Krn + Tlc could be a more important assemblage in B-bearing whiteschists than has been reported to date, particularly at pressures where orthoamphibole is no longer stable. Received: 21 April 1997 / Accepted: 13 October 1997  相似文献   

16.
Sodic amphiboles in high pressure and ultra-high pressure (UHP) metamorphic rocks are complex solid solutions in the system Na2O–MgO–Al2O3–SiO2–H2O (NMASH) whose compositions vary with pressure and temperature. We conducted piston-cylinder experiments at 20–30?kbar and 700–800?°C to investigate the stability and compositional variations of sodic amphiboles, based on the reaction glaucophane=2jadeite+talc, by using the starting assemblage of natural glaucophane, talc and quartz, with synthetic jadeite. A close approach to equilibrium was achieved by performing compositional reversals, by evaluating compositional changes with time, and by suppressing the formation of Na-phyllosilicates. STEM observations show that the abundance of wide-chain structures in the synthetic amphiboles is low. An important feature of sodic amphibole in the NMASH system is that the assemblage jadeite–talc?±?quartz does not fix its composition at glaucophane. This is because other amphibole species such as cummingtonite (Cm), nyböite (Nyb), Al–Na-cummingtonite (Al–Na-Cm) and sodium anthophyllite (Na-Anth) are also buffered via the model reactions: 3cummingtonite?+?4quartz?+?4H2O=7talc, nyböite?+?3quartz=3jadeite?+?talc, 3Al–Na-cummingtonite + 11quartz + 2H2O=6jadeite + 5talc, and 3 sodium anthophyllite?+?13quartz?+?4H2O=3 jadeite + 7talc. We observed that at all pressures and temperatures investigated, the compositions of newly grown amphiboles deviate significantly from stoichiometric glaucophane due to varying substitutions of AlIV for Si, Mg on the M(4) site, and Na on the A-site. The deviation can be described chiefly by two compositional vectors: [NaAAlIV]<=>[□ASi] (edenite) toward nyböite, and [Na(M4)AlVI]<=>[Mg(M4)MgVI] toward cummingtonite. The extent of nyböite and cummingtonite substitution increases with temperature and decreases with pressure in the experiments. Similar compositional variations occur in sodic amphiboles from UHP rocks. The experimentally calibrated compositional changes therefore may prove useful for thermobarometric applications.  相似文献   

17.
The Archean mafic–ultramafic complex of Lac des Iles, Ontario, Canada, hosts economic platinum group elements (PGE)-Au-Cu-Ni mineralization in the Roby Zone. All lithologies in the North Roby Zone have been affected by hydrothermal alteration. The alteration products include talc (the most dominant mineral), anthophyllite, serpentine, actinolite, tremolite, chlorite, hornblende, zoisite, clinozoisite, epidote and sericite. In the altered rocks, light rare earth elements (La, Ce, Nd, Sm), Pb, Rb, Ba, Cs, S and possibly Y have been added by hydrothermal solution whereas Eu and heavy rare earth elements (Yb, Gd, Dy, Er) remained immobile. There are five types of fluid inclusions in the pegmatitic plagioclase with homogenization temperature and salinity ranging from 240°C to 445°C and 15.37 to 48.52 wt% equivalent NaCl, respectively. The δ18O and δD of talc range form 6.2‰ to 6.9‰ and −28‰ to −48‰, respectively. δ18O and δD water in equilibrium with talc during the hydrothermal alteration suggest a modified source for the hydrothermal solution. Microthermometry and stable isotope studies suggest that high temperature–high salinity fluid was diluted by, and mixed with, low temperature–low salinity meteoric solution. This mechanism precipitated the hydrothermal assemblage and redistributed trace elements during and after pegmatite formation in the North Ruby Zone.  相似文献   

18.
The problem of deriving an optimal set of thermodynamic propertiesof minerals from a diverse experimental data base is reviewedand a preferred methodology proposed. Mathematical pro-gramming(MAP)methods extend the linear programming (LIP) approach first presentedby Gordon (1973), and make it possible to account for the typeof information conveyed, and the uncertainties attending bothphase equilibrium data and direct measurements of phase properties.For phase equilibrium data which are (in most cases) characterizedby non-normal error distributions across experimental brackets,the midpoint of a bracket is no more probable than other points,and the data are best treated by considering the inequalityin the change in Gibbs free energy of reaction at each half-bracket.Direct measurements of phase properties can be assumed to haveapproximately normal error distributions, and the MAP techniqueoptimizes agreement with these values by using the principlesof least squares in the definition of an objective function.The structure of this problem, treatment of uncertainties invarious types of experimental data, and method of optimizingfinal solutions are discussed in some detail.The method is appliedto experimental data in the MgO-SiO2-H2O system, where inconsistenciesamong the data are resolved and an optimal set of thermodynamicproperties is presented. The derived standard state entropiesand volumes agree with all direct measurements (within theiruncertainties), as do enthalpies of formation from the elementsexcept for those of talc (+16 kJ mol–1), anthophyllite(+ 14 kJ mol–1), and brucite (–1 kJ mol–1).Stable phase relations in the system have the topology predictedby Greenwood (1963, 1971), with quartz- and forsterite-absentinvariant points at 683 ?C-6-4 kb and 797 ?C-12 kb respectively,repeating at 552 ?C-120 b and 550 ?C-55 b. The thermodynamicanalysis indicates little remaining flexibility in the phaserelations, which, when combined with suitable activity modelsfor solid solution, should allow for accurate determinationof the conditions of metamorphism of ultramafic rocks.  相似文献   

19.
《Chemical Geology》2007,236(3-4):217-227
The association of arsenate, As(V), and arsenite, As(III), with disordered mackinawite, FeS, was studied in sulfide-limited (Fe:S = 1:1) and excess-sulfide (Fe:S = 1:2) batch experiments. In the absence of arsenic, the sulfide-limited experiments produce disordered mackinawite while the excess-sulfide experiments yield pyrite with trace amounts of mackinawite. With increasing initially added As(V) concentrations the transformation of FeS to mackinawite and pyrite is retarded. At S:As = 1:1 and 2:1, elemental sulfur and green rust are the end products. As(V) oxidizes S(-II) in FeS and (or) in solution to S(0), and Fe(II) in the solid phase to Fe(III). Increasing initially added As(III) concentrations inhibit the transformation of FeS to mackinawite and pyrite and no oxidation products of FeS or sulfide, other than pyrite, were observed. At low arsenic concentrations, sorption onto the FeS surface may be the reaction controlling the uptake of arsenic into the solid phase. Inhibition of iron(II) sulfide transformations due to arsenic sorption suggests that the sorption sites are crucial not only as sorption sites, but also in iron(II) sulfide transformation mechanisms.  相似文献   

20.
Based on field work, prospection and petrographic studies ultramafic complexes and their mineral deposits from eastern Minas Gerais in southeastern Brazil are generally outlined to form a basis for future investigations in this region. The bodies dealt with occur at Ipanema, Córrego Novo, Bela Vista de Minas, Rio Pomba and Liberdade. These ultramafic bodies are generally enclosed in high-grade gneisses and consist of serpentinized peridotites and harzburgites which were metamorphosed together with their country rocks in upper amphibolite to granulite facies. Weathering of these rocks gives rise to nickeliferous laterite, while metamorphism has resulted in anthophyllite asbestos and talc deposits.  相似文献   

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