Spectroscopic Studies on Astrophysically Interesting TaO TaS, ZrS and SiO+ Molecules     

R.R. Reddy  Y. Nazeer Ahammed  B. Sasikala Devi  K. Rama Gopal  P. Abdul Azeem  T.V.R. Rao 《Astrophysics and Space Science》2002,281(4):729-741

The true experimental potential energy curves for the electronic ground states of astrophysically important TaO, TaS, ZrS and SiO⁺molecules are constructed by using the Rydberg–Klein–Rees method as modified by Vanderslice et al. The ground state dissociation energies are determined by curve fitting techniques using the five parameters Hulburt-Hirschfelder (H-H) function. The estimated dissociation energies are 8.19 ± 0.17, 6.9 ±0.14, 5.89 ± 0.12 and 5.75 ± 0.12 eVfor TaO, TaS, ZrS and SiO⁺ respectively. These values are in good agreement with the literature values. The r-centriods and Franck–Condon factors (FC Factors) for the bands of K ² φ _5/2 - X ² Δ _3/2 (K-X) system of TaO, A-X ² Δ (A-X) and B-X ² Δ (B-X)systems of TaS, B ¹ Π - X¹ Σ⁺ (B-X) system of ZrS and B ²Σ⁺ - X² Σ⁺ (B-X) and A ² Π - X² Σ⁺ (A-X)systems of SiO⁺ molecules have been calculated. The Franck–Condon factors (FC factors) are evaluated by the approximate analytical methods of Jarmain and Fraser. The absence of the bands of these systems is explained. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Presence of LaO, ScO and VO Molecular Lines in Sunspot Umbral Spectra     

P. Sriramachandran  S. P. Bagare  N. Rajamanickam  K. Balachandrakumar 《Solar physics》2008,252(2):267-281

High-resolution Fourier Transform Spectrometer sunspot umbral spectra of the National Solar Observatory/National Optical Astronomy Observatory at Kitt Peak were used to detect rotational lines from 19 electronic transition bands of the molecules LaO, ScO and VO, in the wavenumber range of 11 775 to 20 600 cm⁻¹. The presence of lines from the following transitions is confirmed: A ² Π _r1/2 – X ² Σ ⁺(0, 0; 0, 1), A ² Π _r3/2 – X ² Σ ⁺(1, 0), B ² Σ ⁺ – X ² Σ ⁺(0, 0; 0, 1; 1, 0) and C ² Π _r1/2 – A′²Δ _r3/2(0, 0; 1, 1) of LaO; A ² Π _r3/2 – X ² Σ ⁺(0, 0), A ² Π _r1/2 – X ² Σ ⁺(0, 0) and B ² Σ ⁺ – X ² Σ ⁺(0, 0) of ScO; and C ⁴ Σ ⁻ – X ⁴ Σ ⁻(0, 1; 1, 0; 0, 2) and (2, 0) of VO. However, the presence of A ² Π _r3/2 – X ² Σ ⁺(0, 0) and C ² Π _r3/2 – A′²Δ _r5/2(0, 0; 1, 1) of LaO and C ⁴ Σ ⁻ – X ⁴ Σ ⁻(0, 0) of VO are found to be doubtful because the lines are very weak, and detections are difficult owing to heavy blending by strong rotational lines of other molecules. Equivalent widths are measured for well-resolved lines and, thereby, the effective rotational temperatures are estimated for the systems for which the presence is confirmed.  相似文献   

r-Centroids and Franck-Condon factors of the CP,SiC, and CO+ molecules     

R. R. Reddy  R. Viswanath  T. V. R. Rao 《Astrophysics and Space Science》1990,164(1):113-116

Ther-centroids and Franck-Condon factors for the bands of theA ² –X ²⁺ of CP,C ³ –X ³ of SiC, andB ²⁺ –X ²⁺ of CO⁺ molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained.  相似文献   

RKRV Potential Energy Curves, Dissociation Energies, γ-Centroids And Franck-Condon Factors Of YO, CrO, BN, ScO, SiO And AlO Molecules     

R.R. Reddy  Y. Nazeer Ahammed  K. Rama Gopal  P. Abdul Azeem  S. Anjaneyulu 《Astrophysics and Space Science》1998,262(2):223-240

The potential energy curves for the electronic ground states of astrophysically important YO, CrO, BN, ScO, SiO and AlO molecules are constructed techniques using the five-parameter Hulburt-Hirschfelder function. The estimated dissociation energies are 7.235±0.15, 4.337 ± 0.09, 3.917 ± 0.09, 6.899 ± 0.14, 8.181 ± 0.17 and 5.202 ± 0.11 eV for YO, CrO, BN, ScO, SiO and AlO, respectively. The estimated D₀ values are in reasonably good agreement with literature values. The r-Centroids and Franck-Condon factors for the bands of B^{2 +} – X^{2 +} of YO, B⁵ –X⁵ > of CrO, A³ – X³ of BN, B^{2 +} –X^{2 +} of ScO, E^{1 +} – X^{1 +} of SiO and D^{2 +} – X^{2 +} and B^{2 +} –X^{2 +} of AlO molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained.  相似文献   

Astrophysical Molecules AlD and CaH: Transition Probabilities and Dissociation Energy     

F. Partal Ureña  M. Fernández Gómez  J.J. López González  N. Rajamanickam 《Astrophysics and Space Science》2000,272(4):345-352

The Franck-Condon (FC) factors and r-centroids for the bands systemC ¹ Σ ⁺ → X ¹ Σ ⁺ of AlD and E ² Π → X ² Σ ⁺ of CaH have been evaluated by means of a reliable numerical integration procedure by using a suitable potential. The dissociation energy, D _e, for the electronic ground states of AlD and CaH have been estimated by the curve fitting method to the RKRV experimental potential curve turning out to be 3.01 eV and 2.32 eV, respectively. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Astrophysically Useful Parameters for Some Vibronic Transitions of AlH and BH     

B. Karthikeyan  V. Raja  N. Rajamanickam  S. P. Bagare 《Astrophysics and Space Science》2006,306(4):231-234

For molecular identification in astrophysical sources, an astrophysicist needs some spectroscopic parameters such as dissociation energy, vibrational or rotational temperature of the source, band or line wavelengths, transition probability parameters, etc. The Franck-Condon(FC) factors are proportional to the transition probabilities. In this study, the FC factors and r-centroids for the vibronic (vibration-electronic) transitions C ¹ Σ ⁺ → X ¹ Σ ⁺ of aluminium hydride (AlH), b ³ Σ ^{( −)} → a ³ Π, C ¹ Σ ⁺ → A ¹ Π & C ^′1 Δ → Δ ¹ Π of boron hydride (BH) have been evaluated and the results are presented in tables which include band origin/head wavelengths. The physical & astrophysical significances of our evaluated FC factors & r-centroids have been discussed and the possible presence of AlH in sunspot umbral spectra is also predicted. PACS: 33 · 70 · Ca  相似文献   

Franck-Condon factors and r-centroids for certain band systems pf astrophysical molecule BeF     

V. Raja  N. Rajamanickam 《Astrophysics and Space Science》2002,279(3):245-249

The Franck-Condon factors and r-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable numerical integration procedure for the bands of B ² Σ⁺ - X ² Σ⁺, C ²Σ⁺ - X ² Σ⁺ andC ² Σ⁺ - A ² Π_r systems of the astrophysical molecule BeF, using a suitable potential. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Astrophysically useful radiative transition parameters for?the?e¹Π–X¹Σ⁺ and ¹Σ⁺–X¹Σ⁺ systems of zirconium oxide     

R. Shanmugavel  P. Sriramachandran 《Astrophysics and Space Science》2011,332(2):257-262

The zirconium oxide (ZrO) is well known for its astrophysical importance. The radiative transition parameters that include Franck-Condon (FC) factor, r-centroid, electronic transition moments, Einstein coefficient, band oscillator strengths, radiative life time and effective vibrational temperature have been estimated for e ¹Π–X ¹Σ⁺ and ¹Σ⁺–X ¹Σ⁺ band systems of ⁹⁰ZrO molecule for the experimentally known vibrational levels using RKR potential energy curves. A reliable numerical integration method has been used to solve the radial Schr?dinger equation for the vibrational wave functions of upper and lower electronic states based on the latest available spectroscopic data and known wavelengths. The estimated radiative transition parameters are tabulated. The effective vibrational temperatures of these band systems of ⁹⁰ZrO molecule are found to be below 4200 K. Hence, the radiative transition parameters help us to ascertain the presence of ⁹⁰ZrO molecule in the interstellar medium, S stars and sunspots.  相似文献   

Identification of SrF molecular lines in the spectrum of sunspot umbra     

P. Sriramachandran  R. Shanmugavel  S. P. Bagare  N. Rajamanickam 《Astrophysics and Space Science》2009,323(1):41-49

A high resolution spectrum of a sunspot umbra is used for identification of rotational lines due to (0, 0) band of the A ²Π–X ²Σ⁺ system and (0, 0), (1, 1), and (2, 2) bands of the B ²Σ⁺–X ²Σ⁺ system of the molecule SrF. The published sunspot umbral spectrum obtained with Fourier Transform Spectrometer and solar telescope of National Solar Observatory/National Optical Astronomy Observatory at Kitt Peak was used for the study. The new identification of more than 200 SrF lines in the umbral spectrum confirms that this molecule accounts for the majority of lines in the spectral range 15050 to 15360 cm⁻¹ and 17240 to 17300 cm⁻¹. Equivalent widths have been measured for well-resolved lines of these bands and the effective rotational temperatures have been estimated for which the presence is confirmed.  相似文献   

Estimation of the dissociation energy of CO+ from spectroscopic data     

R. R. Reddy  R. Viswanath 《Journal of Astrophysics and Astronomy》1990,11(1):67-72

The potential energy curves for theX ² Σ⁺ andB ² Σ⁺ states of CO⁺ have been constructed by the Rydberg-Klein-Rees (RKR) method as modified by van der Sliceet al. The dissociation energy is estimated to be 7.70±0.19 eV by the method of curve fitting using the five parameter Hulburt-Hirschfelder’s function. The estimated value is in good agreement with the value (7.839 eV) given by Misraet al. Carefull observation of the results reveals that accurateD ₀ value for CO⁺ is 8.33 eV  相似文献   

Comet Hale–Bopp: Velocity Field Of Ions From Fabry-Pérot Imaging     

Bonev  T.  Jockers  K.  Credner  T. 《Earth, Moon, and Planets》1997,77(3):245-252

Fabry-Pérot interferograms of comet Hale-Bopp were obtained on several nights in March and April 1997. For this purpose we utilized the 2-channel focal reducer of the Max-Planck-Institute for Aeronomy at the 2-m telescope of the Pik Terskol Observatory. Solid Fabry-Pérot etalons of resolving power 30000 were used in both channels of the focal reducer. The main aim of this study is to measure the velocities and abundances of OH⁺ and H₂O⁺, both ions closely related to the same parent molecule, H₂O. In the blue channel interferograms we identified several individual OH⁺ rotational lines of the A³Π_i - X³Σ⁻ (0-0) transition and measured their Doppler shifts. The target emissions in the red channel were the H₂O⁺ lines of the A²A₁ − X²B₁ (10-0) band. We found that the line of sight velocities, obtained from the Doppler shifted wavelengths of emissions in the comet are higher in sunward direction than in the plasma tail and do not exceed 20 km s^–1. The corresponding values, deprojected in antisolar direction, are consistent with predictions by magnetohydrodynamical models of the solar-wind-comet interaction, when one accounts for the extremely high gas production rate of comet Hale-Bopp. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Potential energy curves and dissociation energies of NbO,SiC, CP,PH+, SiF+, and NH+     

R. R. Reddy  T. V. R. Rao  R. Viswanath 《Astrophysics and Space Science》1992,189(1):29-38

The potential energy curves for the electronic ground states of astrophysically important NbO, SiC, CP, PH⁺, SiF⁺, and NH⁺ molecules are constructed by the RKRV method. The dissociation energies are determined by curve-fitting techniques using the five-parameter Hulburt-Hirschfelder function. The estimated dissociation energies are 7.86±0.16, 3.66±0.09, 5.12±0.12, 3.08±0.09, 6.46±0.14, and 3.02±0.09 eV for NbO, SiC, CP, PH⁺, SiF⁺, and NH⁺, respectively. The estimatedD ₀ values are in reasonably good agreement with literature values. If we utilizeD ₀ values of PH⁺, SiF⁺, and NH⁺, ionization potentials for PH, SiF, and NH are derived. The ionization potentials are 10.12, 7.13, and 13.66 eV, respectively, for PH, SiF, and NH. Dissociation energies for the above molecules are also estimated by use of the Birge-Sponer extrapolation and Hildenbrand and Murad methods.  相似文献   

On So In Comets     

Krishna Swamy  K. S.  A'hearn  M. F. 《Earth, Moon, and Planets》1999,84(2):109-113

The solution of the statistical equilibrium equations for the SO molecule is used to estimate the expected intensities of microwave lines. The observed fluxes of the microwave lines of SO in Comet Hale–Bopp require approximately 1.8 10²⁸ mol/sec which give fluxes in the A³Π - X³Σ⁻bands below the observable limit, consistent with the observations. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Franck-Condon factors and <Emphasis Type="Italic">r</Emphasis>-centroids for certain band systems of astrophysical molecules SrF and ScF     

P.?Sri?Ramachandran  N.?Rajamanickam  S.?P.?Bagare  Bala?Chandra?KumarEmail author 《Astrophysics and Space Science》2005,295(4):443-449

The Franck-Condon factors and r-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable numerical integration procedure for the bands of B ²∑⁺ − X ²∑⁺, F ²∑⁺ − X ²∑⁺ systems of SrF and C ¹∑⁺ − X ¹∑⁺, G ¹Π − X ¹∑⁺ systems of ScF molecules of astrophysical interest, using a suitable potential.  相似文献   

On the effective temperature of large sunspot umbra using CrH sextets electronic state molecular lines     

P. Sriramachandran  R. Shanmugavel 《Astrophysics and Space Science》2011,336(2):379-389

A high-resolution spectrum clearly shows the presence of A ⁶Σ⁺–X ⁶Σ⁺(0,0;0,1;1,0;2,0;2,1) and (2,2) bands system of CrH molecular lines in the spectral range 10,000 cm⁻¹ to 14,050 cm⁻¹. At least 3928 lines of the six bands, accounting for 57% of the lines registered in the laboratory can be identified with certainty in the sunspot spectrum. Most of the lines are found blended with TiO, CaH, MgH and other atomic species. These molecular lines are typically much more temperature sensitive than atomic lines, which make them ideal, complementary tool for studying cool stellar atmospheres as well as the internal structure of sunspots. Equivalent width for an adequate number of well identified molecular lines of these bands using the Gaussian-profile approximation method versus rotational quantum number J has been used to determine the effective rotational temperature of the CrH molecule. The range of effective rotational temperature value obtained from these bands is 1766 K to 2442 K. This range agrees well with the effective rotational temperatures derived for other molecules in sunspot umbrae.  相似文献   

Optical Spectroscopy and Near-Infrared Observations of Comet C/2000 Wm1 (Linear) in December 2001 from Chile and Brazil     

Picazzio  Enos  De Almeida  Amaury A.  Churyumov  Klim I.  Andrievski  Sergei M.  Luk'yanyk  Igor V. 《Earth, Moon, and Planets》2002,90(1-4):391-400

We report on the preliminary analysis of the high-resolution spectrum of CometC/2000 WM1 (LINEAR), obtained on Dec. 1, 2001 with the Fiber fed ExtendedRange Optical Spectrograph (FEROS) installed on the 1.52-m telescope of ESO(Chile). Many emission lines of the molecules C₂, C₃, CN, CH, CH⁺,NH₂, CO, CO⁺, H₂O⁺ and, presumably, C₂ ^- were identifiedin the spectral range 400–900 nm. Also, near-infrared photometry was performed on Dec. 2 and 3, with the infraredcamera (CamIV) attached to the 0.60-m Boller and Chivens telescope of the Picodos Dias Observatory (LNA/MCT), Brazil. We report the preliminary and comparativeanalysis of the I-J and J-H color indices.  相似文献   

A Molecular Survey of Comet C/1995 O1 (Hale-Bopp) at the IRAM Telescopes     

Bockelée-Morvan  D.  Wink  J.  Despois  D.  Colom  P.  Biver  N.  Crovisier  J.  Gautier  D.  Gérard  E.  Lellouch  E.  Moreno  R.  Paubert  G.  Rauer  H.  Davies  J. K.  Dent  W. R. F. 《Earth, Moon, and Planets》1997,78(1-3):67-67

Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO₂, NH₂CHO and HCOOCH₃ in a comet. HDO was detected through its3₁₂–2₂₁ line at 225.897 GHz,complementing the observation of the 1₀₁–0₀₀ line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC₃N, HNCO, OCS, SO, CN, CO₊, HCO₊, in addition to more ‘classical’species CO, HCN, HNC, CH₃CN, CH₃OH, H₂CO, CS and H₂S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Optical Spectroscopy of Comet C/2000 WM1 (LINEAR) at the Guillermo Harro Astrophysical Observatory in Mexico     

Churyumov  Klim I.  Luk'yanyk  Igor V.  Berezhnoi  Alexei A.  Chavushyan  Vahram H.  Sandoval  Lourdes S.  Palma  Alejandro A. 《Earth, Moon, and Planets》2002,90(1-4):361-368

We present a preliminary analysis of medium resolution optical spectra of comet C/2000 WM1 (LINEAR) obtained on 22 November 2001. Theemission lines of the molecules C₂, C₃, CN, NH₂,H₂O⁺ and presumably CO (Asundi and triplet bands) and C₂ ^-were identified in these spectra. By analysing the brightnessdistributions of the C₂, C₃, CN emission lines along theslit of the spectrograph we determined some physical parameters of theseneutrals, such as their lifetimes and expansion velocities inthe coma. The Franck–Condon factors for the CO Asundi bands and C₂ ^- bands were calculated using a Morse potential model.  相似文献   

Chemistry in luminous AGN and starburst galaxies     

Susanne Aalto 《Astrophysics and Space Science》2008,313(1-3):273-278

Molecular line emission is a useful tool for probing the highly obscured inner kpc of starburst galaxies and buried AGNs. Molecular line ratios serve as diagnostic tools of the physical conditions of the gas—but also of its chemical properties. Both provide important clues to the type and evolutionary stage of the nuclear activity. While CO emission remains the main tracer for molecular distribution and dynamics, molecules such as HCN, HNC, HCO⁺, CN and HC₃N are useful for probing the properties of the denser (n≳10⁴ cm⁻³), star-forming gas. Here I discuss current views on how line emission from these species can be interpreted in luminous galaxies. HNC, HCO⁺ and CN are all species that can be associated both with photon dominated regions (PDRs) in starbursts—as well as X-ray dominated regions (XDRs) associated with AGN activity. HC₃N line emission may identify galaxies where the starburst is in the early stage of its evolution.  相似文献   

Molecular Clouds Toward a New OB Association in Pup-CMa     

J. May  A. L. Gyulbudaghian  H. Alvarez 《Astrophysics》2005,48(4):411-421

We have mapped 16 molecular clouds toward a new OB association in the Pup-CMa region to derive their physical properties. The observations were carried out in the ¹²CO (J = 1 – 0) line with the Southern millimetre-wave Telescope at Cerro Tololo, Chile. Distances have been determined kinematically using the rotation curve of Brand with R_⊙ = 8.5 kpc and V_⊙ = 220 km/s. Masses have been derived adopting a CO luminosity to H₂ conversion factor X = 3.8 . 10²⁰ molecules cm^-2 (K km/s)^-1. The observed mean radial velocity of the clouds is comparable with the mean radial velocity of stars composing an OB association in Pup-CMa; it is in favor of the close connection of clouds with these stars. __________ Published in Astrofizika, Vol. 48, No. 4, pp. 491–501 (October–December, 2005).  相似文献