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1.
长江口潮滩植物根际重金属的分布与累积 总被引：11，自引：0，他引：11
长江口滨岸潮滩芦苇与海三棱燕草根系、茎叶以及根际沉积物中Cu、Pb、Mn、Zn、Cr的含量分析发现，Cu、Pb、Zn、Cr在根系中的含量较高，而Mn在茎叶中的含量达到总量的55％以上。海三棱燕草比芦苇能更有效地累积重金属，两种植物根系。沉积物系统均表现出明显的重金属含量季节变化。植物体内重金属含量一般在冬季富集；芦苇根际沉积物中重金属的含量秋季较低，冬季富集，而海三棱蒲草根际沉积物中Cu、Pb、Mn均在秋季含量较高，Zn、Cr冬季含量最高。 相似文献
2.
泉州湾洛阳江河口桐花树和秋茄红树植物中重金属元素的分布与富集特征 总被引：2，自引：0，他引：2
通过测定泉州湾洛阳江河口红树林区表层沉积物中酸提重金属元素含量及桐花树、秋茄两种红树植物各部位中重金属元素含量,分析了重金属元素在两红树植物不同部位的分布特征及其富集和迁移能力,并初步探讨了两种红树植物体内各重金属元素的主要来源。红树林区各采样点表层沉积物中重金属元素酸提量顺序为:FeMnZnPbCuCrN iCo,Cu和Pb的平均酸提量超过第一类海洋沉积物质量标准限值。同种元素在两种红树植物不同部位中的含量顺序一致:Cu为根枝叶;N i为叶根枝;Fe、Mn、Cr、Zn、Pb、Co为根叶枝。两种红树植物对N i、Cr、Cu、Zn、Fe、Mn的富集能力高于Co和Pb。秋茄对Cu、N i、Mn、Fe、Co的富集能力比桐花树略强些,而对Zn、Cr、Pb的富集能力则相对弱些;但两种植物对各元素的富集能力都达不到超富集植物的要求。两种植物对N i元素的富集能力都大于其他元素,且都集中在叶部,其他元素则主要集中在根部。除N i外,其余元素在两植物体内的迁移系数均小于1。桐花树中的Cr和秋茄中的Cu、Zn、Mn主要来源于林地沉积物,其他元素在两植物各部位均有不同的来源。 相似文献
3.
TCLP法评价泉州市大气降尘重金属的生态环境风险 总被引：3，自引：0，他引：3
对泉州市不同功能区大气降尘中的重金属(Cu、Zn、Pb、Cd、Cr、As、Fe、Mn、Co、Ni、V)含量进行了分析测定,采用由美国环保署(USEPA)提出并被广泛推荐采用的TCLP法对泉州市不同功能区大气降尘中的重金属元素(Cu、Zn、Pb、Cd、Cr)的生态环境风险进行评价。以TCLP法提取的泉州市大气降尘重金属Cu、Cd、Zn、Pb、Cr、As、Fe、Mn、Co、Ni和V含量分别在2.592～63.20、0.084～2.978、9.276～3141、0.147～345.0、0.628～9.696、0.019-5.152、5.037-248.9、55.00-1261、0.040-63.56、0.735-37.43和0.020-24.07 mg/kg之间。根据TCLP法测定项目的法定阈值,泉州市大气降尘不同程度地受到Cu、Zn、Pb、Cd、Cr的污染,其中以Pb、Zn污染最为严重,其次为Cu、Cd、Cr。相关性分析结果显示,Fe、Mn、Ni、Cr、V的TCLP法提取量受样品pH值的显著影响;Pb、Cd、Mn、Co、Ni、As提取量除了受金属本身的总量影响外,还受到其它元素总量和TCLP提取量的影响。主成分分析结果表明,交通尾气尘、燃油尘、装饰材料尘、地面土壤尘、工业粉尘、建筑尘和燃煤烟尘等是泉州市大气降尘的主要来源,占总贡献率的86.01%。 相似文献
4.
基于南通近海(洋口港—吕四)潮滩特点布设潮滩断面并采集表层沉积物,根据样品汞、镉、铅、砷、铬等7种重金属元素含量测试结果,分析研究区沿海潮滩表层沉积物主要重金属元素含量特征,并与江苏其他滨岸地区潮滩沉积物的重金属含量进行对比,初步探讨2009—2012年南通沿海滩涂表层沉积物重金属含量变化与元素的相关性。采用潜在生态危害指数法评价南通近海潮滩表层沉积物中7种重金属元素的潜在生态危害系数及潜在生态风险。南通潮滩表层沉积物重金属含量分布均匀,且低于江苏省苏北其他地区沿海潮滩的沉积物含量。7种重金属元素的相关分析表明,Cu与Pb、Zn具有较好的相关性,Pb与Cd、Hg的相关性最差。潜在生态危害指数法评价表明,南通近岸潮滩表层沉积物7种重金属潜在生态危害系数均属低生态危害范畴,近岸海域(洋口港—吕四段)潮滩表层沉积物环境质量总体较好。 相似文献
5.
湘江是我国重金属污染最严重的河流之一。本次工作利用X射线荧光(XRF)和电感耦合等离子质谱(ICP-MS)分析技术,对湘江竹埠港沉积物进行主量和微量元素分析。结果表明沉积物主量元素含量变化相对稳定,富集Mn O、P2O5、Fe2O3、Al2O3,亏损Ca O、Na2O。微量元素含量变化较大,亏损Ba、Sc、Mn、Sr而富集其他微量元素。对主量元素和稀土元素进行了分析,表明沉积物物源主要是由上游花岗岩风化所提供。对沉积物进行因子分析和相关性分析,表明沉积物源主要以陆源碎屑为主,并有磷灰石和软锰矿等自生副矿物,Ni、Pb、Cu可能来自人为污染源。地累积指数表明Ba为清洁无污染,重金属V、Cr、Co、Ni、Th、U为轻度污染,重金属Cu、Pb、Zn为偏中度污染,Mn为中度污染,Sc为偏重度污染。其中重金属Cr、Ni、Cu、Pb、Zn、Mn、Sc污染应引起关注。 相似文献
6.
采集了长江南京八卦洲段悬浮物、漫滩柱状沉积物和表层沉积物样品,分析了Al、Fe、Mn、Hg、Ni、Cr、Cu、Pb、Cd、Co、Zn含量.结果表明,柱状沉积物元素含量垂向变化较小,反映沉积物来源比较稳定;表层沉积物微量元素含量因子分析反映元素主要受流域地质影响,Cd、Cu、Pb、Zn等元素还叠加人为活动的影响;悬浮物与长江中下游成矿带地质体的Pb同位素206Pb/207Pb比值非常接近,表明长江中下游成矿带来源悬浮物携带以Cd为代表的重金属对江苏沿江土壤重金属富集胚层起着重要的塑造作用. 相似文献
7.
非生物因子对底栖动物无齿相手蟹重金属富集量的影响 总被引：3，自引：0，他引：3
以长江口滨岸滩地生态系统一种常见的大型底栖动物无齿相手蟹(Sesarma dehaani)为研究对象,分析温度、盐度、重金属间相互作用等几个主要非生物因子对无齿相手蟹积累Cu,Zn,Pb,Cr,Ni的影响。结果表明,夏季无齿相手蟹对Cu,Zn,Cr,Ni的累积量高于其他季节,说明较高的温度有助于动物对重金属元素的吸收;秋季,无齿相手蟹体内的Pb含量与盐度显著负相关;春季,无齿相手蟹体内的Zn含量与盐度负相关;无齿相手蟹体内累积的Zn—Ni,Pb—Cr之间相关显著,二者均呈正相关。 相似文献
8.
泉州湾洛阳江河口潮间带沉积物中重金属来源分析 总被引：4，自引：0，他引：4
采用ICP-MS检测技术,对泉州湾洛阳江河口潮间带3个沉积柱中重金属Hg、V、Cr、Mn、Co、Ni、Cu、Zn、Cd、Pb、Fe的含量与垂向分布特征进行了分析,并结合因子分析、聚类分析和元素地球化学特征对柱中各重金属元素的来源进行了探讨。结果表明,泉州湾洛阳江潮间带柱状沉积物中主要受污染元素为Cu、Zn、Cd、Hg,以人类活动输入为主;V、Mn、Co、Ni、Fe主要受地球化学背景值影响,以自然来源为主。并利用V和Fe作为参考元素,将数据进行标准化,以目标元素和V对应Fe的变化趋势做了归一化分析并作散点图,得出的结论与因子分析和聚类分析的结果一致,说明该方法适用于区分沉积物重金属的自然来源和人为来源。 相似文献
9.
污水灌溉区包气带中重金属元素空间分布特征——以太原市某污水灌溉区为例 总被引：2，自引：0，他引：2
在距离灌渠不同距离的包气带中钻孔取样,测定了33个土壤样品中的pH值和Ba、Cr、Cu、Fe、Mn、Ni、Pb、Zn、土壤有机质的质量分数,对这8种重金属元素在土壤样品中的质量分数进行数据统计和空间分析。结果显示:①重金属元素Cr、Cu、Ni、Pb和Zn主要来源于污水,Fe、Mn和Ba除来源于污水外,还有一部分来源于土壤母质;②Cu、Cr、Pb、Zn和Ni的空间分布差异大,变异系数可达75.22%,主要富集表层0~0.3 m深度处和黏土层(黏土层起始深度在1.2~1.5 m,厚度40 cm)中,Fe、Mn和Ba在垂向上主要呈平均分布,空间分布的变异系数为19.09%~33.10%;③包气带中重金属元素平均含量超过当地土壤背景值的3~8倍,已经在包气带表层0~0.3 m深度处和黏土层中积累,而且Ba、Cu、Fe、Mn、Ni、Zn等重金属元素已经迁移到潜水层。 相似文献
10.
对北太平洋28个相对富集铁锰结核的沉积物和间隙水中重金属元素(Cu、Pb、Zn、Cr、Co、Ni)地球化学研究表明:沉积物中重金属元素明显的比陆地土壤、河口、陆架及贫结核洋区的沉积物富集,并与沉积物类型密切有关;沉积物中元素的赋存状态不同,进入间隙水的途径不同;由于Cu、Co的生物作用大于Zn、Ni,使沉积物中 Cu/Zn、Co/Ni比值由钙质软泥—钙、硅软泥—硅质软泥—褐色粘土升高。 相似文献
11.
Huan-Guang Deng Ju Zhang Dong-Qi Wang Zhen-Lou Chen Shi-Yuan Xu 《Environmental Earth Sciences》2010,60(1):57-63
Zn, Cu, Cr and Pb concentrations of the sediment collected from three tidal flat sites of Yangtze estuary were investigated
in October 2003. Results showed that the average concentrations of heavy metals in the sediments were two to three times to
the environment background values of Yangtze estuary tidal flat sediment. The heavy metal concentrations in the sediments
near the Bailonggang (BLG) and Laogang (LG) sewage outfalls were obviously higher than those of Chaoyang (CY) tidal flat where
there are no sewage outfalls near the coast. And the concentrations of heavy metals in the surface sediments of LG tidal flat
decreased with the increasing of the distance to the sewage outfalls. The heavy metal concentration profile in the sediment
core changed with the depth, and generally reached maximum values at the depth of plant roots. The assessment results showed
that the sediments of LG, BLG and CY tidal flat had been polluted by heavy metals in different level. The pollution degree
of heavy metals in the sediments was as follows: Zn > Cu > Pb > Cr. The potential ecological risks of the four heavy metals
in three tidal flat sites sediment were all at a middle level, and Cu and Pb made the main contributions. The adverse ecological
effects caused by the four heavy metals did not occur frequently. 相似文献
12.
Distribution and speciation of heavy metals in surface sediments from the Yangtze estuary and coastal areas 总被引：3，自引：2，他引：1
Xue Li Ying Wang Baohua Li Chenghong Feng Yaxin Chen Zhenyao Shen 《Environmental Earth Sciences》2013,69(5):1537-1547
The concentrations and speciation of heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) in the sediments of the nearshore area, river channel and coastal zones of the Yangtze estuary, China, were systematically investigated in this study. The concentrations of all heavy metals except Ni in the sediments of the nearshore area were higher than those of the river channel and coastal zones. In the nearshore area, the concentrations of most heavy metals except Hg in the sediments of the southern branch were higher than those of the northern branch because of the import of pollutants from the urban and industrial activities around. When compared with the threshold effect level (TEL) and geochemical background levels, Cr, Ni and As accumulated and posed potential adverse biological effects. The speciation analysis suggested that Cd, Pb and Zn in the sediments of the three zones showed higher bioavailability than the other heavy metals, and thus posed ecological risk. Significant correlations were observed among Cr, Cu, Ni and Zn (r > 0.77) in the nearshore area, Ni, Cu, Zn and Pb (r > 0.85) in the river channel and Ni, Cu, Cr, Pb and Zn (r > 0.75) in the coastal zone. Principal component analysis (PCA) indicated that the discharge of unban and industrial sewage, shipping pollution and the properties of the sediments (contents of Fe, Mn, Al, TOC, clay and silt) dominated the distribution of heavy metal in the nearshore area, river channel and coastal zones of the Yangtze estuary. 相似文献
13.
The island city of Bombay is surrounded by Thane creek in the east and Ulhas river on the north. These two aquatic regimes act as receptacles of industrial waste and sewage discharges from the city and also lithogenic fluxes from the adjacent basaltic terrain.
Two consecutive sets of pre-monsoon and post-monsoon samples of water, suspended solids and sediments were collected from the intertidal zone of Thane Creek and along the Ulhas River. These were analysed for toxic heavy metals such as Fe. Mn, Ni, Co, Pb, Zn, Cu, Cr, Hg and Cd and the degree of metal contamination was determined. Using this data the pattern and mechanism of distribution of heavy metals in water, suspended solids and sediments were investigated. These are closely related to discharges of industrial effluents and domestic sewage and largely controlled by basic geochemical processes. 相似文献
14.
15.
鸭绿江河口及近岸地区沉积物中重金属分布的影响因素分析 总被引：15，自引：1，他引：14
对鸭绿江河口不同地区沉积物中重金属分布特征和埋藏通量的垂向变化进行了分析;探讨了其独特的动力环境等因素对重金属分布的影响;评价了鸭绿江河口地区重金属污染状况及潜在生态风险程度.结果显示,自1920年代到2000年以来,除了Cu的含量和埋藏通量逐年减小之外,Cr、Ni、Zn、Cd、Pb、As和Hg的浓度和埋藏通量具有逐渐增加的趋势;鸭绿江河口地区重金属总体污染程度为重到严重,其中西水道沉积物的重金属总体污染程度和总潜在生态风险程度均最高,重金属污染已经对鸭绿江河口地区的生态环境构成了严重的危害;粒度控制效应不是鸭绿江河口地区重金属分布的最主要影响因素;Cu和其他几种重金属有着不同的来源;最大浑浊带独特的动力机制是造成中水道重金属(除Cu外)的高值分布区和最大浑浊带内的高悬沙浓度分布区相对应的最主要原因. 相似文献
16.
A recent history of metal accumulation in the sediments of the Thames Estuary, United Kingdom 总被引：4，自引：0，他引：4
Sediment cores were collected from the Tilbury Tidal Basin in the Thames Estuary to determine the depositional history of metals in the estuary. Profiles of metals in sediments deposited in the lower Thames Estuary show a 30–50% decrease in concentration for Ag, Cd, Cu, Pb, and Zn, and a 70% decrease for Hg in recent decades. Historic depth soundings data showed the decreases in metal concentrations occurred between 1944 and 1966. The decline in sediment metal concentrations has been attributed to reduced inputs to the estuary, following updating of the major sewage treatment works in 1959 and 1963. This is indicated by the through-core distribution of Mn which implies that prior to 1960 the sediments were deposited in anoxic conditions, which subsequently improved. An increase in Mn concentrations observed in one of the cores has been attributed to increases in the dissolved oxygen of the estuarine waters resulting from the increased efficiency of the sewage treatment works. 相似文献
17.
S. Venkatramanan T. Ramkumar I. Anithamary S. Vasudevan 《Arabian Journal of Geosciences》2014,7(1):123-130
Surface sediments collected at the Tirumalairajan river estuary and their surrounding coastal areas were analyzed for the bulk metal concentration. The sediments were collected from post- and premonsoon seasons. Dominances of heavy metals are in the following order: Fe > Mn > Zn > Pb > Cu in both seasons from estuary and coastal area. The results reveal that Fe, Mn, Cu, Pb, and Zn demonstrated an increased pattern from the estuary when compared to the coastal area. The heavy metal pattern of the sediments of the Tirumalairajan river estuary and its surrounding coastal area offered strong evidence that the coastal area was a major source of heavy metals to the estuarine region. For various metals, the contamination factor and geoaccumulation index (I geo) have been calculated to assess the degree of pollution in sediments. The contamination factor and geoaccumulation index show that Zn, Pb, and Cu unpolluted to moderately pollute the sediments in estuarine part. This study shows the major sources of metal contamination in catchment and anthropogenic ones, such as agriculture runoff, discharge of industrial wastewater, and municipal sewage through the estuary and adjoining coastal area. 相似文献
18.
鸭绿江河口西岸潮间带柱状沉积物中重金属的分布特征及其对流域变化的响应 总被引：1，自引：0，他引：1
2010年和2011年在鸭绿江西水道和西岸潮间带共采集4根柱状样,通过对2mPb测年、粒度、总有机碳、重金属元素等多指标综合分析,探讨了：（1）鸭绿江河口西水道和西岸潮间带柱状沉积物中重金属的垂向分布及其来源：（2）重金属分布的粒度控制作用：（3）不同时期的粒度和重金属分布变化及其对流域变化的响应。结果表明：f1）Cu和zn可能来源于有机质降解的内源释放：Cr和Ni表征了岩石风化剥蚀形成陆源碎屑的自然来源：Cd和Pb反映了人类活动的影响。（2）除西岸潮间带的Cd和Pb含量可能部分受来源影响外,研究区的粒度效应是控制鸭绿江地区重金属含量分布的最主要因素。（3）粒度变化与流域演变密切相关,重金属含量对流域变化和人类活动响应明显,大致以1940年、1970年、1995年为界分为四个沉积阶段：1940年以前,自然演变对鸭绿江河口西岸潮间带的重金属分布控制明显,而1940年来至今,人类活动的控制作用日益凸显。 相似文献
19.
Spatial and depth-wise distribution of sediment components, organic carbon and selected metals (Fe, Mn, Al, Ni, Cr, Co, Zn and Pb) is studied across upper and middle tidal flats from lower and middle estuarine regions of Kundalika Estuary, central west coast of India. Silt and clay form the major components in lower and middle estuary, respectively. Sand, silt, clay and organic carbon showed band-type distribution along the estuary. The sediment deposition over the years took place in varying hydrodynamic conditions in lower and middle estuarine regions. Upper flats of the lower estuary represent mud while middle flats of the lower estuary facilitated the deposition of sandy mud. Correlation results indicated the importance of clay and organic carbon in removal and trapping of metals at lower and middle estuary, respectively. Factor analysis indicated that the distribution of metals is largely controlled by Fe–Mn oxyhydroxides and organic carbon. The middle flats of the lower estuary showed an anthropogenic source for Ni, Cr and Co while middle flats of the middle estuary showed a mainly lithogenic source. 相似文献
20.
选择太仓市郊区河流沉积物为研究对象,开展了重金属污染现状及评价研究。研究表明,相对于地壳或页岩平均值,沉积物中大部分重金属呈现不同程度的富集;地质累积指数和富集因子分析表明,位于城镇附近的采样点受到污染,且主要污染因子为Cr、Cu、Cd、Pb、Zn等。结果显示,沉积物Zn含量高达1770mg／kg,是农用污泥Zn使用容许最高值500mg／kg的3倍多,沉积物由于Zn、Cr、Cu等的严重污染不能用作施用污泥;利用重金属与Fe之间的相关特征结果显示,城镇工业、生活污水的排放是沉积物重金属污染的主要因素。 相似文献