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1.
The potential for in situ biodegradation of tert‐butyl alcohol (TBA) by creation of aerobic conditions in the subsurface with recirculating well pairs was investigated in two field studies conducted at Vandenberg Air Force Base. In the first experiment, a single recirculating well pair with bromide tracer and oxygen amendment successfully delivered oxygen to the subsurface for 42 d. TBA concentrations were reduced from approximately 500 μg/L to below the detection limit within the treatment zone and the treated water was detected in a monitoring transect several meters downgradient. In the second experiment, a site‐calibrated model was used to design a double recirculating well pair with oxygen amendment, which successfully delivered oxygen to the subsurface for 291 d and also decreased TBA concentrations to below the detection limit. Methylibium petroleiphilum strain PM1, a known TBA‐degrading bacterium, was detectable at the study site but addition of oxygen had little impact on the already low baseline population densities, suggesting that there was not enough carbon within the groundwater plume to support significant new growth in the PM1 population. Given favorable hydrogeologic and geochemical conditions, the use of recirculating well pairs to introduce dissolved oxygen into the subsurface is a viable method to stimulate in situ biodegradation of TBA or other aerobically degradable aquifer contaminants.  相似文献   

2.
This study tests the feasibility of an aquifer remediation concept proposed by Gvirtzman and Gorelick (1992) that involves the removal of volatile organic compounds (VOCs) dissolved in ground water. The principal is 10 inject air into a well, creating airlift pumping, which is used as a means of in-well vapor stripping. The partially treated water is diverted away from the well and infiltrates back to the water table, thus allowing remediation of a larger aquifer volume.
A remediation well prototype, constructed in a laboratory aquifer model, was used to demonstrate the processes involved. The removal rates of trichloroethylene, toluene, and chloroform were monitored using eight triple-level observation wells. The continuous decrease of VOC concentrations during the short-term experiment has yielded macroscopic evidence that the process offers some promise. It was found that the flow field in the saturated zone. involving the continuous water circulation between the pumping well and the recharging area, caused temporal and spatial variation in remediation efficiency.  相似文献   

3.
This paper presents analytical solutions for determining non-steady-state capture zones produced by a single recovery well and steady-state capture zones produced by multiple recovery wells. Analysis of non-steady-slate capture zones is based on the lime-dependent location of caplure zone stagnation points and the geometric similarity between steady-slate and non-steady-state capture zones. The analytical solution of steady-state capture zones is obtained from spatial variations of discharge potential across the capture zone boundary. Both capture zone analyses are based on the assumptions of uniform flow field with a constant hydraulic conductivity, the Dupuit assumption of insignificant vertical flow, a negligible delayed yield, and a fully penetrating well with a constant pumping rate. For a ground water pump-and-trcat remediation program, the pumping rate and well location design variables can be adjusted to ensure containment of the ground water contaminant plume.  相似文献   

4.
Modeling effects of multinode wells on solute transport   总被引:1,自引:0,他引:1  
Long-screen wells or long open boreholes with intraborehole flow potentially provide pathways for contaminants to move from one location to another in a ground water flow system. Such wells also can perturb a flow field so that the well will not provide water samples that are representative of ground water quality a short distance away from the well. A methodology is presented to accurately and efficiently simulate solute transport in ground water systems that include wells longer than the grid spacing used in a simulation model of the system and hence are connected to multiple nodes of the grid. The methods are implemented in a MODFLOW-compatible solute-transport model and use MODFLOW's Multi-Node Well Package but are generic and can be readily implemented in other solute-transport models. For nonpumping multinode wells (used to simulate open boreholes or observation wells, for example) and for low-rate pumping wells (in which the flow between the well and the ground water system is not unidirectional), a simple routing and local mixing model was developed to calculate nodal concentrations within the borehole. For high-rate pumping multinode wells (either withdrawal or injection, in which flow between the well and the ground water system is in the same direction at all well nodes), complete and instantaneous mixing in the wellbore of all inflows is assumed.  相似文献   

5.
In Situ Biorestoration as a Ground Water Remediation Technique   总被引:1,自引:0,他引:1  
In situ biorestoration, where applicable, is indicated as a potentially very cost-effective and environmentally acceptable remediation technology. Many contaminants in solution in ground water as well as vapors in the unsaturated zone can be completely degraded or transformed into new compounds by naturally occurring indigenous microbial populations. Undoubtedly, thousands of contamination events are remediated naturally before the contamination reaches a point of detection. The need is for methodology to determine when natural biorestoration is occurring, the stage the restoration process is in, whether enhancement of the process is possible or desirable, and what will happen if natural processes are allowed to run their course.
In addition to the nature of the contaminant, several environmental factors are known to influence the capacity of indigenous microbial populations to degrade contaminants. These factors include dissolved oxygen, pH, temperature, oxidation-reduction potential, availability of mineral nutrients, salinity, soil moisture, the concentration of specific pollutants, and the nutritional quality of dissolved organic carbon in the ground water.
Most enhanced in situ bioreclamation techniques available today are variations of hydrocarbon degradation procedures pioneered and patented by Raymond and coworkers at Suntech during the period 1974 to 1978. Nutrients and oxygen are introduced through injection wells and circulated through the contaminated zone by pumping one or more producing wells.
The limiting factor in remediation technology is getting the contaminated subsurface material to the treatment unit or units, or in the case of in situ processes, getting the treatment process to the contaminated material. The key to successful remediation is a thorough understanding of the hydrogeologic and geochemical characteristics of the contaminated area.  相似文献   

6.
7.
Recirculating wells are increasingly being used for ground water remediation and aquifer characterization investigations. Determination of flow rate is required for proper design and spacing of recirculation wells. The measurement of flow rate, however, can be difficult using standard equipment. To overcome some of the flow measurement problems associated with more common measurement systems, a new device in the form of a downhole weir was developed for recirculating wells that use a two-casing design. The weir was designed to measure flow rates between 10 and 40 gpm. In this flow range, the weir had an accuracy of ±2.8 gpm. This accuracy may be improved with some modifications.  相似文献   

8.
Contaminants have been threatening the Engelse Werk wellfield located between the town of Zwolle and the IJssel River in the Netherlands. Chemical analysis of water samples taken in production wells, both at the IJssel River and near the Zwolle railway station, indicated elevated concentrations of mainly organic contaminants including benzene, bentazon, acenaftene, trichloroethane, and bromacil. Immediate contaminant prevention and remediation measures are needed to safeguard the production wells. Ground water flow and transport models were developed to assist in the design of remediation strategies. Ground water flow models indicated that the IJssel River and a waste disposal ditch at the railway station are within the capture zone of the wellfield. A chloride transport model simulated minimum travel times in the order of four to 13 years for contaminants in the IJssel River to reach the production wells of the wellfield. A transport model for benzene was set up to advise on the remediation measures to be taken at the waste disposal ditch to clean up the contamination in the upper aquifer between this site and the Engelse Werk wellfield. The designed remediation system consists of 12 pumping wells with a combined capacity of 1650 m3/day. The system is capable of reducing the benzene levels at the threatened production wells at the Engelse Werk wellfield to a permissible level below 0.1 μg/L within a period of 5 years.  相似文献   

9.
Field Test of the In Situ Permeable Ground Water Flow Sensor   总被引:1,自引:0,他引:1  
Two in situ permeable flow sensors, recently developed at Sandia National Laboratories, were field tested at the Brazos River Hydrologic Field Site near College Station, Texas. The flow sensors use a thermal perturbation technique to quantify the magnitude and direction of ground water flow in three dimensions. Two aquifer pumping tests lasting eight and 13 days were used to field test the flow sensors. Components of ground water flow as determined from piezometer gradient measurements were compared with ground water flow components derived from the 3-D flow sensors. The changes in velocity magnitude and direction of ground water flow induced by the pump were evaluated using flow sensor data and piezometric analyses. Flow sensor performance closely matched piezometric analysis results. Ground water flow direction (azimuth), as measured by the flow sensors and derived in the piezometric analysis, predicted the position of the pumping well accurately. Ground water flow velocities measured by the flow sensors compared well to velocities derived in the piezometric analysis. A significant delay in flow sensor response to relatively rapid changes in ground water flow was observed. Preliminary tests indicate that the in situ permeable flow sensor provides accurate and timely information on the velocity magnitude and direction of ground water flow.  相似文献   

10.
Volatile organic compounds delected in ground water from wells at Test Area North (TAN) at the Idaho National Engineering Laboratory (INEL) prompted RCRA facility investigations in 1989 and 1990 and a CERCLA-driven RI/FS in 1992. In order to address ground water treatment feasibility, one of the main objectives, of the 1992 remedial investigation was to determine the vertical extent of ground water contamination, where the principle contaminant, of concern is trichloroethylene (TCE). It was hypothesized that a sedimentary interbed at depth in the fractured basalt aquifer could be inhibiting vertical migration of contaminants to lower aquifers. Due to the high cost of drilling and installation of ground water monitoring wells at this facility (greater than $100,000 per well), a real time method was proposed for obtaining and analyzing ground water samples during drilling to allow accurate placement of well screens in zones of predicted VOC contamination. This method utilized an inflatable pump packer pressure transducer system interfaced with a datalogger and PC at land surface. This arrangement allowed for real lime monitoring of hydraulic head above and below the packer to detect leakage around the packer during pumping and enabled collection of head data during pumping for estimating hydrologic properties. Analytical results were obtained in about an hour from an on-site mobile laboratory equipped with a gas chromalograplvmass spectrometer (GC/MS). With the hydrologic and analytical results in hand, a decision was made to either complete the well or continue drilling to the next test zone. In almost every case, analytical results of ground water samples taken from the newly installed wells closely replicated the water quality of ground water samples obtained through the pump packer system.  相似文献   

11.
地下水位变化引起的地面形变   总被引:2,自引:0,他引:2       下载免费PDF全文
本文探讨了抽用地下水对地面形变所造成的影响。文中应用了几个抽水试验实例, 说明了它们在时间上、空间上的相互变化关系。抽水所造成的地下水漏斗区范围内, 不仅能产生垂直形变, 而且在其影响的不同部位, 还形在压缩和拉伸的水平形变。对抽水引起的地面形变与其他因素所造成的地面形变的区别, 进行了视步的讨论。   相似文献   

12.
We characterize the hydraulics of an extraction-injection well pair in arbitrarily oriented regional flow by the recirculation ratio, area, and average residence time in the recirculation zone. Erratic regional flow conditions may compromise the performance of the reactor between a single well pair. We propose an alternative four-well system: two downgradient extraction and two upgradient injection wells creating an inner cell nested within an outer cell. The outer cell protects the inner cell from the influence of regional flow. Compared to a two-well system, the proposed four-well system has several advantages: (1) the recirculation ratio within the nested inner cell is less sensitive to the regional flow direction; (2) a transitional recirculation zone between the inner and outer cells can capture flow leakage from the inner cell, minimizing the release of untreated contaminants; and (3) the size of the recirculation zone and residence times can be better controlled within the inner cell by changing the pumping rates. The system is applied at the Field Research Center in Oak Ridge, Tennessee, where experiments on microbial in situ reduction of uranium (VI) are under way.  相似文献   

13.
A transient flow modeling analysis for potential public-supply wells on western Cape Cod, Massachusetts, demonstrates the difference between transient and steady-state recharge areas can have important implications for wellhead protection. An example of a single pumping well illustrates that commonly used steady-state time-related capture areas do not represent the recharge area and travel times of water being pumped from the well until sufficient time has elapsed for steady-state flow conditions to be established. Until that time, transient recharge areas are needed to account for the portion of water discharging from the well that entered the aquifer before pumping started. An example of two pumping wells demonstrates the same area at the water table cannot supply water to more than one well under steady-state flow conditions. Transient recharge areas to multiple wells can overlap, however, until steady-state flow conditions are established. The same area can, therefore, be a source of water to more than one well during early pumping times, and the water pumped from a given well may derive from source areas, including contaminated areas, that do not lie within the well's steady-state recharge area.  相似文献   

14.
Microencapsulation of degradative organisms enhances microorganism survivability (Stormo and Crawford 1994). The use of encapsulated cell microbeads for in situ biodegradation depends not only on microorganism survival but also on microbead transport characteristics. Two forced-gradient, recirculating-loop tracer experiments were conducted to evaluate the feasibility of encapsulated cell transport and bioremediation on the basis of polystyrene microsphere transport results. The tracer tests were conducted in a shallow, confined, unconsolidated, heterogeneous, sedimentary aquifer using bromide ion and 2 μm, 5 μn, and 15 μm microsphere tracers. Significant differences were observed in the transport of bromide solute and polystyrene microspheres. Microspheres reached peak concentrations in monitoring wells before bromide, which was thought to reflect the influence of aquifer heterogeneity. Greater decreases in microsphere C/Co ratios were observed with distance from the injection wells than in bromide C/Co ratios, which was attributed to particle filtration and/or settling. Several methods might be considered for introducing encapsulated cell microbeads into a subsurface environment, including direct injection into a contaminated aquifer zone, injection through a recirculating ground water flow system, or emplacement in a subsurface microbial curtain in advance of a plume. However, the in situ use of encapsulated cells in an aquifer is probably limited to aquifers containing sufficiently large pore spaces, allowing passage of at least some encapsulated cells. The use of encapsulated cells may also be limited by differences in solute and microbead transport patterns and flowpath clogging by larger encapsulated cell microbeads.  相似文献   

15.
The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.  相似文献   

16.
Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.  相似文献   

17.
Funnel-and-Gate Performance in a Moderately Heterogeneous Flow Domain   总被引:1,自引:0,他引:1  
The funnel-and-gate ground water remediation technology (Starr and Cherry 1994) has received increased attention and application as an in situ alternative to the typical pump-and-treat system. Understanding the effects of heterogeneity on system performance can mean the difference between a successful remediation project and one that fails to meet its cleanup goals.
In an attempt to characterize and quantify the effects of heterogeneity on funnel-and-gate system performance, a numerical modeling study of 15 simulated heterogeneous flow domains was conducted. Each realization was tested to determine if the predicted capture width met the capture width expected for a homogeneous flow domain with the same hulk properties. This study revealed that the capture width of the funnel-and-gate system varied significantly with the level of heterogeneity of the aquifer.
Two possible remedies were investigated for bringing systems with less than acceptable capture widths to acceptable levels of performance. First, it was determined that enlarging the funnel and gate via a factor of safety applied to the design capture width could compensate for the capture width variation in the heterogeneous flow domains. In addition, it was shown that the use of a pumping well downstream of the funnel and gate could compensate for the effects of aquifer heterogeneity on the funnel-and-gate capture width. However, if a pumping well is placed downstream of the funnel and gate to control the hydraulic gradient through the gate, consideration should be given to the gate residence time in relation to the geochemistry of the contaminant removal or destruction process in the gate.  相似文献   

18.
Langseth DE  Smyth AH  May J 《Ground water》2004,42(5):689-699
Predicting the future performance of horizontal wells under varying pumping conditions requires estimates of basic aquifer parameters, notably transmissivity and storativity. For vertical wells, there are well-established methods for estimating these parameters, typically based on either the recovery from induced head changes in a well or from the head response in observation wells to pumping in a test well. Comparable aquifer parameter estimation methods for horizontal wells have not been presented in the ground water literature. Formation parameter estimation methods based on measurements of pressure in horizontal wells have been presented in the petroleum industry literature, but these methods have limited applicability for ground water evaluation and are based on pressure measurements in only the horizontal well borehole, rather than in observation wells. This paper presents a simple and versatile method by which pumping test procedures developed for vertical wells can be applied to horizontal well pumping tests. The method presented here uses the principle of superposition to represent the horizontal well as a series of partially penetrating vertical wells. This concept is used to estimate a distance from an observation well at which a vertical well that has the same total pumping rate as the horizontal well will produce the same drawdown as the horizontal well. This equivalent distance may then be associated with an observation well for use in pumping test algorithms and type curves developed for vertical wells. The method is shown to produce good results for confined aquifers and unconfined aquifers in the absence of delayed yield response. For unconfined aquifers, the presence of delayed yield response increases the method error.  相似文献   

19.
A confined aquifer may become unconfined near the pumping wells when the water level falls below the confining unit in the case where the pumping rate is great and the excess hydraulic head over the top of the aquifer is small. Girinskii's potential function is applied to analyze the steady ground water flow induced by pumping wells with a constant-head boundary in a mixed confined-unconfined aquifer. The solution of the single-well problem is derived, and the critical radial distance at which the flow changes from confined to unconfined condition is obtained. Using image wells and the superposition method, an analytic solution is presented to study steady ground water flow induced by a group of pumping wells in an aquifer bounded by a river with constant head. A dimensionless function is introduced to determine whether a water table condition exists or not near the pumping wells. An example with three pumping wells is used to demonstrate the patterns of potentiometric surface and development of water table around the wells.  相似文献   

20.
Field experiments were conducted to evaluate the efficiency of iron-oxide-coated sand (ICS) and surfactant modified zeolite (SMZ) to remove viruses and bacteria from ground water. The reactive media were employed as filter packs of a pumping well that withdrew sewage effluent from a constructed wetland at a rate of 0.72 L/min. The contact time of the pumped water with the filter pack (10 cm thick) was about two minutes. Upgradient of the pumping well, the sewage effluent was spiked with MS-2 bacteriophage and E. coli. While the employed ICS filter pack failed to remove viruses and bacteria to a significant degree, the SMZ filter pack removed more than 99% of the viruses and 100% of E. coli from the ground water while fresh. In an additional field experiment using the same configuration but leaving the filter pack in place for more than five months, the SMZ filter pack was still removing 100% of E. coli , but failed to reduce virus numbers to a significant degree.  相似文献   

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