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1.
Roles of Melting and Metasomatism in the Formation of the Lithospheric Mantle beneath the Leizhou Peninsula, South China 总被引:2,自引:1,他引:1
YU JIN-HAI; O'REILLY SUZANNE Y.; ZHANG MING; GRIFFIN W. L.; XU XISHENG 《Journal of Petrology》2006,47(2):355-383
This study characterizes the nature of fluid interaction andmelting processes in the lithospheric mantle beneath the Yingfenglingand Tianyang volcanoes, Leizhou Peninsula, South China, usingin situ trace-element analyses of clinopyroxene, amphibole andgarnet from a suite of mantle-derived xenoliths. Clinopyroxenesfrom discrete spinel lherzolites exhibit large compositionalvariations ranging from extremely light rare earth element (LREE)-depletedto LREE-enriched. Trace-element modelling for depleted samplesindicates that the Leizhou lherzolites are the residues of amantle peridotite source after extraction of 111% meltgenerated by incremental melting in the spinel lherzolite fieldwith the degree of melting increasing upwards from about 60km to 30 km. This process is consistent with gradational meltingat different depths in an upwelling asthenospheric column thatsubsequently cooled to form the current lithospheric mantlein this region. The calculated melt production rate of thiscolumn could generate mafic crust 56 km thick, whichwould account for most of the present-day lower crust. The formationof the lithospheric column is inferred to be related to Mesozoiclithosphere thinning. Al-augite pyroxenites occur in compositexenoliths; these are geochemically similar to HIMU-type oceanisland basalt. These pyroxenites postdate the lithospheric columnformation and belong to two episodes of magmatism. Early magmatism(forming metapyroxenites) is inferred to have occurred duringthe opening of the South China Sea Basin (3215 Ma), whereasthe most recent magmatic episode (producing pyroxenites withigneous microstructures) occurred shortly before the eruptionof the host magmas (60·3 Ma). Trace-element traversesfrom the contacts of the Al-augite pyroxenite with the spinelperidotite wall-rock in composite xenoliths record gradientsin the strength and nature of metasomatic effects away fromthe contact, showing that equilibrium was not attained. Significantenrichment in highly incompatible elements close to the contacts,with only slight enrichment in Sr, LREE and Nb away from thecontact, is inferred to reflect the different diffusion ratesof specific trace elements. The observed geochemical gradientsin metasomatic zones show that Sr, La, Ce and Nb have the highestdiffusion rates, other REE are intermediate, and Zr, Hf andTi have the lowest diffusion rates. Lower diffusion rates observedfor Nb, Zr, Hf and Ti compared with REE may cause high fieldstrength element (HFSE) negative anomalies in metasomatizedperidotites. Therefore, metasomatized lherzolites with HFSEnegative anomalies do not necessarily require a carbonatiticmetasomatizing agent. KEY WORDS: China; lithosphere; mantle xenoliths; clinopyroxene trace elements; mantle partial melting; mantle metasomatism; trace-element diffusion rates 相似文献
2.
The upper mantle under La Palma,Canary Islands: formation of Si−K−Na-rich melt and its importance as a metasomatic agent 总被引:3,自引:1,他引:3
E. Wulff-Pedersen Else-Ragnhild Neumann B. B. Jensen 《Contributions to Mineralogy and Petrology》1996,125(2-3):113-139
Mantle xenoliths hosted by the Historic Volcan de San Antonio, La Palma, Canary Islands, fall into two main group. Group I consists of spinel harzburgites, rare spinel lherzolites and spinel dunites, whereas group II comprises spinel wehrlites, amphibole wehrlites, and amphibole clinopyroxenites. We here present data on group I xenoliths,
including veined harzburgites and dunites which provide an excellent basis for detailed studies of metasomatic processes.
The spinel harzburgite and lherzolite xenoliths have modal ol−opx−cpx ratios and mineral and whole rock major element chemistry
similar to those found in Lanzarote and Hierro, and are interpreted as highly refractory, old oceanic lithospheric mantle.
Spinel dunites are interpreted as old oceanic peridotite which has been relatively enriched in olivine and clinopyroxene (and
highly incompatible elements) through reactions with basaltic Canarian magmas, with relatively high melt/peridotite ratio.
Group I xenoliths from La Palma differ from the Hierro and Lanzarote ones by a frequent presence of minor amounts of phlogopite (and
amphibole). Metasomatic processes are also reflected in a marked enrichment of strongly incompatible relative to moderately
incompatible trace elements, and in a tendency for Fe−Ti enrichment along grain boundaries in some samples. The veins in the
veined xenoliths show a gradual change in phase assemblage and composition of each phase, from Fe−Ti-rich amphibole+augite+Fe−Ti-oxides+apatite+basaltic
glass, to Ti-poor phlogopite+Cr-diopside±chromite+ Si−Na−K-rich glass+fluid. Complex reaction zones between veins and peridotite
include formation of clinopyroxene±olivine+glass at the expense of orthopyroxene in harzburgite, and clinopyroxene+spinel±amphibole±glass
at the expense of olivine in dunite. The dramatic change in glass composition from the broadest to the narrowest veins includes
increasing SiO2 from 44 to 67 wt%, decreasing TiO2/Al2O3 ratio from >0.24 to about 0.02, and increasing K2O and Na2O from 1.8 to >7.0 wt% and 3.8 to 6.7 wt%, respectively. The petrographic observations supported by petrographic mixing calculations
indicate that the most silicic melts in the veined xenoliths formed as the result of reaction between infiltrating basaltic
melt and peridotite wall-rock. The highly silicic, alkaline melt may represent an important metasomatic agent. Pervasive metasomatism
by highly silicic melts (and possibly fluids unmixed from these) may account for the enriched trace element patterns and frequent
presence of phlogopite in the upper mantle under La Palma.
Received: 15 January 1996 / Accepted 30 May 1996 相似文献
3.
Features of the Early Palaeozoic Mantle beneath Langao County and Its Formation Mechanism 总被引:1,自引:0,他引:1
XU Xueyi HUANG Yuehu XIA Linqi XIA ZuchunXi ''an Institute of Geology Mineral Resources Chinese Academy ofGeological Sciences Youyi Ro Xi''an Zhou Jian Fei Zhenbi 《《地质学报》英文版》1999,73(3):356-365
Phlogopite-amphibole pyroxenite xenoliths contained in an Early Palaeozoic alkali subvolcanic lam-prophyre complex in Langao County, Shaanxi Province, are metasomatized mantle xenoliths, composed mainly of clinopyroxene, amphibole, phlogopite, apatite, pervoskite, ilmenite and sphene with well-developed subsolidus metamorphism-deformation textures, such as "triple points" and "cataclastic boundaries" . Minerological studies indicate that clinopyroxene is rich in SiO2 and MgO and poor in TiO2 and Al2O3, which is notably different from magmatogenic deep-seated megacrysts and phenocrysts formed in the range of mantle pressure. Amphibole and phlogopite have the compositional feature of mantle-derived amphibole and phlogopite. Sm-Nd isotope studies suggest that the metasomatized mantle beneath Langao County is the product of metasomatism of primitive mantle by melt (fluid) derived from the mantle plume, and the mantle metasomatism occurred 650 Ma ago. The process of mantle metasomatism changed from mantle me 相似文献
4.
E. Wulff-Pedersen E. -R. Neumann R. Vannucci P. Bottazzi L. Ottolini 《Contributions to Mineralogy and Petrology》1999,137(1-2):59-82
Mantle xenoliths hosted by the historic Volcan de San Antonio, La Palma, Canary Islands include veined spinel harzburgites
and spinel dunites. Glasses and associated minerals in the vein system of veined xenoliths show a gradual transition in composition
from broad veins to narrow veinlets. Broad veins contain alkali basaltic glass with semi-linear trace element patterns enriched
in strongly incompatible elements. As the veins become narrower, the SiO2-contents in glass increase (46 → 67 wt% SiO2 in harzburgite, 43 → 58 wt% in dunite) and the trace element patterns change gradually to concave patterns depleted in moderately
incompatible elements (e.g. HREE, Zr, Ti) relative to highly incompatible ones. The highest SiO2-contents (ca. 68% SiO2, low Ti-Fe-Mg-Ca-contents) and most extreme concave trace element patterns are exhibited by glass in unveined peridotite
xenoliths. Clinopyroxenes shift from LREE-enriched augites in basaltic glass, to REE-depleted Cr-diopside in highly silicic
glass. Estimates indicate that the most silicic glasses represent melts in, or near, equilibrium with their host peridotites.
The observed trace element changes are compatible with formation of the silicic melts by processes involving infiltration
of basaltic melts into mantle peridotite followed by reactions and crystallization. The Fe-Mg interdiffusion profiles in olivine
porphyroclasts adjacent to the veins indicate a minimum period of diffusion of 600 years, implying that the reaction processes
have taken place in situ in the upper mantle. The CaO-TiO2-La/Nd relationships of mantle rocks may be used to discriminate between metasomatism caused by carbonatitic and silicic melts.
Unveined mantle xenoliths from La Palma and Hierro (Canary Islands) show a wide range in La/Nd ratios with relatively constant,
low-CaO contents which is compatible with metasomatism of “normal” abyssal peridotite by silicic melts. Peridotite xenoliths
from Tenerife show somewhat higher CaO and TiO2 contents than those from the other islands and may have been affected by basaltic or carbonatitic melts. The observed trace
element signatures of ultramafic xenoliths from La Palma and other Canary Islands may be accounted for by addition of small
amounts (1–7%) of highly silicic melt to unmetasomatized peridotite. Also ultramafic xenoliths from other localities, e.g.
eastern Australia, show CaO-TiO2-La/Nd relationships compatible with metasomatism by silicic melts. These results suggest that silicic melts may represent
important metasomatic agents.
Received: 15 November 1998 / Accepted: 17 May 1999 相似文献
5.
Mechanisms and Sources of Mantle Metasomatism: Major and Trace Element Compositions of Peridotite Xenoliths from Spitsbergen in the Context of Numerical Modelling 总被引:11,自引:6,他引:11
IONOV DMITRI A.; BODINIER JEAN-LOUIS; MUKASA SAMUEL B.; ZANETTI ALBERTO 《Journal of Petrology》2002,43(12):2219-2259
Mineral and whole-rock chemical data for peridotite xenolithsin basaltic lavas on Spitsbergen are examined to reassess mechanismsof meltfluid interaction with peridotites and their relativerole versus melt composition in mantle metasomatism. The enrichmentpatterns in the xenoliths on primitive mantle-normalized diagramsrange from ThLaCe inflections inweakly metasomatized samples (normally without amphibole) toa continuous increase in abundances from Ho to Ce typical foramphibole-bearing xenoliths. Numerical modelling of interactionbetween depleted peridotites and enriched melts indicates thatthese patterns do not result from simple mixing of the two end-membersbut can be explained by chromatographic fractionation duringreactive porous melt flow, which produces a variety of enrichmentpatterns in a single event. Many metasomatized xenoliths havenegative high field strength element and Pb anomalies and Srspikes relative to rare earth elements of similar compatibility,and highly fractionated Nb/Ta and Zr/Hf. Although amphiboleprecipitation can produce NbTa anomalies, some of thesefeatures cannot be attributed to percolation-related fractionationalone and have to be a signature of the initial melt (possiblycarbonate rich). In general, chemical and mineralogical fingerprintsof a metasomatic medium are strongest near its source (e.g.a vein) whereas element patterns farther in the metasomaticcolumn are increasingly controlled by fractionationmechanisms. KEY WORDS: Spitsbergen; lithospheric mantle; metasomatism; trace elements; theoretical modelling 相似文献
6.
Thor H. Hansteen Andreas Klügel Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》1998,132(1):48-64
Gabbroic and ultramafic xenoliths and olivine and clinopyroxene phenocrysts in basaltic rocks from Gran Canaria, La Palma,
El Hierro, Lanzarote and La Gomera (Canary Islands) contain abundant CO2-dominated fluid inclusions. Inclusion densities are strikingly similar on a regional scale. Histogram maxima correspond to
one or more of the following pressures: (1) minimum 0.55 to 1.0 GPa (within the upper mantle); (2) between 0.2 and 0.4 GPa
(the Moho or the lower crust); (3) at about 0.1 GPa (upper crust). Fluid inclusions in several rocks show a bimodal density
distribution, the lower-density maximum comprising both texturally early and late inclusions. This is taken as evidence for
an incomplete resetting of inclusion densities, and simultaneous formation of young inclusions, at well-defined magma stagnation
levels. For Gran Canaria, pressure estimates for early inclusions in harzburgite and dunite xenoliths and olivine phenocrysts
in the host basanites overlap at 0.9 to 1.0 GPa, indicating that such magma reservoir depths coincide with levels of xenolith
entrainment into the magmas. Magma chamber pressures within the mantle, inferred to represent levels of mantle xenolith entrainment,
are 0.65–0.95 GPa for El Hierro, 0.60–0.68 GPa for La Palma, and 0.55–0.75 GPa for Lanzarote. The highest-density fluid inclusions
in many Canary Island mantle xenoliths have probably survived in-situ near-isobaric heating at the depth of xenolith entrainment.
Inclusion data from all islands indicate ponding of basaltic magmas at Moho or lower crustal depths, and possibly at an additional
higher level, strongly suggestive of two main crustal accumulation levels beneath each island. We emphasize that repeated
magmatic underplating of primitive magmas, and therefore intrusive accretion, are important growth mechanisms for the Canary
Islands, and by analogy, for other ocean islands. Comparable fluid inclusion data from primitive rocks in other tectonic settings,
including Iceland, Etna and continental rift systems (Hungary, South Norway), indicate that magma accumulation close to Moho
depths shortly before eruption is not, however, restricted to oceanic intraplate volcanoes. Lower crustal ponding and crystallization
prior to eruption may be the rule rather than the exception, independent of the tectonic setting.
Received: 30 May 1997 / Accepted: 6 February 1998 相似文献
7.
Several spinel peridotite xenoliths from Spitsbergen have SrNdisotopic compositions that plot to the right of the mantlearray defined by oceanic basalts and the DM end-member(depleted mantle, with low 87Sr/86Sr and high 143Nd/144Nd).These xenoliths also show strong fractionation of elements withsimilar compatibility (e.g. high La/Ce), which cannot be producedby simple mixing of light rare earth element-depleted peridotiteswith ocean island basalt-type or other enriched mantle melts.Numerical simulations of porous melt flow in spinel peridotitesapplied to SrNd isotope compositions indicate that thesefeatures of the Spitsbergen peridotites can be explained bychemical fractionation during metasomatism in the mantle. Chromatographiceffects of melt percolation create a transient zone where thehost depleted peridotites have experienced enrichment in Sr(with a radiogenic isotope composition) but not in Nd, thusproducing SrNd decoupling mainly controlled by partitioncoefficients and abundances of Sr and Nd in the melt and theperidotite. Therefore, SrNd isotope decoupling, earlierreported for some other mantle peridotites worldwide, may bea signature of metasomatic processes rather than a source-relatedcharacteristic, contrary to models that invoke mixing with hypotheticalSr-rich fluids derived from subducted oceanic lithosphere. Pbisotope compositions of the Spitsbergen xenoliths do not appearto be consistently affected by the metasomatism. KEY WORDS: Spitsbergen; lithospheric mantle; metasomatism; radiogenic isotopes; theoretical modelling 相似文献
8.
Ishimaru Satoko; Arai Shoji; Ishida Yoshito; Shirasaka Miki; Okrugin Victor M. 《Journal of Petrology》2007,48(2):395-433
9.
华北中、新生代岩石圈地幔的交代作用:含金云母地幔岩提供的证据 总被引:4,自引:3,他引:4
本文对华北克拉通三个不同地区(河北汉诺坝、内蒙古集宁三义堂、河南鹤壁)新发现的含金云母尖晶石二辉橄榄岩和尖晶石橄榄单斜辉石岩捕虏体进行了详细的矿物组成、单斜辉石的微量元素和 Sr-Nd 同位素研究。通过与相同地区不含金云母尖晶石二辉橄榄岩捕虏体的系统对比发现通常含金云母的地幔橄榄岩比不含金云母的地幔橄榄岩岩富 Al_2O_3、CaO、NaO、K_2O、TiO_2,但相对贫镁;其单斜辉石的 LREE 更为富集,但 Sr、Nd 同位素组成则相对亏损。这说明地幔交代作用不仅能够造成地幔橄榄岩的玄武质组分和稀土元素的富集,而且亦能够造成全岩和橄榄石 Mg~#的降低和同位素组成的相对亏损。捕虏体的 Rb-Sr 等时线年龄暗示地幔交代作用发生在中、新生代;其交代熔体来源于软流圈。同时说明华北新生代岩石圈地慢普遍存在的主、微量元素和同位素组成类似于"大洋型"岩石圈地幔的特征很可能是岩石圈地幔橄榄岩与软流圈来源的熔体的大规模反应的结果,而非真正意义上的新增生的岩石圈地幔。 相似文献
10.
BECCALUVA L.; BONADIMAN C.; COLTORTI M.; SALVINI L.; SIENA F. 《Journal of Petrology》2001,42(1):173-188
Mantle xenoliths included in the alkaline basic lavas from thePaleogene Veneto Volcanic Province (VVP) consist of predominantspinel lherzolites (216% clinopyroxene) and minor spinelharzburgites (42% clinopyroxene), mainly protogranulartextured. Most of the xenoliths show superimposed textural evidenceof metasomatic processes, consisting of reaction patches andspongy clinopyroxenes, variably associated with glass and secondaryolivine, clinopyroxene, spinel and feldspar. Whole-rock andmineral major and trace element data indicate a complex historyof depletion and enrichment processes undergone by the continentallithospheric mantle beneath a within-plate region. Protogranular-texturedclinopyroxenes from lherzolites show heavy rare earth element(HREE) contents 相似文献
11.
Constraints on the Trace Element Composition of the Archean Mantle Root beneath Somerset Island, Arctic Canada 总被引:1,自引:6,他引:1
Peridotites that sample Archean mantle roots are frequentlyincompatible trace element enriched despite their refractorymajor element compositions. To constrain the trace element budgetof the lithosphere beneath the Canadian craton, trace elementand rare earth element (REE) abundances were determined fora suite of garnet peridotites and garnet pyroxenites from theNikos kimberlite pipe on Somerset Island, Canadian Arctic, theirconstituent garnet and clinopyroxene, and the host kimberlite.These refractory mantle xenoliths are depleted in fusible majorelements, but enriched in incompatible trace elements, suchas large ion lithophile elements (LILE), Th, U and light rareearth elements (LREE). Mass balance calculations based on modalabundances of clinopyroxene and garnet and their respectiveREE contents yield discrepancies between calculated and analyzedREE contents for the Nikos bulk rocks that amount to LREE deficienciesof 7099%, suggesting the presence of small amounts ofinterstitial kimberlite liquid (0·42 wt %) toaccount for the excess LREE abundances. These results indicatethat the peridotites had in fact depleted or flat LREE patternsbefore contamination by their host kimberlite. LREE and Sr enrichmentin clinopyroxene and low Zr and Sr abundances in garnet in low-temperatureperidotites (8001100°C) compared with high-temperatureperidotites (12001400°C) suggest that the shallowlithosphere is geochemically distinct from the deep lithospherebeneath the northern margin of the Canadian craton. The Somersetmantle root appears to be characterized by a depth zonationthat may date from the time of its stabilization in the Archean. KEY WORDS: Canada; mantle; metasomatism; peridotite; trace elements 相似文献
12.
WITT-EICKSCHEN G.; SECK H. A.; MEZGER K.; EGGINS S. M.; ALTHERR R. 《Journal of Petrology》2003,44(6):1077-1095
The Pb isotope compositions of amphiboles and clinopyroxenesin spinel peridotite and pyroxenite mantle xenoliths from theintra-plate Quaternary volcanic fields of the Eifel province(Germany) are strongly correlated with their SrNd isotopeand trace element compositions. High-temperature anhydrous xenolithsfrom a depth of around 60 km have trace element and SrNdPbisotope compositions similar to the depleted source of mid-oceanridge basalts (Depleted MORB Mantle, DMM). Amphibole-bearingxenoliths from shallower depths (<45 km) provide evidencefor three temporally distinct episodes of mantle metasomatismin the subcontinental lithosphere: (1) aqueous fluids from anisotopically enriched (EM-like) mantle reservoir caused amphiboleformation during deformation in the shallow continental lithosphericmantle and may be subduction related, probably associated withthe last major tectonic event that influenced the area (Hercynianorogeny). (2) During a second phase of mantle metasomatism theEM-like lithospheric mantle was affected by melts from an ancient,HIMU-like (high time-integrated µ = 238U/204Pb) mantlesource. The HIMU-like component introduced by these fluids hada much more radiogenic Pb isotope composition than the asthenosphericsource of the widespread Cenozoic magmatism in Europe and maybe linked to reactivation of ancient subducted crustal domainsduring the Hercynian orogeny or to early Cretaceous deep-sourcedmantle plumes. (3) During a brief final stage the heterogeneouslyenriched EMHIMU subcontinental lithosphere was locallymodified by basaltic melts migrating along fractures and veinsthrough the upper mantle as a consequence of the Cenozoic Eifelvolcanism. Although a DMM component is completely lacking inthe metasomatic fluids of the metasomatic episodes 1 and 2,the vein melts of episode 3 and the Cenozoic Eifel lavas requiremantle sources containing three end-member components (DMMHIMUEM).Thus, mobilization of the more depleted mantle material occurredat the earliest in the Tertiary, contemporaneously with thedevelopment of the extensive rift system and main melt generationin Europe. Alternatively, the variety of SrNdPbisotope signatures of the metasomatic agents may have been producedby melting of isotopically distinct mantle domains in a heterogeneousuprising mantle plume. KEY WORDS: Eifel; Europe; mantle xenoliths; metasomatism; Pb isotopes 相似文献
13.
Gabbro xenoliths reported in this paper were collected in northern Fuerteventura, the Canary Island located closest to the
coast of Africa. The xenoliths are very fresh and consist of Ti–Al-poor clinopyroxene + plagioclase (An87–67) + olivine (Fo72–86) ± orthopyroxene. Clinopyroxene and orthopyroxene are constantly and markedly depleted in light rare earth elements (LREE)
relative to heavy REE (HREE), as expected for cumulus minerals formed from highly refractory N-MORB-type melts. In contrast,
whole-rock Primordial Mantle-normalized trace element patterns range from mildly S-shaped (mildly depleted in Pr–Sm relative
to both the strongly incompatible elements Rb–La and the HREE) to enriched. Estimates show that the trace element compositions
of the rocks and their minerals are compatible with formation as N-MORB gabbro cumulates, which have been infiltrated at various
extents (≤1% to >5%) by enriched alkali basaltic melts. The enriched material is mainly concentrated along grain boundaries
and cracks through mineral grains, suggesting that the infiltration is relatively recent, and is thus associated with the
Canary Islands magmatism. Our data contradict the hypothesis that a mantle plume was present in this area during the opening
of the Atlantic Ocean. No evidence of continental material that might reflect attenuated continental crust in the area has
been found. Gabbro xenoliths with REE and trace element compositions similar to those exhibited by the Fuerteventura gabbros
are also found among gabbro xenoliths from the islands of La Palma (western Canary Islands) and Lanzarote. The compositions
of the most depleted samples from these islands are closely similar, implying that there was no significant change in chemistry
during the early stages of formation of the Atlantic oceanic crust in this area. Strongly depleted gabbros similar to those
collected in Fuerteventura have also been retrieved in the MARK area along the central Mid-Atlantic Ridge. The presence of
N-MORB oceanic crust beneath Fuerteventura implies that the continent–ocean transition in the Canary Islands area must be
relatively sharp, in contrast to the situation both further north along the coast of Morocco, and along the Iberian peninsula. 相似文献
14.
Tertiary Ultrapotassic Volcanism in Serbia: Constraints on Petrogenesis and Mantle Source Characteristics 总被引:5,自引:1,他引:4
PRELEVIC D.; FOLEY S. F.; ROMER R. L.; CVETKOVIC V.; DOWNES H. 《Journal of Petrology》2005,46(7):1443-1487
The Serbian province of Tertiary ultrapotassic volcanism isrelated to a post-collisional tectonic regime that followedthe closure of the Tethyan Vardar Ocean by Late Cretaceous subductionbeneath the southern European continental margin. Rocks of thisprovince form two ultrapotassic groups; one with affinitiesto lamproites, which is concentrated mostly in the central partsof the Vardar ophiolitic suture zone, and the other with affinitiesto kamafugites, which crops out in volcanoes restricted to thewestern part of Serbia. The lamproitic group is characterizedby a wide range of 87Sr/86Sri (0·707350·71299)and 143Nd/144Ndi (0·512510·51216), whereasthe kamafugitic group is isotopically more homogeneous witha limited range of 87Sr/86Sri (0·705990·70674)and 143Nd/144Ndi (0·512630·51256). ThePb isotope compositions of both groups are very similar (206Pb/204Pb18·5818·83, 207Pb/204Pb 15·6215·70and 208Pb/204Pb 38·7438·99), falling withinthe pelagic sediment field and resembling Mesozoic flysch sedimentsfrom the Vardar suture zone. The Sr and Nd isotopic signaturesof the primitive lamproitic rocks correlate with rare earthelement fractionation and enrichment of most high field strengthelements (HFSE), and can be explained by melting of a heterogeneousmantle source consisting of metasomatic veins with phlogopite,clinopyroxene and F-apatite that are out of isotopic equilibriumwith the peridotite wall-rock. Decompression melting, with varyingcontributions from depleted peridotite and ultramafic veinsto the final melt, accounts for consistent HFSE enrichment andisotopic variations in the lamproitic group. Conversely, themost primitive kamafugitic rocks show relatively uniform Srand Nd isotopic compositions and trace element patterns, andsmall but regular variations of HFSE, indicating variable degreesof partial melting of a relatively homogeneously metasomatizedmantle source. Geochemical modelling supports a role for phlogopite,apatite and Ti-oxide in the source of the kamafugitic rocks.The presence of two contrasting ultrapotassic suites in a restrictedgeographical area is attributable to the complex geodynamicsituation involving recent collision of a number of microcontinentswith contrasting histories and metasomatic imprints in theirmantle lithosphere. The geochemistry of the Serbian ultrapotassicrocks suggests that the enrichment events that modified thesource of both lamproitic and kamafugitic groups were relatedto Mesozoic subduction events. The postcollisional environmentof the northern Balkan region with many extensional episodesis consistent at regional and local levels with the occurrenceof ultrapotassic rocks, providing a straightforward relationshipbetween geodynamics and volcanism. KEY WORDS: kamafugite; lamproite; Mediterranean; Serbia; mantle metasomatism; veined mantle; petrogenesis 相似文献
15.
NEUMANN E.-R.; WULFF-PEDERSEN E.; PEARSON N. J.; SPENCER E. A. 《Journal of Petrology》2002,43(5):825-857
Mantle xenoliths from Tenerife show evidence of metasomatismand recrystallization overprinting the effects of extensivepartial melting. The evidence includes: recrystallization ofexsolved orthopyroxene porphyroclasts highly depleted in incompatibletrace elements into incompatible-trace-element-enriched, poikiliticorthopyroxene with no visible exsolution lamellae; formationof olivine and REECr-rich, strongly ZrHfTi-depletedclinopyroxene at the expense of orthopyroxene; the presenceof phlogopite; whole-rock CaO/Al2O3 >> 1 (Ca metasomatism) inrecrystallized rocks; and enrichment in incompatible elementsin recrystallized rocks, relative to rocks showing little evidenceof recrystallization. The higher-than-normal degreeof partial melting that preceded the metasomatism probably resultsfrom plume activity during the opening of the Central AtlanticOcean. SrNd isotopic compositions are closely similarto those of Tenerife basalts, indicating resetting from theexpected original mid-ocean ridge basalt composition by themetasomatizing fluids. Metasomatism was caused by silicic carbonatitemelts, and involved open-system processes, such as trappingof elements compatible with newly formed acceptor minerals,leaving residual fluids moving to shallower levels. The compositionsof the metasomatizing fluids changed with time, probably asa result of changing compositions of the melts produced in theCanary Islands plume. Spinel dunites and wehrlites representrocks where all, or most, orthopyroxene has been consumed throughthe metasomatic reactions. KEY WORDS: Canary Islands; Tenerife; mantle xenoliths; geochemistry; Ca metasomatism; open-system processes; lithosphere; ocean islands 相似文献
16.
Volcanism in the Vitim Volcanic Field, Siberia: Geochemical Evidence for a Mantle Plume Beneath the Baikal Rift Zone 总被引:6,自引:1,他引:5
JOHNSON J. S.; GIBSON S. A.; THOMPSON R. N.; NOWELL G. M. 《Journal of Petrology》2005,46(7):1309-1344
The Baikal Rift is a zone of active lithospheric extension adjacentto the Siberian Craton. The 616 Myr old Vitim VolcanicField (VVF) lies approximately 200 km east of the rift axisand consists of 5000 km3 of melanephelinites, basanites, alkaliand tholeiitic basalts, and minor nephelinites. In the volcanicpile, 142 drill core samples were used to study temporal andspatial variations. Variations in major element abundances (e.g.MgO = 3·314·6 wt %) reflect polybaric fractionalcrystallization of olivine, clinopyroxene and plagioclase. 87Sr/86Sri(0·70390·7049), 143Nd/144Ndi (0·51270·5129)and 176Hf/177Hfi (0·28290·2830) ratiosare similar to those for ocean island basalts and suggest thatthe magmas have not assimilated significant amounts of continentalcrust. Variable degrees of partial melting appear to be responsiblefor differences in Na2O, P2O5, K2O and incompatible trace elementabundances in the most primitive (high-MgO) magmas. Fractionatedheavy rare earth element (HREE) ratios (e.g. [Gd/Lu]n > 2·5)indicate that the parental magmas of the Vitim lavas were predominantlygenerated within the garnet stability field. Forward major elementand REE inversion models suggest that the tholeiitic and alkalibasalts were generated by decompression melting of a fertileperidotite source within the convecting mantle beneath Vitim.Ba/Sr ratios and negative K anomalies in normalized multi-elementplots suggest that phlogopite was a residual mantle phase duringthe genesis of the nephelinites and basanites. Relatively highlight REE (LREE) abundances in the silica-undersaturated meltsrequire a metasomatically enriched lithospheric mantle source.Results of forward major element modelling suggest that meltingof phlogopite-bearing pyroxenite veins could explain the majorelement composition of these melts. In support of this, pyroxenitexenoliths have been found in the VVF. High Cenozoic mantle potentialtemperatures (1450°C) predicted from geochemical modellingsuggest the presence of a mantle plume beneath the Baikal RiftZone. KEY WORDS: Baikal Rift; mafic magmatism; mantle plume; metasomatism; partial melting 相似文献
17.
GREGOIRE M.; MOINE B. N.; O'REILLY SUZANNE Y.; COTTIN J. Y.; GIRET A. 《Journal of Petrology》2000,41(4):477-509
Mantle xenoliths in alkaline lavas of the Kerguelen Islandsconsist of: (1) protogranular, Cr-diopside-bearing harzburgite;(2) poikilitic, Mg-augite-bearing harzburgite and cpx-poor lherzolite;(3) dunite that contains clinopyroxene, spinel phlogopite, andrarely amphibole. Trace element data for rocks and mineralsidentify distinctive signatures for the different rock typesand record upper-mantle processes. The harzburgites reflectan initial partial melting event followed by metasomatism bymafic alkaline to carbonatitic melts. The dunites were firstformed by reaction of a harzburgite protolith with tholeiiticto transitional basaltic melts, and subsequently developed metasomaticassemblages of clinopyroxene + phlogopite ± amphiboleby reaction with lamprophyric or carbonatitic melts. We measuredtwo-mineral partition coefficients and calculated mineralmeltpartition coefficients for 27 trace elements. In most samples,calculated budgets indicate that trace elements reside in theconstituent minerals. Clinopyroxene is the major host for REE,Sr, Y, Zr and Th; spinel is important for V and Ti; orthopyroxenefor Ti, Zr, HREE, Y, Sc and V; and olivine for Ni, Co and Sc. KEY WORDS: mantle xenoliths; mantle metasomatism; partition coefficients; Kerguelen Islands; trace elements 相似文献
18.
Garnetite Xenoliths and Mantle-Water Interactions Below the Colorado Plateau, Southwestern United States 总被引:1,自引:0,他引:1
Garnetite xenoliths from ultramafic diatremes in northeasternArizona provide insights into hydration and metasomatism inthe mantle. The garnetites contain more than 95% garnet, someof which has complex compositional zonation related to growthin fractures within grains. Accessory minerals include rutile,ilmenite, chlorite, clinopyroxene, and zircon. Zircon grainsin one rock were analyzed in situ to determine UPb agesand Hf isotopic compositions. Most UPb analyses ploton or near concordia in the range 6085 Ma but a few arediscordant. The range in 176Hf/177Hf is about 0·28180·2828,with grains zoned to more radiogenic Hf from interiors to rims.The garnetite protolith contained zircons at least 1·8Ga in age, and garnet and additional zircon crystallized episodicallyduring the interval 8560 Ma. The garnetites are interpretedas mantle analogues of rodingites, formed in metasomatic reactionzones caused by waterrock interactions in Proterozoicmantle during late Cretaceous and Cenozoic subduction of theFarallon plate. Associated eclogite xenoliths may have beenparts of these same reaction zones. The rodingite hypothesisrequires serpentinization in the mantle wedge 700 km from thetrench, beginning 510 Myr before tectonism related tolow-angle subduction. KEY WORDS: garnetite; LuHf, mantle; rodingite; metasomatism 相似文献
19.
Petrology and Geochemistry of Eclogite Xenoliths from the Colorado Plateau: Implications for the Evolution of Subducted Oceanic Crust 总被引:2,自引:0,他引:2
Eclogite xenoliths from the Colorado Plateau, interpreted asfragments of the subducted Farallon plate, are used to constrainthe trace element and SrNdPb isotopic compositionsof oceanic crust subducted into the upper mantle. The xenolithsconsist of almandine-rich garnet, Na-clinopyroxene, lawsoniteand zoisite with minor amounts of phengite, rutile, pyrite andzircon. They have essentially basaltic bulk-rock major elementcompositions; their Na2O contents are significantly elevated,but K2O contents are similar to those of unaltered mid-oceanridge basalt (MORB). These alkali element characteristics areexplained by spilitization or albitization processes on thesea floor and during subduction-zone metasomatism in the fore-arcregion. The whole-rock trace element abundances of the xenolithsare variable relative to sea-floor-altered MORB, except forthe restricted Zr/Hf ratios (36·937·6).Whole-rock mass balances for two Colorado Plateau eclogite xenolithsare examined for 22 trace elements, Rb, Cs, Sr, Ba, Y, rareearth elements, Pb, Th and U. Mass balance considerations andmineralogical observations indicate that the whole-rock chemistriesof the xenoliths were modified by near-surface processes afteremplacement and limited interaction with their host rock, aserpentinized ultramafic microbreccia. To avoid these secondaryeffects, the Sr, Nd and Pb isotopic compositions of mineralsseparated from the xenoliths were measured, yielding 0·704530·70590for 87Sr/86Sr, 3·1 to 0·5 for Nd and 18·92819·063for 206Pb/204Pb. These isotopic compositions are distinctlymore radiogenic for Sr and Pb and less radiogenic for Nd thanthose of altered MORB. Our results suggest that the MORB-likeprotolith of the xenoliths was metasomatized by a fluid equilibratedwith sediment in the fore-arc region of a subduction zone andthat this metasomatic fluid produced continental crust-likeisotopic compositions of the xenoliths. KEY WORDS: Colorado Plateau; eclogite xenolith; geochemistry; subducted oceanic crust 相似文献
20.
Na Metasomatism in the Island-Arc Mantle by Slab Melt--Peridotite Interaction: Evidence from Mantle Xenoliths in the North Kamchatka Arc 总被引:20,自引:0,他引:20
The Pliocene (7 Ma) Nb-enriched arc basalts of the ValovayamVolcanic Field (VVF) in the northern segment of the Kamchatkaarc, Russia, host abundant mantle xenoliths, including spinelIherzolites. Textural and microstructural evidence for high-temperature,multi-stage, creep-related deformations in spinel Iherzolitessupports a sub-arc mantle derivation. Pyroxene chemistry indicatesthe existence of two compositional suites: (1) a Cr-diopsidesuite with low-Tt, moderate-Al clinopyroxene compositions, and(2) an Al-augite suite with high Al and Tt, and low Cr concentrationsin clinopyroxene. Some spinel lherzolite xenoliths contain metasomaticAl-augite-type clinopyroxene, Al-Tt spinel, and felsic veinssimilar to trondhjemite melt. The Al-augite series xenolithstypically contain high-Na plagioclase, Cr-poor, Al-Fe-Mg andAl-Tt-Fe spinels, with occasional almandine-grossularite garnetand high-Al and -Na pargasitic amphibole. Pyroxene and spinel compositional trends suggest that the Crdiopsideseries xenoliths from the VVF Nb-enriched arc basalts representan island-arc mantle affected by a metasomatic event. Occurrenceof high-Na plagioclase and trondhjemitic veins favors the additionof a metasomatic component with high Na, Al and Si to the northernKamchatka arc mantle. Trondhjemitic veins, representing siliceousslab melts, compositionally exemplify the metasomatic component.Na metasomatism by peridotite-slab melt interaction is an importantmantle hybridization process responsible for arc-related alkalinemagma generation from a veined sub-arc mantle. KEY WORDS: metasomatism; island arc; mantle xenoliths; Kamchatka; mantle 相似文献