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1.
Detailed site investigations to assess potential inhalation exposure and risk to human health associated with the migration of petroleum hydrocarbon vapors from the subsurface to indoor air are frequently undertaken at leaking underground storage tank (UST) sites, yet documented occurrences of petroleum vapor intrusion are extremely rare. Additional assessments are largely driven by low screening‐level concentrations derived from vapor transport modeling that does not consider biodegradation. To address this issue, screening criteria were developed from soil‐gas measurements at hundreds of petroleum UST sites spanning a range of environmental conditions, geographic regions, and a 16‐year time period (1995 to 2011). The data were evaluated to define vertical separation (screening) distances from the source, beyond which, the potential for vapor intrusion can be considered negligible. The screening distances were derived explicitly from benzene data using specified soil‐gas screening levels of 30, 50, and 100 µg/m3 and nonparametric Kaplan‐Meier statistics. Results indicate that more than 95% of benzene concentrations in soil gas are ≤30 µg/m3 at any distance above a dissolved‐phase hydrocarbon source. Dissolved‐phase petroleum hydrocarbon sources are therefore unlikely to pose a risk for vapor intrusion unless groundwater (including capillary fringe) comes in contact with a building foundation. For light nonaqueous‐phase liquid (LNAPL) hydrocarbon sources, more than 95% of benzene concentrations in soil gas are ≤30 µg/m3 for vertical screening distances of 13 ft (4 m) or greater. The screening distances derived from this analysis are markedly different from 30 to 100 ft (10 to 30 m) vertical distances commonly found cited in regulatory guidance, even with specific allowances to account for uncertainty in the hydrocarbon source depth or location. Consideration of these screening distances in vapor intrusion guidance would help eliminate unnecessary site characterization at petroleum UST sites and allow more effective and sustainable use of limited resources.  相似文献   

2.
Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.  相似文献   

3.
A growing number of state and local governments and petroleum-related companies require the use of release detection systems for underground petroleum storage tanks. This has resulted in a confusing array of commercially available petroleum product detection devices, many of which have not been extensively field-tested. These systems, which are installed in ground water observation wells, vapor wells or U-tubes, include hydrocarbon-detecting paste, bailers, interface probes, electrical resistivity sensors, thermal-conductivity sensors, hydrocarbon-soluble devices, hydrocarbon-permeable materials and vapor detectors. This paper describes the available state-of-the-art technology for leak detection and the application for which each system is best suited.  相似文献   

4.
A detailed seasonal study of soil vapor intrusion at a cold climate site with average yearly temperature of 1.9 °C was conducted at a house with a crawlspace that overlay a shallow dissolved‐phase petroleum hydrocarbon (gasoline) plume in North Battleford, Saskatchewan, Canada. This research was conducted primarily to assess if winter conditions, including snow/frost cover, and cold soil temperatures, influence aerobic biodegradation of petroleum vapors in soil and the potential for vapor intrusion. Continuous time‐series data for oxygen, pressure differentials, soil temperature, soil moisture, and weather conditions were collected from a high‐resolution monitoring network. Seasonal monitoring of groundwater, soil vapor, crawlspace air, and indoor air was also undertaken. Petroleum hydrocarbon vapor attenuation and biodegradation rates were not significantly reduced during low temperature winter months and there was no evidence for a significant capping effect of snow or frost cover that would limit oxygen ingress from the atmosphere. In the residual light nonaqueous phase liquid (LNAPL) source area adjacent to the house, evidence for biodegradation included rapid attenuation of hydrocarbon vapor concentrations over a vertical interval of approximately 0.9 m, and a corresponding decrease in oxygen to less than 1.5% v/v. In comparison, hydrocarbon vapor concentrations above the dissolved plume and below the house were much lower and decreased sharply within a few tens of centimeters above the groundwater source. Corresponding oxygen concentrations in soil gas were at least 10% v/v. A reactive transport model (MIN3P‐DUSTY) was initially calibrated to data from vertical profiles at the site to obtain biodegradation rates, and then used to simulate the observed soil vapor distribution. The calibrated model indicated that soil vapor transport was dominated by diffusion and aerobic biodegradation, and that crawlspace pressures and soil gas advection had little influence on soil vapor concentrations.  相似文献   

5.
Water-in-oil mixtures such as emulsions, often form and complicate oil spill countermeasures. The formation of water-in-oil mixtures was studied using more than 300 crude oils and petroleum products. Water-in-oil types were characterized by resolution of water at 1 and 7 days, and some after 1 year. Rheology measurements were carried out at the same intervals. The objective of this laboratory study was to characterize the formed water-in-oil products and relate these properties to starting oil properties. Analysis of the starting oil properties of these water-in-oil types shows that the existence of each type relates to the starting oil viscosity and its asphaltene and resin contents. This confirms that water-in-oil emulsification is a result of physical stabilization by oil viscosity and chemical stabilization by asphaltenes and resins. This stabilization is illustrated using simple graphical techniques. Four water-in-oil types exist: stable, unstable, meso-stable and entrained. Each of these has distinct physical properties.  相似文献   

6.
We developed a new semi-analytical source zone depletion model (SZDM) for multicomponent light nonaqueous phase liquids (LNAPLs) and incorporated this into an existing screening model for estimating cleanup times for chemical spills from railroad tank cars that previously considered only single-component LNAPLs. Results from the SZDM compare favorably to those from a three-dimensional numerical model, and from another semi-analytical model that does not consider source zone depletion. The model was used to evaluate groundwater contamination and cleanup times for four complex mixtures of concern in the railroad industry. Among the petroleum hydrocarbon mixtures considered, the cleanup time of diesel fuel was much longer than E95, gasoline, and crude oil. This is mainly due to the high fraction of low solubility components in diesel fuel. The results demonstrate that the updated screening model with the newly developed SZDM is computationally efficient, and provides valuable comparisons of cleanup times that can be used in assessing the health and financial risk associated with chemical mixture spills from railroad-tank-car accidents.  相似文献   

7.
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.  相似文献   

8.
Groundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O2 concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O2 and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O2 and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O2 and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.  相似文献   

9.
The toxic action of bicomponent mixtures of phenols and heavy metals on luminous bacteria has been studied. It was established that phenolic compounds displaying properties of structural-specific agents whose influence is based on chemical reactions with receptors in mixtures with heavy metals of mercury, cadmium in low concentrations caused additive, and with the increase of metal concentration-more than additive, effects. Phenolic compounds acting as structurally-nonspecific agents (resorcinol), whose toxicity is stipulated by their physico-chemical properties, produce a less than additive effect in a mixture with heavy metals.  相似文献   

10.
New and improved techniques and apparatus for testing the mechanical properties of materials at high presures and temperatures are described. These include an improved Griggs-type deformation apparatus designed to operate to 5 GPa and associated servo-controlled hydraulic drive and electronics, the design of hydrostatic (molten alkali halide mixtures) pressure assemblies to measure flow stresses as low as a few MPa, the characterization of temperature gradients and friction in such assemblies, measurement of the melting curve of an alkali halide mixture used as a confining pressure medium, and the measurement of acoustic emissions.  相似文献   

11.
A field screening method was developed for rapid measurement of benzene and gasoline range total petroleum hydrocarbons (TPHg) concentrations in groundwater. The method is based on collecting photoionization detector (PID) measurements from vapor samples. The vapor samples are collected by bubbling air through groundwater samples (air sparging) with a constant volume, temperature and sparging rate. The level of accuracy, sensitivity, precision, and statistical significance of the estimated concentrations, derived from the screening method, are comparable to conventional laboratory analytical results at concentrations equal to or greater than 150 µg/L for benzene and greater than 50 µg/L for TPHg. The method's concentration estimations can assist in making real‐time decisions regarding location of dissolved plumes and light nonaqueous phase liquid (LNAPL) source zones at many fuel release sites. The screening method was tested in the laboratory and in the field with 208 and 107 samples, respectively. The study concludes that the screening method can be used as a tool to aid in completing a site conceptual model as well as analyzing groundwater from monitoring wells.  相似文献   

12.
Releases of petroleum products from leaking residential storage tanks are a growing problem in the stale of New Jersey. Approximately two releases per day have been reported to the New Jersey Department of Environmental Protection. Product releases may cause aquifers to become contaminated, may affect surface water, or cause vapor problems inside households. As of 1992, there arc no federal or state regulations pertaining to the maintenance and monitoring of residential petroleum storage tanks. Regulations are essential for protecting drinking water supplies. The regulations must address installation procedures, lank materials, monitoring, and tank location.  相似文献   

13.
《国际泥沙研究》2020,35(6):563-575
Erosion of mixed cohesive and noncohesive sediments is studied using the erosion test instrument SEDFlume. The sediment mixtures are composed of well-sorted quartz sand (0.25–0.5 mm) and one of the three used muds: kaolinite, kaolinite-bentonite and Mississippi River muds. The mud contents cover from 0 to 100%. The measured data of erosion rate and bed shear stress are used to examine the segmented linear, nonlinear, and exponential erosion models. The parameters of each erosion model are related to the physical properties of sediment mixtures, including clay fraction, mud fraction, mixture dry density, and mud dry density. It is found that the three models can fit well with the data, and their parameters have strong relations with the mud fraction and mud dry density, to a less extent with the clay fraction, but not with the mixture dry density.  相似文献   

14.
《Marine pollution bulletin》1987,18(10):528-533
The suitability of fluorescence spectroscopy for the determination of aromatic concentrations in mussel tissue was investigated. A mixture of aromatic compounds, with a total emission spectrum similar to those of the samples, was found to be the most suitable standard with measurement being made at the emission maximum. Significant correlations were found between aromatic hydrocarbon concentrations obtained by fluorescence spectroscopy and both aliphatic and aromatic hydrocarbon concentrations obtained by gas chromatographic analysis (GC). Results indicate that analysis of the aliphatic fraction by GC and fluorescence analysis of the aromatic fraction provides a suitable estimation of the relative degree of contamination of mussel tissues by petroleum hydrocarbons.  相似文献   

15.
Screening level models are now commonly used to estimate vapor intrusion for subsurface volatile organic compounds (VOCs). Significant uncertainty is associated with processes and models and, to date, there has been only limited field-based evaluation of models for this pathway. To address these limitations, a comprehensive evaluation of the Johnson and Ettinger (J&E) model is provided through sensitivity analysis, comparisons of model-predicted to measured vapor intrusion for 11 petroleum hydrocarbon and chlorinated solvent sites, and review of radon and flux chamber studies. Significant intrusion was measured at five of 12 sites with measured vapor attenuation ratios (αm's) (indoor air/source vapor) ranging from ∼1 × 10−6 to 1 × 10−4. Higher attenuation ratios were measured for studies using radon, inert tracers, and flux chambers; however, these ratios are conservative owing to boundary conditions and tracer properties that are different than those at most VOC-contaminated sites. Reasonable predictions were obtained using the J&E model with comparisons indicating that model-predicted vapor attenuation ratios (αp's) were on the same order, or less than the αm's. For several sites, the (m were approximately two orders of magnitude less than the a 's indicating that the J&E model is conservative in these cases. The model comparisons highlight the importance in using appropriate input parameters for the J&E model. The regulatory implications associated with use of the J&E model to derive screening criteria are also discussed.  相似文献   

16.
Screening level models are now commonly used to estimate vapor intrusion for subsurface volatile organic compounds (VQCs). Significant uncertainty is associated with processes and models and, to date, there has been only limited field-based evaluation of models for this pathway. To address these limitations, a comprehensive evaluation of the Johnson and Ettinger (J&E) model is provided through sensitivity analysis, comparisons of model-predicted to measured vapor intrusion for 11 petroleum hydrocarbon and chlorinated solvent sites, and review of radon and flux chamber studies. Significant intrusion was measured at five of 12 sites with measured vapor attenuation ratios (αm's) (indoor air/source vapor) ranging from ∼1 × 10−6 to 1 × 10−4. Higher attenuation ratios were measured for studies using radon, inert tracers, and flux chambers; however, these ratios are conservative owing to boundary conditions and tracer properties that are different than those at most VOC-contaminated sites. Reasonable predictions were obtained using the J&E model with comparisons indicating that model-predicted vapor attenuation ratios (αp's) were on the same order, or less than the αm's. For several sites, the αm were approximately two orders of magnitude less than the αp's indicating that the J&E model is conservative in these cases. The model comparisons highlight the importance in using appropriate input parameters for the J&E model. The regulatory implications associated with use of the J&E model to derive screening criteria are also discussed.  相似文献   

17.
Recycled tire rubber in mixtures with granular soils has been found recently applications in many civil engineering projects. The paper presents a synthesis of the dynamic strain-dependent properties of the commonly used soil/rubber mixtures, which are necessary in any seismic design. We focus herein on high-amplitude resonant column tests on granular soil/rubber mixtures with varying percentage of rubber. The most important characteristics of the dynamic properties of the mixtures like the confining pressure, the content of rubber, the grain-size characteristics of the physical portion of the mixtures as well as the relative size of soil versus rubber solids, are thoroughly discussed. We propose generic normalized shear modulus and damping ratio versus shearing strain amplitude curves for dry mixtures of sand/rubber (SRM) and gravel/rubber (GRM) appropriate for the engineering practice. Finally, we summarize analytical expressions for small-strain shear modulus and damping ratio for SRM and GRM proposed in previous studies.  相似文献   

18.
This article considers the effectiveness of a seismic isolation system composed of a shallow layer of soil mixed with sand and rubber from shredded tires. A thorough review of past work is first provided, which is then followed by an evaluation of the constitutive properties of sand-rubber soil mixtures when these undergo large states of deformation and slip. Finally, a comprehensive set of simulations that involve a structure underlain by a strongly non-linear, seismic isolating layer when subjected to a variety of actual earthquakes scaled to various peak accelerations, are considered in detail. It is shown that the concept of using soil-rubber mixtures for the purposes of seismic isolation appears promising. A thickness for the rubber–soil mixture of just 2–3 m is likely to be enough to achieve good levels of reductions in the seismic response of the structure. This suggests the desirability of following these analyses with large-scale experimental verifications, not only to fully validate the concept, but also to quantify and assess the numerical predictions with our simple even if non-linear mechanical models, and verify the large-strain constitutive properties of the soil mixtures inferred from laboratory analyses.  相似文献   

19.
This study focuses on the prediction of the porosity of nonuniform sediment mixtures,considering the effects of particle packing.A random particle packing model has been developed for the porosity of bimodal mixtures by extending the existing random particle filling theory.Coefficients in the developed model are calibrated by fitting the model to measured data for a variety of bimodal mixtures,including spherical glass particles,rounded quarry grains,and natural sediments.The model coefficients ...  相似文献   

20.
Spur dikes are river training structures that have been extensively used worldwide for towards enhancing flood control and the stability of embankments and riverbanks.However,scour around spur dikes can be a major problem affecting their stability and hydraulic performance.The precise computation of temporal scour depth at spur dikes is very important for the design of economical and safe spur dikes.This study focuses on experimentally assessing the temporal variation of scour depth around a vertical wall spur dike and identifying the parameters,which mostly influence spur dike performance for a channel bed surface comprised of sand-gravel mixtures.In the current study,the authors did physical experiments in a flume based study to obtain new data,aimed at deriving a new predictive model for spur dike scour and comparing its performance to others found in the literature.It was found that the dimensionless temporal scour depth variation increases with an increase in(i)the threshold velocity ratio,(ii)the densimetric Froude number of the bed surface sediment mixture,(iii)the flow shallowness(defined as the ratio of the approach flow depth,y,to the spur dike’s transverse length,l),and(iv)the flow depth-particle size ratio.It is also concluded that the temporal scour depth variation in the sediment mixture is influenced by the non-uniformity of sediment and decreases with an increase in the non-uniformity of the sediment mixture.A new mathematical model is derived for the estimation of temporal scour depths in sand-gravel sediment mixtures.The proposed equation has been calibrated and validated with the experimental data,demonstrating a good predictive capacity for the estimation of temporal scour depth evolution.  相似文献   

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