首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
The observation of oil inclusions trapped prior to 2.0 Ga in Palaeoproterozoic rocks and the ability to obtain detailed molecular geochemical information from them provide a robust way for understanding the early biogeochemical evolution of the Earth. Oil-bearing fluid inclusions (FI) in ca. 2.45 Ga fluvial metaconglomerate of the Matinenda Formation at Elliot Lake, Canada were trapped in quartz and feld-spar during diagenesis and early metamorphism of the host rock, probably before ca. 2.2 Ga. The 2.1 Ga FA Formation sandstone of the Franceville Basin in Gabon that hosts the Oklo natural fission reactors has also been discovered to contain abundant Palaeoproterozoic oil-bearing FIs. This oil occurs within H2O and CO2-dominated inclusions trapped in syntaxial quartz overgrowths and intragranular and transgranular microfractures in detrital quartz, and was most likely trapped 2.1–1.98 Ga. Molecular geochemical analyses of both FI oils reveal a wide range of compounds, including n-alkanes, isoprenoids, monomethylalkanes, aromatic hydrocarbons, and trace amounts of complex multi-ring biomarkers including terpanes, hopanes, methylhopanes, steranes and diasteranes. To ensure a reliable interpretation of oil inclusions, a comprehensive series of outside-rinse blanks and procedural system blanks was analysed by gas chromatography-mass spectrometry; quantitative amounts of the hydrocarbons in these blanks were compared to the FI extracts, so as to provide confidence limits on the experimental integrity of each compound class. Maturity ratios based on reliably detected compound classes show that the FI oils were generated in the oil window, with no evidence of extensive thermal cracking. The presence of biomarkers for cyanobacteria and eukaryotes derived from and trapped in rocks deposited prior to 2.0 Ga is consistent with early evolution of oxygenic photosynthesis and suggests that some aquatic settings had become sufficiently oxygenated for sterol biosynthesis by this time. The extraction of biomarker molecules from Palaeoproterozoic oil-bearing FIs thus establishes a new method, using low detection limits and system blank levels, to trace evolution through Earth’s early history that avoids the potential contamination problems affecting shale-hosted hydrocarbons. Supported by the ARC Discovery Grant, which includes a QEII Fellowship to A.D., the Natural Sciences and Engineering Research Grant to D.M., and by the National Aeronautics and Space Administration Astrobiology Institute (R.B.)  相似文献   

2.
The Luliang and Baoshan basins are two small ba- sins in Yunnan Province. In the recent ten years or so, there have been found a number of natural gas pools of commercial importance in the two basins. Although the gas pools are small in size, the natural …  相似文献   

3.
springerlink.com Studies of mantle fluids are currently one of the hot topics in the earth science, greatly contributing to re-vealing origins and evolutions of fluids. In general, the concept of mantle fluids refers to their active compo-nents, such as CO2, H2O, N2, etc., while the noble gases inert in chemical properties belong to another research system. Due to their marked differences in various fluid sources of the Earth[1], the isotopic sig-natures of He and Ar have been widely used a…  相似文献   

4.
This study presents baseline data for future geochemical monitoring of the active Tacaná volcano–hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO3–SO4 waters are thought to have formed by the absorption of a H2S/SO2–CO2-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO3-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ18O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at ~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ18O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO2-dominated. The δ13CCO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in 3He/4He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric 3He/4He ratio (R A)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (4He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO2/3He ratio of gases: bubbling springs with lower gas/water ratios show higher 3He/4He ratios and consequently lower CO2/3He ratios (e.g. Zarco spring). Typical Central American CO2/3He and 3He/4He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 1010 and 6.0 ± 0.9 R A, respectively). The L/S (5.9 ± 0.5) and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc, Tacaná.  相似文献   

5.
  相似文献   

6.
The composition of fluid inclusions(FI)often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock.Influence on composition and carbon isotopic composition of gas during primary migration,reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin.The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane.Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in FIs.Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.  相似文献   

7.
The composition of fluid inclusions (FI) often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock. Influence on composition and carbon isotopic composition of gas during primary migration, reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin. The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane. Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in Fls. Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.  相似文献   

8.
Significant changes in the helium and carbon isotopic composition of shallow thermal waters vs. gas and a crater fumarolic gas have been recorded at Stromboli prior and during the 2002–2003 eruption. The3He/4He ratios corrected for air contamination (Rc/Ra), and δ13C of fumarolic gases gradually increased from May to November 2002 before the eruption onset. These variations imply early degassing of a gas-rich magma at depth that likely fed both the intense Strombolian activity and small lava overflows recorded during that period. The lava effusion of late December 2002 was shortly preceded by a marked Rc/Ra decrease both in water and fumarolic gases. Comparison of He/CO2 and CH4/CO2 ratios in dissolved gas and with values rules out the Rc/Ra decrease due to an increasing input of radiogenic4He. The Rc/Ra decrease is attributed to the He isotope fractionation during rapid magma ascent and degassing. A new uprising of 3He-rich magma probably occurred in January to February 2003, when Rc/Ra ratios displayed the highest values in dissolved gases ever measured before (4.56 Rc/Ra). The increase in He/CO2 and CH4/CO2 ratios and decrease in δ13C of dissolved CO2 was recorded after the 5 April 2003 explosive paroxysm, likely caused by enhanced gas-water interaction inducing CO2 dissolution. No anomalous Rc/Ra values were recorded in the same period, when usual Strombolian activity gradually resumed.Editorial responsibility: H Shinohara  相似文献   

9.
The results of studying the composition of hydrocarbon gases (C1–C5) and organic matter in bottom sediments of the Ivankovo Reservoir in 1995, 2004, and 2005 are given. The methods used in the study include vapor-phase gas chromatography, instrumental pyrolysis gas chromatography, and mass-spectrometry for determining organic carbon δ 13Corg. The gas field of bottom sediments in different regions of the reservoir varies widely in terms of gas saturation and the spectrum of hydrocarbon gases. This suggests the heterogeneous composition of organic matter in the sediments and different conditions of its input and transformation processes. The gases were found to contain saturated hydrocarbons from methane to pentane C1–C5, including isomers i-C4 and i-C5 and unsaturated compounds C2–C4. A correlation was found to exist between methane distribution and the distribution of its more high-molecular homologues, which confirms their genetic relationship in bottom sediments. The obtained results show an increase in the rate of microbiological processes and organic matter transformation for most regions in the Ivankovo Reservoir. The only exceptions are the zones of Moshkovichskii Bay and the sections at Gorodnya and Konakovo, where technogenic organic matter is being accumulated. The high information value of hydrocarbon gases as biogeochemical markers of the sources of organic matter and the rates of its transformation is demonstrated. The isotopic composition of organic-matter carbon in the bottom sediments of the Ivankovo Reservoir δ 13C varies from ?26.21 to ?30.86‰.  相似文献   

10.
Noble gas concentrations and isotopic compositions have been determined for four submarine volcanic glasses from the Valu Fa Ridge (VFR) in the southern Lau Basin. The samples are the least differentiated ones from this area, and they display enrichments in fluid-mobile elements similar to the nearby island arc. 3He/4He ratios are slightly below average MORB (6.8–7.8 times atmospheric), whereas Ne, Ar, Kr, and Xe have isotopic compositions very similar to air. Together with previously published data from the Valu Fa Ridge and other spreading segments in the Lau Basin, our data show a systematic latitudinal variation of increasing Ne, Ar, Kr, and Xe abundances from north to south as well as Ne and Ar isotopic compositions changing from MORB-like to atmosphere-like in the same direction. Moreover, isotopic compositions and noble gas abundances of the lavas correlate strongly with Ba/Nb ratios and H2O concentrations. Based on these observations and mass balance arguments, we propose that the atmospheric noble gases come from the subducting oceanic crust and are not due to shallow contamination with air dissolved in seawater or assimilation of old crust. Our data suggest that the noble gases released from the subducting slab are atmospheric and thus contain little or no solar He and Ne. In addition to the fact that ratios of He to heavy noble gases are small in aged ocean crust, He has possibly fractionated from the other noble gases due to its higher diffusivity, and thus He transport from the subducting slab into the mantle wedge is probably insignificant. We propose that the 3He/4He ratios lower than MORB observed in the VFR lavas result from radiogenic ingrowth of He in a highly depleted, and hence degassed, mantle wedge after the enrichment of U and Th released from the downgoing slab.  相似文献   

11.
Introduction Hilbert-Huang transform (HHT) is a great break in processing nonlinear and non-stationary data and can be successfully used in many science domains. There are mainly two parts in this method. The first part is to decompose the original data into several intrinsic mode functions (IMF) with the empirical mode decomposition (EMD). IMF components are derived from the original data directly according to the local characteristics in the data under some rules, so that IMF are poste…  相似文献   

12.
（黄培华）（苏维加）（陈金波）ＳｅｉｓｍｉｃｉｔｙａｎｄｓｔｒｅｓｓｆｉｅｌｄｉｎＯｋｉｎａｗａＴｒｏｕｇｈａｎｄＲｙｕｋｙｕｒｅｇｉｏｎｓ￥Ｐｅｉ－ＨｕａＨＵＡＮＧ；Ｗｅｉ－ｊｉａＳＵａｎｄＪｉｎ－ＢｏＣＨＥＮ（ＤｅｐａｒｔｍｅｎｔｏｆＥａｒｔｈａ...  相似文献   

13.
Crustal movement and deformation in Taiwan and its coastal area   总被引：1，自引：0，他引：1  
Introduction Both Taiwan Island and Chinese mainland belong to Eurasian plate in geological structure. And the nearest distance between Taiwan Island and Fujian Province, which is located on the opposite coast, is only 130 km. Although there are high-precision GPS networks in both Taiwan and Fujian Province, joint GPS measurement cannot be made directly because of the inconvenient contact due to the strait between them. However, the GPS networks arranged on b…  相似文献   

14.
The strength and architecture of roots and other below-ground organs of riparian and aquatic plants affect plant resistance to uprooting and contribute to reinforcing river bank, bar and bed materials. Therefore, root properties are an important element in models for estimating river bank stability and such models may focus on the role of plants by using root strength–diameter relationships for the particular plant species that are present. Here we explore the degree to which there appear to be significant differences in strength–diameter relationships between and within species-specific data sets obtained for two riparian tree/shrub (Populus nigra, Salix alba) and two emergent aquatic macrophyte (Sparganium erectum, Phalaris arundinacea) species in different European river environments. While the analysed data sets were not specifically collected to answer these research questions, the results are sufficiently compelling to make the case for the collection of a more comprehensive data set and its rigorous analysis. This would allow recommendations to be made on the degree to which (i) species-specific or more general relationships between root/rhizome strength and diameter are appropriate, (ii) such relationships are applicable within and between rivers in different geographical regions and subject to different local environmental conditions, and (iii) further (minimalist) field observations are needed to calibrate such relationships for investigations of new locales or species. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

15.
Introduction Rayleigh wave is a kind of seismic wave propagating along the surface of the Earth, its propagation speed depends chiefly on the S-wave velocity structure of the Earth. Rayleigh wave energy of different periods concentrated in different depth ranges. The layered structure of the Earth causes the phenomenon of dispersion of surface waves, that is, surface waves of different periods are propagated with different speeds. By measuring the dispersion curves of surface waves the S-wav…  相似文献   

16.
Using pure S wave fitting method, we studied the shear wave velocity structures under the Ordos block and its eastern and southern marginal areas. The results show that the velocity structure beneath Yulin station in the interior of Ordos block is relatively stable, where no apparent change between high and low velocity layers exists and the shear wave velocity increases steadily with the depth. There is a 12km thick layer at the depth of 25km under this station, with an S wave velocity (Vs=3.90km/s) lower than that at the same depth in its eastern and southern areas (Vs≥4.00km/s). The crust under the eastern margin of Ordos block is thicker than that of the Yulin station, and the velocity structures alternate between the high and low velocity layers, with more low velocity layers. It has the same characteristic as having a 10km-thick low velocity layer (Vs=3.80km/s) in the lower crust but buried at a depth of aout 35km. Moreover, we studied the Vp/Vs ratio under each station in combination with the result of P wave velocity inversion. The results show that, the average velocity ratio of the Yulin station at the interior of Ordos block is only 1.68, with a very low ratio (about 1.60) in the upper crust and a stable ratio of about 1.73 in the mid and lower crust, which indicates the media under this station is homogenous and stable, being in a state of rigidity. But at the stations in the eastern and southern margins of the Ordos block, several layers of high velocity ratio (about 1.80) have been found, in which the average velocity ratio under Kelan and Lishi stations at the eastern margin is systemically higher than that of the general elastical body waves (1.732). This reflects that the crust under the marginal areas is more active relatively, and other materials may exist in these layers. Finally, we discussed the relationship among earthquakes, velocity structures beneath stations and faults.  相似文献   

17.
Introduction When the distribution of a cluster of earthquakes is concentrated, distance between hypocen-ters is much smaller than the event-station distance and than the scale length of the velocity het-erogeneity in the hypocenter region; in this case, the ray path from each hypocenter to a common station will be almost the same. The relative location method can be applied to accurate location of the cluster in the above case. In this approach, the relative location is calculated with the ar…  相似文献   

18.
In this paper, we make a comparative analysis and correlation test for the seismic activities in the South Japan and the Ludong-Huanghai block (a secondary tectonic unit in the North China) and approach the relationship between the energy release processes of these two areas by using co-integration analysis and Granger causality test for the time series of random variables. The results show that the seismic activities in these two areas are correlative and synchronous to a certain extent, and their release series of cumulative strain energy are contemporaneously cor-relative. Both energy series are first-order difference stationary processes and there is secular and steady co-integration between them. We make a positive analysis on the first-order difference energy series through Granger causality test based on vector error correction (VEC) model and find there is unilateral Granger causality and prominent co-integration between the two energy release processes.  相似文献   

19.
The distribution of two formation pathways of biogenic methane, acetate fermentation and reduction of CO2, has been extensively studied. In general, CO2 reduction is the dominate pathway in marine envi- ronment where acetate is relatively depleted because of SRB consuming. While in terrestrial freshwater or brackish environment, acetate fermentation is initially significant, but decreases with increasing buried depth. In this paper, character of biogenic gases is profiled in the XS3-4 well of the Sebei 1 gas field in the Sanhu depression, Qaidam Basin. It indicates that those two pathways do not change strictly with increasing buried depth. CO2 reduction is important near the surface (between 50 m and 160 m), and at the mesozone (between 400 and 1650 m). While acetate fermentation is the primary pathway at two zones, from 160 to 400 m and from 1650 to 1700 m. δ 13C of methane generated in those two acetate fermentation zones varies greatly, owing to different sediment circumstances. At the sec- ond zone (160-400 m), δ 13C1 ranges from ?65‰ to ?30‰ (PDB), because the main deposit is mudstone and makes the circumstance confined. At the fourth zone of the well bottom (1650-1700 m), δ 13C1 is lighter than ?65‰ (PDB). Because the deposit is mainly composed of siltstone, it well connects with outer fertile groundwater and abundant nutrition has supplied into this open system. The high con- centration of acetate is a forceful proof. δ 13C of methane would not turn heavier during fermentation, owing to enough nutrition supply. In spite of multi-occurrence of acetate fermentation, the commercial gas accumulation is dominated by methane of CO2-reduction pathway. A certain content of alkene gases in the biogenic gases suggests that methanogensis is still active at present.  相似文献   

20.
Geology and Exploration of Oil and Gas in the Ordos Basin   总被引：2，自引：0，他引：2  
The Ordos basin is rich in oil and gas resources. The structures in the basin are generally rather gentle. Most of the oil and gas pools already found are belong to the types of lithologic, lithostratigraphic and paleo-geomorphic with thin reservoirs. The geology of oil and gas and the generation and distribution of oil and gas resources in the Ordos basin is analyzed in detail in the paper. It is also pointed out in the paper that what direction should be taken in oil and gas exploration in the basin, and that the important role of the seismic prospecting technologies in the discovery of large oil and gas fields in the basin could not be replaced.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号