首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 656 毫秒
1.
Abstract— All groups of chondritic meteorites contain discrete grains of forsteritic olivine with FeO contents below 1 wt% and high concentrations of refractory elements such as Ca, Al, and Ti. Ten such grains (52 to 754 μg) with minor amounts of adhering matrix were separated from the Allende meteorite. After bulk chemical analysis by instrumental neutron activation analysis (INAA), some samples were analyzed with an electron microprobe and some with an ion microprobe. Matrix that accreted to the forsterite grains has a well‐defined unique composition, different from average Allende matrix in having higher Cr and lower Ni and Co contents, which implies limited mixing of Allende matrix. All samples have approximately chondritic relative abundances of refractory elements Ca, Al, Sc, and rare‐earth elements (REE), although some of these elements, such as Al, do not quantitatively reside in forsterite; whereas others (e.g., Ca) are intrinsic to forsterite. The chondritic refractory element ratios in bulk samples, the generally high abundance level of refractory elements, and the presence of Ca‐Al‐Ti‐rich glass inclusions suggest a genetic relationship of refractory condensates with forsteritic olivine. The Ca‐Al‐Ti‐rich glasses may have acted as nuclei for forsterite condensation. Arguments are presented that exclude an origin of refractory forsterite by crystallization from melts with compositions characteristic of Allende chondrules: (a) All forsterite grains have CaO contents between 0.5 and 0.7 wt% with no apparent zoning, requiring voluminous parental melts with 18 to 20 wt% CaO, far above the average CaO content of Allende chondrules. Similar arguments apply to Al contents. (b) The low FeO content of refractory forsterite of 0.2‐0.4 wt% imposes an upper limit of ～1 wt% of FeO on the parental melt, too low for ordinary and carbonaceous chondrule melts, (c) The Mn contents of refractory forsterites are between 30 to 40 ppm. This is at least one order of magnitude below the Mn content of chondrule olivines in all classes of meteorites. The observed Mn contents of refractory forsterite are much too low for equilibrium between olivine and melts of chondrule composition, (d) As shown earlier, refractory forsterites have O‐isotopic compositions different from chondrules (Weinbruch et al., 1993a). Refractory olivines in carbonaceous chondrites are found in matrix and in chondrules. The compositional similarity of both types was taken to indicate that all refractory forsterites formed inside chondrules (e.g., Jones, 1992). As refractory forsterite cannot have formed by crystallization from chondrule melts, we conclude that refractory forsterite from chondrules are relic grains that survived chondrule melting and probably formed in the same way as refractory forsterite enclosed in matrix. We favor an origin of refractory forsterite by condensation from an oxidized nebular gas.  相似文献   

2.
Abstract— The outer portions of many type I chondrules (Fa and Fs <5 mol%) in CR chondrites (except Renazzo and Al Rais) consist of silica‐rich igneous rims (SIRs). The host chondrules are often layered and have a porphyritic core surrounded by a coarse‐grained igneous rim rich in low‐Ca pyroxene. The SIRs are sulfide‐free and consist of igneously‐zoned low‐Ca and high‐Ca pyroxenes, glassy mesostasis, Fe, Ni‐metal nodules, and a nearly pure SiO2 phase. The high‐Ca pyroxenes in these rims are enriched in Cr (up to 3.5 wt% Cr2O3) and Mn (up to 4.4 wt% MnO) and depleted in Al and Ti relative to those in the host chondrules, and contain detectable Na (up to 0.2 wt% Na2O). Mesostases show systematic compositional variations: Si, Na, K, and Mn contents increase, whereas Ca, Mg, Al, and Cr contents decrease from chondrule core, through pyroxene‐rich igneous rim (PIR), and to SIR; FeO content remains nearly constant. Glass melt inclusions in olivine phenocrysts in the chondrule cores have high Ca and Al, and low Si, with Na, K, and Mn contents that are below electron microprobe detection limits. Fe, Ni‐metal grains in SIRs are depleted in Ni and Co relative to those in the host chondrules. The presence of sulfide‐free, SIRs around sulfide‐free type I chondrules in CR chondrites may indicate that these chondrules formed at high (>800 K) ambient nebular temperatures and escaped remelting at lower ambient temperatures. We suggest that these rims formed either by gas‐solid condensation of silica‐normative materials onto chondrule surfaces and subsequent incomplete melting, or by direct SiO(gas) condensation into chondrule melts. In either case, the condensation occurred from a fractionated, nebular gas enriched in Si, Na, K, Mn, and Cr relative to Mg. The fractionation of these lithophile elements could be due to isolation (in the chondrules) of the higher temperature condensates from reaction with the nebular gas or to evaporation‐recondensation of these elements during chondrule formation. These mechanisms and the observed increase in pyroxene/olivine ratio toward the peripheries of most type I chondrules in CR, CV, and ordinary chondrites may explain the origin of olivine‐rich and pyroxene‐rich chondrules in general.  相似文献   

3.
Bulk major element composition, petrography, mineralogy, and oxygen isotope compositions of twenty Al‐rich chondrules (ARCs) from five CV3 chondrites (Northwest Africa [NWA] 989, NWA 2086, NWA 2140, NWA 2697, NWA 3118) and the Ningqiang carbonaceous chondrite were studied and compared with those of ferromagnesian chondrules and refractory inclusions. Most ARCs are marginally Al‐richer than ferromagnesian chondrules with bulk Al2O3 of 10–15 wt%. ARCs are texturally similar to ferromagnesian chondrules, composed primarily of olivine, pyroxene, plagioclase, spinel, Al‐rich glass, and metallic phases. Minerals in ARCs have intermediate compositions. Low‐Ca pyroxene (Fs0.6–8.8Wo0.7–9.3) has much higher Al2O3 and TiO2 contents (up to 12.5 and 2.3 wt%, respectively) than that in ferromagnesian chondrules. High‐Ca pyroxene (Fs0.3–2.0Wo33–54) contains less Al2O3 and TiO2 than that in Ca,Al‐rich inclusions (CAIs). Plagioclase (An77–99Ab1–23) is much more sodic than that in CAIs. Spinel is enriched in moderately volatile element Cr (up to 6.7 wt%) compared to that in CAIs. Al‐rich enstatite coexists with anorthite and spinel in a glass‐free chondrule, implying that the formation of Al‐enstatite was not due to kinetic reasons but is likely due to the high Al2O3/CaO ratio (7.4) of the bulk chondrule. Three ARCs contain relict CAIs. Oxygen isotope compositions of ARCs are also intermediate between those of ferromagnesian chondrules and CAIs. They vary from ?39.4‰ to 13.9‰ in δ18O and yield a best fit line (slope = 0.88) close to the carbonaceous chondrite anhydrous mineral (CCAM) line. Chondrules with 5–10 wt% bulk Al2O3 have a slightly more narrow range in δ18O (?32.5 to 5.9‰) along the CCAM line. Except for the ARCs with relict phases, however, most ARCs have oxygen isotope compositions (>?20‰ in δ18O) similar to those of typical ferromagnesian chondrules. ARCs are genetically related to both ferromagnesian chondrules and CAIs, but the relationship between ARCs and ferromagnesian chondrules is closer. Most ARCs were formed during flash heating and rapid cooling processes like normal chondrules, only from chemically evolved precursors. ARCs extremely enriched in Al and those with relict phases could have had a hybrid origin (Krot et al. 2002) which incorporated refractory inclusions as part of the precursors in addition to ferromagnesian materials. The occurrence of melilite in ARCs indicates that melilite‐rich CAIs might be present in the precursor materials of ARCs. The absence of melilite in most ARCs is possibly due to high‐temperature interactions between a chondrule melt and the solar nebula.  相似文献   

4.
Abstract— Cooling rates of chondrules provide important constraints on the formation process of chondrite components at high temperatures. Although many dynamic crystallization experiments have been performed to obtain the cooling rate of chondrules, these only provide a possible range of cooling rates, rather than providing actual measured values from natural chondrules. We have developed a new model to calculate chondrule cooling rates by using the Fe‐Mg chemical zoning profile of olivine, considering diffusional modification of zoning profiles as crystals grow by fractional crystallization from a chondrule melt. The model was successfully verified by reproducing the Fe‐Mg zoning profiles obtained in dynamic crystallization experiments on analogs for type II chondrules in Semarkona. We applied the model to calculating cooling rates for olivine grains of type II porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite. Calculated cooling rates show a wide range from 0.7 °C/h to 2400 °C/h and are broadly consistent with those obtained by dynamic crystallization experiments (10–1000 °C/h). Variations in cooling rates in individual chondrules can be attributed to the fact that we modeled grains with different core Fa compositions that are more Fe‐rich either because of sectioning effects or because of delayed nucleation. Variations in cooling rates among chondrules suggest that each chondrule formed in different conditions, for example in regions with varying gas density, and assembled in the Semarkona parent body after chondrule formation.  相似文献   

5.
Mg‐rich olivine is a ubiquitous phase in type I porphyritic chondrules in various classes of chondritic meteorites. The anhedral shape of olivine grains, their size distribution, as well as their poikilitic textures within low‐Ca pyroxene suggest that olivines suffer dissolution during chondrule formation. Owing to a set of high‐temperature experiments (1450–1540 °C) we determined the kinetics of resorption of forsterite in molten silicates, using for the first time X‐ray microtomography. Results indicate that forsterite dissolution in chondrule‐like melts is a very fast process with rates that range from ~5 μm min?1 to ~22 μm min?1. Forsterite dissolution strongly depends on the melt composition, with rates decreasing with increasing the magnesium and/or the silica content of the melt. An empirical model based on forsterite saturation and viscosity of the starting melt composition successfully reproduces the forsteritic olivine dissolution rates as a function of temperature and composition for both our experiments and those of the literature. Application of our results to chondrules could explain the textures of zoned type I chondrules during their formation by gas‐melt interaction. We show that the olivine/liquid ratio on one hand and the silica entrance from the gas phase (SiOg) into the chondrule melt on the other hand, have counteracting effects on the Mg‐rich olivine dissolution behavior. Silica entrance would favor dissolution by maintaining disequilibrium between olivine and melt. Hence, this would explain the preferential dissolution of olivine as well as the preferential abundances of pyroxene at the margins of chondrules. Incipient dissolution would also occur in the silica‐poorer melt of chondrule core but should be followed by crystallization of new olivine (overgrowth and/or newly grown crystals). While explaining textures and grain size distributions of olivines, as well as the centripetal distribution of low‐Ca pyroxene in porphyritic chondrules, this scenario could also be consistent with the diverse chemical, isotopic, and thermal conditions recorded by olivines in a given chondrule.  相似文献   

6.
We found a large (~2 mm) compound object in the primitive Yamato 793408 (H3.2‐an) chondrite. It consists mostly of microcrystalline material, similar to chondrule mesostasis, that hosts an intact barred olivine (BO) chondrule. The object contains euhedral pyroxene and large individual olivine grains. Some olivine cores are indicative of refractory forsterites with very low Fe‐ and high Ca, Al‐concentrations, although no 16O enrichment. The entire object is most likely a new and unique type, as no similar compound object has been described so far. We propose that it represents an intermediate stage between compound chondrules and macrochondrules, and formed from the collision between chondrules at low velocities (below 1 m s?1) at high temperatures (around 1550 °C). The macrochondrule also trapped and preserved a smaller BO chondrule. This object appears to be the first direct evidence for a genetic link between compound chondrules and macrochondrules. In accordance with previous suggestions and studies, compound chondrules and macrochondrules likely formed by the same mechanism of chondrule collisions, and each represents different formation conditions, such as ambient temperature and collision speed.  相似文献   

7.
Abstract– We report trace element analyses from mineral phases in chondrules from carbonaceous chondrites (Vigarano, Renazzo, and Acfer 187), carried out by laser ablation inductively coupled plasma‐mass spectrometry. Results are similar in all three meteorites. Mesostasis has rare earth element (REE) concentrations of 10–20 × CI. Low‐Ca pyroxene has light REE (LREE) concentrations near 0.1 × CI and heavy REE (HREE) near 1 × CI, respectively. Olivine has HREE concentrations at 0.1–1 × CI and LREE around 10?2 × CI. The coarsest olivine crystals tend to have the most fractionated REE patterns, indicative of equilibrium partitioning. Low‐Ca pyroxene in the most pyroxene‐rich chondrules tends to have the lowest REE concentrations. Type I chondrules seem to have undergone a significant degree of batch crystallization (as opposed to fractional crystallization), which requires cooling rates slower than 1–100 K h?1. This would fill the gap between igneous calcium‐aluminum‐rich inclusions (CAIs) and type II chondrules. The anticorrelation between REE abundances and pyroxene mode may be understood as due to dilution by addition of silica to the chondrule melt, as in the gas‐melt interaction scenario of Libourel et al. (2006). The rapid cooling rate (of the order of 1000 K h?1) which seems recorded by low‐Ca pyroxene, contrasted with the more diverse record of olivine, may point to a nonlinear cooling history or suggest that formation of pyroxene‐rich chondrule margins was an event distinct from the crystallization of the interior.  相似文献   

8.
NWA 2737, the second known chassignite, mainly consists of cumulate olivine crystals of homogeneous composition (Fo = 78.7 ± 0.9). These brown colored olivine grains exhibit two sets of perpendicular planar defects due to shock. Two forms of trapped liquids, interstitial melts and magmatic inclusions, have been examined. Mineral assemblages within the olivine‐hosted magmatic inclusions include low‐Ca pyroxene, augite, kaersutite, fluorapatite, biotite, chromite, sulfide, and feldspathic glass. The reconstructed parental magma composition (A#) of the NWA 2737 is basaltic and resembles both the experimentally constrained parental melt composition of chassiginites and the Gusev basalt Humphrey, albeit with lower Al contents. A# also broadly resembles the average of shergottite parent magmas or LAR 06319. However, we suggest that the mantle source for the chassignite parental magmas was distinct from that of the shergottite meteorites, particularly in CaO/Al2O3 ratio. In addition, based on the analysis of the volatile contents of kaersutite, we derived a water content of 0.48–0.67 wt% for the parental melt. Finally, our MELTS calculations suggest that moderate pressure (approximately 6.8 kb) came closest to reproducing the crystallized melt‐inclusion assemblages.  相似文献   

9.
Abstract— Terminal particles and mineral fragments from comet 81P/Wild 2 were studied in 16 aerogel tracks by transmission and secondary electron microscopy. In eight tracks clinopyroxenes with correlated Na2O and Cr2O3 contents as high as 6.0 wt% and 13.0 wt%, respectively, were found. Kosmochloric (Ko) clinopyroxenes were also observed in 4 chondritic interplanetary dust particles (IDPs). The Ko‐clinopyroxenes were often associated with FeO‐rich olivine ± Cr‐rich spinel ± aluminosilicate glass or albitic feldspar, assemblages referred to as Kool grains (Ko = kosmochloric Ca‐rich pyroxene, ol = olivine). Fine‐grained (submicron) Kool fragments have textures suggestive of crystallization from melts while coarse‐grained (>1 μm) Kool fragments are often glass‐free and may have formed by thermal metamorphism in the nebula. Average major and minor element distributions between clinopyroxenes and coexisting FeO‐rich olivines are consistent with these phases forming at or near equilibrium. In glass‐bearing fine‐grained Kool fragments, high concentrations of Na in the clinopyroxenes are inconsistent with existing experimentally determined partition coefficients at equilibrium. We speculate that the availability of Cr in the melt increased the clinopyroxene Na partition coefficient via a coupled substitution thereby enhancing this phase with the kosmochlor component. The high temperature minerals, fine‐grain sizes, bulk compositions and common occurrence in the SD tracks and IDPs support the idea that Kool grains could have been precursors to type II chondrules in ordinary chondrites. These grains, however, have not been observed in these meteorites suggesting that they were destroyed during chondrule formation and recycling or were not present in the nebula at the time and location where meteoritic chondrules formed.  相似文献   

10.
Abstract– The nakhlites, a subgroup of eight clinopyroxenites thought to come from a single geological unit at the Martian surface, show melt inclusions in augite and olivine. In contrast to olivine‐hosted melt inclusions, augite‐hosted melt inclusions are not surrounded by fractures, and are thus considered preferential candidates for reconstructing parent liquid compositions. Furthermore, two types of augite‐hosted melt inclusion have been defined and characterized in four different nakhlites (Northwest Africa [NWA] 817, Nakhla, Governador Valadares, and NWA 998): Type‐I isolated inclusions in augite cores that contain euhedral to subhedral augite, Ti‐magnetite, and pigeonite plus silica‐rich glass and a gas bubble; Type‐II microinclusions that form trails crosscutting host augite crystals. Fast‐heating experiments were performed on selected pristine primary augite‐hosted melt inclusions from these four samples. Of these, only data from Nakhla were considered robust for reconstruction of a nakhlite parental magma composition (NPM). Based upon careful petrographic selection and consideration of iron‐magnesium ratios, our data are used to propose an NPM, which is basaltic (49.1 wt% SiO2), of high Ca/Al (1.95), and K2O‐poor (0.32 wt%). Thermodynamic modeling at an oxygen fugacity one log unit below the QFM buffer using the MELTS and PETROLOG programs implies that Mg‐rich olivine was not a liquidus phase for this composition. Our analysis is used to suggest that olivine megacrysts found in the nakhlites are unlikely to have coprecipitated with augite, and thus may have been introduced during or subsequent to accumulation in the magma chamber, possibly from more evolved portions of the same chamber.  相似文献   

11.
Abstract Detailed analysis of cumulate and melt inclusion assemblages in the chassignites provide important constraints on the nature of the melt trapped as inclusions in cumulus olivine (and, by extension, parental magma compositions), the pressures of crystallization, and magmatic volatile contents. These mineral assemblages show strong similarities to the experimental fractionation assemblages that produce the sodic silica‐saturated alkalic lavas on Earth (e.g., Ascension Island, Azores, the Nandewar volcano of Australia). The experimental assemblages were produced from silica‐saturated hawaiite at pressures above 4.3 kbar with dissolved water contents above 0.5 wt%. Such pressures are consistent with Ti:Al ratios of the melt‐inclusion pyroxenes in the Chassigny meteorite. Pyroxene compositions suggest early high crystallization temperatures and thus relatively low initial water and F contents. Feldspars indicate that melt evolution proceeded to rhyolite compositions both within the interstices of the cumulate olivine and within the melt inclusions, even though rhyolitic glass is only found within olivine‐hosted polyphase melt inclusions. The observed rhyolite glass is compositionally similar to the alkali‐rich rhyolite of Ascension Island which is produced experimentally by crystallization of hawaiite. It is proposed that the melt trapped in cumulus olivine of the Chassigny dunite was similar to a terrestrial silica‐saturated hawaiite, while that trapped in olivine of the Northwest Africa (NWA) 2727 dunite was less evolved, perhaps mildly alkalic basalt. Melts similar to terrestrial intra‐plate tholeiite could be parental to the cumulus minerals and evolve upon crystallization at pressures above 4.3 kbar and water contents above ?0.4 wt% to mildly alkalic basalt, silica‐saturated hawaiite, and alkali‐rich rhyolite. The melt inclusion assemblages are inconsistent with either crystallization of a low‐Al, high‐Fe basalt, or low‐pressure crystallization of a terrestrial‐like tholeiite.  相似文献   

12.
We report microscopic, cathodoluminescence, chemical, and O isotopic measurements of FeO‐poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2‐ung), Northwest Africa 11086 (CM2‐an), and Allan Hills 77307 (CO3.0). The general petrographic, chemical, and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand‐alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO‐rich refractory forsterites, which are restricted to ?17O <?4‰ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule‐forming regions.  相似文献   

13.
Abstract— Anorthite‐rich chondrules in CR and CH carbonaceous chondrites consist of magnesian low‐Ca pyroxene and forsterite phenocrysts, FeNi‐metal nodules, interstitial anorthite, Al‐Ti‐Cr‐rich low‐Ca and high‐Ca pyroxenes, and crystalline mesostasis composed of silica, anorthite and high‐Ca pyroxene. Three anorthite‐rich chondrules contain relic calcium‐aluminum‐rich inclusions (CAIs) composed of anorthite, spinel, ±Al‐diopside, and ± forsterite. A few chondrules contain regions which are texturally and mineralogically similar to magnesian (type I) chondrules and consist of forsterite, low‐Ca pyroxene and abundant FeNi‐metal nodules. Anorthite‐rich chondrules in CR and CH chondrites are mineralogically similar to those in CV and CO carbonaceous chondrites, but contain no secondary nepheline, sodalite or ferrosilite. Relatively high abundances of moderately‐volatile elements such as Cr, Mn and Si in the anorthite‐rich chondrules suggest that these chondrules could not have been produced by volatilization of the ferromagnesian chondrule precursors or by melting of the refractory materials only. We infer instead that anorthite‐rich chondrules in carbonaceous chondrites formed by melting of the reduced chondrule precursors (olivine, pyroxenes, FeNi‐metal) mixed with the refractory materials, including relic CAIs, composed of anorthite, spinel, high‐Ca pyroxene and forsterite. The observed mineralogical and textural similarities of the anorthite‐rich chondrules in several carbonaceous chondrite groups (CV, CO, CH, CR) may indicate that these chondrules formed in the region(s) intermediate between the regions where CAIs and ferromagnesian chondrules originated. This may explain the relative enrichment of anorthite‐rich chondrules in 16O compared to typical ferromagnesian chondrules (Russell et al., 2000).  相似文献   

14.
Abstract— We have studied a unique impact-melt rock, the Ramsdorf L chondrite, using optical and scanning microscopy and electron microprobe analysis. Ramsdorf contains not only clast-poor impact melt (Begemann and Wlotzka, 1969) but also a chondritic portion (>60 g) with what appears at low magnification to be a normal, well-defined chondritic texture. However, detailed studies at high magnification show that >90 vol% of the crystals in the chondritic portion were largely melted by the impact: the chondrules lack normal microtextures and are ghosts of the original features. The only relics from the precursor chondrules are olivine crystals, which have the highest melting temperature (～1620 °C). Pyroxene-rich chondrules were so extensively melted that no phenocrysts were preserved and the melt crystallized in situ before significant mixing with exterior olivine-rich melts. Fine-grained pyroxene chondrule ghosts have sharper boundaries with the matrix than porphyritic olivine and pyroxene chondrule ghosts, probably because pyroxene-rich melts are significantly more viscous. Complex textures that formed by injection of melt along cracks and fractures in relic olivines suggest that the chondritic portion of Ramsdorf formed directly from petrologic type 3–4 material by strong shock. We infer that Ramsdorf was largely melted by shock pressures of ～75–90 GPa and that chondrule ghosts and relic olivine phenocrysts were locally preserved by rapid cooling. Quenching was not due to the addition of cold clasts into the melt but to heterogeneous shock heating that only caused internal melting of large olivines and pyroxenes. Ramsdorf appears to be one of the most heavily shocked meteorites that has retained some trace of its original texture.  相似文献   

15.
Abstract— Plagioclase‐rich chondrules (PRCs) in the reduced CV chondrites Efremovka, Leoville, Vigarano and Grosvenor Mountains (GRO) 94329 consist of magnesian low‐Ca pyroxene, Al‐Ti‐Cr‐rich pigeonite and augite, forsterite, anorthitic plagioclase, FeNi‐metal‐sulfide nodules, and crystalline mesostasis composed of silica, anorthitic plagioclase and Al‐Ti‐Cr‐rich augite. The silica grains in the mesostases of the CV PRCs are typically replaced by hedenbergitic pyroxenes, whereas anorthitic plagioclase is replaced by feldspathoids (nepheline and minor sodalite). Some of the PRCs contain regions that are texturally and mineralogically similar to type I chondrules and consist of forsterite, low‐Ca pyroxene and abundant FeNi‐metal nodules. Several PRCs are surrounded by igneous rims or form independent compound objects. Twelve PRCs contain relic calcium‐aluminum‐rich inclusions (CAIs) composed of anorthite, spinel, high‐Ca pyroxene, ± forsterite, and ± Al‐rich low‐Ca pyroxene. Anorthite of these CAIs is generally more heavily replaced by feldspathoids than anorthitic plagioclase of the host chondrules. This suggests that either the alteration predated formation of the PRCs or that anorthite of the relic CAIs was more susceptible to the alteration than anorthitic plagioclase of the host chondrules. These observations and the presence of igneous rims around PRCs and independent compound PRCs suggest that the CV PRCs may have had a complex, multistage formation history compared to a more simple formation history of the CR PRCs. Relatively high abundances of moderately‐volatile elements such as Cr, Mn and Si in the PRCs suggests that these chondrules could not have been produced by volatilization of ferromagnesian chondrule precursors or by melting of refractory materials only. We infer instead that PRCs in carbonaceous chondrites formed by melting of the reduced chondrule precursors (magnesian olivine and pyroxene, FeNi‐metal) mixed with refractory materials (relic CAIs) composed of anorthite, spinel, high‐Ca pyroxene, and forsterite. The mineralogical, chemical and textural similarities of the PRCs in several carbonaceous chondrite groups (CV, CO, CH, CR) and common presence of relic CAIs in these chondrules suggest that PRCs may have formed in the region(s) intermediate between the regions where CAIs and ferromagnesian chondrules originated.  相似文献   

16.
Several olivine‐phyric shergottites contain enough olivine that they could conceivably represent the products of closed‐system crystallization of primary melts derived from partial melting of the Martian mantle. Larkman Nunatak (LAR) 06319 has been suggested to represent a close approach to a Martian primary liquid composition based on approximate equilibrium between its olivine and groundmass. To better understand the olivine–melt relationship and the evolution of this meteorite, we report the results of new petrographic and chemical analyses. We find that olivine megacryst cores are generally not in equilibrium with the groundmass, but rather have been homogenized by diffusion to Mg# 72. We have identified two unique grain types: an olivine glomerocryst and an olivine grain preserving a primary magmatic boundary that constrains the time scale of eruption to be on the order of hours. We also report the presence of trace oxide phases and phosphate compositions that suggest that the melt contained approximately 1.1% H2O and lost volatiles during cooling, also associated with an increase in oxygen fugacity upon degassing. We additionally report in situ rare earth element measurements of the various mineral phases in LAR 06319. Based on these reported trace element abundances, we estimate the oxygen fugacity in the LAR 06319 parent melt early in its crystallization sequence (i.e., at the time of crystallization of the low‐Ca and high‐Ca pyroxenes), the rare earth element composition of the parent melt, and those of melts in equilibrium with later formed phases. We suggest that LAR 06319 represents the product of closed‐system crystallization within a shallow magma chamber, with additional olivine accumulated from a cumulate pile. We infer that the olivine megacrysts are antecrysts, derived from a single magma chamber, but not directly related to the host magma, and suggest that mixing of antecrysts within magma chambers may be a common process in Martian magmatic systems.  相似文献   

17.
Abstract— A new, large, ordinary chondrite has been recovered from near the strewn field of Gibeon iron meteorites in Namibia, and is designated Korra Korrabes, after the farm property on which the specimens were found in 1996–2000. A total of ～140 kg of related specimens were recovered, including a large stone of 22 kg, and hundreds of smaller objects between 2 g and several kilograms. Cut surfaces indicate that Korra Korrabes is a breccia, containing 10–20% of light grey‐brown clasts up to 3 cm across in a uniform, darker grey‐brown host that contains abundant round chondrules, and irregular grains of Fe‐Ni metal and troilite up to 1 cm across. The vast majority of the stone is unshocked, although some clasts show mild shock features (stage S2), and one chondrule fragment is moderately shocked (stage S3). Weathering grade varies between W1 and W2. Microprobe analyses indicate variable compositions of olivine (Fa13.8–27.2, n = 152, percent mean deviation = 7.82%) and low‐Ca pyroxene (multiply twinned clinobronzite, Fs8.4–27.8, n = 68). There is excellent preservation of magmatic textures and mineralogy within many chondrules, including normally zoned olivine (Fa13.8–18.9) and low‐Ca pyroxene (Fs0.2–20.9) phenocrysts, and abundant glass, some of whose compositions are unusually alkaline (Na2O + K2O = 13.6–16.3 wt%) and Ca‐deficient (CaO = 0‐0.75 wt%), seemingly out of magmatic equilibrium with associated clinoenstatite or high‐Al calcic clinopyroxene crystals. Textural and mineralogical features indicate that Korra Korrabes is an H3 chondrite breccia, which represents the largest and least equilibrated stony meteorite yet recovered from Namibia; it is now one of the four largest unequilibrated ordinary chondrites worldwide.  相似文献   

18.
Abstract— Crystal‐bearing lunar spherules (CLSs) in lunar breccia (14313, 14315, 14318), soil (68001, 24105), and impact‐melt rock (62295) samples can be classified into two types: feldspathic and olivine‐rich. Feldspathic CLSs contain equant, tabular, or acicular plagioclase grains set in glass or a pyroxene‐olivine mesostasis; the less common olivine‐rich CLSs contain euhedral or skeletal olivine set in glass, or possess a barred‐olivine texture. Bulk‐chemical and mineral‐chemical data strongly suggest that feldspathic CLSs formed by impact melting of mixtures of ferroan anorthosite and Mg‐suite rocks that compose the feldspathic crust of the Moon. It is probable that olivine‐rich CLSs also formed by impact melting, but some appear to have been derived from distinctively magnesian lunar materials, atypical of the Moon's crust. Some CLSs contain reversely‐zoned “relic” plagioclase grains that were not entirely melted during CLS formation, thin (≤5 μm thick) rims of troilite or phosphate, and chemical gradients in glassy mesostases attributed to metasomatism in a volatile‐rich (Na‐K‐P‐rich) environment. Crystal‐bearing lunar spherules were rimmed and metasomatized prior to brecciation. Compound CLS objects are also present; these formed by low‐velocity collisions in an environment, probably an ejecta plume, that contained numerous melt droplets. Factors other than composition were responsible for producing the crystallinity of the CLSs. We agree with previous workers that relatively slow cooling rates and long ballistic travel times were critical features that enabled these impact‐melt droplets to partially or completely crystallize in free‐flight. Moreover, incomplete melting of precursor materials formed nucleation sites that aided subsequent crystallization. Clearly, CLSs do not resemble meteoritic chondrules in all ways. The two types of objects had different precursors and did not experience identical rimming processes, and vapor fractionation appears to have played a less important role in establishing the compositions of CLSs than of chondrules. However, the many detailed similarities between CLSs and chondrules indicate that it is more difficult to rule out an origin for some chondrules by impact melting than some have previously argued. Differences between CLSs, chondrules, and their host rocks possibly can be reconciled with an impact‐melt origin for some chondrules when different precursors, the higher gravity of the Moon compared to chondrite parent bodies, and the likely presence of nebular gas during chondrule formation are taken into account.  相似文献   

19.
Abstract— We performed a detailed study of silica‐rich components (SRC) in the paired CH chondrites Acfer 182 and 207. These SRCs appear either as chondrules or fragments, and they contribute <0.1 vol% to the bulk meteorite. They usually contain a silica and a silicate portion. Both portions are, in most cases, cryptocrystalline and have bulk SiO2‐concentrations between 65 and 85 wt%. The silicate generally has a pyroxene normative composition. The silica often appears as blebs within the silicate matrix or vice versa. If there are no blebs, silica and silicate still form rounded interfaces. The SRCs are depleted in refractory elements like Ca, Al, and Ti relative to CI. A few SRC‐like objects are extremely rich in Mn and show no depletion in refractory elements. We conducted micro‐Raman studies on the silica portions of the SRCs to determine their structure, and we identified several silica phases: α‐quartz, cristobalite, glass, and a yet unidentified polymorph. The silicate portion is glass when the silica is glass and crystalline when the silica is crystalline. The low contents of Al and Ca make an igneous origin of the SRCs very unlikely, and the absence of metal excludes the formation by reduction of pyroxene. We suggest, instead, a fractional condensation origin of the SRCs from a Si‐enriched gas after removal of gaseous Mg by forsterite condensation. Additional evidence for fractional condensation is provided by a unique layered object with olivine in the core, pyroxene and metal at the rim, and silica at the outermost border; these layers record the condensation sequence. Two chondrules were found with several percent of Mn and high Cr, Na, and K contents, providing further evidence for condensation from a fractionated gas. The texture of the SRCs and the occurrence of cristobalite and silica glass, however, require formation by liquid immiscibility at high temperatures, above 1968 K, and subsequent fast cooling. Therefore, we propose a 2‐stage model for the formation of SRCs in CH chondrites: 1) fractional condensation of forsterite, enstatite, and SiO2‐rich phases; and 2) reheating of SiO2‐rich components to temperatures above 1968 K followed by rapid cooling. All other phases identified in CH chondrites can be understood within the framework of this model. Thus, the extremely unequilibrated CH chondrites provide a wealth of evidence for fractional condensation processes in the early solar nebula, in metals (Meibom et al. 1999), and in silicates.  相似文献   

20.
Abstract— To assess whether the alkali behavior observed in chondrules of primitive meteorites is attributable to volatilization from the raw materials of chondrules during chondrule formation events or attributable to condensation processes from the nebular gas, we set up a new experimental device able to expose silicate melt samples to a controlled alkali partial pressure at high temperature under fixed O fugacity. Using a mixture of potassium carbonate (K2CO3) and graphite (C) as the source of the K gas (Kg), we studied the condensation kinetics of K and its solubility in CaO‐MgO‐Al2O3‐SiO2 silicate melts, according to the reaction 2 K (g) + 1/2 (g) = K2O (melt) From these results, we show that alkali entering in chondrules from the nebular gas is a viable mechanism to explain the chondrules alkali contents and their δ41K‐isotopic signatures, at timescales relevant to chondrule formation. Finally, we also suggest that chondrules may have formed in non‐canonical nebular environments and that the flash‐heating scenario is not a prerequisite to chondrule formation.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号