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1.
The effect of fluorine on the solubilities of Mn-columbite (MnNb2O6), Mn-tantalite (MnTa2O6), zircon (ZrSiO4) and hafnon (HfSiO4) were determined in highly fluxed, water-saturated haplogranitic melts at 800 to 1000 °C and 2 kbar. The melt composition corresponds to the intersection of the granite minimum with the albite–orthoclase tieline (Ab72Or28) in the quartz–albite–orthoclase system (Q–Ab–Or), which is representative of a highly fluxed melt, from which high field strength element minerals may crystallize. The melt contains 1.7 wt.% P2O5, 1.05 wt.% Li2O and 1.83 wt.% B2O3. The main purpose of this study is to examine the effect of F on columbite, tantalite, zircon and hafnon solubility for a melt with this composition. Up to 6 wt.% fluorine was added as AgF in order to keep the aluminum saturation index (ASI, molar Al/[Na + K]) of the melt constant. In an additional experiment F was added as AlF3 to make a glass peraluminous. The nominal ASI of the melts are close to 1 for the minimum composition and approximately 1.32 in peraluminous glasses, but if Li is considered as an alkali, the molar ratio Al/[Na + K + Li] of the melts are alkaline (0.87) and subaluminous (1.09), respectively.The molar solubility products [MnO] 1 [Nb2O5] and [MnO] 1 [Ta2O5] are nearly independent of the F content of the melt, at approximately 18.19 ± 1.2 and 43.65 ± 2.5 × 10− 4 (mol2/kg2), respectively for the minimum composition. By contrast, there is a positive dependence of zircon and hafnon solubilities on the fluorine content in the minimum composition, which increases from 2.03 ± 0.03 × 10− 4 (mol/kg) ZrO2 and 4.04 ± 0.2 × 10− 4 (mol/kg) HfO2 for melts with 0 wt.% F to 3.81 ± 0.3 × 10− 4 (mol/kg) ZrO2 and 6.18 ± 0.04 × 10− 4 (mol/kg) HfO2 for melts with 8 wt.% F. Comparison of the data from this work and previous studies indicates that ASI of the melt seems to have a stronger effect than the contents of fluxing elements in the melt and the overall conclusion is that fluorine is less important (relative to melt compositions) than previously thought for the control on the behavior of high field strength elements in highly evolved granitic melts. Moreover, this study confirms that although Nb, Ta, Zr and Hf are all high field strength elements, Nb–Ta and Zr–Hf are complexed differently in the melt.  相似文献   

2.
Small granitoids emplaced into the early Jurassic volcani-clastic succession in the Yusufeli area, northeastern Turkey, can be temporally and geochemically classified into two groups: early Jurassic low-K and late Jurassic high-K. 40Ar–39Ar hornblende analyses yielded 188.0 ± 4.3 Ma for the Dutlup?nar intrusion, dating the subduction related rifting in the region. It comprises metaluminous to weakly peraluminous (ASI = 0.94–1.11) granodiorite and, to a lesser extent, tonalite whose K2O-poor (< 2.04 wt.%) nature and weak negative Eu anomalies (Eu/Eu? = 0.9–0.7) preclude derivation by fractional crystallization from a K-rich melt. Sr, Nd and Pb isotopic data reveal derivation by partial melting from an already cooled tholeiitic basic rocks which had mantle-like isotope signature. The Sumbated intrusion formed in the late Jurassic (153.0 ± 3.4 Ma) and consists chiefly of metaluminous (ASI = 0.84–0.99) quartz monzodiorite. Medium to high-K2O, relatively high MgO and Sr contents, flat HREE patterns without prominent Eu anomalies, slightly positive εNd(t) values (+ 1.5 to + 2.5) and low ISr ratios (0.7046–0.7056) are consistent with an origin by dehydration melting of a juvenile source, above the garnet stability field, dominated by likely K-amphibole bearing calc-alkaline mafic rocks. Geochemical data show that fractional crystallization from a Sumbated-like quartz monzodioritic magma is the fundamental process responsible for the evolved compositional range of the Keçikaya intrusion. The geochemical and geochronological data presented here indicate that the late Jurassic magmatism occurred in a post-collisional setting. Slab-breakoff, which was followed by shortly after collision, seems to be the most plausible mechanism for the generation of medium to high-K calc-alkaline rocks of the Sumbated and the Keçikaya intrusions, indicating a switch in the geodynamic setting, e.g., from pre-collision to post-collision in the middle Jurassic in the eastern Pontides.  相似文献   

3.
The behavior of tantalum and zirconium in pegmatitic systems has been investigated through the determination of Ta and Zr solubilities at manganotantalite and zircon saturation from dissolution and crystallization experiments in hydrous, Li-, F-, P- and B-bearing pegmatitic melts. The pegmatitic melts are synthetic and enriched in flux elements: 0.7–1.3 wt% Li2O, 2–5.5 wt% F, 2.8–4 wt% P2O5 and 0–2.8 wt% B2O3, and their aluminum saturation index ranges from peralkaline to peraluminous (ASILi = Al/[Na + K + Li] = 0.8 to 1.3) with various K/Na ratios. Dissolution and crystallization experiments were conducted at temperatures varying between 700 and 1,150°C, at 200 MPa and nearly water-saturated conditions. For dissolution experiments, pure synthetic, end member manganotantalite and zircon were used in order to avoid problems with slow solid-state kinetics, but additional experiments using natural manganotantalite and zircon of relatively pure composition (i.e., close to end member composition) displayed similar solubility results. Zircon and manganotantalite solubilities considerably increase from peraluminous to peralkaline compositions, and are more sensitive to changes in temperature or ASI of the melt than to flux content. A model relating the enthalpy of dissolution of manganotantalite to the ASILi of the melt is proposed: ∆H diss (kJ/mol) = 304 × ASILi − 176 in the peralkaline field, and ∆H diss (kJ/mol) = −111 × ASILi + 245 in the peraluminous field. The solubility data reveal a small but detectable competitivity between Zr and Ta in the melt, i.e., lower amounts of Zr are incorporated in a Ta-bearing melt compared to a Ta-free melt under the same conditions. A similar behavior is observed for Hf and Ta. The competitivity between Zr (or Hf) and Ta increases from peraluminous to peralkaline compositions, and suggests that Ta is preferentially bonded to non-bridging oxygens (NBOs) with Al as first-neighbors, whereas Zr is preferentially bonded to NBOs formed by excess alkalies. As a consequence Zr/Ta ratios, when buffered by zircon and manganotantalite simultaneously, are higher in peralkaline melts than in peraluminous melts.  相似文献   

4.
We conducted a geochronological and geochemical study on the Paleoproterozoic potassic granites in the Lushan area, southern margin of the North China Craton (NCC) to understand the tectonic regime of the NCC at 2.2–2.1 Ga. This rock suite formed at 2194 ± 29 Ma. The rocks are rich in SiO2 (76.10–77.73 wt.%), and K2O (5.94–6.90 wt.%) with high K2O + Na2O contents from 7.56 wt.% to 8.48 wt.%, but poor in CaO (0.10–0.28 wt.%), P2O5 (0.02–0.05 wt.%) and MgO (0.01–0.30 wt.%, Mg# = 1.08–27.3), indicating they experienced fractional crystallization. Major element compositions suggest the potassic granites share an affinity with high K calc-alkaline granite. Even though the Lushan potassic granitic rocks have high A/CNK ratios (1.11–1.25), which can reach peraluminous feature, the very low P2O5 contents and negative correlation of P2O5 and SiO2 ruling out they are S-type granites. Different from peralkaline A-type granites, the Lushan potassic granites have variable Zr concentrations (160–344 ppm, 226 ppm on average) and 10,000 Ga/Al ratios (1.76–3.00), together with high zircon saturation temperatures (TZr = 826–885 °C), indicating they are fractionated aluminous A-type granites. Enriched LREE ((La/Yb)N = 9.72–81.8), negative Eu anomalies, and low Sr/Y with no correlations in Sr/Y and Sr/Zr versus CaO suggest the possible presence of Ca-rich plagioclase and absence of garnet in the residual. Magmatic zircon grains have variable εHf(t) values (−2.4 to +7.3) with zircon two-stage Hf model ages (TDMC) varying from 2848 Ma to 2306 Ma (mostly around ca. 2.5 Ga), and are plotted in the evolution line of crustal felsic rock. We propose that the rocks mainly formed by partial melting of ca. 2.50 Ga tonalitic–granodioritic crust as a result of upwelling mantle-derived magmas which provided thermal flux and source materials in an intra-continent rifting. The ca. 2.2 Ga magmatism suggests that intra-continental rifting occurred at 2.35–1.97 Ga at least in the southern margin of the NCC after its final cratonization in the late Neoarchean.  相似文献   

5.
Yudai is a newly discovered copper deposit associated with a porphyritic quartz diorite, in the Kalatag district of the eastern Tianshan, China. SHRIMP U-Pb dating of zircons from the diorite yielded an age of 432 ± 3 Ma. The diorite is peraluminous (ASI = 0.98–1.10), calc-alkaline to tholeiitic with high Al2O3 of 16.6–17.7 wt% and Mg# of 57.4–67.4. Trace element characteristics of the diorite show it is enriched in Ba, K and Sr, and depleted in Nb, Ta, Ti, with a positive Eu anomaly and high Sr/Y and La/Yb ratios. This diorite has positive εNd(t) values ranging from 6.2 to 8.4 with low initial 87Sr/86Sr ratios of 0.704336 to 0.704450. These geochemical and isotopic characteristics indicate that the adakite-like diorite, associated with the copper mineralization, was emplaced in an island arc setting and resulted from partial melting of subducted oceanic plate in a mantle wedge.  相似文献   

6.
The Late Cretaceous bimodal Yunshan (Yongtai) volcanics in Fujian province contain peralkaline rhyolites, the only presence of such rhyolites in southeastern China. Whole-rock and mineral chemical compositions are analyzed for the coexisting aluminous (metaluminous to weakly peraluminous)-peralkaline high-silica rhyolites from the Yunshan volcanics. They are sparsely porphyritic, and contain K-feldspar, ferromagnesian minerals, quartz, magnetite, and titanomagnetite phenocrysts, as well as accessory minerals such as fayalite, chevkinite, apatite and zircon. The mineral assemblage indicates an oxidizing pre-eruption condition. These rhyolites exhibit diagnostic geochemical features of A-type granites, such as elevated 104 * Ga/Al (mostly greater than 2.6) and FeOT/(FeOT + MgO) ratios, enrichment in high field strength elements (HFSE) such as Zr (>400 ppm) and Nb, and strong depletion in Al2O3 (<13 wt%), CaO, Ba and Sr. On the basis of their petrographic and geochemical characteristics, it is suggested that the rhyolite magmas are derived from partial melting of H2O-poor (meta) granitic igneous rocks in the deep crust, and cannot be fractionated from the coeval Yunshan mafic magmas. Geochemical variations of major and trace elements indicate the possible fractionation of K-feldspar, calcium-rich pyroxene, Fe–Ti oxides and minor chevkinite during the magma evolution. In peralkaline rhyolites, we found that the pre-existing Fe–Ti oxide and hedenbergite phenocrysts had been transformed into aegirine + oxide and aegirine + oxide + fluorite assemblages, respectively. These mineral assemblages are the products of the subsolidus reaction of pre-existing phenocrysts and extraneous Na–F-rich fluids. Such Na–F-rich fluids may be derived from the degassing of the subvolcanic rocks. The reactions indicate that the Yunshan peralkaline rhyolites could be generated through the reaction of highly fractionated aluminous silica magmas and Na–F-rich fluids.  相似文献   

7.
Early Paleozoic peraluminous granites are abundant in the eastern part of the Qilian orogen, northeastern margin of the Tibetan Plateau. A combined study involving geochronology, whole-rock geochemical and Sr–Nd–Hf isotopic compositions for three Early Paleozoic peraluminous granitic plutons (Jishishan, Ledu and Shichuan plutons) from the eastern Qilian orogen was carried out to evaluate the causes of chemical variations and generation mechanisms of peraluminous granitic magmas. These granitic plutons have magma crystallization ages of 455–427 Ma and are moderately to strongly peraluminous (A/CNK = 1.03–1.18). Geochemical and Sr–Nd–Hf isotopic data indicate that they consist substantially of crust-derived melts. The Jishishan and Ledu peraluminous granites were dominantly produced by partial melting of Precambrian orthogneisses. The Shichuan monzogranites, with low HREE contents (e.g., Yb = 0.80–1.83 ppm) and slightly negative εNd(t) (− 5.3 to − 2.3) and positive εHf(t) (+ 1.6 to + 3.4), could be derived from immature crustal materials. Relatively high average zircon saturation temperatures (> 750 °C for each pluton), obvious negative Eu anomalies (Eu/Eu* = 0.28–0.80) and low Pb/Ba ratios (0.03–0.16) for the Jishishan, Ledu and Shichuan granites are consistent with crustal melting involving biotite breakdown under fluid-absent conditions. Our results suggest that compositional variations of moderately to strongly peraluminous granitic magmas are mainly controlled by source compositions and melting conditions, while the processes such as mixing with mantle-derived magma, fractional crystallization, restite unmixing and peritectic assemblage entrainment were insignificant (or only play secondary roles) in their genesis. Late Ordovician to Middle Silurian crustal anatexis in the eastern Central Qilian was probably linked with slab break-off which may be an important mechanism in addition to lithospheric delamination for the generation of moderately to strongly peraluminous granites in a post-collisional setting.  相似文献   

8.
This work describes the in situ analysis of loparite [(Na,REE)Ti2O6], a perovskite group mineral with extremely low Rb/Sr ratios and high rare earth contents, by LA-(MC)-ICP-MS for the determination of U–Pb ages together with Sr and Nd isotopic composition. The reliability of these data were validated by analysis of a loparite standard by TIMS solution methods. Data are given for loparite from the Lovozero and Khibiny peralkaline complexes of the Kola Alkaline Province (Russia). For Lovozero loparite the Tera–Wasserburg intercept age for 15 loparites analysed is 373 ± 11 Ma, and the weighted 207Pb corrected 206Pb/238U age is 373 ± 2 Ma. For Khibiny loparite, the intercept age for 5 loparites analysed is 375 ± 10 Ma, and the weighted 207Pb corrected 206Pb/238U age is 374 ± 3 Ma. The common Pb compositions for Lovozero and Khibiny loparites are identical i.e. 207Pb/206Pb = 0.898 ± 0.009 and 0.898 ± 0.007, respectively. The 87Sr/86Sr initial ratios of Lovozero loparite range from 0.703552 to 0.703682 (av. 0.703611), and εNd (t370) from + 3.8 to + 4.4 (av. + 4.0). The 87Sr/86Sr initial ratios of Khibiny loparite range from 0.703560 to 0.703871, and εNd (t730) from + 4.0 to + 4.8. Our data indicate that in situ LA-(MC)-ICP-MS analysis of loparite provides accurate and precise estimates of the intrusion ages and isotopic composition of peralkaline rocks.  相似文献   

9.
The Paleozoic granitoids of the Sierra de San Luis comprise the Ordovician tonalite suite (OTS; metaluminous to mildly peraluminous calcic tonalite–granodiorites) and granodiorite–granite suite (OGGS; peraluminous calcic to calc-alkaline granodiorite–monzogranites), as well as the Devonian granite suite (DGS; peraluminous alkali-calcic monzogranites) and monzonite–granite suite (DMGS; metaluminous alkali-calcic quartz monzonite–monzogranite ± granodiorite, mildly peraluminous alkalicalcic monzogranites). The OTS has relatively high K2O, CaO, and YbN and low Cr, Ni, Ba, Sr, Rb/Sr, Sr/Y, and (La/Yb)N, as well as negative Eu/Eu1, high 87Sr/86Sr (0.70850–0.71114), and unradiogenic εNd(470Ma) (−5.3 to −6.0), which preclude an origin of variably fractionated mantle melts and favour a mafic lower crustal source. The OGGS consists of two granitoids: (1) high-temperature characterized by low Al2O3/TiO2, Rb/Sr, and (La/Yb)N, a smooth negative Eu/Eu1, and relatively high CaO and (2) low-temperature with high Al2O3/TiO2 and Rb/Sr, low CaO, (La/Yb)N, and Sr/Y, and negative Eu/Eu1. Melting of metagreywackes at pressures below 10 kbar with a variable supply of water could account for the chemistry of the high-T OGGS, whereas dehydration melting of biotite-bearing metasedimentary sources at low pressures is proposed for the low temperature OGGS. Melting of crustal sources relates to a contemporaneous mafic magmatism.Devonian magmatism is characterized by high Ba, Sr, K2O, Na2O, Sr/Y, and (La/Yb)N. Sources for the DGS include metasedimentary or metatonalitic protoliths. Biotite dehydration melting triggered by the addition of heat, supplied by mantle-derived magmas, is proposed. High Ba, Sr, LREE, MgO, Cr, Ni, Zr, and V of the monzonites suggest an enriched lithospheric mantle source. Low Yb and Y and high Sr and (La/Yb)N indicate a garnet-rich residual assemblage (P ⩾ 10 kbar). Melts for the peraluminous rocks may have derived from a metasedimentary or metaigneous source at lower pressures in a process dominated by biotite consumption and plagioclase in the residue.The Ordovician granitoids are synkinematic with compressive deformation related to the early stages of Famatinian convergence. The Devonian magmatism is synkinematic with a system of shear zones that were active during the Achalian cycle.  相似文献   

10.
The Tumen molybdenite–fluorite vein system is hosted by carbonate rocks of the Neoproterozoic Luanchuan Group, located on the southern margin of the North China Craton (NCC) in central China. Previous studies divided the mineralization into four stages according to the crosscutting relationships between veinlets and their mineral assemblages. In this contribution, two distinctive types of fluorite mineralization are recognized: 1) the first type (Type 1) includes colourless, white or green fluorite grains present in Stage 1 veins; and 2) the second type includes Type 2a purple fluorite present in Stage 2 veins and does not coexist with sulfides, and Type 2b purple fluorite crystals associated with sulfides in Stage 2 veins. The rare earth element (REE) content in the fluorite ranges between 13.8 and 27.9 ppm in Type 1, 16.9 and 27.2 ppm in Type 2a, and 42.5 and 75.1 ppm in Type 2b, which suggests that the fluorite was precipitated from acidic fluids (given that REEs are mobile in saline HCl-bearing fluids at high temperature (~ 400 °C)). Comparing the REE chemistry of the Stage 1 against Stage 2 fluorite, the LREE/HREE ratios decrease from 9.8 to 4.0, La/Yb ratios decrease from 16.0 to 6.9 and La/Ho ratios decrease from 10.2 to 3.0, indicating that the hydrothermal process was at high-T and low-pH conditions. The Eu/Eu* ratios in the fluorite decrease from 1.11 ± 0.35 for Type 1 through 0.89 ± 0.19 for Type 2a to 0.75 ± 0.17 for Type 2b, suggesting a gradual increase in oxygen fugacity (fO2) and pH of the mineralising fluid. The Tb/Ca, Tb/La and Y/Ho ratios of the fluorite types indicate that they were formed from the interaction between magmatic fluids and carbonate wallrocks. The fluorite samples show similar REE + Y (REY) patterns to those of dolostone units in the Luanchuan Group and the nearby Neoproterozoic syenite, suggesting that the REY in the fluorite was mainly sourced from the host-rocks, although the syenite could be an additional minor source.  相似文献   

11.
The polymetallic Mykonos vein system in the Cyclades, Greece, consists of 15 tension-gashes filled with barite, quartz, pyrite, sphalerite, chalcopyrite and galena in ca. 13.5 Ma, I-type, Mykonos monzogranite. Zones of silica and chlorite–muscovite alteration are associated with the veins and overprint pervasive silicification, phyllic and argillic alteration that affected large parts of the monzogranite. The mineralization cements breccias and consists of an early barite–silica–pyrite–sphalerite–chalcopyrite assemblage followed by later argentiferous galena. A combination of fluid inclusion and stable isotope data suggests that the barite and associated mineralization were deposited from fluids containing 2 to 17 wt.% NaCl equivalent, at temperatures of ~ 225° to 370 °C, under a hydrostatic pressure of ≤ 100 bars. The mineralizing fluids boiled and were saturated in H2S and SO2.Calculated δ18OH2O and δDH2O, initial 87Sr/86Sr isotope compositions and the trace and REEs elements contents are consistent with a model in which the mineralizing fluids were derived during alteration of the Mykonos intrusion and subsequently mixed with Miocene seawater. Heterogeneities in the calculated δ34SSO4− 2 and δ34SH2S compositions of the ore fluids indicate two distinct sources for sulfur, namely of magmatic and seawater origin, and precipitation due to reduction of the SO4− 2 during fluid mixing. The physicochemical conditions of the fluids were pH = 5.0 to 6.2, logfS2 = − 13.8 to − 12.5, logfO2 = − 31.9 to − 30.9, logfH2S(g) = − 1.9 to − 1.7, logfTe2 = − 7.9 and logα(SO4− 2(aq)/H2S(aq)) = + 2.6 to + 5.5. We propose that retrograde mesothermal hydrothermal alteration of the Mykonos monzogranite released barium and silica from the alkali feldspars. Barite was precipitated due to mixing of SO4− 2-rich Miocene seawater with the ascending Ba-rich magmatic fluid venting upwards in the pluton.  相似文献   

12.
《Applied Geochemistry》2005,20(6):1099-1105
Fluorite is one of the secondary minerals precipitated in pore spaces at the future nuclear waste repository site at Yucca Mountain, Nevada. The authors have conducted (U–Th)/He dating of this fluorite in an attempt to constrain the temperature and timing of paleo-fluid flux into the site. Repeated analysis of colourless fluorite yielded a weighted average age of 9.7 ± 0.15 Ma (2σ), younger than previously determined sanidine 40Ar/39 Ar ages (12.8 Ma) for deposition of the tuff.Laboratory He-diffusion experiments conducted on the Yucca fluorite yield a preliminary He closure temperature (Tc) of 90 ± 10 °C (cooling rate of 10 °C/Ma) and previous studies have determined that the fluorite precipitated from warm fluids (65–80 °C) at depths of <400 m. However, minerals can experience partial He loss at temperatures well below the Tc and therefore the (U–Th)/He age of 9.7 Ma is interpreted to be a cooling age. This result implies that the last period of elevated temperature fluid circulation through the Yucca site was approximately 9.7 Ma ago.It was observed that the purple coloured outer portion of the fluorite nodule yielded non-reproducible and invariably older ages than colourless fluorite. Several possible reasons are suggested.  相似文献   

13.
Orogenic gold mineralization in the Amalia greenstone belt is hosted by oxide facies banded iron-formation (BIF). Hydrothermal alteration of the BIF layers is characterized by chloritization, carbonatization, hematization and pyritization, and quartz-carbonate veins that cut across the layers. The alteration mineral assemblages consist of ankerite-ferroan dolomite minerals, siderite, chlorite, hematite, pyrite and subordinate amounts of arsenopyrite and chalcopyrite. Information on the physico-chemical properties of the ore-forming fluids and ambient conditions that promoted gold mineralization at Amalia were deduced from sulfur, oxygen and carbon isotopic ratios, and fluid inclusions from quartz-carbonate samples associated with the gold mineralization.Microthermometric and laser Raman analyses indicated that the ore-forming fluid was composed of low salinity H2O-CO2 composition (~3 wt% NaCl equiv.). The combination of microthermometric data and arsenopyrite-pyrite geothermometry suggest that quartz-carbonate vein formation, gold mineralization and associated alteration of the proximal BIF wall rock occurred at temperature-pressure conditions of 300 ± 30 °C and ∼2 kbar. Thermodynamic calculations at 300 °C suggest an increase in fO2 (10−32–10−30 bars) and corresponding decrease in total sulfur concentration (0.002–0.001 m) that overlapped the pyrite-hematite-magnetite boundary during gold mineralization. Although hematite in the alteration assemblage indicate oxidizing conditions at the deposit site, the calculated low fO2 values are consistent with previously determined high Fe/Fe + Mg ratios (>0.7) in associated chlorite, absence of sulfates and restricted positive δ34S values in associated pyrite. Based on the fluid composition, metal association and physico-chemical conditions reported in the current study, it is confirmed that gold in the Amalia fluid was transported as reduced bisulfide complexes (e.g., Au(HS)2−). At Amalia, gold deposition was most likely a combined effect of increase in fO2 corresponding to the magnetite-hematite buffer, and reduction in total sulfur contents due to sulfide precipitation during progressive fluid-rock interaction.The epigenetic features coupled with the isotopic compositions of the ore-forming fluid (δ34SΣS = +1.8 to +2.3‰, δ18OH2O = +6.6 to +7.9‰, and δ13CΣC = −6.0 to −7.7‰ at 300–330 °C) are consistent with an externally deep-sourced fluid of igneous signature or/and prograde metamorphism of mantle-derived rocks.  相似文献   

14.
Three plutons (Deh-Siahan, Bande-Bagh and Baghe-Khoshk Sharghi, collectively referred to as the DBB hereafter) in southwestern Kerman, in the southeastern part of the Urumieh–Dokhtar magmatic assemblage (UDMA) of the Zagros orogenic belt differ from the typical calc-alkaline metaluminous, I-type intrusions of the region. The DBB intrusions have a distinct lithological assemblage varying from diorite through monzogranite and monzonite to alkali feldspar syenite and alkali granite. The DBB granitoids are metaluminous to slightly peraluminous, alkaline to shoshonitic in composition and have high total alkali contents with K2O > Na2O, high FeOT/MgO values, and low CaO and MgO contents. They are enriched in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu) and depleted in Sr and Ba relative to primordial mantle, and have low concentrations of transitional metals. These features along with various geochemical discriminant diagrams suggest that the DBB granitoids are post-collisional A-type granitoids, which had not been recognized previously in the UDMA. The chondrite-normalized REE patterns of the DBB granitoids show slightly enriched light REEs [(La/Sm)N = 2.26–4.13], negative Eu anomalies [(Eu/Eu*)N = 0.19–0.74] and flat heavy REE patterns [(Gd/Yb)N = 0.80–1.87]. The negative Eu anomaly indicates an important role for plagioclase and/or K-feldspar during fractional crystallization. Whole-rock Rb–Sr isotope analysis yields an isochron age of 33 ± 1 Ma with an initial 87Sr/86Sr value of 0.7049 ± 0.0001. Whole-rock Sm–Nd isotope analysis gives εNdt values from + 2.56 to + 3.62 at 33 Ma. The positive εNdt and low ISr values of the DBB granitoids together with their TDM of 0.6–0.7 Ga suggest their formation from partial melting of a lithospheric mantle source, modified by fluids or melts from earlier subduction processes. Melting of lithospheric mantle occurred via a dehydration melting process at pressures below the garnet stability field, as a consequence of lithospheric mantle delamination or break-off of a subducted slab and melting of the lithospheric mantle by upwelling of hot asthenosphere. On the basis of Rb/Sr age dating and the post-collisional geochemical signatures of the DBB granitoids, along with extensive pre-collisional volcanic eruptions in Middle Eocene, we suggest Late Eocene for the time of collision between the Arabian and Central Iranian plates. This also implies that the calc-alkaline I-type intrusions in the southwestern Kerman and in other parts of the UDMA may have formed in a post-collisional context.  相似文献   

15.
《Lithos》2007,93(1-2):126-148
Fenite aureoles around carbonatite dykes, and alteration associated with Fe–REE–Nb ore bodies at Bayan Obo, Inner Mongolia, China, show alkali silicate assemblages containing aegirine–augite, (magnesio-)riebeckite, (magnesio-)arfvedsonite, and phlogopite, accompanied by varying amounts of apatite, albite and quartz. In both fenites and orebodies simple thermodynamic constraints indicate mineral parageneses are consistent with rock buffered cooling accompanied by the infiltration of a range of externally buffered hydrothermal fluids. Statistical analysis of amphibole chemistry indicates that even in apparently texturally well constrained paragenetic stages wide variations in chemistry occur in both the ore bodies and fenites. Much of this variation is attributable to the Mg and F content of amphibole, and is therefore interpreted as a result of variation in externally controlled variables (P, T, initial fluid composition) rather than internally controlled variables such as protolith composition. Similarities in chemistry exist between fenite and some ore body amphiboles. Thermodynamic analysis of the composition of biotite and apatite allows constraints to be placed on the F-content of hydrothermal fluids, and indicates relatively consistent compositions in fenites and orebodies (log aHF/aH2O = − 3.8 to − 3.6 at 300 °C and 1 kbar). Amphibole and biotite associated with niobate mineralization are both enriched in fluorine relative to the rest of the paragenesis, and biotite compositions indicate significantly higher HF activities in the hydrothermal fluid (log aHF/aH2O = − 2.6 at 300 °C and 1 kbar). The data presented here reinforce previous interpretations of the complex, multistage nature of mineralisation at Bayan Obo, but are still consistent with a direct involvement of carbonatite derived fluids during ore genesis.  相似文献   

16.
Daraban Leucogranite dykes intruded discordantly into the basal serpentinized harzburgite of the Mawat Ophiolite, Kurdistan region, NE Iraq. These coarse grained muscovite-tourmaline leucogranites are the first leucogranite dykes identified within the Mawat Ophiolite. They are mainly composed of quartz, K-feldspar, plagioclase, tourmaline, muscovite, and secondary phologopite, while zircon, xenotime, corundum, mangano-ilemnite and cassiterite occur as accessories.The A/CNK value of the granite dyke samples varies from 1.10 to 1.22 indicating a strongly peraluminous composition. CaO/Na2O ranges from 0.11 to 0.15 and Al2O3/TiO2 from 264 to 463, similar to the strongly peraluminous (SP) granites exposed in ‘high-pressure’ collision zones such as the Himalayas.Ar–Ar muscovite step-heating dating yields 37.57 ± 0.25 and 38.02 ± 0.53 Ma plateau ages for two samples which are thought to reflect either their magmatic emplacement or resetting during collision-related metamorphism. Mineral chemistry shows evidence of both primary and secondary types of muscovite, with cores favouring the magmatic interpretation and slight effects of a late syn-serpentinization fluid seen at the rims.Geochemical features of Daraban Leucogranite dykes favour a syn-collisional tectonic setting. They probably formed in response to the continental collision between Eurasia and Arabia during the initial stage of the opening of the Gulf of Aden at 37 Ma. The muscovite ages and geochemical features of Daraban Leucogranite are strong evidence for the timing of the continental collision between northeastern Arabia and Eurasia in Kurdistan region of Iraq.  相似文献   

17.
The Carris orebody consists of two partially exploited W–Mo–Sn quartz veins formed during successive shear stages and multipulse fluid fillings. They cut the Variscan post-D3 Gerês I-type granite. The most important ore minerals are wolframite, scheelite, molybdenite and cassiterite. There are two generations of wolframite. The earlier generation of wolframite is rare and has the highest WO4Mn content (91 mol%) and the most common wolframite contains 26–57 mol% WO4Mn. Re–Os dating of molybdenite from the ore quartz veins and surrounding granite yields ages of 279 ± 1.2 Ma and 280.3 ± 1.2 Ma, respectively which are in very good agreement with the previous ID-TIMS U–Pb zircon age for the Carris granite (280 ± 5 Ma).3He/4He ratio of pyrite ranging between 0.73 and 2.71 Ra (1 Ra = 1.39 × 10− 6) and high 3He/36Ar (0.8–5 × 10− 3) indicate a mixture of a crustal radiogenic helium fluid with a mantle derived-fluid.The fluid inclusion studies on quartz intergrown with wolframite and scheelite, beryl and fluorite reveal that two distinct fluid types were involved in the genesis of this deposit. The first was a low to medium salinity aqueous carbonic fluid (CO2 between 4 and 14 mol%) with less than 1.95 mol% N2, which was only found in quartz associated with wolframite. The other was a low salinity aqueous fluid found in all the four minerals. The homogenization temperatures indicate minimum entrapment temperatures of 226–310 °C (average 280 °C) for the H2O–CO2–N2–NaCl fluid and average temperatures of 266 °C for scheelite and 242 °C, 190 °C and 160 °C for the last generations of beryl, fluorite and quartz, respectively. It was estimated that wolframite was deposited ~ 7 km depth, assuming a lithostatic pressure, probably due to strong pressure fluctuation caused by seismic events triggered by brittle tectonics during the exhumation event. Precipitation of scheelite and sulphides took place later, at the same depth, but under a hydrostatic or suprahydrostatic pressure regime, and probably caused by mixing between the magmatic–hydrothermal fluid and meteoric waters that deeply penetrated the basement during post-Variscan decompression.  相似文献   

18.
Numerous intrusive rocks of varying ages and compositions exist in the Paleozoic to Tertiary periods in the Eastern Pontides. Carboniferous intrusive rocks are commonly observed in the southern part of the Eastern Pontides. The nature of the rocks in the northern part of the region has not been determined because of Upper Cretaceous and Tertiary volcano-sedimentary units. Whole-rock geochemical, isotopic and geochronological data obtained from five different mapped granitoid bodies located in the northern part of the Eastern Pontides allow for the proper reconstruction of Carboniferous magmatism and the geodynamic evolution of the region.According to laser ablation ICP-MS U–Pb zircon dating, the Özdil, Soğuksu, Seslikaya, Kızılağaç and Şahmetlik plutons have similar 206Pb/238U vs. 207Pb/235U concordia ages of 340.7 ± 1.8 Ma and 323.1 ± 1.5 Ma, 348.4 ± 1.6 Ma, 335.4 ± 1.4 Ma, 337.2 ± 0.6 Ma and 334.5 ± 1.4 Ma, respectively. The aluminium saturation index (ASI) values of all of the samples from the plutons are between 1.0 and 1.32, which indicate peraluminous melt compositions. The plutons have SiO2 contents between 59 and 79 wt.% and show low- to high-K calc-alkaline characteristics. The plutons are enriched in large-ion lithophile and light rare earth elements and are depleted in high-field strength elements. Chondrite-normalized rare earth element patterns are characterized by concave-upward shapes and pronounced negative Eu anomalies, with LaCN/YbCN = 1.9–46.8 and EuCN/Eu* = 0.19–1.76. The studied plutons show considerable variations in 87Sr/86Sr(i) (0.70255 to 0.71006) and εNd(i) values (− 4.8 to − 7.1), as well as Nd model ages (1.15 to 2.47 Ga). The Pb-isotopic ratios are 206Pb/204Pb = 17.11–18.60, 207Pb/204Pb = 15.58–15.64 and 208Pb/204Pb = 36.95–38.62. The crystallization temperatures of the melts range from 676 to 993 °C, as determined by zircon and apatite saturation thermometry.These data suggest that the Carboniferous granitic magmas were produced by the partial melting of meta-mafic to meta-felsic lower crustal source rocks, with minor contributions from the mantle. Collectively, these rocks represent a late stage of Hercynian magmatism in the northern part of the Eastern Pontides.  相似文献   

19.
The Schurwedraai alkali granite is one of a number of prominent ultramafic-mafic and felsic intrusions in the Neoarchaean to Palaeoproterozoic sub-vertical supracrustal collar rocks of the Vredefort Dome, South Africa. The alkali granite intruded the Neoarchaean Witwatersrand Supergroup and has a peralkaline to peraluminous composition. A new zircon SHRIMP crystallization age of 2052 ± 14 Ma for the Schurwedraai alkali granite places it statistically before the Vredefort impact event at 2023 ± 4 Ma and within the accepted emplacement interval of 2050–2060 Ma of the Bushveld magmatic event. The presence of the alkali granite and associated small ultramafic-mafic intrusions in the Vredefort collar rocks extends the southern extremity of Bushveld-related intrusions to some 120 km south of Johannesburg and about 150 km south of the current outcrop area of the Bushveld Complex. The combined effect of these ultramafic-mafic and felsic bodies may have contributed to a pronouncedly steep pre-impact geothermal gradient in the Vredefort area, and to the amphibolite-grade metamorphism observed in the supracrustal collar rocks of the Vredefort Dome.  相似文献   

20.
The behaviour of niobium and tantalum in magmatic processes has been investigated by conducting MnNb2O6 and MnTa2O6 solubility experiments in nominally dry to water-saturated peralkaline (aluminium saturation index, A.S.I. 0.64) to peraluminous (A.S.I. 1.22) granitic melts at 800 to 1035 °C and 800 to 5000 bars. The attainment of equilibrium is demonstrated by the concurrence of the solubility products from dissolution, crystallization, Mn-doped and Nb- or Ta-doped experiments at the same pressure and temperature. The solubility products of MnNb2O6 (Ksp Nb) and MnTa2O6 (Ksp Ta) at 800 °C and 2 kbar both increase dramatically with alkali contents in water-saturated peralkaline melts. They range from 1.2 × 10−4 and 2.6 × 10−4 mol2/kg2, respectively, in subaluminous melt (A.S.I. 1.02) to 202 × 10−4 and 255 × 10−4 mol2/kg2, respectively, in peralkaline melt (A.S.I. 0.64). This increase from the subaluminous composition can be explained by five non-bridging oxygens being required for each excess atom of Nb5+ or Ta5+ that is dissolved into the melt. The Ksp Nb and Ksp Ta also increase weakly with Al content in peraluminous melts, ranging up to 1.7 × 10−4 and 4.6 × 10−4 mol2/kg2, respectively, in the A.S.I. 1.22 composition. Columbite-tantalite solubilities in subaluminous and peraluminous melts (A.S.I. 1.02 and 1.22) are strongly temperature dependent, increasing by a factor of 10 to 20 from 800 to 1035 °C. By contrast columbite-tantalite solubility in the peralkaline composition (A.S.I. 0.64) is only weakly temperature dependent, increasing by a factor of less than 3 over the same temperature range. Similarly, Ksp Nb and Ksp Ta increase by more than two orders of magnitude with the first 3 wt% H2O added to the A.S.I. 1.02 and 1.22 compositions, whereas there is no detectable change in solubility for the A.S.I. 0.64 composition over the same range of water contents. Solubilities are only slightly dependent on pressure over the range 800 to 5000 bars. The data for water-saturated sub- and peraluminous granites have been extrapolated to 600 °C, conditions at which pegmatites and highly evolved granites may crystallize. Using a melt concentration of 0.05 wt% MnO, 70 to 100 ppm Nb or 500 to 1400 ppm Ta are required for manganocolumbite and manganotantalite saturation, respectively. The solubility data are also used to model the fractionation of Nb and Ta between rutile and silicate melts. Predicted rutile/melt partition coefficients increase by about two orders of magnitude from peralkaline to peraluminous granitic compositions. It is demonstrated that the γNb2O5/γTa2O5 activity coefficient ratio in the melt phase depends on melt composition. This ratio is estimated to decrease by a factor of 4 to 5 from andesitic to peraluminous granitic melt compositions. Accordingly, all the relevant accessory phases in subaluminous to peraluminous granites are predicted to incorporate Nb preferentially over Ta. This explains the enrichment of Ta over Nb observed in highly fractionated granitic rocks, and in the continental crust in general. Received: 9 August 1996 / Accepted: 26 February 1997  相似文献   

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