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1.
Helium isotope analyses are central to modern earth science and measured by many noble gas laboratories around the globe (Burnard, 2013; Wieler et al., 2002), spanning a wide spectrum of fundamental research – from identifying primordial reservoirs in the Earth mantle to paleoclimate reconstructions. The CRONUS-Earth initiative included the manufacturing, distribution and analysis of a pyroxene reference material (CRONUS-P) that was designed to be useful for internal reliability control of 3He measurements within a few percent and potentially for 4He on a higher level of uncertainty.This short paper describes the CRONUS-P material and its performance as 3He and 4He reference sample for noble gas laboratories. The companion paper by Blard et al. 2015 describes in depth the inter-laboratory helium isotope experiment within CRONUS-Earth.We show normalized helium isotope data of CRONUS-P measured at three different noble gas laboratories. Data from all three laboratories show no relation between helium isotope concentrations and sample mass, implying that the material is homogeneous. The data show that CRONUS-P is useful as an internal standard for 3He within better 2% (1σ) and for 4He within better 10%.  相似文献   

2.
This study reports an inter-laboratory comparison of the 3He and 4He concentrations measured in the pyroxene material CRONUS-P. This forms part of the CRONUS-Earth and CRONUS-EU programs, which also produced a series of natural reference materials for in situ produced 26Al, 10Be, 14C, 21Ne and 36Cl.Six laboratories (GFZ Potsdam, Caltech Pasadena, CRPG Nancy, SUERC Glasgow, BGC Berkeley, Lamont New York) participated in this intercomparison experiment, analyzing between 5 and 22 aliquots each. Intra-laboratory results yield 3He concentrations that are consistent with the reported analytical uncertainties, which suggests that 3He is homogeneous within CRONUS-P. The inter-laboratory dataset (66 determinations from the 6 different labs) is characterized by a global weighted mean of (5.02 ± 0.12) × 109 at g−1 with an overdispersion of 5.6% (2σ). 4He is characterized by a larger variability than 3He, and by an inter-lab global weighted mean of (3.60 ± 0.18) × 1013 at g−1 (2σ) with an overdispersion of 10.4% (2σ).There are, however, some systematic differences between the six laboratories. More precisely, 2 laboratories obtained mean 3He concentrations that are about 6% higher than the clustered other 4 laboratories. This systematic bias is larger than the analytical uncertainty and not related to the CRONUS-P material (see Schaefer et al., 2015). Reasons for these inter-laboratory offsets are difficult to identify but are discussed below. To improve the precision of cosmogenic 3He dating, we suggest that future studies presenting cosmogenic 3He results also report the 3He concentration measured in the CRONUS-P material in the lab(s) used in a given study.  相似文献   

3.
3He is among the most commonly measured terrestrial cosmogenic nuclides, but an incomplete understanding of the 3He production rate has limited robust interpretation of cosmogenic 3He concentrations. We use new measurements of cosmogenic 3He in olivine from a well-dated lava flow at Tabernacle Hill, Utah, USA, to calibrate the local 3He production rate. The new 3He measurements (n = 8) show excellent internal consistency and yield a sea level high latitude (SLHL) production rate of 123 ± 4 at g?1 yr?1 following the Lal (1991)/Stone (2000) scaling model [Lal, D., 1991. Cosmic ray labeling of erosion surfaces: in situ nuclide production rates and erosion models. Earth and Planetary Science Letters, 104, 424–439.; Stone, J.O., 2000. Air pressure and cosmogenic isotope production. Journal of Geophysical Research, 105, 23753–23759.]. We incorporate the new measurements from Tabernacle Hill in a compilation of all published production rate determinations, characterizing the mean global SLHL production rates (e.g. 120 ± 9.4 at g?1 yr?1 with Lal (1991)/Stone (2000)). The internal consistency of the global 3He production rate dataset is as good as the other commonly used cosmogenic nuclides. Additionally, 3He production rates in olivine and pyroxene agree within experimental error. The 3He production rates are implemented in an age and erosion rate calculator, forming a new module of the CRONUS-Earth web-based calculator, a simple platform for cosmogenic nuclide data interpretation [Balco, G., Stone, J., Lifton, N.A., and Dunai, T.J., 2008. A complete and easily accessible means of calculating surface exposure ages or erosion rates from 10Be and 26Al measurements. Quaternary Geochronology, 3, 174–195.]. The 3He calculator is available online at http://www.cronuscalculators.nmt.edu/.  相似文献   

4.
We present a sensitivity analysis of the isochron approach of Goehring et al. (2013) for paired measurements of in situ 14C/10Be from glacially sculpted bedrock surfaces. This analysis tests how sensitive the resulting exposure durations from this technique are to both the number of samples analyzed and their locations along a glacial trough transect, using a dataset from Goehring et al. (2011) as a test case. A simple equally weighted combinatorial approach was employed to (1) generate non-repetitive combinations of n subsets of samples arranged from the ten possible samples (where n < 10), and (2) estimate the exposure duration and uncertainty for each set of simulations. Results from the Goehring et al. (2011) data indicate that five samples evenly distributed along a transect parallel to the ice margin are the minimum number of samples required for this method, while eight or more samples provide an optimal combination of accuracy and precision at the 1σ level. These findings should be applicable to paired in situ 14C/10Be measurements from other polished bedrock troughs at glacial margins, but need further experimental confirmation.  相似文献   

5.
We have measured 36Cl in three rock surfaces of the Yenicekale building complex in Hattusha (Bo?azköy, Turkey). Hattusha was the capital of Hittite Empire which lasted from about 1650/1600 to 1200 BC. At Yenicekale, Hittite masons flattened the summit of an outcropping limestone knoll to form an artificial platform as the foundation for a building. Next they built a circuit wall along the lateral precipices of the flattened bedrock platform. We took one sample from the limestone bedrock platform and two samples from limestone building blocks of the circuit wall for cosmogenic 36Cl analysis. Calculated exposure ages are 20 ± 1 ka for the sample from the bedrock platform and 24 ± 1 ka and 52 ± 2 ka for the circuit wall blocks. These exposure ages are significantly older than the age expected based on the estimated time of construction between 3.2 ka and 3.7 ka. We conclude that the sampled surfaces contain significant inherited cosmogenic 36Cl. We cannot directly determine exposure ages for the building complex based on these three samples. On the other hand we may use the measured concentrations to determine how much of the rock was removed from the platform during flattening. To this end we modeled the variation of 36Cl production with depth at Yenicekale using the results from the bedrock sample. We conclude that the Hittite masons removed only around 3 m from top of the limestone block. This means that the volume of rock removed from the bedrock platform is significantly less than the volume in the circuit wall atop the platform. They did not gain enough rock from this flattening to make the building. In agreement with this, the first results of our detailed microfacies analysis indicate that many of the building blocks are not of the same facies as the underlying limestone and must have been quarried elsewhere. Although we were not able to exposure date the Yenicekale complex due to the presence of inherited 36Cl, our data suggest that Hittite masons excavated (most of) the building stones not at Yenicekale, but in quarries outside of Hattusha and then transported them to the construction site. These quarries have not yet been identified.  相似文献   

6.
In 2001, a small H4 chondrite, Frontier Mountain (FRO) 01149, was found on a glacially eroded surface near the top of Frontier Mountain, Antarctica, about 600 m above the present ice level. The metal and sulphides are almost completely oxidized due to terrestrial weathering. We used a chemical leaching procedure to remove weathering products, which contained atmospheric 10Be and 36Cl in a ratio similar to that found in Antarctic ice. The FRO 01149 meteorite has a terrestrial age of 3.0 ± 0.3 Myr based on the concentrations of the cosmogenic radionuclides 10Be, 26Al and 36Cl. This age implies that FRO 01149 is the oldest stony meteorite (fossil meteorites excluded) discovered on Earth. The noble gas cosmic ray exposure age of FRO 01149 is ~ 30 Myr. The meteorite thus belongs to the 33 Myr exposure age peak of H-chondrites.The bedrock surface on which FRO 01149 was found has wet-based glacial erosional features recording a former high-stand of the East Antarctic ice sheet. This ice sheet evidently overrode the highest peaks (> 2800 m a.s.l.) of the inland sector of the Transantarctic Mountains in northern Victoria Land. We argue that FRO 01149 was a local fall and that its survival on a glacially eroded bedrock surface constrains the age of the last overriding event to be older than ~ 3 Myr. The concentrations of in-situ produced cosmogenic 10Be, 26Al and 21Ne in a glacially eroded bedrock sample taken from near the summit of Frontier Mountain yield a surface exposure age of 4.4 Myr and indicate that the bedrock was covered by several meters of snow. The exposure age is also consistent with bedrock exposure ages of other summit plateaus in northern Victoria Land.  相似文献   

7.
Over the last decades, cosmogenic exposure dating has permitted major advances in many fields of Earth surface sciences and particularly in paleoglaciology. Yet, exposure age calculation remains a complicated and dense procedure. It requires numerous choices of parameterization and the use of an accurate production rate.This study describes the CREp program (http://crep.crpg.cnrs-nancy.fr) and the ICE-D production rate online database (http://calibration.ice-d.org). This system is designed so that the CREp calculator will automatically reflect the current state of this global calibration database production rate, ICE-D. ICE-D will be regularly updated in order to incorporate new calibration data and reflect the current state of the available literature.CREp is a Octave/Matlab© online code that computes Cosmic Ray Exposure (CRE) ages for 3He and 10Be. A stand-alone version of the CREp code is also released with the present article. Note however that only the online version is connected to the online database ICE-D. The CREp program offers the possibility to calculate ages with two scaling models: i.e. the empirical Lal-Stone time-dependent model (Balco et al., 2008; Lal, 1991; Stone, 2000) with the muon parameters of Braucher et al. (2011), and the Lifton-Sato-Dunai (LSD) theoretical model (Lifton et al., 2014). The default atmosphere model is the ERA-40 database (Uppala et al., 2005), but one may also use the standard atmosphere for comparison (N.O.A.A, 1976). To perform the time-dependent correction, users may import their own geomagnetic database for paleomagnetic corrections or opt for one of the three proposed datasets (Lifton, 2016; Lifton et al., 2014; Muscheler et al., 2005).For the important choice of the production rate, CREp is linked to a database of production rate calibration data that is part of the ICE-D (Informal Cosmogenic-nuclide Exposure-age Database) project (http://calibration.ice-d.org). This database includes published empirical calibration rate studies that are publicly available at present, comprising those of the CRONUS-Earth and CRONUS-EU projects, as well as studies from other projects. In the present study, the efficacy of the different scaling models has also been evaluated looking at the statistical dispersion of the computed Sea Level High Latitude (SLHL) production rates. Lal/Stone and LSD models have comparable efficacies, and the impact of the tested atmospheric model and the geomagnetic database is also limited.Users however have several possibilities to select the production rate: 1) using a worldwide mean value, 2) a regionally averaged value (not available in regions with no data), 3) a local unique value, which can be chosen among the existing dataset or imported by the user, or 4) any combination of multiple calibration data.If a global mean is chosen, the 1σ uncertainty arising from the production rate is about 5% for 10Be and 10% for 3He. If a regional production rate is picked, these uncertainties are potentially lower.CREp is able to calculate a large number of ages in a reasonable time (typically < 30 s for 50 samples). The user may export a summary table of the computed ages and the density probability function associated with each age (in the form of a spreadsheet).  相似文献   

8.
We report concentrations of cosmogenic 10Be and 36Cl used to determine erosion depths in the recently deglaciated bedrock at Goldbergkees in the Eastern Alps. The glacier covered the sampling sites during the Little Ice Age (LIA) until c. 1940. The youngest ages calculated from these concentrations match the known exposure time after the post‐LIA exposure of <100 years. The apparent age (no cover, no erosion) of most samples, however, is significantly older. We show that the measured nuclide concentrations represent subglacial erosion depths, rather than exposure times. In particular, erosion depths calculated using 10Be and 36Cl concentrations of individual samples match well, whereas apparent 36Cl ages are consistently older than 10Be ages. The bedrock at the ‘youngest’ surfaces was deeply eroded (≥ 297 cm) by the Goldbergkees during the late Holocene. In contrast, bedrock at the margin of the LIA ice extent was eroded ≤35 cm. These values convert to subglacial erosion rates on the order of 0.1 mm/a to >5 mm/a. While modeled erosion rates depend on the duration of glacial cover and erosion intrinsic to the different exposure scenarios used for calculation (700–3300 years), modeled total erosion depths are insensitive (5–20% change). Analysis of erosion depths on the transverse valley profile shows a general trend of greatest erosion part way up the valley side and less erosion under thin ice at the lateral margin. A second profile along the valley axis indicates depth of erosion is greatest where the ice abuts the foot of the investigated bedrock riegel and at its lee side just beyond the crest. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

9.
The arguments presented by Lowe et al. [Lowe, D.J., Wilson, C.J.N., Newham, R.M., Hogg, A.G., 2010. Dating the Kawakawa/Oruanui eruption: comment on “optical luminescence dating of a loess section containing a critical tephra marker horizon, SW North Island of New Zealand” by R. Grapes et al. Quaternary Geochronology 5(4), 493–496] against our IRSL results, which suggested that the widespread Kawakawa tephra (KkT) could be considerably younger than the generally accepted 27.1 ka cal BP age, are unsustainable. We discuss the points raised by Lowe et al., in terms of: 1) Presentation and analysis of luminescence ages (comparison between reporting and error margins of luminescence and 14C ages, statistical treatment of age data); 2) Possible sources of error (“upbuilding pedogenesis” and its affect on U and Th distribution in loess, effect of biotubation, variation of K in loess, single grain luminescence dating of quartz, probability of luminescence age underestimation in dating tephra); 3) Stratigraphic and paleoenvironmental considerations (ages of tephras overlying KkT, timing of the end of Ohakea loess deposition and its distribution; 4) Radiocarbon-based ages of KkT (problems with the currently accepted 14C 27.1 ka cal BP age of KkT). We stress that our study was not to establish a new benchmark age for the KkT, but to open debate about the currently accepted benchmark age of the KkT, which we deem to be erroneous.  相似文献   

10.
Over 30 samples from bedrock and boulders from the Veliki vrh rock avalanche have been collected for surface exposure dating. The limestone rocks have been radiochemically treated to isolate and determine long-lived 36Cl by accelerator mass spectrometry. It could be shown that the Veliki vrh rock avalanche from the Košuta Mountain (Slovenia) event can be very likely linked to one of the major historical earthquakes in Europe happening on the 25th of January 1348. Taken into account independently determined denudation rates, inherited 36Cl originating from pre-exposure at shallow depths (20–55 m) could be calculated. The high amount of inherited 36Cl, i.e. 17–46% of the total 36Cl, makes this site not suitable for a precise determination of the 36Cl production rate as it was originally anticipated. Veliki vrh is a “classic” rock avalanche of high velocity. The slope failed in the upper part with a translational slide predominantly along the bedding planes, whereas dynamic fragmentation is the cause for further crushing of the material and the long runout.  相似文献   

11.
An important constraint on the reliability of cosmogenic nuclide exposure dating is the rigorous determination of production rates. We present a new dataset for 10Be production rate calibration from Mount Billingen, southern Sweden, the site of the final drainage of the Baltic Ice Lake, an event dated to 11,620 ± 100 cal yr BP. Five samples of flood-scoured bedrock surfaces (58.5°N, 13.7°E, 105–120 m a.s.l.) unambiguously connected to the drainage event yield a reference 10Be production rate of 4.19 ± 0.20 atoms g−1 yr−1 for the CRONUS-Earth online calculator Lm scaling and 4.02 ± 0.18 atoms g−1 yr−1 for the nuclide specific LSDn scaling. We also recalibrate the reference 10Be production rates for four sites in Norway and combine three of these with the Billingen results to derive a tightly clustered Scandinavian reference 10Be production rate of 4.13 ± 0.11 atoms g−1 yr−1 for the CRONUS Lm scaling and 3.95 ± 0.10 atoms g−1 yr−1 for the LSDn scaling scheme.  相似文献   

12.
The Huancané II moraines deposited by the Quelccaya Ice Cap in southern Peru were selected by the CRONUS-Earth Project as a primary site for evaluating cosmogenic-nuclide scaling methods and for calibrating production rates. The CRONUS-Earth Project is an effort to improve the state of the art for applications of cosmogenic nuclides to earth-surface chronology and processes. The Huancané II moraines are situated in the southern Peruvian Andes at about 4850 m and ∼13.9°S, 70.9°W. They are favorable for cosmogenic-nuclide calibration because of their low-latitude and high-elevation setting, because their age is very well constrained to 12.3 ± 0.1 ka by 34 radiocarbon ages on peat bracketing the moraines, and because boulder coverage by snow or soil is thought to be very unlikely. However, boulder-surface erosion by granular disintegration is observed and a ∼4% correction was applied to measured concentrations to compensate. Samples from 10 boulders were analyzed for 10Be, 26Al, and 36Cl. Interlaboratory bias at the ∼5% level was the largest contributor to variability of the 10Be samples, which were prepared by three laboratories (the other two nuclides were only prepared by one laboratory). Other than this issue, variability for all three nuclides was very low, with standard deviations of the analyses only slightly larger than the analytical uncertainties. The site production rates (corrected for topographic shielding, erosion, and radionuclide decay) at the mean site elevation of 4857 m were 45.5 ± 1.6 atoms 10Be (g quartz)−1 yr−1, 303 ± 15 atoms 26Al (g quartz)−1 yr−1, and 1690 ± 100 atoms 36Cl (g K)−1 yr−1. The nuclide data from this site, along with data from other primary sites, were used to calibrate the production rates of these three nuclides using seven global scaling methods. The traditional Lal formulation and the new Lifton-Sato-Dunai calibrations yield average ages for the Huancané samples that are in excellent-to-good agreement with the radiocarbon age control (within 0.7% for 10Be and 36Cl and 6% for 26Al). However, all of the neutron-monitor-based methods yielded ages that were too young by about 20%. The nuclide production ratios at this site are 6.74 ± 0.34 for 26Al/10Be in quartz and 37.8 ± 2.3 (atoms 36Cl (g K)−1) (atom 10Be (g SiO2)−1)−1 for 36Cl/10Be, in sanidine and quartz, respectively.  相似文献   

13.
In-situ cosmogenic 36Cl production rates from spallation of Ca and K determined in several previously published calibration studies differ by up to 50%. In this study we compare whole rock 36Cl exposure ages with 36Cl exposure ages evaluated in Ca-rich plagioclase in the same 10 ± 3 ka lava sample taken from Mt. Etna (Sicily, 38° N). The exposure age of the sample was determined by K–Ar and corroborated by cosmogenic 3He measurements on cogenetic pyroxene phenocrysts. Sequential dissolution experiments showed that high Cl concentrations in plagioclase grains could be reduced from 450 ppm to less than 3 ppm after 16% dissolution. 36Cl exposure ages calculated from the successive dissolution steps of this leached plagioclase sample are in good agreement with K–Ar and 3He age. Stepwise dissolution of whole rock grains, on the other hand, is not as effective in reducing high Cl concentrations as it is for the plagioclase. 330 ppm Cl still remains after 85% dissolution. The 36Cl exposure ages derived are systematically about 30% higher than the ages calculated from the plagioclase. We could exclude contamination by atmospheric 36Cl as an explanation for this overestimate. Magmatic 36Cl was estimated by measuring a totally shielded sample, but was found to account for only an insignificant amount of 36Cl in the case of the 10 ka whole rock sample. We suspect that the overestimate of the whole rock exposure age is due to the difficulty in accurately assessing all the factors which control production of 36Cl by low-energy neutron capture on 35Cl, particularly variable water content and variable snow cover. We conclude that some of the published 36Cl spallation production rates might be overestimated due to high Cl concentrations in the calibration samples. The use of rigorously pretreated mineral separates reduces Cl concentrations, allowing better estimates of the spallation production rates.In the Appendix of this paper we document in detail the equations used. These equations are also incorporated into a 36Cl calculation spreadsheet made available in the supplementary data.  相似文献   

14.
The Lavini di Marco rock avalanche deposit (“Marocca di Marco”) is located along the left side of the middle Adige Valley, south of the town of Rovereto (NE Italy). The deposit is estimated to have a volume of ∼2 × 108 m3 and cover an area of ∼6.8 km2. It comprises Jurassic Calcari Grigi limestones that detached from the western slope of Mt. Zugna Torta. The Lavini di Marco is composed of at least two different rock avalanche bodies, the main deposit known as Lavini di Marco (the principal) and the much smaller Costa Stenda deposit. Costa Stenda deposits overlie Lavini di Marco deposits. Samples for 36Cl exposure dating were collected from boulders within the deposits, from sliding plane bedrock and from the bedrock wall at the head scarp. Exposure ages range from 800 ± 210 to 21310 ± 1000 years. The latter age stands as a notable outlier suggesting that that Costa Stenda boulder was exposed for a considerable amount of time in the pre-slide bedrock. Lavini di Marco and Costa Stenda boulder ages are 2600 ± 200, 2700 ± 200, 3100 ± 300, 3300 ± 300, 3400 ± 300, 4400 ± 290, 5300 ± 300, and 5400 ± 300 years. The latter three are Costa Stenda boulders which we also interpret to contain inherited nuclide concentrations. The five remaining boulder ages cluster around 3000 years. We calculate a mean age for the Lavini di Marco and Costa Stenda rockslides of 3000 ± 400 years. Within the uncertainties of our data the two slides were simultaneous. For the bedrock sliding plane we obtained significantly younger ages, 1600 ± 100 and 1400 ± 100 years, and for the head scarp 800 ± 200 years. The sliding plane ages record small-scale reactivation which seems to overlap in time with a catastrophic flood event of the Adige River in Verona, as reported in the Fulda Annales, in 883 AD. Only the single age of 800 ± 210 years suggests activity at Lavini di Marco coincident with the well-known Verona earthquake (1117 AD).  相似文献   

15.
Precise 40Ar/39Ar age determinations made on basalt groundmass collected from the SP and upper and lower Bar Ten lava flows in the San Francisco and Uinkaret volcanic fields of Arizona, USA, yield ages of 72 ± 4, 97 ± 10, and 123 ± 12 ka (2σ; relative to Renne et al., 2010, 2011, full external precision), respectively. Previous ages of the SP lava flow include a K–Ar age of 70 ± 8 ka and OSL ages of 5.5–6 ka. 40Ar/39Ar age constraints, relative to the optimization model of Renne et al. (2010, 2011), of 81 ± 50 and 118 ± 64 ka (2σ; full external precision) were previously reported for the upper and lower Bar Ten lava flows, respectively. The new 40Ar/39Ar ages are within uncertainty of previous age constraints, and are more robust, accurate, and precise. Preliminary cosmogenic 3He and 21Ne production rates from the Bar Ten flows reported by Fenton et al. (2009) are updated here, to account for the improved quality of the 40Ar/39Ar data. The new 40Ar/39Ar age for the SP flow yields cosmogenic 3He and 21Ne production rates for pyroxene (119 ± 8 and 26.8 ± 1.9 at/g/yr; error-weighted mean, 2σ uncertainty; Dunai (2000) scaling method) that are consistent with production rate values reported throughout the literature. The 40Ar/39Ar and cosmogenic 3He and 21Ne data support field observations indicating the SP flow has undergone negligible erosion. The SP flow contains co-existing phenocrysts of olivine and pyroxene, as well as xenocrysts of quartz in a fine-grained groundmass facilitating cross-calibration of cosmogenic production rates and production-rate (3He, 10Be, 14C, 21Ne, 26Al, and 36Cl). Thus, we propose the SP flow is an excellent location for a cosmogenic nuclide production-rate calibration site (SPICE: the SP Flow Production-Rate Inter-Calibration Site for Cosmogenic-Nuclide Evaluations).  相似文献   

16.
Cosmogenic 3He can be used to date a wide range of mineral phases because it is produced from all target elements and can be readily measured above atmospheric contamination. Calcite is a particularly attractive target mineral due to its natural abundance, large crystal size (>1 mm), and low He closure temperature (<70 °C), which limit non-cosmogenic 3He components (Copeland et al., 2007). However, several recent studies have shown that some calcite may not be retentive to helium, even under surface temperatures (Cros et al., 2014; Copeland et al., 2007). This study thus explores 3He retention and production in natural calcite samples at four different sites. Samples from two high elevation sites appear retentive to 3He over 10 kyr timescales, whereas two additional sites clearly suffer from diffusive loss of 3He. Step-degassing experiments suggest that diffusion in calcite is controlled by multiple diffusion domains, with an apparent activation energy of 25–27 kcal mol−1. Although minor 3He loss is expected from the smallest diffusion domains, the observed kinetics cannot explain the poor retention at all sites. We thus propose that opaque (non-transparent) calcite may be more retentive due to the presence of imperfections in the crystal lattice. We conclude that 3He dating of calcite shows promise in some settings. However, because retention depends on crystallographic variability it must be evaluated on a case-by-case basis until robust criteria for retention can be identified.  相似文献   

17.
Over the past decade several studies have shown the improvements to radiocarbon chronologies that arise when Acid Base Oxidation-Stepped Combustion (ABOx-SC, Bird et al., 1999) pretreatment methods are applied to the dating of charcoal thought to be >30 ka BP. However, few studies have examined whether the use of ABOx-SC produces dates that are not only older, but accurate on known-age charcoal samples that could not be decontaminated using the routine Acid–Base–Acid (ABA) pretreatment protocol. In this study we date 9 charcoal fragments found below the Campanian Ignimbrite (CI) tephra layer, dated by 40Ar/39Ar to 39,230 ± 45 years (De Vivo et al., 2001, Rolandi et al., 2003), from three Palaeolithic sites. When treated with the ABOx-SC pretreatment protocol, the radiocarbon dates provide an accurate terminus post quem for the CI. In contrast, the ABA protocol consistently underestimates the age of the tephra. These results serve as a warning against the use of consistency as an indicator for reliability, demonstrate that the routine ABA method is not sufficient to decontaminate charcoal samples from sites of Palaeolithic age, and show that ABOx-SC produces not only older, but accurate age estimates.  相似文献   

18.
This paper highlights potential complications that may arise while using in situ produced 10Be to date exposure or burial events using diagenetic silica (chert). The initiation and evolution of large gravitational collapses in sedimentary rocks were constrained using cosmic ray exposure dating. Because these collapses occurred in a stratigraphic level composed of chert (diagenetic silica) concretions interbedded in limestone layers, their development was studied by performing in situ-produced 36Cl and 10Be concentration measurements in both the limestone and coexisting diagenetic silica (chert), respectively. Following the routinely used decontamination and preparation protocols for 10Be produced in diagenetic silica, large discrepancies were observed with exposure ages determined by 36Cl within carbonate for samples originating from the same scarp. While 36Cl exposure ages were clustered as expected for a unique single gravitational event, 10Be exposure ages were scattered along the same studied scarps. To determine the origin of such a bias, petrological investigations were carried out for chert (diagenetic silica). Thin sections highlighted a complex mineralogical texture characterized by remnant silicified ooids showing calcitic cores, calcite inclusions and a dominant amorphous hydrated silica (grain > 20 μm). To decipher and characterize the potential origins of the excess measured 10Be within diagenetic silica, all samples were first reprocessed following the routine decontamination protocol (HCL–H2SiF6 leachings and three partial HF dissolutions) but starting from three different grain size fractions (GS1: 1000–500, GS2: 500–250 and GS3: 250–50 μm). The resulting concentrations clearly showed a decreasing 10Be content as a function of the grain size, but still yielded 10Be exposure ages significantly higher than 36Cl counterparts. Because potential adsorption of 10Be at the surface of amorphous silica grains was suspected, partial dissolution steps following by a leaching step in hydroxylamine were investigated. Finally, it seems that an additional leaching in KOH allowed removal of the amorphous silica phase and the measured 10Be concentrations yielded 10Be exposure ages agreeing within uncertainties with the 36Cl ones. This work suggests that measuring in situ produced 10Be within chert (amongst other types of diagenetic silica, e.g. flint, hornstone, jasper, etc.) containing amorphous silica requires caution.  相似文献   

19.
We have evaluated all parameters for the calculation of cosmogenic 36Cl production rates and thus surface exposure ages in dolomite and limestone. We found that we can use either of both published negative muon stopping rates until more information is available. The largest uncertainty of the age estimation in the upper meter of rock comes from the 36Cl production rate from Ca spallation and, in the case of 50–100 ppm Cl content, from the production rate of epithermal neutrons, which we estimate at 760 ± 150 neutrons/g_air/yr (1σ). For a sample with representative amounts of Ca and Cl (20 wt% Ca and 50 ppm Cl, or 40 wt% Ca and 100 ppm Cl), the age can be calculated with a precision of 7–10% in the top 1.5 m of the depth profile. Further improvement of 36Cl calculations depends on new calibration of 36Cl production from Ca spallation, re-evaluation of 36Cl production by low-energy neutron capture on 35Cl, as well as of the muon flux and muon capture based on the most recent measurement data.  相似文献   

20.
This study aims at determining the chlorine and chlorine-36 fallout rates in an experimental beech forest site located in NE France (48°31′55″ N, 5°16′8″ E). A monthly record of Cl and 36Cl concentrations in rainfall samples collected above the canopy was performed during two years, from March 2012 to February 2014. The results show that the Cl concentrations mainly originate from sea-spray while the 36Cl concentrations originate from the stratosphere and therefore present a seasonal dependency. Abrupt and important inputs of 36Cl from the stratosphere indeed yield sharp increases of the recorded concentrations during the spring-summer. We also show that a too short sampling period might bias the determined 36Cl fallout rate. To smooth the seasonal and sporadic bursts of 36Cl, a minimum of 6 months sampling period is required. A mean 36Cl fallout rate of (77 ± 21) atoms m−2 s−1 can be deduced from our study, which is 45% higher than the modelled value. This discrepancy suggests more studies aiming at measuring the 36Cl fallout rate worldwide are necessary.  相似文献   

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