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1.
The Rhön area as part of the Central European Volcanic Province (CEVP) hosts an unusual suite of Tertiary 24-Ma old hornblende-bearing alkaline basalts that provide insights into melting and fractionation processes within the lithospheric mantle. These chemically primitive to slightly evolved and isotopically (Sr, Nd, Pb) depleted basalts have slightly lower Hf isotopic compositions than respective other CEVP basalts and Os isotope compositions more radiogenic than commonly observed for continental intraplate alkaline basalts. These highly radiogenic initial 187Os/188Os ratios (0.268–0.892) together with their respective Sr–Nd–Pb isotopic compositions are unlikely to result from crustal contamination alone, although a lack of Os data for lower crustal rocks from the area and limited data for CEVP basalts or mantle xenoliths preclude a detailed evaluation. Similarly, melting of the same metasomatized subcontinental lithospheric mantle as inferred for other CEVP basalts alone is also unlikely, based on only moderately radiogenic Os isotope compositions obtained for upper mantle xenoliths from elsewhere in the province. Another explanation for the combined Nd, Sr and Os isotope data is that the lavas gained their highly radiogenic Os isotope composition through a mantle “hybridization”, metasomatism process. This model involves a mafic lithospheric component, such as an intrusion of a sublithospheric primary alkaline melt or a melt derived from subducted oceanic material, sometime in the past into the lithospheric mantle where it metasomatized the ambient mantle. Later at 24 Ma, thermal perturbations during rifting forced the isotopically evolved parts of the mantle together with the peridotitic ambient mantle to melt. This yielded a package of melts with highly correlated Re/Os ratios and radiogenic Os isotope compositions. Subsequent movement through the crust may have further altered the Os isotope composition although this effect is probably minor for the majority of the samples based on radiogenic Nd and unradiogenic Sr isotope composition of the lavas. If the radiogenic Os isotope composition can be explained by a mantle-hybridization and metasomatism model, the isotopic compositions of the hornblende basalts can be satisfied by ca. 5–25% addition of the mafic lithospheric component to an asthenospheric alkaline magma. Although a lack of isotope data for all required endmembers make this model somewhat speculative, the results show that the Re–Os isotope system in continental basalts is able to distinguish between crustal contamination and derivation of continental alkaline lavas from isotopically evolved peridotitic lithosphere that was contaminated by mafic material in the past and later remelted during rifting. The Hf isotopic compositions are slightly less radiogenic than in other alkaline basalts from the province and indicate the derivation of the lavas from low Lu–Hf parts of the lithospheric mantle. The new Os and Hf isotope data constrain a new light of the nature of such metasomatizing agents, at least for these particular rocks, which represent within the particular volcanic complex the first product of the volcanism.  相似文献   

2.
《Comptes Rendus Geoscience》2018,350(3):100-109
We investigated mafic and felsic volcanic rocks from the Bamoun plateau, a magmatic province located north of Mount Cameroon, in the continental part of the Cameroon Volcanic Line (CVL). Basalts and dacites were probably emplaced more than 40 Ma ago, while basanites represent very young volcanic eruptions. Among the basalts, some of them have suffered crustal contamination during their uprise through the continental crust, and their primary trace element and isotopic compositions have been slightly modified. The formation of the dacites was also accompanied by some crustal contamination. Non-contaminated rocks show that the oldest magmas are transitional basalts formed by relatively high degrees of partial melting of a moderately enriched mantle source, probably containing pyroxenites. Recent basanites were produced by very low partial melting degrees of an enriched mantle source with HIMU composition, but different from the source of the nearby Mount Cameroon lavas. The mantle beneath the CVL is thus very heterogeneous, and the tendency towards more alkaline mafic-ultramafic compositions in the youngest volcanic manifestations along the CVL seems to be a general feature of all CVL.  相似文献   

3.
Average 87Sr/86Sr ratios for lavas from Quaternary and Pleistocene volcanoes of the Kurile island arc, NW Pacific, decrease from 0.7035 in the south to 0.7032 in the north. The northern Kuriles are characterised by K2Oricher volcanics and by an older crust. Varying ratios show no simple relation to crustal thickness or geochemical indicators of crustal contamination. This is thought to reflect the immature character of the crust — its simatic composition, low Rb/Sr ratios and youthfulness. Older lavas from the Kuriles (Lower Tertiary, Miocene) have similar or slightly higher 87Sr/86Sr ratios; some have suffered slight alteration and possibly crustal contamination. Quaternary volcanics from the Kurile and Aleutian arcs have the lowest 87Sr/86Sr ratios of all circum-Pacific arcs and this may be ascribed to (a) the isotopic individuality of the landward North American plate and/or (b) the high degree of mechanical coupling between the Pacific and North American plates reducing the amount of subducted 87Sr-rich sediments and seawater. An isotopic boundary between island arcs is located in central Hokkaido. The primary basaltic magmas of the Kuriles were derived from mantle recently contaminated by radiogenic Sr. Subsequent fractionation to andesites and dacites occurred by closed-system fractional crystallization.  相似文献   

4.
Volcanic rocks on the island of Lipari show the entire range of Sr, Nd, Pb isotopic compositions displayed by other islands in the Aeolian archipelago. The rapid isotopic evolution of subaerial volcanic rocks on Lipari towards crustal values together with the appropriate isotopic composition of the neighbouring Calabrian crust (Serre) indicate that many geochemical characteristics observed in the lavas can be attributed to contamination and mixing with crustal materials and melts. Interpretation of the data is complicated by the fact that underplating onto the crust-mantle boundary and the specific lithologies present in the crustal section differ underneath each individual sector of the island. In the central and northern parts of the island, metapelitic rocks were incorporated to provide the more radiogenic Sr isotopic compositions of some lavas. The products from M. Guardia in the southern part of Lipari, where activity is restricted to the last 30–40 ka, bear geochemical similarities to the island of Vulcano, where it is proposed that considerable remobilization of the crust took place in the presence of mafic mantle-derived melts. On Lipari the petrogenetic processes of magma mixing and assimilation dominate over fractional crystallization, and the observed increase of K2O over Na2O can be correlated with contributions from metapelitic crustal lithologies. It is suggested that the variability in isotopic composition and the budget of alkalis (Na2O versus K2O) in the lavas can be explained by invoking a heat source from an intruding asthenospheric MORB-type mantle into a cooler lithospheric crust/mantle during the opening of the Tyrrhenian basin.  相似文献   

5.
Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources, a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators of slab-fluids such as (Sr/P) n and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. δ 18O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal interaction in this juvenile arc, in stark contrast to Os isotopes, which are highly sensitive to interaction with young, mafic material in the lower crust.  相似文献   

6.
Geochemical and isotopic studies showed that the Late Cretaceous-Early Paleocene magmatic rocks of northern Kamchatka were formed in different geodynamic zones of a Late Cretaceous-Early Paleocene suprasubduction system: from a volcanic front to a back-arc rift basin. Suprasubduction magmas were derived from upper mantle garnet or spinel lherzolites variably depleted in terms of Nd isotopic composition or enriched in HFSE and showing varying Th/La, Th/Ta, Zr/Nb, and Nb/U ratios. Subduction-related fluids played an active role in this process. The suprasubduction mantle melts were not contaminated by crustal materials enriched in radiogenic Nd. A weak imprint of contamination was identified only in the lavas of Karaginsky Island.  相似文献   

7.
Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3–10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7–3.6 Ma) tholeiitic basalts, and (3) Recent (1.9–0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and 87Sr/86Sr (0.70395–0.70417) and less radiogenic Pb isotopic ratios (206Pb/204Pb = 18.12–18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core–mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.  相似文献   

8.
Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO2 rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO2) to quartz latite (67% SiO2). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO2 peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km3 high-SiO2 peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes appear to require development of relatively large magma chambers in the crust that are sustained by large basalt fluxes from the mantle. The lack of extensive crustal contamination and mixing in the Miocene lavas may be related to a decreased basalt flux or initiation of blockfaulting that prevented pooling of basaltic magma in the crust.  相似文献   

9.
Crustal contamination of basalts located in the western United States has been generally under-emphasized, and much of their isotopic variation has been ascribed to multiple and heterogeneous mantle sources. Basalts of the Miocene Columbia River Basalt Group in the Pacific Northwest have passed through crust ranging from Precambrian to Tertiary in age. These flows are voluminous, homogenous, and underwent rapid effusion, all of which are disadvantages for crustal contamination while en route to the surface. The Picture Gorge Basalt of the Columbia River Basalt Group erupted through Paleozoic and Mesozoic oceanic accreted terranes in central Oregon, and earlier studies on these basalts provided no isotopic evidence for crustal contamination. New Sr, Nd, Pb, and O isotopic data presented here indicate that the isotopic variation of the Picture Gorge Basalt is very small, 87Sr/86Sr=0.70307–0.70371, Nd=+7.7-+4.8, 18O=+5.6±6.1, and 206Pb/204Pb=18.80–18.91. Evaluation of the Picture Gorge compositional variation supports a model where two isotopic components contributed to Picture Gorge Basalt genesis. The first component (C1) is reflected by low 87Sr/86Sr, high Nd, and nonradiogenic Pb isotopic compositions. Basalts with C1 isotopic compositions have large MgO, Ni, and Cr contents and mantle-like 18O=+5.6. C1 basalts have enrichments in Ba coupled with depletions in Nb and Ta. These characteristics are best explained by derivation from a depleted mantle source which has undergone a recent enrichment by fluids coming from a subducted slab. This C1 mantle component is prevalent throughout the Pacific Northwest. The second isotopic component has higher 87Sr/ 86Sr and 18O, lower Nd, and more radiogenic Pb isotopic compositions than C1. There is a correlation in the Picture Gorge data of Sr, Nd, and Pb isotopes with differentiation indicators such as decreasing Mg#, and increasing K2O/TiO2, Ba, Ba/Zr, Rb/Sr, La/Sm, and La/Yb. Phase equilibrium and mineralogical constraints indicate that these compositional characteristics were inherited in the Picture Gorge magmas at crustal pressures, and thus the second isotopic component is most likely crustal in origin. Mixing and open-system calculations can produce the isotopic composition of the most evolved Picture Gorge flows from the most primitive compositions by 8 to 21% contamination of isotopic compositions similar to accreted terrane crust found in the Pacific Northwest. Therefore, in spite of the disadvantages for crustal contamination and their narrow range in isotopic compositions, the process controlling isotopic variation within the Picture Gorge Basalt is primarily crustal contamination. We suggest that comprehensive analyses for basaltic suites and careful consideration of these data must be made to test for crustal contamination, before variation resulting from mantle heterogeneity can be assessed.Deceased  相似文献   

10.
The Saurashtra region in the northwestern Deccan continental flood basalt province (India) is notable for compositionally diverse volcano-plutonic complexes and abundant rhyolites and granophyres. A lava flow sequence of rhyolite-pitchstone-basaltic andesite is exposed in Osham Hill in western Saurashtra. The Osham silicic lavas are Ba-poor and with intermediate Zr contents compared to other Deccan rhyolites. The Osham silicic lavas are enriched in the light rare earth elements, and have εNd (t = 65 Ma) values between −3.1 and −6.5 and initial 87Sr/86Sr ratios of 0.70709-0.70927. The Osham basaltic andesites have initial εNd values between +2.2 and −1.3, and initial 87Sr/86Sr ratios of 0.70729-0.70887. Large-ion-lithophile element concentrations and Sr isotopic ratios may have been affected somewhat by weathering; notably, the Sr isotopic ratios of the silicic and mafic rocks overlap. However, the Nd isotopic data indicate that the silicic lavas are significantly more contaminated by continental lithosphere than the mafic lavas. We suggest that the Osham basaltic andesites were derived by olivine gabbro fractionation from low-Ti picritic rocks of the type found throughout Saurashtra. The isotopic compositions, and the similar Al2O3 contents of the Osham silicic and mafic lavas, rule out an origin of the silicic lavas by fractional crystallization of mafic liquids, with or without crustal assimilation. As previously proposed for some Icelandic rhyolites, and supported here by MELTS modelling, the Osham silicic lavas may have been derived by partial melting of hot mafic intrusions emplaced at various crustal depths, due to heating by repetitively injected basalts. The absence of mixing or mingling between the rhyolitic and basaltic andesite lavas of Osham Hill suggests that they reached the surface via separate pathways.  相似文献   

11.
At 39.5° S in the southern volcanic zone of the Andes three Pleistocene-recent stratovolcanoes, Villarrica, Quetrupillan and Lanin, form a trend perpendicular to the strike of the Andes, 275 to 325 km from the Peru-Chile trench. Basalts from Villarrica and Lanin are geochemically distinct; the latter have higher incompatible element abundances and La/Sm but lower Ba/La and alkali metal/La ratios. These differences are consistent with our previously proposed models involving: a) a west to east decrease in an alkali metal-rich, high Ba/La slab-derived component which causes an across strike decrease in degree of melting; or b) a west to east increase in the contamination of subduction-related magma by enriched subcontinental lithospheric mantle. Silicic and mafic lavas from the stratovolcanoes have overlapping Sr, Nd and O isotopic ratios. Silicic lavas also have geochemical differences that parallel those of their associated basalts, e.g., rhyolite from Villarrica has lower La/Sm and incompatible element contents than high-SiO2 andesite from Lanin. At each volcano the most silicic lavas can be modelled by closed system fractional crystallization while andesites are best explained by magma mixing. Apparently crustal contamination was not an important process in deriving the evolved lavas. Basaltic flows from small scoria cones, 20–35 km from Villarrica volcano have high incompatible element contents and low Ba/La, like Lanin basalts, but trend to higher K/Rb (356–855) and lower 87Sr/ 86Sr (0.70361–0.70400) than basalts from either stratovolcano. However all basalts have similar Nd, Pb and O isotope ratios. The best explanation for the unique features of the cones is that the sources of SVZ magmas, e.g., slab-derived fluids or melts of the subcontinental lithospheric mantle, have varying alkali metal and radiogenic Sr contents. These heterogeneities are not manifested in stratovolcano basalts because of extensive subcrustal pooling and mixing. This model is preferable to one involving crustal contamination because it can account for variable Sr isotope ratios and uniform Nd and Pb isotope ratios among the basalts, and the divergence of the cones from across-strike geochemical trends defined by the stratovolcanoes.  相似文献   

12.
Volcanism along the northwest boundary of the Arabian Plate found in the Gaziantep Basin, southeast Turkey, is of Miocene age and is of alkaline and calc-alkaline basic composition. The rare earth element data for both compositional series indicates spinel–peridotite source areas. The rare earth and trace elements of the alkaline lavas originate from a highly primitive and slightly contaminated asthenospheric mantle; those of the calc-alkaline lavas originate from a highly heterogeneous, asthenospheric, and lithospheric mantle source. Partial melting and magmatic differentiation processes played a role in the formation of the petrological features of these volcanics. These rocks form two groups on the basis of their ~(87) Sr/~(86) Sr and ~(143) Nd/~(144) Nd isotopic compositions in addition to their classifications based on their chemical compositions(alkaline and calc-alkaline). These isotopic differences indicate a dissimilar parental magma. Therefore, high Nd isotope samples imply a previously formed and highly primitive mantle whereas low Nd isotope samples may indicate comparable partial melting of an enriched heterogeneous shallow mantle. Other isotopic changes that do not conform to the chemical features of these lavas are partly related to the various tectonic events of the region, such as the Dead Sea Fault System and the Bitlis Suture Zone.  相似文献   

13.
The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high 87Sr/86Sr(i) (0.70631–0.71001), low 143Nd/144Nd(i) (0.512145–0.512488) and high Pb isotope ratios (206Pb/204Pb = 18.838–19.148; 207Pb/204Pb = 15.672–15.725; 208Pb/204Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.  相似文献   

14.
U-Pb zircon age, geochemical, and Sr-Nd-Pb isotopic data of mafic dykes from eastern Shandong Province, eastern China is reported herein. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon analyses of two samples from the investigated mafic dykes yield consistent ages ranging from 121.9 Ma ± 0.47 Ma to 122.9 Ma ± 0.61 Ma. The mafic dykes are characterized by high (87Sr/86Sr) i ranging from 0.7087 to 0.7089, low εNd(t) values ranging from -16.9 to -17.8, 206Pb/204Pb = 17.15 to 17.17, 207Pb/204Pb = 15.45 to 15.47, and 208Pb/204Pb = 37.59 to 37.68. Results from the current study suggest that the mafic dykes are derived from partial melting of ancient lithospheric mantle that was variably hybridized by melts derived from foundered lower crustal eclogite. The mafic dykes may have been generated through subsequent insignificant crystal fractionation and very minor crustal contamination during magma ascent. Combined with previous studies, the current findings provide new evidence that the intense lithospheric thinning beneath the eastern Shandong Province of eastern China occurred at ~120 Ma, and that this condition was caused by the removal of the lower lithosphere (mantle and lower crust).  相似文献   

15.
The Yampa volcanic field (late Miocene) consists of about 70 outcrops of monogenetic cinder cones, lavas, dykes, volcanic necks and hydrovolcanic pyroclastic deposits and is situated in the most northerly part of the Rio Grande rift. Contemporaneous extension in this part of the rift was small, but there is geological and geophysical evidence that, by the late Miocene, the area was underlain by hot asthenosphere convected by the Yellowstone mantle plume. The Yampa rocks are mafic and chemically diverse, including basanites, alkali basalts, potassic trachybasalts, hawaiites and shoshonites. About half the rocks bear the xenocryst suite feldspar, pyroxene, Fe–Ti oxide, amphibole, biotite. There is a tendency for xenocryst-free rocks to be the most mafic, interpreted to indicate that the xenocrysts are cognate, and represent cumulate material from fractional crystallization of the magmas in deep crustal magma chambers. The elemental and isotopic (Nd and Sr) variations can be modelled by mixing variable proportions of partial melts of local lithospheric mantle with an OIB end-member formed by partial melting of asthenosphere. The OIB end-member appears to have the elemental and isotopic composition of typical Northern Hemisphere OIB, in particular the plume-derived basanites of Loihi seamount, Hawaii. The OIB end-member at Yampa is interpreted to have been derived from mantle convected in the Yellowstone mantle plume.  相似文献   

16.
The Eocene-Miocene Mianeh-Hashtroud igneous district in NW Iran is part of the Turkish–Caucasus–Iranian collision zone, a key region to decipher the assembly and differentiation of Gondwana-derived terranes along the Alpine-Himalayan convergence zone. Major inherited tectonic structures control in space and time the Mesozoic-Cenozoic transition from oceanic subduction to continental collision in the region. The geology of the study area is dominated by a polyphase, long-lived magmatic activity, spanning from ~45 to ~6 Ma. The igneous products are subalkaline to alkaline, with intermediate to acid compositions and a high-K calcalkaline to shoshonitic affinity. Evidence of crustal contamination is attested by inherited zircons in the oldest (Eocene-Oligocene) samples, with ages spanning from Neo-Archean to Paleocene. The Sr-Nd isotopic compositions of the Eocene-Oligocene samples plot close to the Bulk Silicate Earth estimate, whereas the Miocene samples document stronger crustal contamination. The lack of correlation between Nd-Sr isotopes and SiO2 supports a scenario of magma differentiation of different magma batches rather than crustal contamination. Major oxide and Sr-Nd isotopic variation lead us to suggest that magmatism is the consequence of re-melting of earlier underplated (Mesozoic-Tertiary) magmatic products, controlled by amphibole-dominated fractionation processes. Regional scale correlations show long-lived Cenozoic magmatism in NW Iran and Caucasus region, where the main porphyry and epithermal deposits occur. We propose that the Cenozoic collisional magmatism and the associated mineralisation at the junction between NW-Iran and Caucasus was controlled by the activity of a major, lithosphere-scale inherited boundary, transverse to the convergence zone. In such a geodynamic setting, the along-strike segmentation of the lithosphere slab generated asthenospheric melts, their upwelling into the metasomatised supra-subduction mantle wedge and the potential activation of different mantle and crustal sources, with consequent mineral endowment in the region.  相似文献   

17.
We report major and trace element abundances and Sr, Nd andPb isotopic data for Miocene (16·5–11 Ma) calc-alkalinevolcanic rocks from the western segment of the Carpathian arc.This volcanic suite consists mostly of andesites and dacites;basalts and basaltic andesites as well as rhyolites are rareand occur only at a late stage. Amphibole fractionation bothat high and low pressure played a significant role in magmaticdifferentiation, accompanied by high-pressure garnet fractionationduring the early stages. Sr–Nd–Pb isotopic dataindicate a major role for crustal materials in the petrogenesisof the magmas. The parental mafic magmas could have been generatedfrom an enriched mid-ocean ridge basalt (E-MORB)-type mantlesource, previously metasomatized by fluids derived from subductedsediment. Initially, the mafic magmas ponded beneath the thickcontinental crust and initiated melting in the lower crust.Mixing of mafic magmas with silicic melts from metasedimentarylower crust resulted in relatively Al-rich hybrid dacitic magmas,from which almandine could crystallize at high pressure. Theamount of crustal involvement in the petrogenesis of the magmasdecreased with time as the continental crust thinned. A strikingchange of mantle source occurred at about 13 Ma. The basalticmagmas generated during the later stages of the calc-alkalinemagmatism were derived from a more enriched mantle source, akinto FOZO. An upwelling mantle plume is unlikely to be presentin this area; therefore this mantle component probably residesin the heterogeneous upper mantle. Following the calc-alkalinemagmatism, alkaline mafic magmas erupted that were also generatedfrom an enriched asthenospheric source. We propose that bothtypes of magmatism were related in some way to lithosphericextension of the Pannonian Basin and that subduction playedonly an indirect role in generation of the calc-alkaline magmatism.The calc-alkaline magmas were formed during the peak phase ofextension by melting of metasomatized, enriched lithosphericmantle and were contaminated by various crustal materials, whereasthe alkaline mafic magmas were generated during the post-extensionalstage by low-degree melting of the shallow asthenosphere. Thewestern Carpathian volcanic areas provide an example of long-lastingmagmatism in which magma compositions changed continuously inresponse to changing geodynamic setting. KEY WORDS: Carpathian–Pannonian region; calc-alkaline magmatism; Sr, Nd and Pb isotopes; subduction; lithospheric extension  相似文献   

18.
Many objections have been raised as to the ability of subcontinental lithospheric mantle to produce voluminous amounts of basalt, because this upper part of the mantle is thought to be refractory, and the geotherm is rarely above the peridotite solidus at these depths under continents. However, in the Pacific Northwest of the USA during the Neogene, the subcontinental lithospehric mantle has been proposed as a key source for basalts erupted within the northern Basin and Range, and for the Columbia River flood basalts erupted on the Columbia Plateau. An alternative explanation to melting in the subcontinental lithospheric mantle, which equally well explains the chemical compositions thought to originate there, is that these magmas were contaminated by crust of varying ages. Calc-alkaline lavas, which occupy the Blue Mountains in the center of this region, hold clues to the latter process. Their elevated trace element ratios (e.g., Ba/Zr, K2O/P2O5), coupled with differentiation indicators such as Mg? [molar Mg/(Mg?+?Fe)], and Sr, Nd, and Pb isotopic compositions, can most reasonably be explained by crustal contamination. Appraisal of continental peridotite xenolith data indicates that high trace element ratios such as Ba/Zr in continental basalts cannot result from melting in the subcontinental lithospheric mantle. Instead, as with the calc-alkaline lavas, these high ratios in the tholeiites most likely indicate crustal contamination. Furthermore, the peridotite xenoliths do not have a relative depletion in Nb and Ta that is observed in most of the lavas within the region. Relatively minor volumes of tholeiites erupted in late Neogene times in the northern Basin and Range (Hi-Mg olivine tholeiites) and Columbia Plateau (Saddle Mountains basalts), are the only lavas which have trace element and isotopic compositions consistent with being derived from, or largely interacting with a subcontinental lithospheric mantle in the Pacific Northwest. In contrast to the prior studies, we suggest that the mantle sources for most of the basalts in this region were ultimately beneath the lithospheric mantle.  相似文献   

19.
《International Geology Review》2012,54(10):1234-1252
ABSTRACT

The lower Miocene (~22–19 Ma) volcanic units in the NE–SW-trending Tunçbilek–Domaniç basin, located in the northeastern-most part of the Neogene successions in western Anatolia, are composed of (1) high-K, calc-alkaline dacitic to rhyolitic volcanic rocks of the Oklukda?? volcanics; (2) calc-alkaline low-MgO (evolved) basalts; and (3) high-MgO mildly alkaline basalts of the Karaköy volcanics. Sr isotopic ratios of the volcanic units increase from high-MgO (~0.7055–0.7057) to low-MgO basaltic rocks (~0.7066–0.7072) and then to dacitic-rhyolitic rocks (0.7081–0.7086). Geochemical features of the volcanic rocks reveal that the calc-alkaline evolved basalts were formed by mixing of basic and acidic magmas.

Geochemical studies in the last decade show that the Miocene mafic volcanic rocks in western Anatolia are mainly composed of high-MgO shoshonitic-ultrapotassic rocks (SHO-UK), of which mantle sources were variably, but also intensely metasomatized with crustally derived materials during collisional processes in the region. However, geochemical comparison of the high-MgO basalts of the Karaköy volcanics with the SHO-UK rocks in this region reveal that that the former has too low 87Sr/86Sr(i) and high 143Nd/144Nd(i) ratios, with lower LILE and LREE abundances, which are firstly described here. These features are interpreted to be derived from more slightly enriched lithospheric mantle sources than that of the SHO-UK. Accepting the SHO-UK rocks in the region were derived from mantle sources that had been metasomatized by northward subduction of crustal slices during Alpine collisional processes, it is proposed that the imbrication and direct subduction of crustal slices were not reached to, and were limited in the mantle domains beneath the basin. The dacites of the Oklukda?? volcanics might be formed either by high-degree melting of the same sources with the SHO-UK, or by melting of the lower crustal mafic sources as previously proposed, and then evolved into the rhyolites via fractional crystallization with limited crustal contribution.  相似文献   

20.
The Eocene volcano-sedimentary units of Northern Anatolia are confined into a narrow zone trending parallel to the Intra Pontide and İzmir–Ankara–Erzincan sutures, along which the northern branch of the Neotethys Ocean was closed during a period between Late Maastrichtian and Paleocene. The Middle Eocene formations overlie both the imbricated and highly deformed units of the suture zone, which are Paleocene or older in age, as well as the formations of adjacent continental blocks with a regional disconformity. Therefore, they can be regarded to be post-collisional. These units are composed of subaerial to shallow marine sedimentary beds (i.e. the Örencik formation) at the base and a subaerial volcanic unit (i.e. the Hamamözü formation) in the middle and at the top. This sudden facies change from marine to subaerial environment in the Middle Eocene is a common phenomenon across northern Turkey, implying that a regional uplift event occurred possibly across the suture zone before the initiation of the volcanism during Lutetian. The Middle Eocene lavas span the whole compositional range from basalts to rhyolites and display a calc-alkaline character except for alkaline to mildly-alkaline lavas from the top of the sequence. All lavas display a distinct subduction signature. Our geochemical data indicate that calc-alkaline lavas were derived from a subduction-modified source, whereas alkaline to mildly-alkaline lavas of the late stage were possibly sourced by an enriched mantle domain. Magmas evolved in magma chambers emplaced possibly at two different crustal levels. Magmas in deeper (> 13 km) and possibly larger chambers fractionated hydrous mafic minerals (e.g. amphibole and biotite), two pyroxenes and plagioclase and assimilated a significant amount of crustal material. Intermediate to acid calc-alkaline lavas and pyroclastics were derived from these chambers. Magmas in the shallower chambers, on the other hand (~ < 12 km), crystallized anhydrous mineral assemblages, assimilated little or no crustal material and fed basic to intermediate lavas in the region. Both deep and shallow chambers were periodically replenished by mafic magmas. We argue that a slab breakoff model explains better than any alternative model (i) why the volcanism during the Middle Eocene was confined into a rather narrow belt along the suture zone, (ii) why it initiated almost contemporaneous with a regional uplift after the continental collision event, (iii) why it postdated arc volcanism along the Pontides in the north by 15–20 My, (iv) why it assimilated significant amount of crustal material, and (v) why alkalinity of lavas increased in time.  相似文献   

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