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1.
赣南花岗岩风化壳型稀土矿床中纳米级稀土矿物的研究   总被引:1,自引:0,他引:1  
为揭示次生风化成因稀土矿物的赋存形态和分布特征,对赣南安远岗下稀土矿区花岗岩风化壳剖面进行了研究。采集风化壳不同层位的样品进行分选、提纯,场发射扫描电镜和透射电镜研究结果表明,与稀土矿物紧密相关的粘土矿物是高岭石和埃洛石等,风化壳中发现的纳米级稀土矿物既有附着于其他矿物表面的微细颗粒,也有呈集合体存在的稀土矿物(可能为方铈石),这一现象有助于进一步认识风化壳稀土矿床的形成过程。  相似文献   

2.
用石墨炉原子吸收光谱(GFAAS)或感应耦合等离子体质谱(ICP-MS)评估了几种预富集天然水中溶解金的方法。在GFASS之前用阴离子交换法和在ICP-MS之前用溶剂萃取法,两种方法都证实有相似的回收率,低的检出限(2L样品检出限分别是0.4ng.L^-1和0.2ng.L^-1)和好重现性。还用仪器中子活化分析(INAA)进行了颗粒金的平行分析,以提供一个对转(迁)移金的完整的评价,检出在0.4~  相似文献   

3.
砂土颗粒级配是影响砂土工程性质的重要参数之一,传统的颗分试验方法由于试验原理不同而具有不同的适用范 围。为更加方便、准确地获取砂土颗粒级配,提出了一种基于数字图像处理技术来获取SEM照片中的砂颗粒粒径参数及级 配特征的新方法。将准备好的砂土样品打磨成薄片放在扫描电镜下拍照,然后利用Photoshop软件对照片进行拼接,并采用 自主研发的SMAS数字图像分析系统对拼接好的照片进行定量分析处理,获取样品的微观结构参数,将获得的“土颗粒等 效直径”和“土颗粒面积”分别等效为实际土颗粒粒径和土颗粒质量,进而换算得到砂土的颗粒级配曲线;然后将通过数 字图像技术获得的砂土颗粒级配曲线与通过传统筛分法和激光粒度分析法得到的颗粒级配曲线进行对比,验证了提出的数 字图像处理方法的有效性和可靠性,同时分析了两种方法之间存在的差异及其原因,并对数字图像处理方法和传统颗分方 法各自的优缺点进行了讨论。  相似文献   

4.
以渝东南-黔北地区牛蹄塘组页岩岩心及野外新鲜露头样品为研究对象,运用低温液氮吸附实验和氩离子抛光扫描电镜观察,划分页岩微纳米级孔隙类型,并对其发育程度和形态结构进行定量表征,结合页岩样品地球化学测试数据,明确页岩微观孔隙发育主控因素,试图建立微纳米级孔隙发育程度与主控因素定性或半定量关系。结果表明:研究区牛蹄塘组页岩微纳米级孔隙分为有机孔、无机孔和微裂缝3大类,包括7个亚类。有机质粒内孔结构特征为球状、细瓶颈状和墨水瓶状,无机孔主要为串珠状、球状和楔状,微裂缝呈四方开口的平行板状、夹板状。有机质粒内孔、矿物粒间孔和微裂缝为主要孔隙类型,且具有较好连通性,可作为页岩气赋存空间和渗流通道。页岩孔隙以中孔为主,其次为宏孔,孔隙直径分布范围主要在1~50 nm。比表面积主要由孔径≤5 nm孔隙所提供,页岩孔隙孔径越小,对比表面积贡献越大,越有利于页岩气吸附聚集,随着孔隙体积的增加,比表面积不断增加。有机碳含量是控制页岩微纳米级孔隙发育和比表面积的最重要内因,特别体现在对微孔和中孔发育的控制上;黏土矿物含量增加能增强页岩吸附能力,但对孔隙体积和比表面积主控作用不明显;脆性矿物含量主要控制宏孔发育,对页岩吸附的贡献可以忽略;热演化程度过低或过高均不利于有机质孔隙的发育,微纳米孔隙体积随着成熟度增加呈现出先增后减的趋势,对于高过成熟页岩,不同干酪根类型的有机质孔隙发育程度和比表面积大小次序为Ⅰ型>Ⅱ型>Ⅲ型。  相似文献   

5.
王文远  刘嘉麒 《地球科学》2000,25(1):98-102
利用细颗粒热释光技术对渭南剖面重要地层界线片的7个样品进行了年龄测定,并在此基础,结合已发表我项式回归方法建立了渭南剖面高分辨率的古气候时间标尺,其中S0/国-1,L1-1/L1-2,L1-4/国-5,L1-5/S1,S1/L2的界线年龄分别为1.1,2.5,5.1,7.6,12.8ka除了L1-4/L1-5的界线年龄与氧同位素3阶段的起始年龄差距较大之外,它们与SPECMAP深海氧同位素5以上各  相似文献   

6.
香港气溶胶烃类物质组成,分布及来源初探   总被引:13,自引:2,他引:13  
成玉  李顺诚 《地球化学》1997,26(3):45-53
总悬浮颗粒和10μm以下人体可吸入颗粒物,即RSP样品采自香港市区和郊区,样品采用超声抽提和硅胶层析柱分离,使用气相色谱,气相色谱-质谱(GC,GC-MSD)分析饱和烃和芳烃馏分。研究表明,TSP样品中含有化石燃料燃烧和生物来源的脂肪烃,包括正构烷烃,甾烷和藿烷类等有机物。芳香烃主要由2-7环的多环芳烃组成,其中10种属美国优先控制污染物,RSP样品中主要含生物来源的正构烷烃,含少量代表化石燃烧产  相似文献   

7.
广西龙胜丹洲群细碧岩锆石U-Pb及Sm-Nd等时线年龄   总被引:14,自引:0,他引:14  
用单颗粒锆石U-Pb及全岩、全岩-矿物Sm-Nd等时线法对广西龙胜丹洲群细碧岩进行了地质年代学研究。结晶锆石年龄为977±10Ma,代表细碧岩的形成时代;锆石U-Pb及全岩Sm-Nd等时线均反映出~0.6Ga的一次后期事件年龄,很可能代表一次较大规模富CO2流体的热液蚀变作用时代,即本区受细碧岩层控的滑石矿的成矿年龄;细碧岩全岩矿物Sm-Nd内部等时线年龄为201±40Ma,代表了印支期岩浆热事件的时代。  相似文献   

8.
广西龙胜丹洲群细碧岩锆石U—Pb及Sm—Nd等时线年龄   总被引:9,自引:1,他引:9  
甘晓华  李献华 《地球化学》1996,25(3):270-276
用单颗粒锆石U-Pb及全岩、全岩-矿物Sm-Nd等时线法对广西龙胜丹洲群细碧岩进行了地质年代学研究。结晶锆石年龄为977±10Ma,代表细碧岩的形成时代;锆石U-Pb及全岩Sm-Nd等时线均反映出 ̄0.6Ga的一次后期事件年龄,很可能代表一次较大规模富CO2流体的热液蚀变作用时代,即本区受细碧岩层控的滑石矿的成矿年龄;细碧岩全岩-矿物Sm-Nd内部等时线年龄为201±40Ma,代表了印支期岩浆热事  相似文献   

9.
砂土颗粒级配是影响砂土工程性质的重要参数之一,传统的颗分试验方法由于试验原理不同而具有不同的适用范 围。为更加方便、准确地获取砂土颗粒级配,提出了一种基于数字图像处理技术来获取SEM照片中的砂颗粒粒径参数及级 配特征的新方法。将准备好的砂土样品打磨成薄片放在扫描电镜下拍照,然后利用Photoshop软件对照片进行拼接,并采用 自主研发的SMAS数字图像分析系统对拼接好的照片进行定量分析处理,获取样品的微观结构参数,将获得的“土颗粒等 效直径”和“土颗粒面积”分别等效为实际土颗粒粒径和土颗粒质量,进而换算得到砂土的颗粒级配曲线;然后将通过数 字图像技术获得的砂土颗粒级配曲线与通过传统筛分法和激光粒度分析法得到的颗粒级配曲线进行对比,验证了提出的数 字图像处理方法的有效性和可靠性,同时分析了两种方法之间存在的差异及其原因,并对数字图像处理方法和传统颗分方 法各自的优缺点进行了讨论。  相似文献   

10.
分形理论是宏观上定量评价储层非均质性的有效手段。以阳泉新景矿高煤级煤样品压汞数据为基础,建立分形几何模型,定量描述了孔隙结构。实验结果表明:样品孔隙以纳米孔为主,孔径、比表面积及孔容也集中分布在纳米孔段。煤样孔径65 nm以上的孔隙具有显著的分形特征,分维值分布范围为2.89~2.99,体积增量呈现阶段式的变化,孔隙结构复杂;孔径65 nm以下孔隙几乎无分形特征,比表面积增量与孔径在对数坐标中呈线性关系;基于分形特征及分子运动规律,将储层孔隙以孔径65 nm为界划分为扩散孔和渗透孔2个大类6个小类。分维值与体积孔隙中值半径、总孔隙体积呈负相关,与孔径65 nm以上的孔隙体积、比表面积呈正相关,与孔隙度无相关性。分形分维值对储层结构具有较全面的表征能力,可以作为综合指标在煤储层孔隙研究中加以应用。   相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

17.
18.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

19.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

20.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

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