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1.
Mineralizing fluids at the San Martín skarn show an evolution characterized by prograde and retrograde associations. The prograde mineral associations consist of (1) a massive garnet zone, (2) a tremolite ± garnet zone, and (3) a late association of quartz, sphalerite, calcite and fluorite lining the vugs in the garnet zone. The fluids of the prograde associations exhibit decreasing temperatures of homogenization (Th) and variable salinities. The fluids of the massive garnet zone have salinities of 36 wt.% NaCl equiv. and Th of 645 to 570 °C, corresponding to pressures of 1055 bar. At the tremolite ± garnet zone, Th range from 438 to 354 °C. In the late association at the endoskarn, the following evolution can be drawn: (a) salinities of 50 to 42 wt.% NaCl equiv., and Th of 455 to 346 °C in quartz, (b) salinities of 46 wt.% NaCl equiv., and Th of 415 to 410 °C in sphalerite, (c) salinities of 50 to 37 wt.% NaCl equiv., and Th of 479 to 310 °C in calcite, (d) salinities of 33 to 28 wt.% NaCl equiv. and of 24 to 22 wt.% KCl in fluorite, and (e) two types of fluids with salinities of 2 and 39 wt.% NaCl equiv. and Th 344 and 300 °C, respectively, in later saccharoidal quartz segregations. The retrograde mineral associations comprise pervasive propylitic alteration to carbonization, and mantos with sulfides. Fluids in epidote have salinities of 7.6 wt.% NaCl equiv. and Th of 287 to 252 °C, and in calcite have salinities of 9.2 to 1 wt.% NaCl equiv. and Th of 188 to 112 °C. Fluids in the sulfide assemblages in the mantos have salinities of 8 to 3 wt.% NaCl equiv. and Th 300 °C, with corresponding pressures of 94 bar. Fluids in late epithermal veins close to the intrusive body have salinities of 10 to 5 wt.% NaCl equiv. and Th of 275 to 200 °C, and distal veins show salinities of 2 to 1 wt.% NaCl equiv. and Th of 160 °C. 相似文献
2.
The Sar-Cheshmeh porphyry Cu–Mo deposit is located in Southwestern Iran (65 km southwest of Kerman City) and is associated with a composite Miocene stock, ranging in composition from diorite through granodiorite to quartz-monzonite. Field observations and petrographic studies demonstrate that the emplacement of the Sar-Cheshmeh stock took place in several pulses, each with associated hydrothermal activity. Molybdenum was concentrated at a very early stage in the evolution of the hydrothermal system and copper was concentrated later. Four main vein Groups have been identified: (I) quartz+molybdenite+anhydrite±K-feldspar with minor pyrite, chalcopyrite and bornite; (II) quartz+chalcopyrite+pyrite±molybdenite±calcite; (III) quartz+pyrite+calcite±chalcopyrite±anhydrite (gypsum)±molybdenite; (IV) quartz±calcite±gypsum±pyrite±dolomite. Early hydrothermal alteration produced a potassic assemblage (orthoclase-biotite) in the central part of the stock, propylitic alteration occurred in the peripheral parts of the stock, contemporaneously with potassic alteration, and phyllic alteration occurred later, overprinting earlier alteration. The early hydrothermal fluids are represented by high temperature (350–520 °C), high salinity (up to 61 wt% NaCl equivalent) liquid-rich fluid inclusions, and high temperature (340–570 °C), low-salinity, vapor-rich inclusions. These fluids are interpreted to represent an orthomagmatic fluid, which cooled episodically; the brines are interpreted to have caused potassic alteration and deposition of Group I and II quartz veins containing molybdenite and chalcopyrite. Propylitic alteration is attributed to a liquid-rich, lower temperature (220–310 °C), Ca-rich, evolved meteoric fluid. Influx of meteoric water into the central part of the system and mixing with magmatic fluid produced albitization at depth and shallow phyllic alteration. This influx also caused the dissolution of early-formed copper sulphides and the remobilization of Cu into the sericitic zone, the main zone of the copper deposition in Sar-Cheshmeh, where it was redeposited in response to a decrease in temperature. 相似文献
3.
Ultrahigh temperature deformation microstructures in felsic granulites of the Napier Complex, Antarctica 总被引：3，自引：0，他引：3
Detailed electron microscope and microstructural analysis of two ultrahigh temperature felsic granulites from Tonagh Island, Napier Complex, Antarctica show deformation microstructures produced at 1000 °C at 8–10 kbar. High temperature orthopyroxene (Al 7 wt.% and 11 wt.%), exhibits crystallographic preferred orientation (CPO) and frequent subgrain boundaries which point to dislocation creep as the dominating deformation mechanism within opx. Two different main slip systems are observed: in opx bands with exclusively opx grains containing subgrain boundaries with traces parallel to [010] and a strong coupling of low angle misorientations (2.5°–5°) with rotation axes parallel to [010] the dominating slip system is (100)[001]. Isolated opx grains and grain clusters of 2–5 grains embedded in a qtz–fsp matrix show an additional slip system of (010)[001]. The latter slip system is harder to activate. We suggest that differences in the activation of these slip systems is a result of higher differential stresses imposed onto the isolated opx grains and grain clusters. In contrast to opx, large qtz grains (up to 200 μm) show random crystallographic orientation. This together with their elongate and cuspate shape and the lack of systematic in the rotation axes associated with the subgrain boundaries is consistent with diffusion creep as the primary deformation mechanism in quartz.Our first time detailed microstructural observations of ultrahigh temperature and medium to high pressure granulites and their interpretation in terms of active deformation mechanisms give some insight into the type of rheology that can be expect at lower crustal conditions. If qtz is the mineral phase governing the rock rheology, Newtonian flow behaviour is expected and only low differential stress can be supported. However, if the stress supporting mineral phase is opx, the flow law resulting from dislocation creep will govern the rheology of the rock unit; hence, an exponential relationship between stress and strain rate is to be expected. 相似文献
4.
Coaly source rocks are sufficiently different from marine and lacustrine source rocks in their organic matter characteristics to warrant separate guidelines for their assessment using Rock-Eval pyrolysis. The rank threshold for oil generation is indicated by the increase in BI (S1/TOC) at Rank(Sr)9–10 (Tmax 420–430 °C, Ro 0.55–0.6%), and the threshold for oil expulsion is indicated by the peak in QI ([S1+S2]/TOC) at Rank(Sr)11–12.5 (Tmax 430–440 °C, Ro 0.65–0.85%). The pronounced rank-related increase in HI (S2/TOC) prior to oil expulsion renders the use of immature samples inappropriate for source rock characterisation. A more realistic indication of the petroleum generative potential and oil expulsion efficiency of coaly source rocks can be gained from samples near the onset of expulsion. Alternatively, effective HI′ values (i.e. HIs near the onset of expulsion) can be estimated by translating the measured HIs of immature samples along the maturation pathway defined by the New Zealand (or other defined) Coal Band. Coaly source rocks comprise a continuum of coaly lithologies, including coals, shaly coals and coaly mudstones. Determination of the total genetic potential of coaly source rock sequences is best made using lithology-based samples near the onset of expulsion. 相似文献
5.
《Applied Geochemistry》2006,21(7):1093-1108
Peña del Hierro is an abandoned mine site located in the catchment area of the Tinto river (Pyrite Belt, SW Spain). As leaching from the spoils affect the quality of the stream water, the waste dumps have been characterized for mineralogy, geochemistry and granulometry to obtain an estimate of the potential pollution. Waste rock dumps in Peña del Hierro are very heterogeneous and are mainly composed of acid volcanic tuffs > gossan > shales > roasted pyrite ashes > floated pyrite. The volcanic tuffs, the gossan and the shales coexist in the same piles. The roasted pyrite ashes and the floated pyrite form more homogeneous dumps. The dissolution of pyrite concentrated in pyrite ashes and floated pyrite units can generate acid mine drainage. Nevertheless, acid volcanic tuffs, which are rich in pyrite and have no neutralizing minerals, are the main source of these acidic effluents. Only muscovite might partially neutralize the acidity, but the dissolution of this mineral is too slow to compensate for acidity. The occurrence of jarosite in the <2 mm fraction indicates that extreme acid mine drainage occurs. The gossan and roasted pyrite ashes have high contents of trace elements. According to their concentration, As (46–1710 ppm), Pb (113–3455 ppm) and Hg (0–53) are some of the most important toxic trace elements in these wastes. In dumps mainly composed of volcanic tuffs most of the trace elements derive from the gossan mixed in the piles. Gossan is stable in an oxidizing environment, but acidic effluents (pH < 2) can dissolve Fe oxyhydroxides from them and release high amounts of trace elements to the stream water. This research contributes to estimating the production of acid mine drainage and the actual contamination risk of potentially toxic elements in soils and waters of this area, and could be the base for possible future mitigation actions in other areas affected by mining wastes. 相似文献
6.
This study reports on the transfer of contaminants from waste rock dumps and mineralised ground into soils, sediments, waters
and plants at the rehabilitated Mary Kathleen uranium mine in semi-arid northwest Queensland. Numerous waste rock dumps were
partly covered with benign soil and the open pit mine was allowed to flood. The mineralised and waste calc-silicate rock in
the open pit and dumps has major (>1 wt%) Ca, Fe and Mg, minor (>1,000 ppm) Ce, La, Mn, P and S, subminor (>100 ppm) Ba, Cu,
Th and U, and trace (<100 ppm) As, Ni, Pb, Y and Zn values. Consequently, chemical and physical weathering processes have
acted on waste rock and on rock faces within the open pit, mobilising many elements and leading to their dispersion into soils,
stream sediments, pit water and several plant species. Chemical dispersion is initiated by sulfide mineral breakdown, generation
of sulfuric acid and formation of several soluble, transient sulfate minerals as evaporative efflorescent precipitates. Radiation
doses associated with the open pit average 5.65 mSv year−1; waste dumps commonly have lower values, especially where soil-covered. Surface pit water is slightly acid, with high sulfate
values accompanied by levels of U, Cu and Ni close to or above Australian water guideline values for livestock. Dispersion
of U and related elements into soils and stream sediments occurs by physical (erosional) processes and from chemical precipitation.
Plants growing in the mine void, on waste dumps and contaminated soil display evidence of biological uptake of U, LREE, Cu
and Th and to a lesser degree of As, Ni, Pb, Y and Zn, with values being up to 1–2 orders of magnitude above background sites
for the same species. Although rehabilitation procedures have been partly successful in reducing dispersion of U and related
elements into the surrounding environment, it is apparent that 20 years after rehabilitation, there is significant physical
and chemical mobility, including transfer into plants. 相似文献
7.
Dating low temperature events such as magmatic cooling or (hydro-)thermal surges in Archean and Proterozoic terranes is crucial in defining cratonal thermal stabilization after episodic continental growth during the Archean and Early Proterozoic. Rubidium–Sr chronology is potentially a powerful tool in this regard because of its low closure temperature, i.e., <400 °C in most minerals, but has until now been hampered by its relatively low precision compared to high-temperature chronometers. Consequently, Rb–Sr age investigations have so far failed to provide high-precision age constraints on the cooling of rocks older than 2 Ga. Here, it is demonstrated that internal Rb–Sr microchrons can yield important, high-precision age constraints on the cooling history of Archean intrusions. After careful mineral selection and chemical treatment, a Rb–Sr age of 2543.0 ± 4.4 Ma was obtained from the Archean Great Dyke, Zimbabwe Craton, in contrast to the intrusion age of 2575.8 ± 1 Ma, yielding an ambient average cooling of 5 ± 2 °C/Ma. The non-disturbed magmatic Rb–Sr cooling age of the Great Dyke marks the final stage of Zimbabwe craton stabilization and that the greater craton area did not experience any intensive later reheating event during metamorphic or tectonic events. 相似文献
8.
Apatite fission track evidence for Neogene uplift in the eastern Kunlun Mountains, northern Qinghai–Tibet Plateau, China 总被引：1，自引：0，他引：1
Wanming Yuan Jinquan Dong Wang Shicheng Andrew Carter 《Journal of Asian Earth Sciences》2006,27(6):847-856
Forty-one apatite fission track ages (AFT) were determined on samples collected along a N–S section of the eastern Kunlun Mountains across the Middle and South Kunlun Faults between Buqingshan and Dulan. Measured AFT ages lie between 25±2 and 130±10 Ma, and all are significantly younger than their host rock formation or sediment deposition ages. Modelling the AFT data identifies a two stage regional cooling history that spans the last 100 Myrs. The earliest cooling phase occurred between the late Jurassic and early Tertiary and involved a moderate level of cooling between 20 and 40 °C, equivalent to average exhumation rates of =15 m/Myr. The second phase of cooling took place from 20 Ma with cooling rates increasing tenfold. Average exhumation rates for this period are estimated to be in the range of 100–150 m/Myr. The first stage of protracted cooling is consistent with regional evidence from the Qiantang and Lhasa terrans where previous studies have noted low rates of denudation in relation to a back-arc extensional setting. The more recent acceleration in cooling seen in the Kunlun data coincides with an increase in sedimentation rates in the adjacent Qaidam Basin. This points to a phase of Neogene uplift and increased erosion of the Kunlun Range, although contemporaneous monsoon strengthening may also have had a role. 相似文献
9.
H. Wiggering 《Environmental Geology》1993,22(2):99-105
Because of the high degree of automation in the coal mining industry in the Ruhr area, Germany, about 1 metric ton of crushed rock/colliery spoil is brought to the surface for every metric ton of coal. Most of the colliery spoil disposed of must be dumped. These colliery spoil dumps are anthropogenic geological sediment bodies, which have a characteristic facies resulting from geological, technical, and economical factors connected with the formation of the dumps. The relation between the facies of the dumps and these factors, for example, is examplified with the pyrite content within the colliery spoil. Pyrite content within the dumps is dependent both on the conditions during sedimentation and (early) diagenesis and the techniques used for mining and processing. Thus, this geologic-technical facies of the dumps controls the weathering processes on and in dumps. These humaninduced processes are mainly responsible for the environmental impact on soil and groundwater. Oxidation of pyrite as well as alteration of pyrite under anoxic conditions yields dissolution of carbonates, accompanied by gypsum formation, by acid attack and strong acidification takes place. 相似文献
10.
The 92.5 Ma Fort Knox granodiorite stock, near the western end of the Fairbanks Belt in the Yukon–Tanana terrane (YTT) of central Alaska, hosts a world-class gold mine. The stock has been analysed paleomagnetically using thermal and alternating-field step demagnetization and isothermal remanence methods. This pluton retains a primary thermoremanent magnetization at 18 sites (232 specimens) that resides mainly in single-to pseudosingle-domain magnetite with a direction of D = 228.8°, I = 84.3° (N = 18, k = 130, α95 = 3.0°), giving a paleopole at 56.5°N, 197.1°E (dp = 5.9°, dm = 5.8°). The pluton's host rock, the Fairbanks schist, does not retain a stable coherent remanence. Relative to the North American craton, the stock's paleoinclination indicates that the Fairbanks Belt has undergone nonsignificant poleward (northwesterly) translation of 25 ± 750 km only. Analysed in concert with the few available paleoinclinations available for the YTT in Yukon, the paleoinclination suggests further that the YTT has undergone only 250 to 450 km of dextral displacement along the Tintina fault in the past 100 Ma and, therefore, is parautocthonous since the mid-Cretaceous. The stock's paleodeclination records 121 ± 35° of counterclockwise rotation relative to the North American craton. Consideration of models published for Alaska's tectonic evolution suggests that this paleodeclination discordance is caused by rotations associated with the opening of the Canada Basin, with dextral displacement on the Tintina fault, and with development of the western Alaskan orocline. Thus the paleomagnetic results for the Fort Knox stock support a thin-skin tectonic model for the accretion of the YTT and Intermontane Belt terranes to the northern Cordillera. 相似文献
11.
The 36Cl dating method is increasingly being used to determine the surface-exposure history of Quaternary landforms. Production rates for the 36Cl isotopic system, a critical component of the dating method, have now been refined using the well-constrained radiocarbon-based deglaciation history of Whidbey and Fidalgo Islands, Washington. The calculated total production rates due to calcium and potassium are 91±5 atoms 36Cl (g Ca)−1 yr−1 and are 228±18 atoms 36Cl (g K)−1 yr−1, respectively. The calculated ground-level secondary neutron production rate in air, Pf(0), inferred from thermal neutron absorption by 35Cl is 762±28 neutrons (g air)−1 yr−1 for samples with low water content (1–2 wt.%). Neutron absorption by serpentinized harzburgite samples of the same exposure age, having higher water content (8–12 wt.%), is 40% greater relative to that for dry samples. These data suggest that existing models do not adequately describe thermalization and capture of neutrons for hydrous rock samples. Calculated 36Cl ages of samples collected from the surfaces of a well-dated dacite flow (10,600–12,800 cal yr B.P.) and three disparate deglaciated localities are consistent with close limiting calibrated 14C ages, thereby supporting the validity of our 36Cl production rates integrated over the last 15,500 cal yr between latitudes of 46.5° and 51°N. Although our production rates are internally consistent and yield reasonable exposure ages for other localities, there nevertheless are significant differences between these production rates and those of other investigators. 相似文献
12.
Stefania Da Pelo Elodia Musu Rosa Cidu Franco Frau Pierfranco Lattanzi 《Journal of Geochemical Exploration》2009,100(2-3):142-152
The Furtei gold mine in Sardinia (Italy) exploits a volcanic-hosted high-sulphidation epithermal deposit. Large amounts of materials derived from exploitation are present in open pits, waste rock dumps and cyanidation tailings impoundment. Mineralized rocks in outcrops and waste dumps contain significant amounts of sulphides (mainly pyrite and enargite). These materials have a high potential for acid drainage generation and release of toxic elements (notably Cu and As, but also Al, Ni, Co and Cd) as pointed out by laboratory leaching tests and in agreement with chemical composition of waters draining the mining area, that show pH as low as 2, up to 180 mg/L Cu, up to 5 mg/L As, and up to 788 mg/L Al. On the other hand, leaching solutions and waters interacting with mineral assemblages of the propylitic alteration zone (mainly composed of chlorite, quartz, and calcite, with relic magmatic plagioclase) show higher pH, and lower metal loads. Leachates from cyanidation tailings show variable pH (between 6.2 and 9.7, depending on sulphide content in tailings); cyanide concentration varies between 110 µg/L and about 3 mg/L, whereas contents of toxic elements in leachates are, with the exception of Hg, within the limits of Italian regulations for non-dangerous industrial wastes. Reclamation plans provide for confinement of tailings within specific repositories. This measure should effectively reduce the environmental impact of these materials. Reclamation plans should also include an adequate management of other high-sulphide wastes. 相似文献
13.
Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: The role of nucleation kinetics 总被引：1，自引：0，他引：1
Gianluca Iezzi Silvio Mollo Guido Ventura Andrea Cavallo Claudia Romano 《Chemical Geology》2008,253(3-4):91-101
Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of 90 vol.%. The phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable quench temperatures, investigated by coupling experiments with Pt wire and Pt capsule sample containers in set 2, again did not produce crystallization of trachyte, whereas latitic samples are characterized by 10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature < 1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass-forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (< 0.125 °C/min), in comparison to latitic melts (Rc > 0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts. 相似文献
14.
Charles R. Bryan Katheryn B. Helean Brian D. Marshall Patrick V. Brady 《Applied Geochemistry》2009,24(11):2133-2143
Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10−16 to 10−17 mol s−1 kg tuff−1 with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10−15 to 10−16 mol s−1 kg tuff−1 for percolation fluxes of 15 mm a−1 and 1 mm a−1, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a−1 or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L−1) may inhibit feldspar dissolution. 相似文献
15.
Frictional sliding of gabbro gouge under hydrothermal conditions 总被引：12，自引：0，他引：12
We investigated the frictional sliding behaviour of gabbro gouge under hydrothermal conditions. Experiments were performed on 1-mm-thick gabbro gouge sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) in a triaxial testing system with argon gas as the confining medium. In the first series, experiments were conducted under effective normal stresses of 200 MPa and 300 MPa respectively, with pore pressure of 10 MPa. For temperature over 400 °C, pore pressure of 30 MPa was also applied to implement supercritical water conditions. At temperatures up to 615 °C, slip rate steps ranging from 0.0488 μm/s to 1.22 μm/s were applied to obtain the rate dependence of friction.At 200 MPa effective normal stress and a pore pressure of 10 MPa, the steady state rate dependence a–b shows velocity-weakening behaviour for temperatures between 200 and 310 °C. The higher temperature limit for velocity-weakening behaviour to occur extends up to 510 °C under supercritical water conditions with a pore pressure of 30 MPa. For the limited sliding distance in our experiments, only velocity-strengthening behaviour occurred at 300 MPa effective normal stress. Considering the limited displacement (< 3.5 mm), velocity-weakening behaviour may not be excluded in the high effective normal stress case for temperature below 510 °C.The coefficient of friction shows an increasing trend with increasing temperature in the low temperature range. The cut-off temperatures for the increasing trend are 250 °C and 440 °C, respectively for the 200 MPa and 300 MPa effective normal stress cases. Above the cut-off temperatures, the coefficient of friction at 1.83 mm permanent displacement varies around an average of 0.73, which is identical to the average for the oven-dried case [He, C., Yao, W., Wang, Z., Zhou, Y., 2006. Strength and stability of frictional sliding of gabbro gouge at elevated temperatures. Tectonophysics 427, 217–229, doi:10.1016/j.tecto.2006.05.023]. Together with the small value of rate dependence (a–b < 0.0073) for the whole temperature range, these results indicate the absence of fluid-assisted creep.With the result of our experiments as a constraint on strength of frictional sliding, comparison between converted strength for strike–slip faults and creep strength of gabbro-like rocks implies fracturing and faulting behaviours in the lower crust of a cool area (Zhangbei) in North China. 相似文献
16.
High-pressure mafic granulites in the Trans-North China Orogen: Tectonic significance and age 总被引：8，自引：2，他引：6
Jian Zhang Guochun Zhao Min Sun Simon A. Wilde Sanzhong Li Shuwen Liu 《Gondwana Research》2006,9(3):349-362
High-pressure mafic granulites (including retrograded eclogites) have been reported from the Trans-North China Orogen, a Paleoproterozoic orogenic belt along which two discrete continental blocks, referred to as the Eastern and Western Blocks, were amalgamated to form the North China Craton. Extensive metamorphic investigations and geochronology carried out over the last few years provide important insights into the age and significance of these high-pressure granulites, which are critical in understanding of the timing and tectonic processes involved in the assembly of the North China Craton.Most high-pressure mafic granulites in the Trans-North China Orogen preserve the high-pressure granulite facies assemblage garnet + plagioclase + clinopyroxene + quartz, the medium-pressure granulite facies assemblage garnet + plagioclase + clinopyroxene + orthopyroxene ± quartz, the low-pressure granulite facies assemblage orthopyroxene + clinopyroxene + plagioclase ± quartz, and the amphibolite facies assemblage hornblende + plagioclase. Minor high-pressure granulites preserve the early eclogite facies mineral assemblage of garnet + quartz + omphacite pseudomorph (clinopyroxene + Na-rich plagioclase), indicating that they are retrograded eclogites. These mineral assemblages and their P–T estimates define a clockwise P–T path involving near-isothermal decompression and cooling following the peak high-pressure metamorphism, which suggests that they formed during continent–continent collision. Field mapping and geochronology indicate that the precursors of these high-pressure granulites were mafic dykes which were emplaced at 1915 Ma and underwent high-pressure granulite facies metamorphism at 1.85 Ga. Taken together, the high-pressure granulites in the Trans-North China are considered to have resulted from final collision between the Eastern and Western Blocks to form the North China Craton at 1.85 Ga, not at 2.5 Ga as recently proposed by some authors. 相似文献
17.
L. Nyquist D. Bogard A. Yamaguchi C.-Y. Shih Y. Karouji M. Ebihara Y. Reese D. Garrison G. McKay H. Takeda 《Geochimica et cosmochimica acta》2006,70(24):5990-6015
Low concentrations of Th and Fe in the Yamato (Y)-86032 bulk meteorite support earlier suggestions that Y-86032 comes from a region of the moon far distant from the Procellarum KREEP Terrain (PKT), probably from the lunar farside. 39Ar–40Ar, Rb–Sr, Sm–Nd, and Sm-isotopic studies characterize the chronology of Y-86032 and its precursors in the mega regolith. One of the rock types present in a light gray breccia lithology is an anorthosite characterized by plagioclase with An 93, i.e., more sodic than lunar FANs, but with very low 87Rb/86Sr and 87Sr/86Sr similar to those of FANs. (FAN stands for Ferroan Anorthosite). This “An93 anorthosite” has Nd-isotopic systematics similar to those of nearside norites. A FAN-like “An97 anorthosite” is present in a second light-colored feldspathic breccia clast and has a more negative εNd value consistent with residence in a LREE-enriched environment as would be provided by an early plagioclase flotation crust on the Lunar Magma Ocean (LMO). This result contrasts with generally positive values of εNd for Apollo 16 FANs suggesting the possibility of assymetric development of the LMO. Other possible explanations for the dichotomy in εNd values are advanced in the text. The Y-86032 protolith formed at least 4.43 ± 0.03 Ga ago as determined from a Sm–Nd isochron for mineral fragments from the breccia clast composed predominantly of An93 anorthosite and a second clast of more varied composition. We interpret the mineral fragments as being predominatly from a cogenetic rock suite. An 39Ar–40Ar age of 4.36–4.41 ± 0.035 Ga for a third clast composed predominantly of An97 anorthosite supports an old age for the protolith. Initial 143Nd/144Nd in that clast was −0.64 ± 0.13 ε-units below 143Nd/144Nd in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. A maximum in the 39Ar–40Ar age spectrum of 4.23 ± 0.03 Ga for a second sample of the same feldspathic breccia clast probably reflects some diffusive 40Ar loss. Lack of solar wind and lunar atmosphere implanted Ar in the light gray breccia clast allows determination of an 39Ar/40Ar age of 4.10 ± 0.02 Ga, which is interpreted as the time of initial brecciation of this litholgy. After correction for implanted lunar atmosphere 40Ar, impact melt and dark regolith clasts give Ar ages of 3.8 ± 0.1 Ga implying melt formation and final breccia assembly 3.8 Ga ago. Some breccia lithologies were exposed to thermal neutron fluences of 2 × 1015 n/cm2, only about 1% of the fluence experienced by some other lunar highlands meteorites. Other lithologies experienced neutron fluences of 1 × 1015 n/cm2. Thus, Y-86032 spent most of the time following final brecciation deeply buried in the megaregolith. The neutron fluence data are consistent with cosmogenic 38Arcos cosmic ray exposure ages of 10 Ma. Variations among differing lithologies in the amount of several regolith exposure indicators, including cosmogenic noble gas abundances, neutron capture induced variations in Sm isotopic abundances, and Ir contents, are consistent with a period of early (>3.8 Ga ago) lunar regolith exposure, subsequent deep burial at >5 m depth, and ejection from the moon 7–10 Ma ago. 相似文献
18.
Brittle–ductile–brittle deformation during cooling of tonalite (Adamello, Southern Italian Alps) 总被引：1，自引：0，他引：1
Late- to post-magmatic deformation in slightly diachronous contiguous intrusions of the north-western Adamello batholith (Southern Alps, Italy) is recorded as, from oldest to youngest: (i) joints, (ii) solid-state ductile shear zones, (iii) faults associated with epidote-K-feldspar veins and (iv) zeolite veins and faults. Structures (ii) to (iv) are localized on the pervasive precursory network of joints (i), which developed during the earliest stages of pluton cooling. High temperature ( 500 °C), ductile overprinting of joints produced lineations, defined by aligned biotite and hornblende, on the joint surfaces and highly localized mylonites. The main phase of faulting, producing cataclasites and pseudotachylytes, occurred at 250 °C and was associated with extensive fluid infiltration. Cataclasites and pseudotachylytes are clustered along different E–W-striking dextral strike-slip fault zones correlated with the activity of the Tonale fault, a major tectonic structure that bounds the Adamello batholith to the north. Ductile deformation and cataclastic/veining episodes occurred at P = 0.25–0.3 GPa during rapid cooling of the batholith to the ambient temperatures ( 250 °C) that preceded the exhumation of the batholith. Timing of the sequence of deformation can be constrained by 39Ar–40Ar ages of 30 Ma on pseudotachylytes and various existing mineral ages. In the whole composite Adamello batholith, multiple magma pulses were intruded over the time span 42–30 Ma and each intrusive body shows the same ductile-to-brittle structural sequence localized on the early joint sets. This deformation sequence of the Adamello might be typical of intrusions undergoing cooling at depths close to the brittle–ductile transition. 相似文献
19.
Alfonso Encinas Victor Maksaev Luisa Pinto Jacobus P. Le Roux Francisco Munizaga Marcos Zentilli 《Journal of South American Earth Sciences》2006,20(4):369-381
Lahar deposits occur within a shallow marine sedimentary succession of the Pliocene La Cueva Formation in the Coastal Cordillera of central Chile (33°40′–34°15′S). Provenance studies of the abundant volcanic material in the lahar deposits suggest that they derive from denudation by mass wasting of Oligocene–Miocene volcanic rocks on the western slopes of the Main Andean Cordillera at the same latitude. Pliocene rock debris deposits preserved in the region of El Teniente (34°S) and scattered along the westernmost part of the Andes of central Chile indicate catastrophic erosive events related to the rapid uplift of the cordilleran block. This rock debris was deposited by avalanches and transformed further downslope into lahars by dilution with stream water. Lahars were channeled along the ancient drainage system that reached a shallow Pliocene sea at the site of the present Coastal Cordillera. The exceedingly rapid exhumation of active porphyry systems during the Early Pliocene in this part of the Andes may have played a role in affecting hydrothermal processes, brecciation, and diatreme formation at the porphyry systems of El Teniente and Río Blanco–Los Bronces. 相似文献
20.
Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals 总被引：1，自引：1，他引：0
Deformation experiments have been carried out to investigate the effect of dynamic recrystallisation on crystallographic preferred orientation (CPO) development. Cylindrical samples of natural single crystals of quartz were axially deformed together with 1 vol.% of added water and 20 mg of Mn2O3 powder in a Griggs solid medium deformation apparatus in different crystallographic orientations with compression direction: (i) parallel to <c>, (ii) at 45° to <c> and 45° to <a> and (iii) parallel to <a>. The experiments were performed at a temperature of 800 °C, a confining pressure of 1.2 GPa, a strain rate of 10− 6 s− 1, to bulk finite strains of 14–36%. The deformed samples were analysed in detail using optical microscopy, electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Two different microstructural domains were distinguished in the deformed samples: (i) domains with undulatory extinction and deformation lamellae, and (ii) domains with new recrystallised grains. Within the domains of undulatory extinction, crystal-plastic deformation caused gradual rotations of the crystal lattice up to 30° away from the host orientation. New recrystallised grains show a strong CPO with c-axis maxima at 45° to the compression direction. This is the case in all experiments, irrespective of the initial crystallographic orientation. The results show that c-axes are not continuously rotated towards the new maxima. The new grains thus developed through a mechanism different from subgrain rotation recrystallisation. New grains have a subeuhedral shape and numerous microcavities, voids, fluid channels and fluid inclusions at their grain boundaries. No host control is recorded in misorientation axes across their large angle grain boundaries. New grains might have been created by nucleation from solution in the μm-scale voids and microfractures. The CPO most likely developed due to preferred growth of the freshly precipitated grains with orientations suitable for intracrystalline deformation at the imposed experimental conditions. 相似文献