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1.
Certain dikes in the Kangerdlugssuaq area of east Greenland correspond rather closely with the presumed bulk composition of the nearby Skaergaard intrusion and therefore allow a better characterization of the chemistry of the Skaergaard initial magma than has so far been possible. They indicate that Wager's chilled margin composition needs only minor revision, except in the case of Al2O3. Other dikes belonging to the same suite show a range of compositions extending up to the differentiation stage represented by the lower part of the Skaergaard middle zone and these allow an investigation, using computer least squares and Rayleigh fractionation modelling, of the early part of the Skaergaard differentiation trend which is otherwise unexposed. We conclude that the only important cumulus phases at this stage were olivine and plagioclase but clmopyroxene grew by heteradcumulus growth and effectively eliminated all intercumulus liquid. The liquids described here are similar to many ocean-floor basalts. 相似文献
2.
天山地区新元古代-早寒武世火山岩地球化学和岩石成因 总被引：1，自引：0，他引：1
天山地区新元古代-早寒武世玄武质熔岩包括拉斑玄武质和碱性玄武质两个主要岩浆系列，前者是早期（早南华世贝义西组、早震旦世扎摩克提组）喷发的火山岩系的主要组成，后者是晚期（早震旦世苏盖特布拉克组、晚震旦世水泉组、早寒武世西山布拉克组）喷发的火山岩系的主要组成。稀土、微量元素和Sr、Nd同位素特征揭示，这些火山岩均形成于大陆裂谷环境，其源区可能是源于一种似洋岛玄武岩源的软流圈地幔源，并且在岩浆上侵喷发过程中发生了岩石圈的混染。 相似文献
3.
The differentiation of the Skaergaard intrusion 总被引：6，自引：0，他引：6
Conclusions We find no support for the claim that the Skaergaard magma followed the trend of common tholeiitic volcanic magmas, such as those of Iceland and the Scottish Tertiary. The end product of differentiation was not a large mass of rhyolite but an iron-rich, silica-poor liquid not unlike that deduced by Wager in 1960.The proposal that a large mass of rhyolitic liquid occupied the upper levels of the intrusion finds no support in the field. The thick series of ferrogabbos, which became richer in iron and poorer in silica until they reached a field of immiscibility cannot be reconciled with crystallization of a large mass of felsic magma. Mass-balance calculations that indicate otherwise are invalid, because they fail to take into account large volumes of rocks that differ in composition from those assumed in the calculations.While ignoring the existence of major units of the intrusion, Hunter and Sparks propose that lavas in Scotland and Iceland are more relevant to the liquid compositions than rocks that are intimately associated with the intrusion. Their argument that the Skaergaard Intrusion followed a trend of silica enrichment that is universal to tholeiitic magmas is based on an incomplete knowledge of the rocks and faulty calculations of mass-balance relations.We agree that much remains to be learned about the Skaergaard Intrusion and the basic mechanisms of magmatic differentiation. In this case, however, we are ready to hang our case on well-established field relations and a mass of laboratory data for what must be the most intensely studied body of rock on Earth. 相似文献
4.
5.
Jakob K. Jakobsen Christian Tegner C. Kent Brooks Adam J. R. Kent Charles E. Lesher Troels F. D. Nielsen Michael Wiedenbeck 《Contributions to Mineralogy and Petrology》2010,159(1):61-79
Troctolite blocks with compositions akin to the Hidden Zone are exposed in a tholeiitic dyke cutting across the Skaergaard
intrusion, East Greenland. Plagioclase in these blocks contains finely crystallised melt inclusions that we have homogenised
to constrain the parental magma to 47.4–49.0 wt.% SiO2, 13.4–14.9 wt.% Al2O3 and 10.7–14.1 wt.% FeOT. These compositions are lower in FeOT and higher in SiO2 than previous estimates and have distinct La/SmN and Dy/YbN ratios that link them to the lowermost volcanic succession (Milne Land Formation) of the regional East Greenland flood basalt
province. New major- and trace element compositions for the FG-1 dyke swarm, previously taken to represent Skaergaard magmas,
overlap with the entire range of the regional flood basalt succession and do not form a coherent suite of Skaergaard like
melts. These dykes are therefore re-interpreted as feeder dykes throughout the main phase of flood basalt volcanism. 相似文献
6.
腾冲马鞍山、打鹰山、黑空山火山岩浆来源与演化 总被引：10，自引：6，他引：4
本文对马鞍山、打鹰山、黑空山火山岩主微量和Sr、Nd、Pd同位素地球化学研究认为,腾冲火山岩浆源区具有MORB与富集地幔混合之特征,推测为新特提斯俯冲洋壳重新熔融,导致腾冲地区的高钾钙碱性岩浆的火山活动,解释了腾冲在新生代大陆板内构造环境背景下出现岛弧或活动大陆边缘火山岩地球化学特征的现象。马鞍山、打鹰山和黑空山火山高钾钙碱性岩浆经历了岩浆房阶段辉石、钛铁矿的结晶分离作用和岩浆上升过程中斜长石的结晶分离作用,导致岩浆成分从中基性向中酸性演化,火山岩从玄武质粗安岩→粗安岩→粗面质英安岩演化。 相似文献
7.
Xueyuan Yu 《中国地球化学学报》1985,4(2):150-158
The Niutoushan basaltic cone, consisting of subalkali (quartz-tholeiite and olivine-tholeiite) and alkali basalts, is Late Tertiary in age. Its major characteristics are generalized as follows:
- Both early subalkali and late alkali bali basalts are formed under the same geological environment.
- The continuity in chemical composition from subalkali to alkali and the low FeO/MgO in alkali basalts show that they are the products of cognate magmatic differentiation.
- The change from low REE abundance and weak enrichment of LREE in subalkali to high REE abundance and strong enrichment of LREE in alkali basalts indicates obvious REE enrichment and fractionation during magmatic differentiation. Weak positive Eu anomalies in the REE patterns are indicative of their formation under low oxygen fugacity conditions.
- According to the calculated values, 70–75% of the primary olivine tholeiitic magma had been separated as subalkaline basaltic magma, the rest residual magma became alkaline basaltic magma. This result is consistent to the field observation that the outcrop area of subalkali basalts is four times as much as that of alkali basalts.
- The basaltic rocks of Niutoushan show an S-type distribution straddling the thermal barrier on Ol′-Ne′-Qu′ diagram and an evolution tendency for Ne to increase with increasing FeO/MgO. This is in agreement with the melting experimental data on olivine basalts at 10–20 kb.
- Mantle-derived inclusions (spinel lherzolite) in this area occur in both alkali olivine basalts and olivine tholeiites. The latter is of extremely rare occurrence. The formation temperature and pressure of the inclusions in alkalibasalts and olivine tholeiites have been calculated. The results show that the alkaline basaltic magma was separated from the subalkaline basaltic magma at about 20 kb.
8.
The basic volcanic group exposed in the Kadiri schist belt includes high Mg-basalt, basalt, basaltic andestite and dacite. The basalts are tholeiitic in composition and high Mg-basalts, basaltic andesites and dacites show calc-alkaline affinity. Major and trace element characteristics suggest that the volcanic suite has been derived from an initial tholeiitic magma which has given rise to an early basaltic type and a later calc-alkaline type of rocks. An island arc and active continental margin tectonic setting was inferred for these rocks. 相似文献
9.
Within the volcanic sequence of the twin volcanoes of Lyttelton and Akaroa, Banks Peninsula, New Zealand a number of different magma series have been distinguished.An early series of hawaiites (McQueens Valley Formation) was erupted about 32 m.y. ago and is of transitional or mildly tholeiitic chemistry. Stratigraphically above the McQueens Valley Formation, but unconformably overlain by the main volcanic dome sequence, is a unit of rhyolite (Gebbies Pass Rhyolites) which is not directly related to the earlier or later basaltic volcanism. The rhyolite was probably formed during intracrustal melting which was related to the rise of basaltic magma into the crust.Between 12 and 9.7 m.y. a large volcanic dome, composed mainly of hawaiite, was built at Lyttelton. Dykes, which intrude the Lyttelton volcanic sequence, range in composition from basalt to trachyte. Late, mildly alkalic, basaltic flank flows (7.5–5.8 m.y.) occur in several areas and they, and the differentiated rocks of the dyke swarm can be related by a crystal fractionation model which has been quantitatively tested.Following construction of the Lyttelton dome a second larger dome was built at Akaroa between 9 and 7.5 m.y. The rocks of the Akaroa Volcano are principally hawaiites but rocks ranging in composition through to trachyte also occur. The differentiated rocks of the Akaroa volcano have derived from the basaltic rocks by a crystal fractionation controlled process, operating during ascent through the crust.None of the Banks Peninsula basalts appear to have derived from primitive (pyrolitic) mantle material, but progressive changes in the chemistry of the basalts with time implies that the mantle source regions were evolving geochemically as partial melting proceeded. Later lavas tend to be more alkalic and to have lower MgO/FeO ratios than earlier lavas. The volcanic rocks of the Banks Peninsula volcanoes were derived by fractional removal of olivine, plagioclase, clinopyroxene, magnetite and apatite from ascending basaltic magma batches. Variations between the suites reflect differences between the parental magma batches. 相似文献
10.
Plagioclase separates from the Layered Series (LS), Upper Border Series (UBS), and Marginal Border Series (MBS) of the Skaergaard
intrusion were analyzed to examine major and trace element variations. In general, plagioclase from the LS, UBS, and MBS show
similar trends in major elements vs. crystallization: SiO2, Na2O, and K2O progressively increase, and CaO and MgO progressively decrease with fractionation. No abrupt changes in the trends of major
components of Skaergaard plagioclase during the differentiation of the intrusion are observed. Trace elements in plagioclase
reflect changes in the Skaergaard magma and changes in plagioclase distribution coefficients with differentiation. Sr, Ga,
and probably Ba are included elements in Skaergaard plagioclase, but were excluded from the other cumulus phases, and as a
result systematically increased in the magma and plagioclase during differentiation. Be, Cs, Hf, Rb, Ta, U, and Zr, and the
transition metals Co, Cr, Cu, Ni, Sc, V, and Zn were excluded elements in Skaergaard plagioclase, and remained low in plagioclase
during differentiation. Changes in the abundances of these elements in plagioclase during differentiation reflect changes
in their abundance in the magma. With the exception of the lower zone, which is enriched in the light rare earth elements,
rare earth elements in LS plagioclase, in general, increase with differentiation of the Skaergaard intrusion, but decrease
dramatically at the UZa/UZb boundary where abundant apatite first appears. Rare earth elements in UBS plagioclase followed
a similar trend to LS plagioclase, except during the initial and final stages of differentiation. UBS plagioclase is much
more enriched in rare earth elements during the final 20% of crystallization, except for Eu, which is similar in plagioclase
from the two series. The observed trends suggest that the floor and roof sequences became isolated from each other and that
the floor sequence may have been more reducing and the roof sequence more oxidizing during the final 20% of crystallization.
As the Skaergaard magma ceased convection, or convected as isolated cells, during the final stages of differentiation, volatile
elements may have accumulated in the UBS magma, resulting in an increase in ƒO2, and a decrease in Eu/Sm in UBS plagioclase. The observed trends of rare earth elements in plagioclase from the LS and UBS
fit well with theoretical calculations that assume closed-system crystallization, and would be difficult to reconcile with
any model requiring significant discharge of magma from the chamber during the final 20% of crystallization. The enrichment
of light rare earth elements in plagioclase, suggests that the lower part of the intrusion re-equilibrated with a late, light
rare earth element-rich fluid or melt. The recharge model proposed by earlier workers to explain anomalous Sr and Nd isotopes
appears unlikely in light of the two to fourfold enrichment of light rare earth elements in these samples.
Received: 1 October 1999 / Accepted: 14 May 2000 相似文献
11.
In this study potential iron isotope fractionation by magmatic processes in the Earth's crust was systematically investigated. High precision iron isotope analyses by MC-ICP-MS were performed on a suite of rock samples representative for the volcanic evolution of the Hekla volcano, Iceland. The whole series of Hekla's rocks results from several processes. (i) Basaltic magmas rise and induce partial melting of meta-basalts in the lower part of the Icelandic crust. The resulting dacitic magma evolves to rhyolitic composition through crystal fractionation. During this differentiation the δ56/54FeIRMM-014 values increase successively from 0.051 ± 0.021‰ for the primitive dacites to 0.168 ± 0.021‰ for the rhyolites. This increase can be described by a Rayleigh fractionation model using a constant bulk fractionation factor between all mineral phases (M) and the silicate liquid (L) of Δ56/54FeM–L = ? 0.1‰. (ii) The basaltic magma itself differentiates by crystal fractionation to basaltic andesite composition. No Fe isotope fractionation was found in this series. All basalts and basaltic andesites have an average δ56/54FeIRMM-014 value of 0.062 ± 0.042‰ (2SD, n = 9), identical to mean terrestrial basaltic values reported in previous studies. This observation is consistent with the limited removal of iron from the remaining silicate melt through crystal fractionation and small mineral-melt Fe isotope fractionation factors expected at temperatures in excess of 1050 °C. (iii) Andesites are produced by mixing of basaltic andesite with dacitic melts. The iron isotope composition of the andesites is matching that of the basaltic andesites and the less evolved dacites, in agreement with a mixing process. In the Hekla volcanic suite Li concentrations are positively correlated with indicators of magma differentiation. All Hekla rocks have δ7Li values typical for the upper mantle and demonstrate the absence of resolvable Li isotope fractionation during crystal fractionation. As a fluid-mobile trace element, Li concentrations and isotopes are a potential tracer of magma/fluid interaction. At Hekla, Li concentrations and isotope compositions do not indicate any extensive fluid exsolution. Hence, the heavy Fe isotope composition of the dacites and rhyolites can be predominately attributed to fractional crystallisation. Iron isotope analyses on single samples from other Icelandic volcanoes (Torfajökull, Vestmannaeyjar) confirm heavy Fe isotope enrichment in evolving magmas. Our results suggest that the iron isotope composition of highly evolved crust can be slightly modified by magmatic processes. 相似文献
12.
Calc-alkaline dacites are found in the Tertiary Kroksfjordurcentral volcano besides the more typical tholeiitic dacitesand rhyolites characteristic of Icelandic rift zones. It isclear that these calc-alkaline dacites are not subduction related,but their chemistry and petrography are definitely calc-alkaline.They are much lower in Fe and higher in Ca and Al than otherrocks from Iceland with comparable silica percentages. Theyare significantly depleted in the high field strength elements(HFSE, e.g., Nb, Zr, Y, and heavy rare earth elements), andsome of them contain hydrous phases or their relics. The anhydrousphase assemblage and relatively high Fe content of the tholeiiticsilicic rocks indicate generation at shallow depths (PH2o <1kb). The high Ca and Al contents and the depletion of HFSE inthe calc-alkaline dacites indicate generation by partial meltingof amphibolite facies rocks at 5–6 km depth. The generationof the tholeiitic silicic rocks requires a shallow magma chamber,where they could be formed by fractionation of basaltic magma,or by partial melting of country rock heated by basaltic magma.The calc-alkaline dacites require a different volcanotectonicenvironment for their generation. The geothermal gradient requiredis comparable with that of regional geothermal gradients closeto the active rift zones. They were probably formed when thecentral volcano was drifting away from the rift axis and itsactivity was waning. Intrusion of basaltic magma, probably relatedto another volcanic center, mobilized the dacite magma. 相似文献
13.
南澜沧江结合带火山岩岩浆成因——洋脊洋岛与弧岩浆作用的性质 总被引：10，自引：1，他引：9
在对滇西南昌宁—孟连带石炭—二叠纪火山岩和南澜沧江带二叠—三叠纪火山岩的微量元素和稀土元素研究的基础上,划分了岩浆作用类型和岩浆演化系列,探讨了岩浆源区成分特点。昌宁—孟连带玄武质岩浆的演化主要受部分熔融和分离结晶作用控制;这些岩浆可以划分为３个岩浆演化系列：（１）稀土曲线平坦型的洋脊型拉斑玄武岩浆演化系列,其岩浆起源于亏损型地幔;（２）稀土曲线中等富集型的准洋脊型拉斑玄武岩浆演化系列,其岩浆起源于过渡型地幔;（３）稀土曲线强烈富集型的洋岛型碱性玄武岩浆演化系列,其岩浆起源于富集型地幔。南澜沧江带弧火山岩的岩浆成因主要受分离结晶作用控制,也可以划分为３个岩浆演化系列：（１）二叠纪低钾拉斑—中钾钙碱性岩浆演化系列;（２）中南段的晚三叠世低钾拉斑—中钾钙碱性岩浆演化系列;（３）北段的晚三叠世钾玄岩—高钾钙碱性岩浆演化系列 相似文献
14.
The Vandfaldsdalen macrodike, which lies in the Skaergaard region of East Greenland, is a remarkably zoned fossil magma chamber, with a granophyric cap overlying cumulate gabboros. The intrusion is distinctly bimodal, with a large compositional discontinuity at the contact between the gabbro and granophyre. Although the exposed part of the macrodike is in contact with Tertiary basalts and sediments, the granophyre originated by assimilation of xenoliths derived from the underlying Archean basement. Sr and Nd isotopic ratios throughout the cumulate sequence are remarkably similar, indicating insignificant contamination of the gabbro by the granophyre. Modelling of the compositional effects of cooling and crystallization indicate that the cumulate pile resulted from fractional crystallization, with the complicating effects of trapped liquid and post-cumulus fractionation. The uppermost rocks in the mafic part, of the chamber (SiO2=62%; FeO*=12.4%) resulted from about 85% fractional crystallization. A transgressive sill of strongly fractionated magma (SiO2=67%; FeO*=8.8%) formed from extracted intercumulus liquid that was the result of 90% fractional crystallization of the original magma. Mass-balance indicates that typical granophyre is made up of about 75% dissolved xenoliths, by weight, and 25% mantle-derived basaltic magma. The magmas were not measurably affected by material exchange across the interface between the gabbro and granophyre. This magma chamber evolved by both assimilation and fractional crystallization, but the residual liquids formed by fractional crystallization were unaffected by assimilation. Heat exchange between were unaffected by assimilation. Heat exchange between the two parts of the chamber was obviously important, but there was insignificant material exchange. The inability of fractional crystallization and assimilation to affect the same liquid is related to the dynamic behavior of this particular magma chamber, particularly the buoyancy of granophyre relative to evolving tholeiitic magma. 相似文献
15.
Don Snyder Ian S. E. Carmichael R. A. Wiebe 《Contributions to Mineralogy and Petrology》1993,113(1):73-86
The Newark Island layered intrusion, a composite intrusion displaying a similar fractionation sequence to the Skaergaard, has both dikes which preserved liquids fed into the intrusion and chilled pillows of liquids resident in the chamber. This study reports experimentally determined one atmosphere liquid lines of descent of these compositions as a function of oxygen fugacity which varies from QFM (quartz-fayalite-magnetite) to 0.5 log10 units above IW (iron-wustite). These experiments reveal a strong oxygen fugacity dependence on the order of appearance and relative abundances of the Fe–Ti oxide minerals. Titanomagnetite saturates prior to ilmenite at QFM, but the order is reversed at lower oxygen fugacities. In the layered series of the Newark Island intrusion, ilmenite arrives shortly before titanomagnetite and the titanomagnetite/ilmenite ratio decreases monotonically after the cumulus appearance of titanomagnetite. Comparison of the crystallization sequence in the intrusion with that of the experiments requires that the oxygen fugacity in the intrusion increased relative to QFM before titanomagnetite saturation and decreased afterward, but always remained between the QFM and IW buffers. Similar trends in the modes of the Fe–Ti oxides (ilmenite and titanomagnetite) in the Skaergaard, Kiglapait, and Somerset Dam intrusions along with Fe2O3/FeO ratios in MORBs suggest that such a temperature-oxygen fugacity path may be typical of tholeiitic magma differentiation. Calculations of the temperature-density paths of the experimental liquids indicate that, at all possible oxygen fugacities, the density must have decreased abruptly after Fe–Ti oxide saturation. Accordingly, liquids replenishing the intrusion after Fe–Ti oxide saturation should pond at the bottom of the chamber, quenching against older cumulates. Field observation at the Newark Island intrusion confirm this prediction. The similarities in the fractionation paths of several other layered intrusions to that of the Newark Island intrusion suggest that the density of the liquids in these intrusions also decreased after Fe–Ti oxide saturation. Experiments on a suggested initial Skaergaard liquid are consistent with this model. 相似文献
16.
The aim of this study is to quantify the crustal differentiation processes and sources responsible for the origin of basaltic
to dacitic volcanic rocks present on Cordón El Guadal in the Tatara-San Pedro Complex (TSPC). This suite is important for
understanding the origin of evolved magmas in the southern Andes because it exhibits the widest compositional range of any
unconformity-bound sequence of lavas in the TSPC. Major element, trace element, and Sr-isotopic data for the Guadal volcanic
rocks provide evidence for complex crustal magmatic histories involving up to six differentiation mechanisms. The petrogenetic
processes for andesitic and dacitic lavas containing undercooled inclusions of basaltic andesitic and andesitic magma include:
(1) assimilation of garnet-bearing, possibly mafic lower continental crust by primary mantle-derived basaltic magmas; (2)
fractionation of olivine + clinopyroxene + Ca-rich plagioclase + Fe-oxides in present non-modal proportions from basaltic
magmas at ∼4–8 kbar to produce high-Al basalt and basaltic andesitic magmas; (3) vapor-undersaturated (i.e., P
H2O<P
TOTAL) partial melting of gabbroic crustal rocks at ∼3–7 kbar to produce dacitic magmas; (4) crystallization of plagioclase-rich
phenocryst assemblages from dacitic magmas in shallow reservoirs; (5) intrusion of basaltic andesitic magmas into shallow
reservoirs containing crystal-rich dacitic magmas and subsequent mixing to produce hybrid basaltic andesitic and andesitic
magmas; and (6)␣formation and disaggregation of undercooled basaltic andesitic and andesitic inclusions during eruption from
shallow chambers to form commingled, mafic inclusion-bearing andesitic and dacitic lavas flows. Collectively, the geochemical
and petrographic features of the Guadal volcanic rocks are interpreted to reflect the development of shallow silicic reservoirs
within a region characterized by high crustal temperatures due to focused basaltic activity and high magma supply rates. On
the periphery of the silicic system where magma supply rates and crustal temperatures were lower, cooling and crystallization
were more important than bulk crustal melting or assimilation.
Received: 2 July 1997 / Accepted: 25 November 1997 相似文献
17.
Petrological and geochemical studies on some volcanic and sub-volcanic rocks from the Lower Benue rift indicate that they are basalts, basaltic and doleritic sills, trachybasalt and trachyte which generally belong to the alkali basalt series. The alkaline affinity is clearly evident in both their normative and modal mineral compositions, as well as their chemical compositions. The generally high fractionation indices [(La/Yb)N] are 7.06 to 17.65 for the basaltic rocks and 23.59 to 135. 35 for the trachytic rocks, against low values commonly seen in subalkaline (tholeiitic) series, with strong enrichments in the incompatible elements. All this strongly supports their alkaline affinity. The basaltic rocks are generally fine-grained and porphyritic, consisting of phenocrysts of clinopyroxene and olivine in the groundmass of the same minerals together with plagioclase. The clinopyroxene is either diopside or clinoenstatite. The trachyte consists of oligoclase, orthoclase, biotite, quartz and exhibits typical trachytic, flow structure. The basaltic and doleritic sills are commonly altered, with calcite and epidote as common alteration prod-ucts. This alteration, which is reflected in the erratic behaviour of K2O, MnO and P2O5 on Harker variation diagrams, high values of LOI, strong depletions in the more mobile LILE (Rb, K, Ba and Sr) and high Th/Ta ratios, is attributed to the effects of an aqueous fluid phase and crustal contamination. On the whole, the mineralogical, as well as major-, trace-elements and REE data suggest that the rocks are co-genetic and most likely derived from differentiation of an alkali olivine-basalt magma, generating through variable low degrees of partial melting of probably an enriched lithospheric (upper) mantle following an asthenospheric uplift (mantle plume or intumescence) with HIMU signa-tures in a within-plate continental rift tectonic setting. This corroborates earlier results obtained for the intrusive rocks in the region. 相似文献
18.
R. H. Sutcliffe 《Contributions to Mineralogy and Petrology》1987,96(2):201-211
Mafic rocks at Lake Nipigon provide a record of rift-related continental basaltic magmatism during the Keweenawan event at 1109 Ma. The mafic rocks consist of an early, volumetrically minor suite of picritic intrusions varying in composition from olivine gabbro to peridotite and a later suite of tholeiitic diabase dikes, sheets and sills. The diabase occurs primarily as two 150 to 200 m thick sills with a textural stratigraphy indicating that the sills represent single cooling units. Compositional variation in the sills indicates that they crystallized from several magma pulses.The diabases are similar in chemistry to olivine tholeiite flood basalts of the adjacent Keweenawan rift, particularly with respect to low TiO2, K2O and P2O5. The picrites have higher TiO2, K2O and P2O5 than the diabases and are similar to, but more primitive than, high Fe-Ti basalts which erupted early in the Keweenawan volcanic sequence.All of the rocks crystallized from fractionated liquids. The picrites are cumulate rocks derived at shallow crustal depths from a magma controlled predominantly by olivine fractionation. Picritic chills are in equilibrium with olivine phenocrysts of composition Fo80 and are interpreted to represent the least evolved liquids observed. The parental magma of the picrites was probably Fe rich relative to the parental magma of the diabase. The diabase sills crystallized from an evolved basaltic liquid controlled by cotectic crystallization of plagioclase and lesser olivine and pyroxene.The emplacement of dense olivine phyric picritic magmas early in the sequence, followed by later voluminous compositionally evolved magmas of lower density suggests the development of a crustal density filter effect as the igneous event reached a peak. Delamination of the crust-mantle interface may have resulted in the transition from olivine controlled primitive magma to fractionated magma through the development of crustal underplating. 相似文献
19.
新疆哈密香山西铜镍-钛铁矿床系同源岩浆分异演化产物——矿相学、锆石U-Pb年代学及岩石地球化学证据 总被引：19，自引：9，他引：10
香山西岩体是东天山地区发现的唯一的一个铜镍-钛铁复合型含矿岩体,前人对香山西铜镍-钛铁矿床成因认识一直存在争议。本次通过矿相学研究结合电子探针分析,在香山西铜镍矿石中发现了铜镍硫化物与钛铁氧化物共生的现象,并首次测定了香山西钛铁辉长岩的SIMS锆石U-Pb年龄为278.6±1.8Ma(MSWD=1.2),与前人测得香山中岩体角闪辉长岩的锆石U-Pb年龄基本一致,证实了香山西铜镍矿与钛铁矿为共生关系,两者空间上渐变过渡。岩石地球化学研究表明,香山岩体(包括钛铁辉长岩)为同源岩浆经结晶分异作用形成的一套镁铁-超镁铁质岩体,具有拉斑玄武质岩浆分异演化趋势,并且经历了与地壳物质的混染。与中段和东段岩石相比,香山西辉长岩类具有相对高的REE、SiO2(平均48.99%)、K2O+Na2O(平均3.43%)、TiO2(平均1.26%)和明显低的Mg#值(平均62.4),表现出分异演化程度高于中段和东段。经反演得出香山岩体原始岩浆含MgO约10%,FeO约9%,TiO2约1.14%,与同一成矿带内其它含铜镍矿岩体原始岩浆成份相近,应为 普通的拉斑玄武质岩浆。因此,香山西钛铁矿床的形成机制可能是由普通的拉斑玄武质岩浆,经历了较高程度的分异演化导致钛铁氧化物在残余岩浆中逐步富集,岩浆在上升侵位过程中与地壳物质的混染,不仅促使了岩浆中硫化物的饱和,同时提高了岩浆体系的氧逸度,进而促使了钛铁氧化物结晶沉淀。对香山西钛铁矿床成因研究的启示意义在于,除我国攀西地区高钛的玄武质岩浆外,普通的拉斑玄武质岩浆,在有利的分异演化条件下(如初始低氧逸度、相对高度的分异演化、后期与地壳物质混染)也有可能形成大型钛铁矿床。 相似文献
20.
Fe-rich tholeiitic liquids and their cumulate products in the Pleasant Bay layered intrusion, coastal Maine 总被引：4，自引：0，他引：4
R. A. Wiebe 《Contributions to Mineralogy and Petrology》1997,129(4):255-267
Fe-rich tholeiitic liquids are preserved as chilled pillows and as the chilled base of a 27 meter thick macrorhythmic layer
in the Pleasant Bay mafic-silicic layered intrusion. The compositions of olivine (Fo1) and plagioclase (An13−8) in these extremely fine grained rocks suggest that they represent nearly end stage liquids that formed by fractionation
of tholeiitic basalt. Their major element compositions (∼17.5 wt% FeOT and 54 wt%SiO2) closely resemble highly evolved glasses in the Loch Ba ring dike and some recent estimates of end-stage liquids related
to the Skaergaard layered intrusion, and are consistent with recent experimental studies of tholeiite fractionation. Their
trace element compositions are consistent with extensive earlier fractionation of plagioclase, olivine, clinopyroxene, ilmenite,
magnetite and apatite. The mineral assemblage of the chilled rocks (olivine, clinopyroxene, quartz, ilmenite and magnetite),
apatite saturation temperatures, and very low Fe3+/Fe2+indicate conditions of crystallization at temperatures of about 950 °C and f
O
2
about two log units below FMQ. Cumulates that lie about 3 meters above the chilled base of the macrorhythmic layer contain
cumulus plagioclase, olivine, clinopyroxene, ilmenite, apatite and zircon. This mineral assemblage and the Fe-Mg ratio in
clinopyroxene cores suggest that this cumulate was in equilibrium with a liquid having a composition identical to that of
the chilled margin which lies directly beneath it. The high FeOT and low SiO2 concentrations of this cumulate (23.3 and 45.8 wt%, respectively) are comparable to those in late stage cumulates of the
Skaergaard and Kiglapait intrusions. This association of a chilled liquid and cumulate in the Pleasant Bay intrusion suggests
that late stage liquids in tholeiitic layered intrusions may have been more SiO2-rich than field-based models suggest and lends support to recent experimental studies of tholeiite fractionation at low f
O2 which indicate that saturation of an Fe-Ti oxide phase should cause FeOT to decrease in the remaining liquid.
Received: 17 January 1997 / Accepted: 10 June 1997 相似文献