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1.
Daníel Freyr Jónsson Esther Ruth Gudmundsdóttir Gudrún Larsen Bergrún Arna Óladóttir Egill Erlendsson Sigrún Dögg Eddudóttir Olgeir Sigmarsson 《第四纪科学杂志》2020,35(3):410-421
Large Plinian eruptions from Hekla volcano, Iceland, produce compositionally zoned tephra used as key markers in tephrochronology. However, spatial variations in chemical composition of a tephra layer may complicate its identification. An example is the 5950–6180 cal a bp Hekla Ö tephra layer, which shows compositional spread from rhyolite, dacite and andesite to basalt. In soil sections north of Hekla, the SiO2 content of the tephra glass reaches 76 wt% in the lowest unit of the Hekla Ö deposit and decreases to 62–63 wt% in the uppermost unit. Intermingled within the whole deposit are basalt tephra grains having 46–47 wt% SiO2. The composition of the basalt glass includes primitive basalt and a more evolved basalt (MgO >6 and <6 wt%, respectively). Together with literature data, the Hekla Ö tephra and the so-called T-Tephra/Hekla-T are most likely from contemporaneous eruptions of different vents on the Hekla volcanic system, forming a single important marker tephra (Hekla ÖT) deposited over 80% of Iceland. Identification is complicated by its spatial compositional heterogeneity, such as systematic decrease in SiO2 content from the east to the west of Hekla volcano. Consequently, an individual tephra layer from a large explosive eruption can have different composition at different locations. © 2020 John Wiley & Sons, Ltd. 相似文献
2.
Segregation veins are common in lava sheets and result from internal differentiation during lava emplacement and degassing.
They consist of evolved liquid, most likely replaced by gas-filter pressing from a ∼50% crystallised host lava. Pairs of samples,
host lavas and associated segregation veins from the Reykjanes Peninsula (Iceland), Lanzarote (Canary Islands) and the Masaya
volcano (Nicaragua) show extreme mineralogical and compositional variations (MgO in host lava, segregation veins and interstitial
glass ranges from 8–10 wt%, 3–6 wt%, and to less than 0.01 wt%, respectively). These samples allow the assessment of the internal
lava flow differentiation mechanism, since both the parental and derived liquid are known in addition to the last magma drops
in the form of late interstitial glasses. The mineralogical variation, mass-balance calculated from major- and trace element
composition, and transitional metal partition between crystals and melts are all consistent with fractional crystallisation
as the dominant differentiation mechanism. The interstitial glasses are highly silicic (SiO2 = 70–80 wt%) and represent a final product of high-degree (75–97%) fractional crystallisation of olivine tholeiite at a pressure
close to one atmosphere. The tholeiitic liquid-line-of-decent and the composition of the residual melts are governed by the
K2O/Na2O of the initial basaltic magma. The granitic minimum is reached if the initial liquid has a high K2O/Na2O whereas trondhjemitic composition is the final product of magma with low initial K2O/Na2O.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
3.
Olgeir Sigmarsson Didier Laporte Marion Carpentier Bertrand Devouard Jean-Luc Devidal Joan Marti 《Contributions to Mineralogy and Petrology》2013,165(3):601-622
Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF6, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes. 相似文献
4.
Katla volcano,Iceland: magma composition,dynamics and eruption frequency as recorded by Holocene tephra layers 总被引：1，自引：0，他引：1
Bergrún Arna Óladóttir Olgeir Sigmarsson Gudrun Larsen Thor Thordarson 《Bulletin of Volcanology》2008,70(4):475-493
The Katla volcano in Iceland is characterized by subglacial explosive eruptions of Fe–Ti basalt composition. Although the
nature and products of historical Katla eruptions (i.e. over the last 1,100 years) at the volcano is well-documented, the
long term evolution of Katla’s volcanic activity and magma production is less well known. A study of the tephra stratigraphy
from a composite soil section to the east of the volcano has been undertaken with emphasis on the prehistoric deposits. The
section records ∼8,400 years of explosive activity at Katla volcano and includes 208 tephra layers of which 126 samples were
analysed for major-element composition. The age of individual Katla layers was calculated using soil accumulation rates (SAR)
derived from soil thicknesses between 14C-dated marker tephra layers. Temporal variations in major-element compositions of the basaltic tephra divide the ∼8,400-year
record into eight intervals with durations of 510–1,750 years. Concentrations of incompatible elements (e.g. K2O) in individual intervals reveal changes that are characterized as constant, irregular, and increasing. These variations
in incompatible elements correlate with changes in other major-element concentrations and suggest that the magmatic evolution
of the basalts beneath Katla is primarily controlled by fractional crystallisation. In addition, binary mixing between a basaltic
component and a silicic melt is inferred for several tephra layers of intermediate composition. Small to moderate eruptions
of silicic tephra (SILK) occur throughout the Holocene. However, these events do not appear to exhibit strong influence on
the magmatic evolution of the basalts. Nevertheless, peaks in the frequency of basaltic and silicic eruptions are contemporaneous.
The observed pattern of change in tephra composition within individual time intervals suggests different conditions in the
plumbing system beneath Katla volcano. At present, the cause of change of the magma plumbing system is not clear, but might
be related to eruptions of eight known Holocene lavas around the volcano. Two cycles are observed throughout the Holocene,
each involving three stages of plumbing system evolution. A cycle begins with an interval characterized by simple plumbing
system, as indicated by uniform major element compositions. This is followed by an interval of sill and dyke system, as depicted
by irregular temporal variations in major element compositions. This stage eventually leads to a formation of a magma chamber,
represented by an interval with increasing concentrations of incompatible elements with time. The eruption frequency within
the cycle increases from the stage of a simple plumbing system to the sill and dyke complex stage and then drops again during
magma chamber stage. In accordance with this model, Katla volcano is at present in the first interval (i.e. simple plumbing
system) of the third cycle because the activity in historical time has been characterized by uniform magma composition and
relatively low eruption frequency. 相似文献
5.
Bergrún Arna Óladóttir Gudrún Larsen Olgeir Sigmarsson 《Bulletin of Volcanology》2011,73(9):1187-1208
Assessment of potential future eruptive behaviour of volcanoes relies strongly on detailed knowledge of their activity in the past, such as eruption frequency, magnitude and repose time. The eruption history of three partly subglacial volcanic systems, Grímsvötn, Bárdarbunga and Kverkfjöll, was studied by analysing tephra from soil profiles around the Vatnajökull ice-cap, which extend back to ~7.6 ka. Well known regional Holocene marker tephra (e.g. H3, H4, H5) were utilized to correlate profiles. Stratigraphic positions and geochemical compositions were used for fine-scale correlation of basaltic tephra. Around Vatnajökull ice-cap 345 tephra layers were identified, of which 70% originated from Grímsvötn, Bárdarbunga or Kverkfjöll. The eruption frequency of each volcanic system was estimated; Grímsvötn has been the most active with an average of ~7 eruptions/100 years (range 4–14) during prehistoric time (before ~870 AD); Bárdarbunga has been the second most active with ~5 eruptions/100 years (range 1–8); and Kverkfjöll has remained essentially calm with 0–3 eruptions/100 years but showing periodic activity with repose times of >1000 years. All three volcanic systems experienced lulls in activity from 5 ka to 2 ka, referred to as the “Mid-Holocene low”. This reduced eruption frequency appears to have resulted from a decrease in magma generation and delivery from the mantle plume rather than from changes in ice-load/glacier thickness. In prehistoric time, there was a time lag of 1000–3000 years between a peak of activity at volcanoes directly above the mantle plume versus at volcanoes located in the non-rifting part of the Eastern Volcanic Zone, closer to the periphery of the island. This time-space relationship suggests that a significant future increase in volcanism can be expected there, following increased levels of volcanism above the plume. 相似文献
6.
New Thorium Isotope Ratio Measurements in Silicate Reference Materials: A‐THO,AGV‐2, BCR‐2, BE‐N,BHVO‐2 and BIR‐1 
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下载免费PDF全文 Marion Carpentier Abdelmouhcine Gannoun Christian Pin Olgeir Sigmarsson 《Geostandards and Geoanalytical Research》2016,40(2):239-256
A two‐step Th isolation protocol, involving micro‐columns of TRU‐Spec extraction chromatography material and AG1 resin, was evaluated. The MC‐ICP‐MS procedure included 232Th tailing characterisation and correction, and calibrator bracketing using an in‐house standard solution (ThS1) to correct for instrumental mass bias and Faraday cup to secondary electron multiplier relative gain. Repeated analyses of reference solutions (UCSC Th ‘A’, WUN, OU Th ‘U’, IRMM‐36) were consistent with published data. Six reference materials (A‐THO, BCR‐2, AGV‐2, BHVO‐2, BE‐N and BIR‐1) were processed. The average 230Th/232Th values obtained for these samples are in excellent agreement with published data. In addition, we report the first 230Th/232Th values for BE‐N and BIR‐1. The intermediate precisions for rock samples ranged from ± 0.24 to ± 0.49% (2 RSD) and were similar to those achieved for synthetic solutions, thereby supporting the overall validity of the chemical separation, data acquisition and reduction procedures. Counting statistics on the 230Th isotope was the most significant source of uncertainty. The intermediate precision of the mean 230Th/232Th for the Th‐depleted BIR‐1 (5.64 × 10?6 ± 0.27%, 2 RSD) is in the range of the analyses of other reference materials analysed in this study. 相似文献
7.
87 Sr/86Sr (0.70322) and δ
18O ( ∼2.9‰), whereas significantly lower and higher values, respectively, are found in samples from the Bárdarbunga volcanic
system (0.70307 and 3.8‰). These results strongly indicate that the Gjálp magma originated from the Grímsv?tn magma system.
The 1996 magma is of an intermediate composition, representing a basaltic icelandite formed by 50% fractional crystallization
of a tholeiite magma similar in composition to that expelled by the 1998 Grímsv?tn eruption. The differentiation that produced
the Gjálp magma may have taken place in a subsidiary magma chamber that last erupted in 1938 and would be located directly
beneath the 1996 eruption site. This chamber was ruptured when a tectonic fracture propagated southward from Bárdarbunga central
volcano, as indicated by the seismicity that preceded the eruption. Our geochemical results are therefore not in agreement
with lateral magma migration feeding the 1996 Gjálp eruption. Moreover, the results clearly demonstrate that isotope ratios
are excellent tracers for deciphering pathways of magma migration and permit a clear delineation of the volcanic systems beneath
Vatnaj?kull ice sheet.
Received: 1 April 1998 / Accepted: 17 August 1999 相似文献
8.
Séverine Moune Pierre-J. Gauthier Olgeir Sigmarsson 《Geochimica et cosmochimica acta》2006,70(2):461-479
During its last eruption in February 2000, Hekla volcano (Iceland) emitted a sub-Plinian plume that was condensed and scavenged down to the ground by heavy snowstorms, offering the unique opportunity to study the chemistry of the gaseous plume released during highly explosive eruptions. In this paper, we present results on trace element and minor volatile species (sulfates, chlorides, and fluorides) concentrations in snow samples collected shortly after the beginning of the eruption. The goal of this study is to better constrain the degassing and mobility of trace elements in gaseous emissions. Trace element volatility at Hekla is quantified by means of enrichment factors (EF) relative to Be. Well-known volatile trace elements (e.g., transition metals, heavy metals, and metalloids) are considerably enriched in the volcanic plume of Hekla. Their abundances are governed by the primary magmatic degassing of sulfate and/or halide compounds, which are gaseous at magmatic temperature. Their volatility is, however, slightly lower than in basaltic systems, most likely because of the lower magma temperature and higher magma viscosity at Hekla. More surprisingly, refractory elements (e.g., REE, Th, Ba, and Y) are also significantly enriched in the eruptive plume of Hekla where their apparent volatility is two orders of magnitude higher than in mafic systems. In addition, REE patterns normalized to the Hekla 2000 lava composition show a significant enrichment of HREE over LREE, suggesting the presence of REE fluorides in the volcanic plume. Such enrichments in the most refractory elements and REE fractionation are difficult to reconcile with primary degassing processes, since REE fluorides are not gaseous at magma temperature. REE enrichments at Hekla could be attributed to incongruent dissolution of tephra grains at low temperature by F-rich volcanic gases and aerosols within the eruptive plume. This view is supported by both leaching experiments performed on Hekla tephra and thermodynamic considerations on REE mobility in hydrothermal fluids and modeling of glass dissolution in F-rich aqueous solutions. Tephra dissolution may also explain the observed enrichments in other refractory elements (e.g., Th, Y, and Ba) and could contribute to the degassing mass balance of some volatile trace elements, provided they are mobile in F-rich fluids. It thus appears that both primary magmatic degassing and secondary tephra dissolution processes govern the chemistry of eruptive plumes released during explosive eruptions. 相似文献
9.
Marie-Christine Gerbe Alain Gourgaud Olgeir Sigmarsson Russell S Harmon Jean-Louis Joron Ariel Provost 《Bulletin of Volcanology》1992,54(4):284-298
Pyroclastic deposits from the 1982–1983 eruption of Galunggung volcano (Java, Indonesia) reflect preeruptive magmatic evolution which is of interest because of: (1) its duration of nine months, compared to a few hours or days for most historical eruptions; (2) the diversity of eruptive styles, from ash and scoria flows to phreatomagmatic explosions, and to the strombolian activity that marked the end of the eruption; and (3) the progressive variation in chemical composition with time, from andesite (58 wt.% SiO2) to high-Mg basalt (47 wt.% SiO2). The 1982–1983 Galunggung basalts are rather primitive: 10 to 12 wt% MgO, 180 to 200 ppm Ni and 550 to 700 ppm Cr. Despite the presence of about 40% phenocrysts, they may represent the most primitive basalts recognized in western Java. Basalts contain phenocrysts of olivine (Fo90-80), diopside-salite, and plagioclase (An95-75). Andesites contain plagioclase (An80–60), augite, hypersthene (En67-64), and titanomagnetite. The distribution of mineral compositions in each petrographic type is nearly unimodal, although scarce plagioclase and olivine xenocrysts have been observed. Abundance of gabbroic cumulates associated with the pyroclastic flows and evolution of mineral compositions from high-Mg basalts to andesites support crystal fractionation as the main differentiation mechanism, although magma mixing of basaltic andesite and andesite cannot be excluded. Major and trace element trends, which display rough decreases of MgO, CaO, Ni, Cr with increasing degree of differentiation and also linear positive correlations of hygromagmaphile elements, are compatible with both processes. However, some discrepancies are observed between major and trace element modelling, which may be explained to some extent by the influence of in situ crystallization and/or magma mixing. The constancy of 143Nd/144Nd (0.51286±3), 230Th/232Th (0.65±0.02), Th/U (4.08±0.07) ratios, and to a lesser extent 18O values (+5.8 to +6.4 % SMOW) and 87Sr/86Sr ratios (0.70440 to 0.70468) is compatible with a magmatic evolution through fractional crystallization without significant crustal contamination. Nevertheless low-18O and high 87Sr/86Sr values in basaltic andesites may be due to the introduction of meteoric fluids into the Galunggung magma. 相似文献
10.
For the last two decades, Iceland and other oceanic plateaux have been considered as potential analogues for the formation of the early Earth's continental crust. This study examines the compositions of silicic rocks from modern oceanic plateaux, revealing their differences to Archaean continental rock types (trondhjemite–tonalite–granodiorite or TTG) and thereby emphasising the contrasted mechanisms and/or sources for their respective origins. In most oceanic plateaux, felsic magmas are thought to be formed by fractional crystallization of basalts. In Iceland, the interaction between mantle plume and the Mid‐Atlantic ridge results in an abnormally high geothermal gradient and melting of the hydrated metabasaltic crust. However, despite the current `Archaean‐like' high geothermal gradients, melting takes place at a shallow depth and is unable to reproduce the TTG trace element signature. Consequently, oceanic plateaux are not suitable environments for the genesis of the Archaean continental crust. However, their subduction could account for the episodic crustal growth which has occurred throughout the Earth's history. 相似文献