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1.
The strongly deformed eclogites are well developed in ultra-high pressure jadeite-quartzite zone of the Dabie Mountains, Eastern China, and garnets had been deformed strongly. Observations by transmission electron microscopy identified not only structure of plastic deformation occurring as free dislocation, dislocation loops and dislocation walls, but also clusters of water molecules present in the deformed garnet. Using infrared spectroscopy, two types of hydrous components are identified as the hydroxyl and free-water in the garnet. Based on analysis of microstructure mechanism of deformation in garnets, and experimental data of petrology, the clusters of water molecules were considered to lead strong plastic deformation of garnet by dislocations because of mechanical weakening.  相似文献   

2.
Dislocation microstructures in naturally deformed silicate garnets   总被引:1,自引:0,他引:1  
Dislocation microstructures of naturally deformed silicate garnets and olivines in garnet-peridotites and silicate garnets in eclogites from four localities have been observed with a transmission electron microscope (TEM) to clarify the dislocation characteristics of silicate garnets. We have obtained the following results: (1) dislocation densities of garnets in all the garnet-peridotites (ρ = 105−107 cm−2) are always nearly an order of magnitude lower than those of co-existing olivines; (2) dislocation densities of garnets in eclogites (ρ = 105−108 cm−2) which are embedded in garnet-peridotites are almost an order of magnitude higher than those of garnets in the surrounding garnet-peridotites; (3) the dominant Burgers vector, b, of mainly edge dislocations in garnet is 100 for specimens with dislocation density ρ = 105−106 cm−2, while b=1/2111 for specimens with ρ = 107−108 cm−2. Result (1) indicates that the observed dislocations in garnets were formed by plastic deformation under the same stresses as for co-existing olivines, and that there is a similar relationship between applied stress and dislocation density for garnets as for olivines. Result (2) suggests that the stress concentration occurred around eclogites embedded in garnet-peridotites, and the resulting differential stress in garnets in eclogites was further elevated by the interlocking of neighboring hard garnet grains. Finally, result (3) indicates that the dominant Burgers vector of mainly edge dislocations in garnet changes from 100 to 1/2111 with increasing applied differential stress.  相似文献   

3.
The rheology of rocks at depth remains a key point in earth sciences. Deformation of high-temperature–highpressure rocks from the subduction zone has not been fully studied; in particular, the deformation behavior of eclogites remains poorly understood. This research is focused on the microstructure and fabric of retrograded eclogites from the Hongqiyingzi Complex in Chicheng, north Hebei, China, based on photomicrography, scanning electron microscopy(SEM) and electron backscattered diffraction(EBSD) analysis. The analytical results show that plastic deformation occurred in the garnets during exhumation, but they do not show an obvious lattice preferred orientation(LPO). This can be interpreted as being caused by the simultaneous activation of multiple slip systems in the garnets during deformation by dislocation creep. The plagioclases have a special fabric; the(001) LPO presents a maximum in Z direction which can be correlated with a new [100](001) slip system. The misorientation angle distribution(MAD) of the plagioclases in the deformed retrograded garnet augens shows a special bimodal distribution with peaks in both a low-angle range(40?) and a high-angle range(140?). In the retrograded garnet augens(i.e. "white eye socket" garnets) the maximum peak moves from a high-angle range to a low-angle range when we analyze only those plagioclases surrounding the residual garnet porphyroclast. Deformation behavior is controlled by the crystallographic orientation of the host grain and the grain boundary sliding process. Hornblendes in different layers and the retrograded garnet augens show almost the same strong LPO patterns, which are correlated with the [001](010) slip system; and MAD diagrams show a peak in a low-angle range(40?). Integrating recent studies on metamorphism and geochronology, we argue that ductile deformation occurred during the exhumation periods together with retrograded metamorphism.  相似文献   

4.
Plastic properties of materials with garnet structure have been studied under wide temperature conditions, ranging from room temperature to 95% of the melting temperatures, using uniaxial compression and hot microhardness tests. Garnets studied include single crystals of oxide garnets (Y3Al5O12, Gd3Ga5O12 and Y3Fe5O12) and silicate garnets (various solid solutions, including grossular, almandine, andradite, pyrope, spessartine and uvarovite). Both uniaxial compression and hot hardness tests indicate that there is a general trend in the plasticity of garnets when the data are compared at normalized conditions (T/Tm andσ/μ), and that the resistance to plastic deformation in garnets is significantly higher than most of the other minerals in the Earth's mantle. Based on both stress-dip tests and microstructural observations, it is proposed that the creep strength of garnet is largely controlled by the resistance to dislocation glide rather than by recovery processes. This conclusion is consistent with the high Peierls stress inferred from the hot hardness tests. The high Peierls stress in garnets is, presumably, due to the large unit cell (i.e., long Burgers vectors) and/or the bcc packing, which are common to all garnets. We postulate, therefore, that the present results can be applied to the strength of high-pressure garnet (majorite) and suggest that garnet-rich layers in the Earth, such as subducted oceanic crust in the transition zone or a possibly garnet-rich (bottom part of the) transition zone, will be considerably stronger than surrounding regions.  相似文献   

5.
Garnet clinopyroxenites occur within foliated dunite in the Higashi-akaishi peridotite mass, located within the subduction-type high-pressure/low-temperature Sanbagawa metamorphic belt. The garnet clinopyroxenites contain 3–80% garnet, and garnet and clinopyroxene are homogeneously distributed. Garnet crystals contain extensive, regular dislocation arrays and dislocation networks, suggesting that dislocation creep was the dominant deformation mechanism. Analyses of crystallographic orientation maps indicate similar grain sizes and aspect ratios for garnet and clinopyroxene, regardless of modal composition, indicating that these minerals deformed with similar degree of plasticity. Moreover, indexes of crystallographic fabric intensity (i.e., J-index and M-index) for both garnet and clinopyroxene tend to increase with increasing modal composition of garnet. Fourier-transform infrared spectroscopy analysis revealed that water content in garnet is ~60 ppm, whereas that in clinopyroxene is ~70 ppm. Olivine crystal-preferred orientations in the Higashi-akaishi peridotite mass, characterized by [0 0 1] (0 1 0), are thought to have developed during deformation under wet conditions. Consequently, we argue that the presence of water could act to enhance garnet plasticity during deformation. The results reveal contrasting influences of water on the deformation of garnet and diopside: under wet conditions compared with dry, the strain rate increases by two orders of magnitude for garnet but by an order of magnitude for diopside. Given the influence of water on the creep strength of garnet, garnet within the Higashi-akaishi mass may have become significantly as weak as clinopyroxene during deformation.  相似文献   

6.
Palaeozoic kimberlites from Mengyin, Shandong and Fuxian, Liaoning, eastern China, contain plenty of mantle xenoliths (peridotites, eclogites) and megacrystic minerals. In-situ electron and ion microprobe analyses on garnets from these xenoliths and megacrysts as well as relevant theoretical modeling reveal that these garnets were more or less affected by kimberlitic silicate melts prior to the encapsulation, in which eclogitic garnet from Fuxian, Liaoning Province, was little affected by mantle metasomatism, representing the primitive depleted mantle composition. In contrast, garnet from Mengyin, Shandong Province, and all megacrystic garnets were completely modified by metasomatic melts/fluids and reached perfectly chemical equilibrium, thus reflecting the characteristics of the enriched mantle. It is inferred that old lithospheric mantle beneath the North China craton was fairly strongly modified by metasomatism before Palaeozoic kimberlite emplacement.  相似文献   

7.
The rheological properties of upper mantle rocks play an important role in controlling the dynamics of the lithosphere and mantle convection. Experimental studies and microstructures in naturally deformed mantle rocks usually imply that olivine controls the upper mantle rheology. Here we show for the first time evidence from the geometry of folded compositional layers in mantle rocks from Western Norway that garnet-rich rocks can have lower solid-state viscosities than olivine-rich rocks. Modeling of melt-free and dry rheology of garnet and olivine confirms that the reversed viscosity contrast between garnet-rich and olivine-rich layers for this folding event can be achieved over a relatively wide range of temperatures at low stress conditions when the fine-grained garnet deforms by diffusion creep while the coarse-grained olivine deforms by dislocation creep and/or diffusion creep.In general, modeling of the fold viscosity contrast shows that in the stable subcontinental lithospheric mantle or convecting mantle such a reversed viscosity contrast can be formed due to diffusion creep processes in fine-grained garnets in a dry mantle environment or at conditions where the garnet-pyroxene layer is partially molten, i.e. close to solidus–liquidus conditions in the upper mantle. Alternatively in cold plate tectonic settings, e.g. in subduction zones, some water-weakening is a feasible mechanism to create the reversed viscosity contrast between garnet and olivine.  相似文献   

8.
Makoto Takeuchi 《Island Arc》2013,22(4):477-493
In this study, the chemical and optical features of detrital garnets from the Middle Permian to Upper Triassic sandstones in the South Kitakami Belt, Northeast Japan, were examined to reveal the tectonic movement in the provenance. The sandstones contain a large amount of detrital grandite garnet grains with a wide range of andradite content. Among them, some grandite garnet grains show optically anisotropic features and rarely oscillatory zoning and sector twinning. The proportion of the detrital anisotropic grandite garnet increases from the Permian to the Middle Triassic and decreases in the Late Triassic. Such grandite garnets with various andradite contents occur in skarn deposits. Isotropic grandite garnets in the early stage of skarn evolution are distributed widely around a pluton, which affects the thermal metamorphism of the surrounding strata. However, anisotropic grandite garnets are formed along veinlets and fractures in the middle to late hydrothermal stage as the pluton cools, and their distribution is limited to a narrower area near the pluton compared to the metamorphic aureoles formed in the early stage. Changes in the chemical and optical features of the detrital garnets indicate a progressive denudation of the plutonic body accompanying skarn deposits in the provenance. The proportion of detrital anisotropic grandite garnet grains among all of the detrital grandite garnet is considered to be a sensitive indicator of the denudation level in a deeper part of the volcanic arc in association with skarn deposits, together with traditional sandstone composition datasets. This newly proposed method should be useful for clarifying the paleogeography during the Permian to Triassic in the East Asian continental margin, associated with uplift and denudation of the Permian volcanic arc, which seems to have been induced by the collision of the North China and South China Blocks.  相似文献   

9.
High-pressure and high temperature experiments at 20 GPa on (Mg,Fe)SiO3 have revealed stability fields of two types of aluminium-free ferromagnesian garnets; non-cubic garnet and cubic garnet (majorite). Majorite garnet is stable only within a limited compositional variation, 0.2 < Fe/(Mg + Fe)< 0.4, and in the narrow temperature interval of 200°C around 2000°C, while the stability of non-cubic garnet with more iron-deficient compositions persists up to higher temperatures. These two garnets show fractional melting into iron-deficient garnet and iron-rich liquid, and the crystallization field of cubic garnet extends over Fe/(Mg + Fe)= 0.5. The assemblage silicate spinel and stishovite is a low-temperature phase, which also occurs in the iron-rich portion of the MgSiO3—FeSiO3 system. The sequence as given by the Fe/(Mg + Fe) value for the coexisting phases with the two garnets at 2000°C and 20 GPa is: silicate modified spinel aluminium-free garnets silicate spinel.Natural majorite in shock-metamorphosed chondrites is clarified to be produced at pressures above 20 GPa and temperatures around 2000°C. Similar shock events may cause the occurrence of non-cubic garnet in iron-deficient meteorites. Non-cubic garnet could be a stable phase in the Earth's mantle if a sufficiently low concentration of aluminium is present in the layer corresponding to the stable pressure range of non-cubic garnet. The chemical differentiation by melting in the deep mantle is also discussed on the basis of the present experimental results and the observed coexistence of majorite garnet with magnesiowüstite in chondrites.  相似文献   

10.
沂沭断裂带古应力值的探讨   总被引:2,自引:0,他引:2       下载免费PDF全文
本文侧重于利用变形矿物显微构造估算断裂带古应力值的一些理论分析和方法介绍。并以变形石英晶内自由位错密度ρ和方解石变形双晶百分比分别估算了沂沭断裂带西支北段的沂水-汤头断裂及鄌郚-葛沟断裂燕山晚期(K_1后)构造活动的应力值,其结果分别为1000—1500巴和700—1100巴量级。断裂带显微构造可能表明在地质时期的构造应力场作用中,稳态位错蠕变既可发生于韧性变形,又可发生于脆—韧性变形过程中。考虑到断层带“水”的因素,估算中采用McCormick关系式较Weathers关系式可能更接近实际  相似文献   

11.
对那庐断裂带南段构造岩特别是中深层次韧性剪切带中的糜棱岩进行了研究自北向南于部庐断裂带主干断裂沿线选取6条有代表性的初一脆性剪切带进行地质测量,应用高分辨透射电子显微镜对构造岩中变形石英的位错结构进行观察,求得了韧性剪切作用下构造岩石所受的古差异应力和应变速率等一系列应变参数从显微构造角度提出了郊庐断裂带与大别一胶南造山带构造复合(叠加)的证据:构造岩石的一组应变参数是郊庐断裂带的产物,严格受其中的韧性剪切带控制,另一组系大别-胶南造山带与部庐断裂带复合的产物还讨论了都庐断裂带南段中深层次构造岩的变形一变质历史  相似文献   

12.
OM (optical microscope)/TEM (transmission electron microscope) micro- and submicrostructural analysis of hornblende rocks sheared at high temperatures from the Diancangshan area, western Yunnan reveals evidence for deformation in the brittle-ductile transition of hornblende at middle crustal level (about 637℃ and 0.653 GPa) and mechanisms of deformation in the transitional regime are further discussed. Sheared hornblende rocks at middle crustal level have typical mylonitic microstructures, shown by coarse porphyroclasts and fine matrix grains. Different mineral phases in the rocks show distinct deformation characteristics. Hornblende and feldspar grains are intensely deformed with ob- vious grainsize reduction, but quartz grains are recrystallized dominantly by grain growth. Hornblende grains show typical brittle-ductile transition nature. Initial crystallographic orientations of porphyro- clasts have strong effects on the behavior of grains during deformation. There are mainly two types of porphyroclasts, type I "hard" porphyroclasts and type II "soft" porphyroclasts, with [001] perpendicular and parallel to external shear stresses respectively. "Hard" porphyroclasts generally occur as compe- tent grains that are rarely deformed or sometimes deformed by fracturing and dislocation tangling. "Soft" porphyroclasts are highly deformed primarily by dislocation tangling (as shown in the cores of the porphyroclasts), but twinning, dislocation glide and climb probably due to hydrolytic weakening also contribute to dynamic recrystallization of the porphyroclasts into fine grains in the matrix. The micro- and submicrostructures of the two types of porphyroclasts and fine-grained matrix provide powerful evidence for the behavior of brittle-ductile transition of hornblende grains. It is concluded that twinning nucleation is one of the most important processes that operate during dynamic recrystalliza- tion of hornblende crystals at the brittle-ductile transition. (100) [001] twin gliding and dislocation creep (dislocation glide and climb) are mutually enhanced during twinning nucleation. As a newly discovered mechanism of dynamic recrystallization, it may have played more important roles than ever recognized during dynamic recrystallization of crystals with twins in the brittle-ductile transition.  相似文献   

13.
镍锗尖晶石位错域的高温蠕变实验研究   总被引:9,自引:1,他引:9       下载免费PDF全文
利用人工合成的多晶材料研究了镍锗尖晶石在位错域的高温蠕变性质.多晶材料的颗粒尺寸约8μm.单轴压缩试件为圆柱状,使用气体介质围压筒.常压蠕变试验过程中,围压为300MPa,温度为1373-1523K,应力在55-330MPa范围内.从实验结果得出了镍锗尖晶石在位错域的流动律,应力指数n=29±01,表明流动的微观机制为位错蠕变.与其他尖晶石进行对比可以发现一个力学同构群,虽然在正尖晶石和反尖晶石之间存在一定的差异.在位错蠕变域,尖晶石与橄榄石归一化的强度类似.由于尖晶石的剪切模量比橄榄石高50%,其实际强度也比橄榄石高.将橄榄石和尖晶石的蠕变数据外推到地球内部条件时,由于其高应力指数,橄榄石则有可能比尖晶石的强度高.  相似文献   

14.
Using Fourier transform infrared spectroscopy (FTIR), we measured water contents of quartz and feldspar for four thin sections of felsic mylonite and two thin sections of banded granitic gneiss col- lected from a ductile shear zone of middle crust along the Red Rivers-Ailaoshan active fault. The ab- sorbance spectra and peak position suggest that water in quartz and feldspar of granitic gneiss and felsic mylonite occurs mainly as hydroxyl in crystal defect, but also contains inclusion water and grain boundary water. The water contents of minerals were calculated based on the absorbance spectra. Water content of feldspar in granitic gneiss is 0.05 wt%-0.15 wt%, and that of quartz 0.03 wt%-0.09 wt%. Water content of feldspar ribbon and quartz ribbon in felsic mylonite is 0.095 wt%-0.32 wt%, and those of fine-grained feldspar and quartz are 0.004 wt%-0.052 wt%. These data show that the water content of weakly deformed feldspar and quartz ribbons is much higher than that of strongly deformed fine-grained feldspar and quartz. This suggests that strong shear deformation leads to breakage of the structures of constitutional water, inclusion and grain boundary water in feldspar and quartz, and most of water in minerals of mylonite is released to the upper layer in the crust.  相似文献   

15.
Major and trace element zonation patterns were determined in ultrahigh-pressure eclogite garnets from the Western Gneiss Region (Norway). All investigated garnets show multiple growth zones and preserve complex growth zonation patterns with respect to both major and rare earth elements (REE). Due to chemical differences of the host rocks two types of major element compositional zonation patterns occur: (1) abrupt, step-like compositional changes corresponding with the growth zones and (2) compositionally homogeneous interiors, independent of growth zones, followed by abrupt chemical changes towards the rims. Despite differences in major element zonation, the REE patterns are almost identical in all garnets and can be divided into four distinct zones with characteristic patterns.In order to interpret the major and trace element distribution and zoning patterns in terms of the subduction history of the rocks, we combined thermodynamic forward models for appropriate bulk rock compositions to yield molar proportions and major element compositions of stable phases along the inferred pressure-temperature path with a mass balance distribution of REEs among the calculated stable phases during high pressure metamorphism. Our thermodynamic forward models reproduce the complex major element zonation patterns and growth zones in the natural garnets, with garnet growth predicted during four different reaction stages: (1) chlorite breakdown, (2) epidote breakdown, (3) amphibole breakdown and (4) reduction in molar clinopyroxene at ultrahigh-pressure conditions.Mass-balance of the rare earth element distribution among the modelled stable phases yielded characteristic zonation patterns in garnet that closely resemble those in the natural samples. Garnet growth and trace element incorporation occurred in near thermodynamic equilibrium with matrix phases during subduction. The rare earth element patterns in garnet exhibit distinct enrichment zones that fingerprint the minerals involved in the garnet-forming reactions as well as local peaks that can be explained by fractionation effects and changes in the mineral assemblage.  相似文献   

16.
Compositional zoning patterns of the major elements and REEs in prograde-zoned garnets whose Mg/(Mg + Fe) atomic ratios increase rimward have been widely used to understand the metamorphic PT–t trajectories, and the diffusion-limited REE-uptake model is a promising way to interpret their growth rates and the REE diffusion kinetics in the low-temperature eclogite. In order to elucidate their growth kinetics with Skora et al.'s (2006) diffusion-limited REE uptake model for prograde-zoned garnets, we examine the trace-element zoning patterns of two prograde-zoned porphyroblastic garnets (~6 mm in size) in low-temperature eclogites from two different localities. Core-to-rim trace-element profiles in a garnet (prp5–9alm61–67sps1–3grs24–30) of a glaucophane-bearing epidote eclogite of Syros (Cyclades, Greece) are characterized by the presence of Y + HREE peaks in the mantle, which might be attributed to a continuous breakdown of the titanite to form rutile during the garnet growth. In contrast, those in a garnet (prp4–7alm61–68sps3–10grs23–24) extracted from a lawsonite-eclogite of the South Motagua Mélange (SMM) (Guatemala) have prominent central peaks of Y + HREEs. Although the REE profiles of both the garnets can be explained by the diffusion-limited uptake, their Mn profiles suggest that their growth-rate laws are different: i.e., diffusion-controlled (Syros) and interface-controlled (SMM). Prior to the model application, we optimize the number of the parameters as the garnet grows with the interface-controlled processes based on the growth Péclet number. In particular, we propose the ratio of the REE diffusivity in the eclogitic matrix to the garnet growth rate as the new parameter. Visualizing the values of the new parameters allows to readily understand the relationship between the REE profiles and the REE-diffusion/garnet-growth kinetics in low-T eclogite. Our model refinement leads to the simple quantitative characterization of core-to-rim REE profiles in garnet in low-temperature eclogites.  相似文献   

17.
Distribution of hydrous components in jadeite of the Dabie Mountains   总被引:1,自引:0,他引:1  
Two kinds of jadeite occur in the jadeite-quartzite from the Dabie Mountains, Eastern China: associated either with weak or strong deformation. The former shows a uniform composition while the latter shows both uniform and zoning composition. These jadeites were examined with infrared (IR) spectroscopy. All jadeite displays hydroxyl (OH) stretching bands, implying that hydrous components commonly exist in jadeite. The concentration of the hydrous components in the jadeite with weak deformation is homogenous, whereas the concentration of the hydrous components in strongly deformed samples is variable. The correlation between the intensity of OH-band absorbance and compositional zoning of jadeite with strong deformation indicates that Na-rich jadeite can accommodate more OH than Na-poor jadeite. Its interpretation is that there is more Na associated with greater OH availability in the initial crystallization environment. Our data of the comparatively high OH concentrations recorded in the core of the jadeite which contains relative high vacancies in M2 site imply that both OH content and the vacancies in M2 site could decrease during exhumation of the jadeite-quartzite. The decrease of OH solubility in jadeite would result in the formation of H2O fluid during the early exhumation of UHP metamorphic rocks. The H2O fluid transformed from OH during exhumation could trigger and enhance the early retrograde metamorphism of the host rocks and facilitate plastic deformation of jadeite grain by dislocation creep and diffusion creep.  相似文献   

18.
Olivine flow mechanisms at 8 GPa   总被引:1,自引:0,他引:1  
The mechanisms responsible for high-temperature olivine deformation are investigated at a pressure of 8 GPa and temperatures up to 1780 K. San Carlos olivine specimens of different average grain sizes (0.5 and 5 μm) were deformed simultaneously between hard-alumina pistons during relaxation experiments. These experiments are carried out in a multi-anvil high-pressure apparatus coupled with synchrotron X-ray radiation. The different grain-size specimens experienced identical P-T-stress condition at any given time. A new method for measuring strains and strain rates (≥10−6 s−1) of specimens at high pressure is documented. This method uses time-resolved in situ X-ray imaging and an image-analysis computation. The microstructures of run products, recovered after being quenched at different temperatures were characterized by transmission electron microscopy (TEM). We find that high-temperature olivine flow is grain-size insensitive at 8 GPa, which suggests that dislocation creep dominates olivine deformation at high pressure. This result is confirmed by the TEM investigation of our deformed specimens in which we find evidences of the activation of olivine dislocation slip systems. Specimen microstructures are consistent with dynamic recrystallization as an assisting process in olivine deformation during the high-pressure experiments. Extrapolation of our results to the low stress level and large grain size expected in the mantle suggests that dislocation creep assisted by dynamic recrystallization may also dominate natural olivine deformation in the upper mantle.  相似文献   

19.
1999年9月21日台湾发生7.6级地震群,震时长沙井水位记录到了水震波和水位阶图象,本文分析了水城波及水位阶产生的机理,认为,震时地城 力波作用于含水层,使含以的流体压力及有效应力发生变化,周期作用的应力波是井口水位产生震荡变化的原因,而有效应力变化岩石骨架胀缩及岩石颗粒重排,岩石骨架胀缩的不可逆塑性变莆部分和岩石颗粒重排是造成震时水位阶的原因,其中,岩石骨架压缩缃起的水位阶在震后可以部分缓慢恢复。  相似文献   

20.
陈孝德  林传勇 《地震地质》1997,19(4):26-320
山西大同第四纪玄武岩中含有少量小型的幔源包体,主要为尖晶石二辉橄榄岩。包体的变形显微构造反映了上地幔条件下至少有两次变形事件;包体的平衡温度为900~1050℃,平衡压力为1.1~1.7GPa,对应的来源深度为40~60km。由包体的变形显微构造推导的上地幔流变学参数表明,该地区上地幔符合大陆拉张带上地幔的特征。在第四纪时期,该地区上地幔仍然继续其底辟上涌过程  相似文献   

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