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1.
The present article describes As(III) sorption behavior of novel calix[4]arene appended TS‐4 resin. The sorption ability of TS‐4 resin has been evaluated at wide range of pH, i.e., pH 2–14. The maximum As(III) sorption efficiency (95%) was achieved at pH 2, which shows that the TS‐4 resin possesses greater affinity for As(III) at this pH. Column sorption mechanism was evaluated through various operating parameters, i.e., change in concentration, flow rate, bed heights, and pH. The experimental data were also tested against bed depth service time model and from the results; it has been observed that the data is in close agreement with the theoretically calculated values. Thus, from the data it has been revealed that TS‐4 resin has maximum column efficiency of 0.13 mmol g?1. Application of TS‐4 to real samples indicates a slight decrease (2–3%) in extraction efficiency of TS‐4 because of high concentration of total dissolved salts. Thermal behavior was tested by differential scanning calorimetry and it has been observed that TS‐4 resin is stable up to 160°C. TS‐4 resin was found to be regenerable and best regeneration was achieved by using 4% solution of NaOH. It can be deduced from the study that the resin will find its applicability in small as well as industrial scale water purification plants.  相似文献   

2.
The adsorption kinetics of carbamazepine, naproxen, and trimethoprim in aqueous solution by Amberlite? XAD‐7 has been studied. The influence of adsorbent dose (1–3 g/L), stirring rate (80–240 rpm), pH (2–9), temperature (20–60°C), and initial concentration (25–75 ppm) on the adsorption kinetics has been analyzed. The removal efficiency in the first 2 h reaches 85% for carbamazepine, 60% for naproxen, and 70% for trimethoprim. pH appears to be the most important factor conditioning the removal of these latter solutes, whereas carbamazepine adsorption seems to be independent of the pH of the adsorptive solution. Initial concentration and operation temperature moderately influence the adsorption process. Finally, stirring rate scarcely affects the process. The experimental data have been fitted to four kinetic models, namely pseudo‐first and pseudo‐second order, intra‐particle diffusion and Bangham's. The model providing the best fit is the pseudo‐second order one. Again, pH is the factor that affects the adsorption rate in a more remarkable manner although other parameters such as temperature and stirring rate also contribute to accelerate the removal of the solutes. Under the optimal operation conditions, Amberlite? XAD‐7 exhibits a promising ability for the removal of the pharmaceuticals under study.  相似文献   

3.
Batch sorption technique was carried out for the removal of anionic dye Congo red (CR) from aqueous solution using raw rectorite (R‐REC) and organified rectorite (CTA+‐REC) modified by cetyltrimethylammonium bromide (CTAB) as adsorbents. The effects of organification degree of CTA+‐REC as well as the process parameters including the pH of dye solution, sorption time, and initial dye concentration on adsorption capacity for CR were investigated and the sorption kinetics was also evaluated. The results showed that the sorption behaviors of R‐REC and CTA+‐REC for CR followed pseudo‐second‐order kinetic model and the sorption equilibrium data perfectly obeyed the Langmuir isotherm. The thermodynamic parameters including entropy of sorption (ΔS0), enthalpy of sorption (ΔH0), and Gibbs free energy of sorption (ΔG0) were obtained and analyzed. Fourier transform infrared study revealed that a chemisorption process occurred between CR and CTA+‐REC. REC modified by cationic surfactants showed the higher adsorption capacities for CR compared to R‐REC and in theory would be used as an efficient and promising adsorbent for the removal of anionic dyes in wastewater treatment.  相似文献   

4.
A new sorbent was prepared by loading rhodamine B on Amberlite IR‐120. Various physico‐chemical parameters such as effects of adsorbate concentration, contact time, pH, and temperature on the sorption of the dye have been studied. Thermodynamic parameters (ΔH° and ΔS°) were also evaluated for the sorption of dye. Kinetic studies revealed that the sorption of the dye was best fit for pseudo‐second‐order kinetic. The metal ion uptake in different solvent systems has been explored through column studies. On the basis of distribution coefficient (Kd), some heavy metal ions of analytical interest from binary mixtures have been separated. The limit of detection (LOD) for the Ni2+ and Fe3+ metal ions was 0.81 and 0.60 µg L?1, and the limit of quantification (LOQ) was found to be 2.72 and 2.0 µg L?1. This sorbent has also been successfully applied in the analysis of multivitamin formulation. The applicability of the modified resin in the separation of heavy metals constituting real and synthetic samples has been explored.  相似文献   

5.
A stable extractor of metal ions was synthesized through azo linking of o‐hydroxybenzamide (HBAM) with Amberlite XAD‐4 (AXAD‐4) and was characterized by elemental analyses, IR spectral, and thermal studies. Its water regain value and hydrogen ion capacity were found to be 12.93 and 7.68 mmol g?1, respectively. The optimum pH range (with the half‐loading time [min], t1/2) for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were 2.0–4.0 (5.5), 2.0–4.0 (7.0), 2.0–4.0 (8.0), 4.0–6.0 (9.0), 4.0–6.0 (12.0), and 2.0–4.0 (15.0), respectively. Comparison of breakthrough and overall capacities of the metals ascertains the high degree of column utilization (>70%). The overall sorption capacities for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were found to be 0.29, 0.22, 0.20, 0.16, 0.13, and 0.11 mmol g?1 with the corresponding preconcentration factor of 400, 380, 380, 360, 320, and 320, respectively. The limit of preconcentration was in the range of 5.0–6.3 ng mL?1. The detection limit for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) were found to be 0.39, 0.49, 0.42, 0.59, 0.71, and 1.10 ng mL?1, respectively. The AXAD‐4‐HBAM has been successfully applied for the analysis of natural water, multivitamin formulation, infant milk substitute, hydrogenated oil, urine, and fish.  相似文献   

6.
A novel, simple method based on magnetic separation was developed for analytical purposes. In this method, N‐methyl‐D‐glucamine (NMDG) modified magnetic microparticles that were synthesized by using the sol‐gel method were used for the selective extraction and preconcentration of boron from aqueous solutions. This method combines the simplicity and selectivity of solvent extraction with the easy separation of magnetic microparticles from a solution with a magnet without any preliminary filtration step. The structure of the prepared γ‐Fe2O3‐SiO2‐NMDG (magnetic sorbent) composites were characterized by using X‐ray diffraction (XRD), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR). The influence of different parameters on the sorbent capacity, such as the sorption/desorption of boron, magnetic sorbent dosage, pH, equilibrium time, type, and amount of stripping solution, were evaluated by using the magnetic sorbent. Any equilibrium pH greater than 6 can be used for sorption. Desorption from the sorbent was carried out by using 1.0 M HCl. The sorption and desorption efficiency of the γ‐Fe2O3‐SiO2‐NMDG was found as 92.5 ± 0.5% and 99.8 ± 6%, respectively.  相似文献   

7.
A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO3) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.  相似文献   

8.
Ferric oxide‐loaded hybrid sorbents are environmentally benign and exhibit sorption behaviors for chromium removal from waters. In the current study, glycidyl methacrylate‐based polymer (GMD) and nanosized ferric oxide loaded glycidyl methacrylate‐based polymer (GMDFe) were prepared and assayed to examine the effect of ferric oxide loading on chromium sorption from aqueous solution for the first time from the equilibrium and kinetic points of view. The experimental equilibrium data, suitably fitted by the Langmuir and Freundlich isotherms, have shown that ferric oxide loaded hybrid sorbent exhibits higher adsorption capacity than glycidyl methacrylate‐based polymer (GMD). The Langmuir isotherm model was found to be the most suitable one for the Cr(VI) adsorption. The maximum adsorption capacities of GMD and GMDFe sorbents were determined at pH 4 as 109.54 and 157.52 mg/g, respectively. A series of column experiments was carried out to determine the breakthrough curves. The column was regenerated by eluting Cr(VI) using NaOH (10% w/v) solution after adsorption studies.  相似文献   

9.
Flow‐through column experiments were carried out to investigate the influence of pH on the sorption of three phenols (2‐methyl‐4, 6‐dinitrophenol, 2, 4, 6‐trichlorophenol, pentachlorophenol) onto a natural sandy aquifer material collected from a bank filtration site of River Elbe, Germany. For the phenols investigated, an increase in sorption (retardation) with decreasing pH is observed indicating a stronger sorption of the neutral species in comparison to that of the anions formed by dissociation. The anions of 2‐methyl‐4, 6‐dinitrophenol and 2, 4, 6‐trichlorophenol do not show significant sorption. On the contrary, pentachlorophenol showed sorption not only in neutral form but also in ionic form significantly which should be taken into account while assessing the fate and transport of such compound. A linear model based on the degree of protonation (calculated from pH and pKa) can be used to resolve the apparent (observed) sorption coefficient (Kd, app) into its neutral (Kd, n) and ionised (Kd, i) components. Knowing pKa, Kd, n, and Kd, i the apparent sorption coefficient for pH values other than experimentally investigated can be predicted.  相似文献   

10.
Zero‐valent, iron‐encapsulated alginate beads were synthesized and were applied for the removal of Cr(VI) from aqueous solutions. The effects of several important parameters including solution pH, contact time, initial concentration and reaction temperature on Cr(VI) removal levels were investigated in batch studies. An initial solution pH of 1.0 was seen to be most favorable for Cr(VI) removal. The removal process was quick and almost 80% of the removal was attained within 60 min. The kinetic data followed the second‐order equation well. The Cr(VI) removal was almost reaction temperature‐independent and decreased with an increase in Cr(VI) initial concentration. The removal of Cr(VI) by iron‐encapsulated alginate beads was found to be significantly higher than that of non‐encapsulated alginate beads.  相似文献   

11.
Sixteen samples of fulvic acids and XAD‐4 fractions of riverine, estuarine, coastal, and open ocean origin have been studied by emission and synchronous molecular fluorescence spectroscopy. Certain features of the molecular fluorescence are related to the nature, the content, and the origin of those aquatic humic substances (HS). Riverine HS appear several times richer in fluorophores than marine HS, which can be well observed by emission fluorescence spectroscopy. Synchronous‐scan spectra of fulvic acids and of XAD‐4 fractions from the aquatic environments studied, emphasized the quality differences of their fluorophores. These features are useful as tracers of humic substances related with their natural environment source or even with their anthropogenic origin.  相似文献   

12.
Biosorption potential of Cedrus deodara sawdust (CDS) in terms of sorption of Zn(II) ion across liquid phase has been evaluated in the present investigation. The surface of the CDS biomass before the sorption of Zn(II) ions seemed to be more porous, non‐crystalline and heterogeneous. The maximum uptake capacity of CDS was 97.39 mg g?1. Sorption of Zn(II) ion on the surface of CDS sawdust was maximum at pH 5, temperature 45°C, initial concentration of Zn(II) ion 100 mg L?1, biomass dose 1 g L?1, contact time 150 min, and agitation rate 160 rpm. Pseudo second‐order kinetics with the highest linear regression coefficient (R2 = 0.99), and lowest values of error functions, i.e., chi (χ2) and sum of square errors (SSE) against pseudo first‐order rate kinetics showed that the sorption of Zn(II) ion on the surface of CDS was mediated by chemosoprtive forces of attraction rather than physical adsorption. Mechanistically, relatively higher proportion of sorption of Zn(II) ion in early phase of contact time was profoundly explained by Bangham's equation and film diffusivity (Df). Intraparticle or pore diffusion (Dp) of Zn(II) ion inside the pores of CDS was rate limiting step at the later stage of contact time. Furthermore, the thermodynamic study on sorption of metal ion delineated the fact that the Zn(II) sorption on the surface of CDS was spontaneous, endothermic together with increased entropy at solid liquid interface.  相似文献   

13.
Application of Some Complexing Ion Exchangers for Copper Recovery from Natural Water and Wastewater The rational use of water resources is one of the urgent environmental control problems. These problems can be solved by the treatment of sewage. Removal of different non‐ferrous heavy metal ions from wastewater is of great importance. Besides, the selective complexing ion exchangers are of interest because of their good sorption properties. The present paper is devoted to the study of some complexing resins for copper recovery from natural water and sewage. The following carboxylic resins were studied: the cation exchangers KB‐2T, KB‐4 and the amphoteric ion exchangers ANKB 35, AMF‐2T, and AMF‐2S (manufacturer – “TOKEM” company, Kemerovo, Russia). The exchangers investigated differed from each other both by their functional groups and by their matrix physical structures. The copper recovery from CuCl2‐, CuSO4‐, and Cu(NO3)2‐solutions was studied in batch‐experiments (in presence of NaCl, Na2SO4, and NaNO3). The initial copper concentration in the solutions was 0.0002...0.008 mol/L; pH values were 1.0...5.0. After equilibrium (24 h) the resins were separated from the solution. The copper concentration in the solutions after the sorption was determined by the photometrical method with pyridylazoresorcin (λ = 500 nm). On the basis of the experimental data distribution ratio, the separation factors, equilibrium constants, and stability constants of copper complexes in the exchanger phase were calculated. It was found out in this work that the amphoteric ion exchanger AMF‐2T of macroreticular structure is the most effective for the copper sorption from sewage.  相似文献   

14.
In this study, a new solid‐phase extraction procedure has been developed for preconcentration and determination of Co ions in different water samples by flame atomic absorption spectrometry (FAAS). Cobalt was preconcentrated as N,N′‐bis(pyridine‐2‐yl‐methyl)benzene‐1,4‐diamine (Co‐BPMBDA) from sample solutions using a column containing Amberlite XAD‐7 and was determined. In order to achieve the best performance for the method, effects of several parameters such as pH, concentrations of ligand, sample flow rate, eluent, and matrix ions on the method efficiency were investigated. Under optimum conditions, the preconcentration factor was found to be 200 for 1000 mL waters samples. Detection limit based on the 3Sb criterion was calculated as 0.24 µg/L for 100 mL of sample solution and relative standard deviation was found to be 1.8%. The method was applied to determine the trace amounts of cobalt in water samples.  相似文献   

15.
An on‐line solid phase extraction method for the preconcentration and determination of Cu(II) by flame atomic absorption spectrometry has been described. The procedure is based on the retention of Cu(II) ions at pH 6.0 on a minicolumn packed with Amberlite XAD‐1180 resin impregnated with chrome azurol S. After preconcentration, Cu(II) ions adsorbed on the impregnated resin were eluted by 1 mol L?1 HNO3 solution. Several parameters, such as pH, type of eluent, flow rates of sample and eluent solutions, amount of resin were evaluated. At optimized conditions, for 3.5 min of preconcentration time, the system achieved a detection limit of 1.0 µg L?1, and a relative standard deviation of 1.2% at 0.2 µg mL?1 copper. An enrichment factor of 56‐fold was obtained with respect to the copper determination. The proposed method was successfully validated by the analysis of standard reference material (TMDA 54.4 lake water) and recovery studies. The method was applied to the preconcentration of Cu(II) in natural water samples.  相似文献   

16.
The adsorption of Cu(II) ions from aqueous solutions by soda lignin as an absorbent using a batch adsorption system is presented in this paper. The soda lignin used in this study was extracted from black liquor derived from oil palm empty fruit bunches (EFB) using 20% v/v sulfuric acid. The effects of varying experimental parameters such as pH value, adsorbent dosage, different concentrations of Cu(II) ions, and agitation period were investigated. The results revealed that the optimum adsorption of Cu(II) onto soda lignin was recorded at a pH of 5.0 at an adsorbent dosage of 0.5 g soda lignin and an agitation period of 40 min. The adsorption capacities and rates of Cu(II) ions onto soda lignin was evaluated. The Langmuir and Freundlich adsorption models were applied to calculate the isotherm constants. It was found that the adsorption isothermal data could be well interpreted by the Freundlich model. The kinetic experimental data properly correlated with the pseudo‐second‐order kinetic model, which implies that chemical sorption is the rate‐limiting step.  相似文献   

17.
In this study, carboxymethylcellulose (CMC) based thermoresponsive nanocomposite hydrogel was synthesized for the removal of Cu2+ and Pb2+ ions from aqueous solutions. To prepare nanocomposite hydrogel, graft copolymerization of N‐isopropyl acrylamide (NIPAm) and acrylic acid (AA) onto CMC was carried out in Na‐montmorillonite (MMT)/water suspension media and ammonium persulfate (APS) used as initiator. The chemical structures of hydrogels were characterized by Fourier transform infrared (FT‐IR) and X‐ray diffraction spectroscopy (XRD). Lower critical solution temperature (LCST), pH responsivity, swelling, and deswelling properties of the hydrogels were also examined. In addition competitive and non‐competitive removal of Cu2+ and Pb2+ studies were carried out. According to heavy metal sorption studies results, removal capacities of nanocomposite hydrogel for both metal ions were found to be higher than those of pure hydrogel. The analyzed adsorption data showed that the adsorption process of Cu2+ and Pb2+ could be explained by pseudo‐second order kinetic model. Moreover, according to competitive sorption studies, it is found to be that both hydrogels are more selective to Cu2+ ion rather than Pb2+.  相似文献   

18.
The sorption of heavy oil onto sediment collected from Jiaozhou Bay was studied in a series of kinetic and equilibrium experiments using NaCl solutions. The effects of temperature, salinity, and pH of the medium on sorption behavior were investigated.Sorption equilibrium of the heavy oil and sediment was established within 60 min. The process was shown to follow a pseudo-second-order kinetic rate model. The sorption rate decreased with increasing initial heavy oil concentration in the solution. Batch equilibrium experiments showed that the sorption isotherm could be described by the Freundlich model. The standard free energy change and enthalpy change at the temperatures studied (283, 288, 293, and 298 K) were negative. These findings indicated that the process was spontaneous and exothermic. Salinity, pH and temperature influenced sorption performance. Sorption was favored by higher concentrations of NaCl, by lower pH values and by lower temperatures.  相似文献   

19.
This work describes the modification of silica gel with dimethylglyoxime, in order to prepare an effective sorbent for the preconcentration and determination of copper. The sorption capacity of dimethylglyoxime‐modified silica‐gel (DMGMS) was 71.37 mg g–1 and the optimum pH for the quantitative recovery of copper was found to be 5.0. The optimum flow rate, sorbent amount, and sample volume were 1 mL min–1, 300 mg, and 50 mL, respectively. 10 mL of 0.1 mol L–1 HCl was the most suitable eluent. The detection limit of copper was 6.0 ng mL–1. The recommended method, for the determination of copper, is simple and reliable, without any notable matrix effect and can be successfully applied to environmental water samples. Copper recovery in the range from 99–100% was obtained from seawater and thermal spring water using this method. The method was applied to standard reference materials, NIST‐1515 (apple leaves) and NIST‐1643e (simulated fresh water), for the determination of copper and the results were in good agreement with certified values.  相似文献   

20.
A macroporous, hydrophobically modified poly(acrylic acid‐acrylamide) hydrogel was prepared. The fourier transform infrared (FTIR) spectrum and field emission scanning electron microscopy (FE‐SEM) results showed that the hydrogel had a macroporous structure. The dynamic swelling and removal of cationic dyes, crystal violet (CV) and basic magenta (BM), by this macroporous hydrophobically modified poly(acrylic acid‐acrylamide) hydrogel were studied. The adsorption capacity and kinetic and isotherm studies of the cationic dyes into the hydrogels have been evaluated. It was found that the macroporous hydrophobically modified hydrogel (M) exhibited improved swelling and adsorption capacity compared with the non‐macroporous hydrophobically modified hydrogel (NM). The adsorption process agreed very well with the Langmuir model and the adsorption of the cationic dyes depended on the pH of the solution via a mechanism combining swelling, electrostatic, and hydrophobic interactions. Moreover, adsorption kinetic studies showed that the adsorption followed a pseudo‐second‐order kinetic model, indicating that chemical adsorption was the rate‐limiting step.  相似文献   

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