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A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO3) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.  相似文献   
2.
Rainfall distributions in Iran are spatially and temporally heterogeneous, a fact probably linked to the mostly arid and semi-arid climate of the country. On the other hand, water demand is increasing with increasing population and improving life style. At present, the optimal utilization of water resources and irrigation dams is the primary concern of water resource managers. The Eleviyan dam (with a capacity of 60 hm3) was constructed to meet the irrigation and municipal water needs of the Maraghan region (Northwestern Iran). In this study, the efficiency of the Eleviyan irrigation dam system was investigated in three phases by setting up the optimization model that maximized the water release for irrigation purposes after municipal water need were met. In the first phase, the inflows measured in the 21 years prior to the construction of the reservoir, and in the second, the inflows generated by the Monte Carlo simulation method, and in the third phase, the inflows after the construction of the reservoir were used. The results demonstrate that the capacity determined during the preliminary studies was accurate and the operation carried out in the recent periods of operation life was up to a satisfactory standard.  相似文献   
3.
Saner  Halit Serdar  Yucesan  Melih  Gul  Muhammet 《Natural Hazards》2022,111(2):1603-1635
Natural Hazards - Hospitals are the first point of contact for people in the face of disasters that interfere with the daily functioning of life and endanger health and social life. All...  相似文献   
4.
Theoretical and Applied Climatology - Drought is a natural, global and recurring phenomenon caused by climatic anomalies and inevitable meteorological changes. Lake Urmia in northwestern Iran has...  相似文献   
5.
Flow estimations for the Sohu Stream using artificial neural networks   总被引:3,自引:2,他引:1  
In this study, daily rainfall–runoff relationships for Sohu Stream were modelled using an artificial neural network (ANN) method by including the feed-forward back-propagation method. The ANN part was divided into two stages. During the first stage, current flows were estimated by using previously measured flow data. The best network architecture was found to utilise two neurons in the input layer (the delayed flows from the first and second days), two hidden layers, and one output layer (the current flow). The coefficient of determination (R 2) in this architecture was 81.4%. During the second stage, the current flows were estimated by using a combination of previously measured values for precipitation, temperature, and flows. The best architecture consisted of an input layer of 2 days of delayed precipitation, 3 days of delayed flows, and temperature of the current. The R 2 in this architecture was calculated to be 85.5%. The results of the second stage best reflected the real-world situation because they accounted for more input variables. In all models, the variables with the highest R 2 ranked as the previous flow (81.4%), previous precipitation (21.7%), and temperature.  相似文献   
6.
This study investigate the potential of M5 model tree in predicting daily stream flows in Sohu river located within the municipal borders of Ankara, Turkey. The results of the M5 model tree was compared with support vector machines. Both modelling approaches were used to forecast up to 7-day ahead stream flow. A comparison of correlation coefficient and root mean square value indicates that M5 model tree approach works equally well to the SVM for same day discharge prediction. The M5 model tree also works well up to 7-day ahead discharge forecasting in comparison of SVM with this data set. An advantage of using M5 model tree approach is the availability of simple linear models to predict the discharge as well use of less computational time.  相似文献   
7.
Coal flotation studies were carried out in ultrasonically assisted flotation cells. Representative hard coal slime samples from Prosper-Haniel Coal Preparation Plant located in Bottrop, Ruhr Region of Germany were used for this purpose. A Wemco type flotation cell was fitted with transducers and tests were carried out at variable frequency and power. The reagent for coal flotation was Ekofol-440 with variable dosages during conventional and ultrasonic flotation experiments. The results showed that ultrasonic coal flotation yields more combustible recovery and lower ash values in concentrates than conventional flotation by using similar reagent dosages. These results are explained on the basis of efficient surface cleaning of the coal particles.  相似文献   
8.
For the activities of the mining industry land, equipment, material, and energy are used. During operation material and energy flows such as overburden, dead rock, tailings, wastewater, exhaust air, dust, energy, abrasion, coolant and lubricant losses, are released. These released material and energy flows are nearly always without value for the raw material supply chain as they are not production targets. Instead, they have negative effects on the economy and ecology and are, therefore, referred to as ‘non-intended’. The knowledge of the quantities and qualities of these non-intended outputs as a function of the processes and their parameters is the basis for technical and economical measures. A methodology for the acquisition and assessment of the material and energy flows in the mining industry was developed and tested at the Technical University Berlin, Germany. For that purpose and based on a system analysis in different mines, all relevant material and energy flows were assigned to individual processes. Causal relationships, possible interactions, quantities, and qualities were examined as functions of system parameters. Finally, a technical and economic evaluation was performed.  相似文献   
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