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1.
Toshio Kataoka Eiji Yunoki Mitsuo Shimizu Tadashige Mori Osamu Tsukamoto Satoshi Takahashi Hironori Fudeyasu Yukitaka Ohashi Ken Sahashi Toshihiko Maitani Koh'ichi Miyashita Toru Iwata Takayuki Sasaki Yoko Fujikawa Akira Kudo Roger H. Shaw 《Boundary-Layer Meteorology》2003,107(1):219-249
Atmospheric activity concentrations of 212Pb and short-lived 222Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof 222Rn, equilibrium-equivalent concentration of 222Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of222Rn is almost the same as the atmospheric activity concentration of short-lived222Rn daughters.The activity concentrations of 212Pb and the short-lived 222Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of 212Pb and the short-lived 222Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of 220Rn and 222Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of 212Pb to that of the short-lived 222Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of222Rn (the activity concentration of short-lived 222Rn daughters) tothe activity concentration of 222Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived222Rn daughters to that of 222Rn during the three observation periods.These differences can be explained by the submergence of paddy fields. 相似文献
2.
M. Ramonet J. C. Le Roulley P. Bousquet P. Monfray 《Journal of Atmospheric Chemistry》1996,23(2):107-136
The aim of the 222Rn measurements during the airborne campaign TROPOZ II, was first to help in the interpretation of the photochemical studies, and secondly to furnish a data set of 222Rn in the troposphere, for validation of atmospheric transport models. In this paper we present the 222Rn measurements, and their simulation with a 3-D atmospheric transport model based on observed winds. The 222Rn was measured using the active daughters deposit technique with isokinetic aerosol sampling. We have obtained 44 measurements distributed between 65° North and 55° South, from 1 to 11 km height. In 25% of cases, we found relatively high concentrations (> 300 mBq·scm) of 222Rn in the high troposphere (>8 km). The results of 3D simulations and the calculations of back-trajectories allow us to find the origins of the high 222Rn concentrations. The transport model reproduced most of the observed synoptic variations, but it overestimates the concentrations which implies a vertical transport of excessive velocity. 相似文献
3.
Toshio Kataoka Eiji Yunoki Mitsuo Shimizu Tadashige Mori Osamu Tsukamoto Yukitaka Ohashi Ken Sahashi Toshihiko Maitani Koh’ichi Miyashita Toru Iwata Yoko Fujikawa Akira Kudo Roger H. Shaw 《Boundary-Layer Meteorology》2001,101(2):131-156
Concentrations of radon 222Rn andair pollutants, meteorological parametersnear the surface and vertical profiles of meteorological elements were measured atUchio (Okayama City, Okayama Prefecture, Japan) 12 km north from the coast ofthe Inland Sea of Japan. In the nighttime, the 222Rn concentration increased in the case of weak winds, but did not increase as much in the case of moderate or strong winds, as had been expected. In the daytime, the 222Rn concentrationheld at a slightly higher than average level for the period from sunrise to about 1100 JST. It is considered that this phenomenon is due to a period of morning calm, that is, a transition period from land breeze to sea breeze.NO, which is sensitive to traffic volume,brought information concerning advection.Oxidant concentrations,which reflect the availability of sunlight,acted in the reverse manner to 222Rnconcentrations. Thus, a set of 222Rn and air pollutants could provide useful information regarding the local conditions of the atmospheric boundary layer. 相似文献
4.
Concentrations of 222Rn at 0.1 m and 6.5 m height above ground level and 222Rn flux density were measured during nights characterized by strong cooling, light winds and clear sky conditions in the Carpathian
Basin in Hungary. A very stable boundary layer (vSBL) formed on 14 nights between 15 August and 3 September 2009. On 12 nights,
an estimated 72% (s.d. 20%) of 222Rn emitted from the surface since sunset was retained within the lowest 6.5 m above the ground until sunrise the following
morning. On two nights an intermittent increase in wind speed at 9.4 m height was followed by a rise in temperature at 2.0 m
height, indicating a larger atmospheric motion that resulted in 222Rn at 0.1 m around sunrise being the same as around the preceding sunset. It does not seem to be rare in a large continental
basin for a vSBL to be nearly completely decoupled from the atmosphere above for the entire period from sunset to sunrise. 相似文献
5.
6.
For a ground-level continuous release of a trace substance like 222Rn, for which the vertical profile of concentrations is exponential, a quantity, equivalent mixing height h, is defined in this paper in the following way. If the substance were to be redistributed uniformly through a layer such that the concentration were to be equal to that at the surface, then the top of the layer would be h.Relative values of h can be obtained from surface measurements of Radon concentrations, but absolute values require estimates of the vertical fluxes of Radon. A comparison is given of the estimates of h obtained from surface measurements with estimates derived from the vertical profile of Radon from the surface to 100 m.Practical methods are proposed for estimating the surface flux of Rn. 相似文献
7.
Beryllium-7(~7Be)and lead-210(~(210)pb)activities were measured from October 2002 to January 2004 at Waliguan Observatory(WO:36.287°N,100.898°E,3816 m a.s.l(above sea level)in northwest China.~7Be and ~(210)Pb activities are high with overall averages of 14.7±3.5 mBq m~(3)and 1.8±0.8 mBq m~(-3)respectively. For both ~7Be and ~(210)Pb,there are significant short-term and seasonal variations with a commonly low value in summer(May September)and a monthly maximum in april(for ~7Be)and in December(for~(210)Pb). The ratio of ~7Be/~(210)pb showed a broad maximum extending from April to July,coinciding with a seasonal peak in surface ozone(O_3).The seasonal cycles of ~7Be and ~(210)Pb activities were greatly influenced by precipitation and thermal dynamical conditions over the boundary layer,especially for ~(210)Pb.The vertical mixing process between the boundary layer and the aloft air modulates the variations of ~7Be and ~(210)pb at WO in summer.It is indicated that air mass had longer residence time and originated from higher altitudes at WO in the spring-summer time and the winter in 2003.During an event with extremely high weekly- averaged ~7Be concentration(24.8 mBq m~(-3))together with high O_3 levels and low water mixing ratio,we found that air masses had been convectively transported a long distance to WO from high latitude source regions in central Asia,where significant subsiding motions were observed.In another case with the extreme ~(210)pb activity of 5.7 mBq m~(-3)high CO_2 level and specific humidity(in winter),air masses had come from south China and north Indian regions where ~(222)Rn activities were high.This study,using ~7Be and ~(210)Pb as atmospheric tracers,has revealed that complex interactions of convective mixing from the upper troposphere and long-range transports exist at WO. 相似文献
8.
Chemical Assessment of Oceanic and Terrestrial Sulfur in the Marine Boundary Layer over the Northern North Pacific during Summer 总被引：2，自引：0，他引：2
K. Aranami S. Watanabe S. Tsunogai A. Ohki K. Miura H. Kojima 《Journal of Atmospheric Chemistry》2002,41(1):49-66
Dimethylsulfide (DMS) in surface seawater and the air, methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO4
2–) in aerosol, and radon-222 (Rn-222) were measured in the northern North Pacific, including the Bering Sea, during summer (13 July – 6 September 1997). The mean atmospheric DMS concentrations in the eastern region (21.0 ± 5.8 nmole/m3 (mean ± S.D.), n=30) and Bering Sea (19.9 ± 9.8 nmole/m3, n=10) were higher than that in the western region (11.1 ± 6.4 nmole/m3, n=31) (p<0.05), although these regions did not significantly differ in the mean DMS concentration in surface seawater. Mean sea-to-air DMS flux in the eastern region (21.0 ± 10.4 mole/m2/day, n=19) was larger than those in the western region (11.3 ± 16.9 mole /m2/day, n=22) and Bering Sea (11.2 ± 7.8 mole/m2/day, n=7) (p<0.05). This suggests that the longitudinal difference in atmospheric DMS was produced by that in DMS flux owing to wind speed, while the possible causes of the higher DMS concentrations in the Bering Sea include (1) later DMS oxidation rates, (2) lower heights of the marine boundary layer, and (3) more inactive convection. The mean MSA concentrations in the eastern region (1.18 ± 0.84 nmole/m3, n=35) and Bering Sea (1.17 ± 0.87 nmole/m3, n=13) were higher than that in the western region (0.49 ± 0.25 nmole/m3, n=28) (p < 0.05). Thus the distribution of MSA was similar to that of DMS, while the nss-SO4
2– concentrations were higher near the continent. This suggests that nss-SO4
2– concentrations were regionally influenced by anthropogenic sulfur input, because the distribution of nss-SO4
2– was similar to that of Rn-222 used as a tracer of continental air masses. 相似文献
9.
Yves J. Balkanski Daniel J. Jacob Richard Arimoto Mark A. Kritz 《Journal of Atmospheric Chemistry》1992,14(1-4):353-374
The atmospheric distribution of222Rn over the north Pacific is simulated with a three-dimensional chemical tracer model using meteorological input from the NASA-GISS general circulation model (4°×5° resolution). Radon-222 (half-life 3.8 days) is a tracer of continental air. Model results are in good agreement with measurements from ships and aircraft. Strong Asian influence is found throughout the tropospheric column over the north Pacific in spring, reflecting a combination of frequent convection over the continent, strong westerly winds at altitude, and subsidence over the ocean. In summer, the upper troposphere over the north Pacific is heavily affected by deep convection over China; however, Asian influences at the surface are then at their yearly minimum. In winter, strong Asian influence is found near the surface but not at high altitudes. Transport of American air over the Pacific is important only at low latitudes. American sources account for 11% of total222Rn in the model at Midway, 30% at Mauna Loa and 59% at Oahu. Results for Hawaii indicate two seasonal peaks of American influence, one in summer and one in winter. The tropical western Pacific is particularly remote from continental influences year round. 相似文献
10.
环球海洋大气气溶胶化学研究 III：金属形态和入海通量 总被引：8，自引：0，他引：8
中国第三次南极考察和环球科学考察，历经北太平洋、南太平洋、南极半岛海域、南大西洋、北印度洋、以及沿途近岸海域，共收集58个气溶胶样品，采用石墨炉原子吸收法分析其中的水可溶态和酸可溶态的Mn、Fe、Pb、Cu、Cd。气溶胶中金属表现明显陆源向大洋输送的浓度梯度，近岸海域上空金属含量大于大洋上空含量，北太平洋上空含量高于南太平洋和南极半岛海域。气溶胶中金属的水可溶程度，在近岸海域上空依次为Cd＞Mn＞Cu＞Fe＞Pb，百分比分量分别为39%，36%， 23%，14%和5.3%；在大洋上空依次为Cd＞Mn＞Fe＞Cu＞pb，百分比分量分别为62%，44%，11%，3.1%和2.5%。本文还计算和比较各观测海区上空金属从大气输入海水的通量。 相似文献
11.
基于国际大气化学-气候模式比较计划模式数据评估中国沙尘气溶胶直接辐射强迫 总被引：2，自引：0，他引：2
目前气候模式对沙尘气溶胶直接辐射强迫模拟仍有很大不确定性,多模式对比有助于定量评估不确定范围。国际大气化学—气候模式比较计划（Atmospheric Chemistry and Climate Model Intercomparison Project,ACCMIP）旨在评估当前模式对短寿命大气成分辐射强迫和气候效应的模拟能力。基于7个ACCMIP模式模拟的中国地区沙尘气溶胶浓度,我们评估了中国区域沙尘气溶胶直接辐射强迫和不确定性范围。结果显示,中国区域沙尘气溶胶年排放总量为215±163 Tg a-1,区域年均地表浓度为41±27 μg m-3,柱浓度为9±4 kg m-2,光学厚度为0.09±0.05。中国区域年均沙尘气溶胶产生的大气顶短波、长波和总辐射强迫分别为-1.3±0.8 W m-2、0.7±0.4 W m-2和-0.5±0.7 W m-2;地表短波、长波和总的辐射强迫值为-1.5±1.0 W m-2、1.8±0.9 W m-2和0.2±0.2 W m-2。沙尘气溶胶长波辐射强迫对沙尘浓度的垂直分布敏感。高层沙尘气溶胶浓度越大,其在大气顶产生更强的正值长波辐射强迫。然而,沙尘气溶胶短波辐射强迫主要受整层沙尘柱浓度控制,对沙尘浓度的垂直分布较不敏感。本文结果可为中国沙尘气溶胶的气候模拟提供参考。 相似文献
12.
ATTILA: atmospheric tracer transport in a Lagrangian model 总被引：2，自引：0，他引：2
CHRISTIAN REITHMEIER ROBERT SAUSEN 《Tellus. Series B, Chemical and physical meteorology》2002,54(3):278-299
The model ATTILA has been developed to treat the global-scale transport of passive trace species in the atmosphere within the framework of a general circulation model (GCM). ATTILA runs online within the GCM ECHAM4 and advects the centroids of 80.000 to 190.000 constant mass air parcels. Each trace constituent is thereby represented by a mass mixing ratio in each parcel. ATTILA contains state-of-the-art parameterizations of convection, turbulent boundary layer mixing and inter-parcel transport, and provides an algorithm to map the tracer concentrations from the trajectories to the ECHAM model grid. The transport characteristics of ATTILA are evaluated against observations and the standard semi-Lagrangian transport scheme of ECHAM by two experiments. (1) We simulate the distribution of the short-lived tracer radon (222 Rn) in order to examine fast vertical transport over continents, and long-range transport from the continents to remote areas. (2) We simulate the distribution of radiocarbon (14 C) from nuclear weapon tests in order to examine upper tropospheric and stratospheric transport characteristics. Contrary to the semi-Lagrangian scheme, ATTILA shows a greatly reduced meridional transport in the upper troposphere and lower stratosphere, and a reduced downward flux from the stratosphere to the troposphere, especially in mid-latitudes. Since ATTILA is a numerically non-diffusive scheme, it is able to maintain steep gradients, which compare better to the observations than the rather smooth gradients produced by the semi-Lagrangian scheme. 相似文献
13.
Wang Mingxing 《大气科学进展》1984,1(1):76-94
The acidity of precipitation in both clean and polluted areas was calculated for atmospheric CO2 and SO2 in equilibrium with water. pH values of 5 and 4.5 were obtained. In Beijing the pH value is increased due to paniculate chlorine reactivity and rainout of CaO in the atmosphere. The increase of pH value is related to liquid water content in cloud and the elemental concentrations of paniculate Cl and Ca in the atmosphere. This mechanism may help to explain the nonacid rain observed in Beijing where the air pollution problem is serious, as viewed by SO2 concentration and paniculate burden in the atmosphere. 相似文献
14.
Wolfgang Roether 《Boundary-Layer Meteorology》1983,27(1):97-103
In order to obtain field data of ocean-atmosphere gas transfer coefficients, it is preferable to measure the interfacial gas flux in the air rather than in the water. This approach has been reported in the literature for CO2. However, it is shown here that 222Rn and methyliodide, CH3I, may be more suitable gases for air-side flux measurements. 相似文献
15.
Guangjian Wu Baiqing Xu Tandong Yao Chenglong Zhang Shaopeng Gao 《Atmospheric Research》2009,93(4):784-792
This study measured the concentration of heavy metal elements in atmospheric aerosol samples collected between July 2004 and April 2006 at a remote site on Mt. Muztagata (38°17'N, 75°01'E, 4430 m), in the Eastern Pamirs. Inductively coupled plasma mass spectroscopy (ICP–MS) results show that the air at Muztagata contains low concentrations of As and heavy metal elements (Cr, Ni, Cu, Zn, Cd, Pb, and Bi), comparable with those in the Arctic — far lower than in heavily populated or industrialized areas. Observed enrichment factor (EF) values greater than 10 for those elements suggest partly anthropogenic sources. Seasonal variations in the concentrations of Zn, Cd, Pb, Bi, and As resemble those of crustal Al, with greater concentrations during the summer but lower ones in winter. Our results reveal that the background atmosphere in remote inner Asia is only weakly affected by anthropogenic pollution, and demonstrate that high heavy metal concentrations occur during summer but with greater EF values during the winter. The air mass back-trajectory analyses suggest that pollution from West Asia, Central Asia, and South Asia are the main possible source areas that contribute to the heavy metals in aerosols at Muztagata. 相似文献
16.
丘陵区土壤热通量遥感估算模型适应性分析 总被引：1，自引：0，他引：1
利用具有丘陵区典型特征的四川省乐至县气象站的土壤热通量和净辐射观测数据,分析了二者的变化特征,并验证了土壤热通量遥感估算模型的适用性。分析结果表明：晴空土壤热通量G与净辐射Rn存在明显日变化,最大值出现13时左右;其比值G／Rn受土壤湿润程度和地表覆盖的影响,地表湿润、覆盖率高,比值小。在干旱时,瞬时比值可高达0．7,而湿润情况,可低至0．05。对目前广泛使用的G／Rn卫星遥感模型估算结果与实测值的对比分析表明,不同的G／Rn卫星遥感估算模型估算结果存在明显的差异,仅依靠植被指数的模型不适合南方丘陵区。本研究认为Bastiaanssen等的模型较适合丘陵区的土壤热通量遥感估算模型。 相似文献
17.
Résumé Le radon (Rn86
222) et les descendants du thoron (ThB ou Pb82
212) sont utilisés comme traceurs pour l'étude des échanges verticaux de matière. Diverses méthodes permettant le calcul des coefficients de diffusion sont présentées soit dans l'hypothèse simplificatrice du régime stationnaire, soit dans le cas plus général du régime dépendant du temps. L'application de ces méthodes au calcul des coefficients de diffusion sur des données fournies à partir d'un modèle de simulation numérique permet de préciser le degré d'approximation représenté par les diverses hypothèses simplificatrices. Les méthodes de calcul présentées sont appliquées aux mesures expérimentales du radon et du ThB. Ces mesures ont été réalisées de manière continue durant deux ans en trois points de mesures, entre 0 et 100 m de hauteur. Une statistique est présentée sur la variation diurne des échanges et la variation saisonnière de cette variation diurne, ainsi qu'un exemple particulier du traitement des données en régime dépendant du temps.
Continuous measurements of the concentrations of radon and thorium B have been carried out at 3 levels (1.5, 30 and 100 m) during a period of 2 yr (from October 1966 to October 1968) at the site of the future airport of Paris, at Roissy-en-France; at the same time, standard meteorological elements have been measured at the station by the Météorologie Nationale and the vertical gradients (wind and temperature profiles in the first 100 m) by J. Saissac. The work has been undertaken in order to determine the vertical exchange of matter near the ground.The computation of the exchange coefficients has been carried out by using the standard diffusion equation (K theory). The results in the literature as well as statistical analysis of our data lead us to believe that the flux of Rn and ThB at the ground can be considered as horizontally homogeneous in the neighbourhood of the measurement site (the soil is geologically homogeneous over a large area). The differential equation is thus simplified, containing only one space parameter (z), and timet.In this paper we describe the principal computation methods used for determining the exchange coefficients from the measurement of the vertical gradients of tracers. In order to illustrate the approximation errors and fields of applicability of different methods, we have applied them to the data provided from a numerical integration of the diffusion equation, in which one can introduce any profile of diffusivity.We show that during stable periods, the value of the flux of Rn or ThB can be determined forz = 0.Generally, during daylight hours when the motion near the ground is strongly turbulent, the vertical gradient of concentration is not measurable with sufficient accuracy.The daytime diffusion coefficient is therefore not computed by the general methods presented above. This deficiency can be overcome by assuming that the ratio between the mean concentration observed during these periods and the value of the flux at ground level are characteristic of the whole mixing layer. The values of the exchange coefficients obtained by this method are included and range from 5 to 30 m2s-1.The application of the proposed methods to the experimental results has been made for two atmospheric states. Firstly, we have used a simplified method (stationary state) which is applied to the whole experimental data set. We present the diurnal variation, the most probable value of the diffusion coefficients and the seasonal evolution. The values obtained from Rn and ThB measurements have been compared.相似文献
18.
19.
S. Whittlestone 《Journal of Atmospheric Chemistry》1990,11(1-2):27-42
Radon daughters are produced as free ions, but they become attached to aerosol particles at a rate depending on the particle concentration. In the lower marine boundary layer, most of those which do not become attached plate out on the ocean surface. In this paper a simple model is used to examine the influence of several parameters on radon/radon daughter disequilibria in maritime air. The model is compared with experimental data from Cape Grim.The radon daughter to radon ratio, f, decreases from 0.86 to 0.1 as the particle concentration falls from 1000 to 10 cm-3. Estimates of radon concentration at sea level, based on daughter measurements may therefore be in error by as much as a factor of 10 unless allowance is made for particle concentration. At 100 cm-3, the standard deviation of the distribution of measured f values is about 30%, indicating that the particle concentration is not the only factor influencing the loss of radon daughters. The implication is that radon daughters can be used to measure radon concentrations at sea level with an accuracy of about 30%, provided the particle concentration is known.The measurements show that there is a very low proportion of unattached daughers in the air between about 30 and 165 m above sea level. According to the model, this implies that mixing of air up to about 200 m is usually rapid enough to result in plate-out of radon daughters on the ocean on a time scale of less than 100 s. 相似文献
20.
The High Concentration Tails Of The Probability Density Function Of A Dispersing Scalar In The Atmosphere 总被引：1，自引：0，他引：1
The distribution function for concentrations of a scalar pollutant dispersing in the turbulent atmosphere has a finite domain that is bounded above and below. Three methods, based on extreme value statistics, are used to obtainestimates for the upper bound and to describe the high concentration tailbehaviour of the distribution; all three methods are applied to concentrationdata obtained from experimental atmospheric releases. Quantile quantile (QQ)plots are used to assess the goodness of fit of the resulting estimates of thedistribution, and also to compare the performance of the three methods. Thepredicted values for the upper bound are orders of magnitude less than thesource concentration, illustrating that molecular diffusion has a large effecton the high concentrations. 相似文献