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《中国煤炭地质》2020,(4)
库区岩质反倾边坡常在蓄水期发生失稳破坏,其存在特定的破坏模式。在中国水利水电科学研究院改进的Goodman-Bray算法基础上,考虑岩柱间水压力及库水压力对岩柱产生的倾倒力矩以及饱和区岩土体的强度降低,改进该算法对库区反倾边坡蓄水期稳定性进行评价。以Fortran为平台编写岩质反倾边坡稳定性分析程序,通过苗尾水电站工程实例边坡对所提力学模型和分析方法进行验证,并与离散元模拟结果进行对比验证其准确性。反倾边坡失稳模式为"滑动—倾倒—稳定"三段式,坡形隆起处倾倒变形程度更加强烈。蓄水后饱和岩土体抗剪性能变弱,导致坡脚处失稳模式由倾倒转变为滑动,锁固段岩体失去阻滑力后引起边坡整体失稳。 相似文献
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水库蓄水极易诱发库区地质灾害,所以研究水库库岸堆积体边坡在蓄水前后的变形特征及其稳定性具有重要意义。本文基于现场详细的工程地质勘察资料和监测资料,分析了堆积体边坡的结构特征和变形特征;在此基础上,对堆积体的形成和变形机制进行了探讨;最后,采用离散元数值计算方法,对堆积体边坡在蓄水前后的稳定性进行了计算分析。研究结果表明：堆积体形成于古滑坡,水库在短时间（两个月）内大幅度抬高水位近40.00 m,从而激活了古滑坡,导致变形的产生;排水洞和排水孔的施工有效降低了坡体内地下水位,有效减缓了变形的发展,部分测点变形有收敛趋势,但仍需进一步观测。 相似文献
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非饱和-非稳定渗流条件下的边坡临界滑动场 总被引：1，自引：0，他引：1
受季节性降雨或水库运行的影响,岸坡外水位及坡内孔隙水压力场的变化较大,不利于岸坡的稳定性。在水位变化过程中,利用非饱和-非稳定渗流有限元计算得到孔隙水压力场,基于非饱和土的渗流和抗剪强度理论,对水位变化过程中的边坡临界滑动场法进行改进,提出可考虑水位变化与岸坡非饱和-非稳定渗流过程的边坡临界滑动场数值模拟方法。将改进后的水位变化过程中的边坡临界滑动场法分别应用于黏土、粉土岸坡在水位升降过程中的稳定性分析,研究了水位升降速率及基质吸力对岸坡稳定性的影响,并揭示了边坡在水位变化过程中的稳定性变化历程。研究表明,该方法计算结果合理、可靠,更适用于涉水边坡的稳定性计算,且岸坡稳定性变化历程受水位升降速率、基质吸力等多种因素共同影响,只有在考虑非稳定渗流的基础上同时考虑基质吸力的作用才能正确得出水位变化过程中岸坡稳定性变化规律和实质。 相似文献
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在分析库水位变化与岸坡稳定性的一般规律的基础上,对某水库泄洪洞进口高边坡变形机理进行分析。然后计算分析不同水位升降条件下,蓄水＋暴雨、地震、地震＋地下水作用等三种工况的稳定性系数,确定危险警戒水位,并预测未来蓄水及库水位下降情况下泄洪洞进口边坡稳定性与库水位的关系,为蓄水后的边坡防治提供必要的理论依据。 相似文献
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对处于蠕滑阶段的边坡而言,准确确定蠕滑段和锁固段是进行稳定性评价及演化趋势预测的基础和前提。以我国西南山区某水库型岸坡变形体为例,在综合分析岸坡工程地质条件的基础上,通过联合运用野外现场地质调查、地表位移监测、钻孔、平硐、深部位移监测、物探等多种勘察手段,查明了岸坡的结构特征,并分别对岸坡进行地表和深部变形分区。 在此基础上,结合当前稳定性现状,划分出岸坡蠕滑段与锁固段。结果表明:(1)岸坡在河谷下切过程中发生了弯曲倾倒变形,弯曲折断面深度为20～80m;(2)岸坡前部为蠕滑段,中部为锁固段,后部为拉裂段,具备滑移-拉裂-剪断三段式发育特征。研究结果可直接用于该岸坡变形体的稳定性评价,且对于同类型处于蠕滑阶段边坡的勘察手段及综合分析具有一定的借鉴意义。 相似文献
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库岸岸坡失稳是库区的地质灾害之一。在现场勘查和室内试验的基础上,对滑坡力学参数进行分析取值,计算和评价滑坡稳定性,预测滑坡产生的涌浪高度,为水库蓄水提供必要的防治依据。 相似文献
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Saday Azadoglu ALIYEV Ali SARI Bahadir KTEN Ankara University Faculty of Engineering Department of Geological Engineering Tandogan Ankara Turkey 《《地质学报》英文版》2008,82(6)
Concentrations of some heavy metals and trace elements such as Cr,Ga,Ni,Zn,Mo,Cu, Pb,Yb,Y,Nb,Ti,Sr,Ba,Mn,Sc,Co,V,Zr,Fe,Al,W,Se,Bi,Sb,As,Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated.The distribution of the elements in the shells is categorized into four groups.Of these,concentrations of 12 elements(As,Bi,Cd,Co,Ga,Mo,Nb, Sb,Se,Sc,W and Yb)are below zero [(0.053-0.79)×10~(-6)];concentrations of seven elements(Cr,Ni, Pb,V,Y,Zr and Cu)are(1.0-6.0)×10~(-6);concentrations of four elements(Ti,Mn,Ba and Zn)are 10- 20×10~(-6);and concentrations of five elements(Si,Al,Fe,Mg and Sr)are(47.44-268.11)×10~(-6).The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina(Linné),Pitar-rudis(Poll),Nassarius reticulatus(Linné),Venerupis senescens (Coocconi),Mytilus galloprovincialis(Lamarck),Mytilaster lineatus(Gemelin in Linné)and Chlamys glabra.It was found that,in mollusk taxonomy,the elements have unique values.In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks.In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment.Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment. 相似文献
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中国煤中的九种金属元素 总被引：6，自引：0，他引：6
在煤的加工利用过程中,煤中金属元素进入大气、水体和土壤,以致污染环境,这是人们关心的事。本文将介绍镉、钴、铬、铜、锰、钼、镍、铅、锌等九种元素在我国煤中的分布和赋存情况。 相似文献
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Manfred Birke Clemens Reimann Alecos Demetriades Uwe Rauch Hans Lorenz Bodo Harazim Wolfgang Glatte 《Journal of Geochemical Exploration》2010
A total of 1785 European bottled water samples were analyzed using standard laboratory methods. The bottled water samples were purchased in 2008 at supermarkets throughout 40 European countries. The samples were analyzed for 71 chemical parameters (As, Al, As, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, Br−, HCO3−, Cl−, F−, NH4+, NO2−, NO3−, PO43−, SO42−, SiO2, pH, and EC) by quadrupole inductively coupled emission spectroscopy (ICP-QMS, trace elements), inductively coupled plasma atomic emission spectroscopy (ICP-AES, major elements), ion chromatography (IC, anions), atomic fluorescence spectrometry (AFS, Hg), titration (alkalinity), photometric methods (NH4+), potentiometric methods (pH), and conductometric methods (specific electrical conductivity, EC). A very strict quality control procedure was followed by analysing blanks, international reference materials, an internal project standard, and duplicate analyses, as well as by analysing 23 elements by both ICP-QMS and ICP-AES. Analysis of marketed bottled water from springs, wells or boreholes, apart from the evaluation of its quality with respect to inorganic elements, it may provide a cheap alternative to obtain a first impression about groundwater chemistry at the European scale. 相似文献
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Size fractionation of ~40 major and trace elements (TE) in peat soil solutions from the Tverskaya region (Russia) has been
studied using frontal filtration and ultrafiltration through a progressively decreasing pore size (5, 2.5, 0.22 μm, 100, 10,
5, and 1 kD) and in situ dialysis through 6–8 and 1 kD membranes with subsequent analysis by ICP-MS. In (ultra) filter-passed permeates and dialysates
of soil solutions, Fe, Al, and organic carbon (OC) are well correlated, indicating the presence of mixed organo-mineral colloids.
All major anions and silica are present in “dissolved” forms passed through 1 kD membrane. According to their behavior during
filtration and dialysis and association with mineral or organic components, three groups of elements can be distinguished:
(i) species that are weakly affected by size separation operations and largely (>50–80%) present in the form of dissolved
inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, As, Mn) with some proportion of small (1–10 kD) organic complexes (Ca,
Mg, Sr, Ba), (ii) biologically essential elements (Co, Ni, Zn, Cu, Cd) mainly present in the fraction smaller than 1 kD and
known to form strong organic complexes with fulvic acids, and, (iii) elements strongly associated with aluminum, iron and
OC in all ultrafiltrates and dialysates with 30–50% being concentrated in large (>10 kD) colloids (Ga, Y, REEs, Pb, Cd, V,
Nb, Sn, Ti, Zr, Hf, Th, U). For most trace metals, the proportion in the colloidal fraction correlates with their first hydrolysis
constant. This implies a strong control of negatively charged oxygen donors present in inorganic/organic colloids on TE distribution
between aqueous solution and colloid particles. It is suggested that these colloids are formed during plant uptake of Al,
Fe, and TE from mineral matrix of deep soil horizons and their subsequent release in surface horizons after litter degradation
and oxygenation on redox or acid/base fronts. Dissolved organic matter stabilizes Al/Fe colloids and thus enhances trace elements
transport in soil solutions. 相似文献
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岩溶地下河污染物运移特征及自净能力 ——以广西里湖地下河为例 总被引：4，自引：0，他引：4
以广西里湖地下河为研究对象,通过观测地下河系统中污染物的运移行为来研究其自净过程。于不同季节沿着地下河的径流方向进行一个水文年的调查取样。结果发现地下河主要受到NO2-N、NH4+-N、COD和As、Cd、Hg等重金属的污染。污染物从地表进入岩溶含水层,到达地下河出口时部分污染物浓度衰减明显,说明一些离子有明显的自净能力。因地下河的结构和部分管道半充水状态、明暗流交替等水文地质条件,地下河的自净机制主要是物理过程的稀释作用和化学过程的氧化还原反应。通过对比地下河主要离子的衰减量和衰减速率,发现衰减比例最高的为铵态氮,最低为保守元素氯离子。根据衰减速率,将水中的离子和微量元素分为4种衰减特征类型:TFe、Al和Zn一旦进入岩溶含水层后全部衰减;K、Na、Mg、F、Cl、HPO4和TP在洞穴伏流段具有最高的衰减速率;来自生活和工业污染的NH4-N、CODCr、BOD5从上游至下游逐渐减少;Mn、 Ba和Hg从明流转为伏流时衰减速率最快,但在洞穴伏流内存在二次悬浮。 相似文献
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海洋和湖泊具有重要的气候环境和生态调节功能。研究地质历史时期海洋和湖泊生态系统的生物群落的组成、结构和演变,将为解决当前面临的环境问题,评估可持续发展提供科学依据。生物标志物具有生物专属性,提供了使我们能够从分子水平上研究地质历史中各种生物演变的工具。本文初步总结了海洋和湖泊生态系统中的生物标志物(烷烃、酸类、醇类、酮类、酯类、甾类、藿类、萜类和甘油四醚类等)的特征和来源。陆生高等植物来源的生物标志物,以长链的烷烃、脂肪酸、脂肪醇和木质素、萜类等较为常见;水生微藻来源的生物标志物有长链烯酮、烷基二醇和高度支链类异戊二烯类化合物(HBIs)等;微生物来源的生物标志物有细菌藿烷多元醇(BHPs)、异形胞糖脂和支链烷烃类等。今后结合生物标志物单体同位素分析和基因、蛋白质组学等现代分子生物学研究,加强不同生物标志物对应的生物种属的生态学研究,古今生态研究相结合,可以为某些生物标志物的分子来源研究提供新的可行途径。本文还综述了生物标志物指标在重建海洋和湖泊生态系统的组成、结构、生产力和营养状况方面的应用。未来的研究将偏向于从定性向定量化重建转变,在海洋研究中应用较成熟的指标将越来越多的被用于湖泊环境中。此外,多指标结合使用将提高重建古生态系统的可靠度。 相似文献
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Abundance, Sources and Speciation of Trace Elements in Humus-Rich Streams Affected by Acid Sulphate Soils 总被引：3，自引：0，他引：3
The behaviour of trace elements (Al, As, Cd, Co, Cr,Cu, Fe, Mn, Ni, V, Zn) was studied in five humus-richstreams (dissolved organic carbon = 14–40 mg/L)impacted by acid sulphate soils developed in marinesulphide-bearing fine-grained sediments. During heavyrainfalls in autumn, on which the study focusses, themetals Al, Cd, Co, Cu, Mn, Ni and Zn are extensivelyleached from these acidic soils (pH = 2.5–4.5), whileAs, Cr, Fe and V are not leached more strongly fromthis soil type than from areas of till and peat. Aspeciation experiment, based on anion and cationexchange of the stream waters in the field, showedthat (1) the metals Al, Cd, Co, Mn, Ni and Zn aretransported in the streams mainly as inorganiccations, (2) Cu exists mainly in cationic form but isalso to a significant extent associated with dissolvedhumic substances, (3) Fe occurs mainly in the anionicfraction explained by organic coating on colloidal Feoxyhydoxides and (4) the hydrochemistry of As, Cr andV is complex as these elements may exist in severalunquantified anionic fractions and to a minor extentin cationic species/forms. Whereas the proportion ofacid sulphate soils in the catchments had a largeimpact on concentrations levels of several elements inthe stream waters, these soils did not have a largeaffect on the speciation of elements in water. 相似文献
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川南普格杏仁状玄武岩晶洞中产出大量石英、水晶、沥青、葡萄石以及铜矿物,根据其产状和矿物组合分为石英沥青、水晶-沥青及水晶-葡萄石球粒三种类型晶洞。水晶-葡萄石晶洞中矿物组合具明显球粒形貌特点,球粒由中心柱状 水晶及垂直水晶柱面生长的葡萄石球粒内圈与铜矿物球粒外圈组成。铜矿物球粒具有明显圈层结构,由自然铜核、黑铜矿 幔、硅孔雀石与孔雀石壳组成。野外及镜下观察显示,铜矿物集合体形态受自然铜形状和产出控制,铜矿物球粒主要分布 于多个葡萄石球粒边缘的汇聚处,核部自然铜为球粒状;脉状铜矿物由一向伸长自然铜与黑铜矿、硅孔雀石等矿物组成, 分布于晶洞裂隙中。碳同位素与红外光谱研究表明晶洞中的沥青为生物成因,属石油沥青,有机质可能来自下二叠统 （P13）碳酸盐。晶洞中矿物为含有机质成矿溶液依次结晶而成,其顺序为：玉髓或石英→水晶、沥青与自然铜→自然铜与 葡萄石→黑铜矿→硅孔雀石→孔雀石→方解石。沥青的螺旋生长花纹特征、水晶中包裹体均一化温度以及水晶中沥青与自 然铜之间的关系显示,沥青是有机质（原油）受热裂解转变而成,其形成温度约为290~230℃,自然铜的结晶温度为230~ 160℃。 相似文献
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纳日贡玛一带的始新世—渐新世斑岩体多以不规则小岩株形式产出,由二长花岗斑岩组成;岩石化学类型为亚碱性的富钾钙碱性系列,SiO2、Al2O3、K2O、Na2O、LREE,Sr、Rb、Ba、Th、Ce、Mo、Cu、Au、Ag含量高,CaO、TiO2、HREE、Y、Yb、Cr、Sc、Co、Ni亏损。稀土分馏明显,Eu异常不明显。斑岩源岩为壳源,有洋壳物质的混染;其形成模式为陆内俯冲导致软流圈上涌,并向下地壳注入诱发下地壳物质熔融产生岩浆。 相似文献
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黄锡矿-似黄锡矿-硫锡铁铜矿组合及其结构特征 总被引：1，自引：0，他引：1
黄锡矿-似黄锡矿-硫锡铁铜矿产于湖南大义山花岗岩与石炭、二叠系灰岩接触处的富斑铜矿夕卡岩铜矿床中。硫锡铁铜矿在国内属首次发现。它们的化学成分、物理性质、光学性质和晶体结构与国外相同矿物相似。它们都有两种产状,构成多种结构。 相似文献