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1.
In the past, no single standardised method for sampling and sorting benthic macroinvertebrates has been implemented in Germany. Therefore, we tested the suitability of two common sorting protocols, RIVPACS and AQEM/STAR, by taking samples with each protocol at 44 sampling sites. Our results reveal that different methods deliver slightly different assessment results. Moreover these two methods differ in costs. Although the AQEM/STAR protocol takes longer than the RIVPACS protocol, we favoured the AQEM/STAR protocol because of its higher level of standardisation. In order to limit costs to an acceptable level, a modification of the AQEM/STAR protocol (MAS method) is developed. This method is highly standardised, gives stable assessment results and is relatively inexpensive (€ 224.00 for processing of an average sample). A detailed protocol of the newly developed method is given.  相似文献   

2.
With the aim of finding an efficient, standardised and practical protocol for sorting macroinvertebrate samples for water management practice, three different sorting techniques were tested: RIVPACS sorting, a modified AQEM/STAR (MAS) sorting protocol and a Live-sorting method. Based on the same AQEM/STAR sample to ensure comparable results, we compared RIVPACS and MAS sorting for 20 samples, and Live-sorting and MAS for a different set of 20 samples. Comparisons were based on both ecological and financial parameters relevant for the implementation of the EU Water Framework Directive in Germany. Parameters include recently developed multimetric assessment indices, their stream type specific core metric results, time effort and costs. While RIVPACS and MAS sorting produced similar results in terms of ecological assessment, time effort and costs, Live-sorting differed notably in all three respects. Live-sorting is the quickest and least expensive protocol, but shows higher variability than the other protocols. We discuss the differences and the level of standardisation for each of these methods.  相似文献   

3.
The process of selecting invertebrate-based candidate metrics for the German stream assessment system is described. The aim was to identify metrics indicating degradation types other than organic pollution and acidification (“general degradation”). For 18 out of 24 German stream types a data base of roughly 2,000 benthic invertebrate samples was generated; for each sample 79 metrics were calculated. Data on land use in the catchment were compiled for all sampling sites, together with data on hydromorphology for many sampling sites. Hydromorphological and land use parameters, which describe a clear gradient in the data sets were identified by Non-metric Multidimensional Scaling (NMS). Correlation analyses between land use/hydromorphological parameters and metric results were calculated separately for the individual stream types. Among those metrics best indicating catchment- and hydromorphological degradation in the majority of stream types are: proportion of Ephemeroptera, Plecoptera and Trichoptera; proportion of Plecoptera (mainly suited for mountain streams); number of Plecoptera taxa; proportion of xenosaprobic taxa; proportion of epirhithral preferring taxa. Differences of metric correlations between stream types and between degradation types are discussed, leading to a list of candidate metrics for assessing German streams.  相似文献   

4.
This paper summarises the results of the “Rhithron Ecology Group” meeting in Essen (March 2000), supplemented by a literature evaluation.An extended view of small mountain streams in Central Europe under “potentially natural conditions” is presented. We focus on the potential impact of natural transverse structures (debris dams and beaver dams) on stream morphology, hydrology, habitat composition and communities. Furthermore, impact of other stream morphological features, which are presently lacking in the Central European landscape, is described.We suggest that Central European mountain streams are characterised by a higher proportion of lentic zones under “potentially natural conditions”. Morphological degradation leads to a loss of lentic zones and to an increase of current velocities and corresponding changes in faunal composition, particularly higher abundance and proportion of rheophilic species and a decrease of species preferring lentic zones. This should be regarded in future stream assessment.  相似文献   

5.
Settled particles of fresh, labile organic matter may be a significant source of oxygen demand and nutrient regeneration in seasonally-hypoxic regions caused by nutrient inputs into stratified coastal zones. Studying the dynamics of this material requires sediment sampling methods that include flocculent organic materials and overlying water (OLW) at or above the sediment–water interface (SWI). A new coring device (“HYPOX” corer) was evaluated for examining nitrogen- (N) and oxygen-dynamics at the SWI and OLW in the northern Gulf of Mexico (NGOMEX). The HYPOX corer consists of a “Coring Head” with a check-valve, a weighted “Drive Unit,” and a “Lander,” constructed from inexpensive components. The corer collected undisturbed sediment cores and OLW from sediments at NGOMEX sampling sites with underlying substrates ranging from sand to dense clay. The HYPOX corer could be deployed in weather conditions similar to those needed for a multi-bottle rosette water-sampling system with 20 L bottles. As an example of corer applicability to NGOMEX issues, NH4+ cycling rates were examined at hypoxic and control sites by isotope dilution experiments. The objective was to determine if N-dynamics in OLW were different from those in the water column. “Ammonium demand,” as reflected by potential NH4+ uptake rates, was higher in OLW than in waters collected from a meter or more above the bottom at both sites, but the pattern was more pronounced at the hypoxia site. By contrast, NH4+ regeneration rates were low in all samples. These preliminary results suggest that heterotrophic activity and oxygen consumption in OLW in the hypoxic region may be regulated by the availability of NH4+, or other reduced N compounds, rather than by the lack of sufficient labile organic carbon.  相似文献   

6.
The so-called “Graded Unit” comprises 17.2 m of the core from the research borehole Nördlingen 1973 and is thought to represent fall-back material, which has been sorted similar to tephra. Samples from six levels of these air-borne impact debris sediments in the Ries Crater have been analyzed for Ir, Ni, Co, Cr and Fe. The concentrations of these elements are negatively correlated with average grain size and accordingly the depth of the samples indicating the presence of a surface correlated component and are hence consistent with vapour deposition of meteoritic material on small dust grains. The largest Ir concentration found is 230 pg/g, a factor of 28 higher than the indigenous concentration. Enrichment factors in the uppermost layer of the “Graded Unit” are about 28 for Ir, approximately 2 for Fe, Co, Ni and 1.5 for Cr. If the enrichment of all elements determined were of meteoritic origin, then the “net meteoritic composition” is most closely matched by aubrites as suggested previously. However, it seems more likely that the observed concentration trends of Cr, Fe, Co and Ni are due to mineral sorting. Therefore the only as yet certain indication of meteoritic material is the presence of Ir, which is not sufficient to further constrain the nature of the projectile.  相似文献   

7.
Based on benthic macroinvertebrate samples from 57 sites of streams in the European Central Highlands (Ecoregion 9; Illies (1978). Limnofauna Europaea, Stuttgart), the composition and the abundance of Simuliid species were analysed in relation to hydromorphological and land use parameters. Sampling sites were located at two stream types differing in catchment geology, stream morphology and channel width. Land use data were taken from the official German information system for cartography and topography (ATKIS) and the German River Habitat Survey. Land use categories suitable to describe the sampling sites were ‘agricultural land’, ‘urban’ and near-natural areas. Hydromorphological parameters of the sites were recorded using the AQEM site protocol (AQEM Consortium (2002). Manual for the application of the AQEM system. A comprehensive method to assess European streams using benthic macroinvertebrates, developed for the purpose of the Water Framework Directive. EVK1-CT1999-00027, Version 1.0. Available via the Internet from www.aqem.de). Relevant parameters controlling Simuliid distribution in streams were the mineral substrates and the biotic microhabitats. Blackfly larvae and pupae were sampled at each site for 15 min. Statistical analysis was performed by CANOCO® (Ter Braak & Smilauer (1997). CANOCO Version 4.5. Biometrics Plant Research International, Wageningen, The Netherlands) using redundancy analysis (RDA).

Our results show a stream type-specific composition of the Blackfly fauna. The analyses reveal sensitivity of the Simuliid species to morphological degradation, which is indicated by the shift in the longitudinal zonation of the Simuliid communities. Especially, Prosimulium hirtipes (Fries, 1824) and Simulium argyreatum Meigen, 1838 are typical representatives of headwater streams. While they seem to indicate undisturbed conditions of this stream type and react sensitively to the degradation of stream habitats, Simulium ornatum Meigen, 1818 and Simulium equinum (Linnaeus, 1758) are more tolerant to stream degradation.

On catchment scale, ‘% natural forest’ and ‘% agricultural land use’ illustrate the degree of degradation of the two selected stream types. ‘Average stream depth’ and ‘relation riffles/pools’ account for hydromorphological degradation reflected by Simuliid species on the smaller reach scale. The analysis of habitat quality revealed that ‘% woody debris’ represents an important parameter of morphological degradation reflected by the Blackfly community.  相似文献   


8.
Many streams and rivers worldwide are restored with the intention to mitigate degradation caused by human activities, but these rehabilitation projects often involve physical instream work with diggers or other heavy machinery. The short-term effects of such restoration works on stream ecosystems are rarely investigated. The primary aim of our study was to assess the short-term effects of physical instream restoration works (which likely increased instream fine sediment load temporarily) on the benthic macroinvertebrate community in a lowland soft-bottomed stream, and our second aim was to compare the results of semi-quantitative kick-net and quantitative Surber sampling in this assessment. Invertebrates were collected using these two methods from three Control and three Impact sites, before and two days after recontouring the stream banks and installing instream woody cover features. Three of seven macroinvertebrate community-level indexes suggested positive short-term effects of the restoration works, whereas none indicated negative effects. By contrast, seven of the 14 most common taxa were negatively affected by the restoration works, possibly due to increased fine sediment levels reducing habitat quality for these taxa. These differences imply that taxon-specific invertebrate responses may be more suitable for detecting short-term impacts of instream restoration works than community-level metrics. Community indexes and common taxa were also likely affected by a drought in the spring and summer before restoration, which may have obscured some effects of the restoration works. Finally, kick-net and Surber sampling methods yielded similar findings for the community-level metrics but differed more for the common taxa, probably because the two methods sampled different microhabitats within the stream. Consequently, we recommend that for routine monitoring of macroinvertebrate communities in lowland soft-bottomed streams, the semi-quantitative kick-net sampling method should be used.  相似文献   

9.
10.
The patterns of variation of TiO2 conent during magmatic evolution are different in the so called “orogenic” and “anorogenie” basic associations; these last terms, which are the cause of much misunderstanding, can be replaced by the terms “isotitaniferous” and “anisotitaniferous”.  相似文献   

11.
We have used two different sampling techniques to study the geochemical response of a small lowland rural catchment to episodic storm runoff. The first method involves traditional daily spot sampling and has been used to develop a standard end‐member mixing analysis (EMMA) of the relative contributions of ground water flow and surface runoff to the total stream flow. The second method utilizes a continuous sampling device, powered by an osmotic pump, to produce an integrated 24‐h sample of the stream flow. When combined with the EMMA results from the spot samples, analyses of the integrated samples reveal the presence of a third component that makes a significant contribution to the dissolved NO3, Ca and K export from the catchment during the rising limb of the hydrographic profile of a storm event following a prolonged dry period. The storm occurred in the middle of the night, so that the response of the stream chemistry was not captured by the daily samples. We hypothesize that this third component is derived from the flushing of stored soil water that contains the geochemical signature of decaying vegetation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

12.
Mapping and sampling with DSRV “Alvin” has established that sulfide blocks 0.5 m across, dredged from the axial valley of the Endeavour Segment at 47°57′N, are samples of unusually large sulfide structures. The steep-sided structures, up to 30 m in length, 20 m in height, and 10–15 m across, are localized by venting along normal faults at the base of the western axial valley wall, and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest. High-temperature fluids (350 to more than 400°C) pass through the massive sulfide structures and enter seawater through small, concentric “nozzle-like” features projecting from the top or the sides of the larger vent structures. Diffuse, low-temperature flow is pervasive in the vicinity of the active sulfide structures, exiting from basalt and sulfide surfaces alike. Evidence of recent volcanic activity is sparse.The two largest samples taken with the dredge would not have been recoverable using the submersible. These samples represent massive, complex portions of the sulfide structures which were not closely associated with rapid high-temperature fluid flow at the time of sampling; they contain textural evidence of sealed hydrothermal fluid exit channels. Mineralogy is dominated by Fe sulfides nnd amorphous silica. Pyrite, marcasite, wurtzite, chalcopyrite, and iss are the most common sulfide phases. Pyrrhotite, galena, and sphalerite are present in trace amounts. Barite, amorphous silica, and chalcedony are the only non-sulfide phases; anhydrite is not observed in any of the dredge samples, although it is common in the chimney-like samples recovered by “Alvin”.Specific mineralogical-textural zones within the dredge samples are anaoogous to individual layers in East Pacific Rise at 21°N and southern Juan de Fuca Ridge samples, with two exceptions: a coarse-grained, highly porous Fe sulfide-rich interior containing sulfidized tubeworm casts, and a 2–5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica. The porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber. The amorphous silica deposited from a seawater/hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber; conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate. These silica-rich zones are the densest, most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features.Observations in these samples are consistent with two distinct phases of development. Phase 1 is analogous to chimney growth and construction at 21°N and ends when flow channels become sealed to rapid flow of through-going fluid. The flow is evidently redirected within the structure. Phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater/hydrothermal fluid mixtures. Evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures.  相似文献   

13.
Deep-water samples collected during the Kaiko project are often associated with biological communities located on geological structures favorable to fluid venting. The evidence of fluid venting are the temperature anomalies, the decrease in sulfate concentrations, the content in methane and the lowC1(C2 +C3) ratio of light hydrocarbons. Because of large dilution by ambiant seawater during sampling it is difficult to compute the composition of the advected end-member pore fluid. Part of this fluid should originate in the “petroleum window”, i.e. at temperature about 60°C. Modeling the upward flow of water, taking into account the anomalies of temperature measured on the seafloor and the geochemical anomalies, leads to non-steady-state advection of the pore fluid. The occurrence of a deep component in the fluid has implications for the geological and tectonic models of the subduction zones off Japan.  相似文献   

14.
Hans Jürgen Hahn   《Limnologica》2006,36(2):119-137
Between June 2001 and December 2002, 18 hyporheic and groundwater bores were sampled for fauna and environmental data using phreatic traps. The bores were situated in three different natural geographic regions in Palatinate, Southwestern Germany.Faunal data correlated with the relative amount of detritus, bacterial abundances and the standard deviation of temperature, while very few and weak correlations were found with physical–chemical variables. Dissolved oxygen was assumed to be a limiting factor for most metazoans with a critical concentration at around 0.5–1 mg l−1.To quantify the strength of the hydrological exchange with surface water and its effects on fauna, a so-called GW-Fauna-Index was developed and calculated using the relative amount of detritus, standard deviation of temperature, and oxygen concentration. From all environmental data and on all spatial scales, this index best explained the total faunal abundance and taxonomic richness.To describe the availability of organic aliments in the groundwater, the terms of “alimonic” and “alimony” [from lat. alimonium=(food) supply] were proposed.Although stygofauna was different in the geographic regions investigated, the GW-Fauna-Index was independent from these regional particularities. Using the GW-Fauna-Index, three groups of groundwater habitats could be classified according to the alimonic conditions. From oligo-alimonic group I samples, fauna was mostly absent, while meso-alimonic group II samples were prevailingly populated by stygobites, and eu-alimonic group III samples by ubiquists and stygoxenes. Total abundances and taxonomic richness increased significantly from group I to group III. Group I samples were characterized by low index values, group II samples by intermediate and group III samples by high values.The GW-Fauna-Index provides promising perspectives for application, but needs some improvement. First of all, detritus should be analysed quantitatively and qualitatively, rather than semi-quantitatively. Also, a standard protocol for sampling has to be developed.  相似文献   

15.
The different basalt types related to rift structure development have been investigated, starting from the pre-rift stage in the northern Ethiopian rift and its eastern escarpment and plateau.The basic volcanic rocks are represented mainly by transitional basalts, both in the pre-rift (plateau) and rift (escarpment and rift floor) stages. A striking feature is that although the plateau basalts show clear tholeiitic affinity and the rift basalts reveal a somewhat pronounced “alkaline” character, the REE and LILE element abundances, however, progressively decrease from the “tholeiitic” basalts of the plateau to the “alkaline” basalts of the rift.All data support the view that such contrasting features may be attributed to a continuous depletion of hygromagmatophile (REE, LILE) elements in the mantle source material, related to the large volumes of magmas produced in the early phase of rift structure development. The transition from “tholeiitic” (plateau) to “alkaline” (rift) transitional basalts is related to decreasing intensity of extensional movements.  相似文献   

16.
The proportion of water younger than 2–3 months (young water fraction, Fyw) has become increasingly investigated in catchment hydrology. Fyw is typically estimated by comparing seasonal tracer cycles in precipitation and streamflow, through water sampling. However, some open research questions remain, such as: (i) whether part of the summer precipitation should be discarded because the high evapotranspiration demand, (ii) how well Fyw serves as a metric to compare catchments, and (iii) how sampling frequency affects Fyw estimates. To address these questions, we investigated Fyw in soil-, ground- and stream waters for the small Mediterranean Can Vila catchment. Rainfall was sampled at 5-mm intervals. Mobile soil water and groundwater were sampled fortnightly. Stream water was sampled depending on flow at variable time intervals (30 min to 1 week). Over 58 months, this sampling provided 1,529 δ18O determinations. Isotopic analyses results led us to include summer precipitation in the input signal. We found the highest Fyw in mobile soil waters (34%), while this was almost zero for groundwater except during wet periods. For stream waters, Fyw depended on the discharge variations, so that the flow-weighted young water fraction () was 22.6%, whereas the time-weighted Fyw was just 6.2%. Both and its discharge sensitivity (Sd) varied when different 12-month sampling periods were investigated. The young water fraction that would be obtained from a virtual thorough sampling () was estimated from the Sd and the observed stream flow. This showed an underestimation of by 25% for the frequent dynamic sampling and 66% for weekly sampling, due to missing high flows. Our results confirm that Fyw and its discharge sensitivity are metrics very sensitive to meteorological forcing during the analysed period. Thus, comparisons between catchments need long-term mean annual values and their variability. Our findings also support the dependence of Fyw estimates on the sampling rate and show the advantages of flow-weighted analysis. Finally, catchment water turnover investigations should be accompanied by the analysis of flow duration curves.  相似文献   

17.
Seasonality plays a critical role in cold mountain regions as variation in air temperature, ground thermal status, and precipitation phase alter the rate, timing and magnitude of hydrological and chemical transport. Additionally, cold mountain catchments can have highly variable topography, geology, permafrost, and landcover, which intrinsically add to this irregularity. Understanding how external and internal variability act to control mass fluxes requires sampling at a high spatial resolution over time, which rarely occurs in cold remote regions. In this work, we conduct five snapshot sampling surveys across 34 subcatchments during the ice-free period in Wolf Creek Research Basin (a mesoscale montane subarctic catchment) and two additional winter surveys across a subset of sites to assess the drivers of variability in stream chemistry and discharge. We sampled for specific conductance (SpC), major ions, and dissolved organic carbon (DOC) and used statistical metrics and Bayesian mixing analysis to quantify patterns of flow and chemistry across space and time. Our results indicate patterns in both flow and chemistry remain largely consistent across seasons for all solutes. However, there was weaker correlation of chemistry between sites, suggesting asynchronous behaviour within the catchment. There was evidence of increasing production of ions and DOC along the stream network during high spring flows but not during low flows. Although concentrations and flows exhibit high seasonality in subarctic mountains, this seasonal variability does not alter spatial patterns that arise from highly variable catchment characteristics.  相似文献   

18.
Isotopes are increasingly used in rainfall-runoff models to constrain conceptualisations of internal catchment functioning and reduce model uncertainty. However, there is little guidance on how much tracer data is required to adequately do this, and different studies use data from different sampling strategies. Here, we used a 7-year time series of daily stable water isotope samples of precipitation and streamflow to derive a range of typical stream sampling regimes and investigate how this impacts calibration of a semi-distributed tracer-aided model in terms of flow, deuterium and flux age simulations. Over the 7 years weekly sampling facilitated an almost identical model performance as daily, and there were only slight deteriorations in performance for fortnightly sampling. Monthly sampling resulted in poorer deuterium simulations and greater uncertainty in the derived parameter sets ability to accurately represent catchment functioning, evidenced by unrealistic reductions in the volumes of water available for mixing in the saturation area causing simulated water age decreases. Reducing sampling effort and restricting data collection to 3 years caused reductions in the accuracy of deuterium simulation, though the deterioration did not occur if sampling continued for 5 years. Analysis was also undertaken to consider the effects of reduced sampling effort over the driest and wettest hydrological years to evaluate effects of more extreme conditions. This showed that the model was particularly sensitive to changes in sampling during dry conditions, when the catchment hydrological response is most non-linear. Across all dataset durations, sampling in relation to flow conditions, rather than time, revealed that samples collected at flows >Q50 could provide calibration results comparable to daily sampling. Targeting only extreme high flows resulted in poor deuterium and low flow simulations. This study suggests sufficient characterization of catchment functioning can be obtained through reduced sampling effort over longer timescales and the targeting of flows >Q50.  相似文献   

19.
The Jemez Mountains volcanic field (JMVF), located in north-central New Mexico, has been a site of basaltic to rhyolitic volcanism since the mid-Miocene with major caldera forming eruptions occurring in the Pleistocene. Eruption of the upper Bandelier Tuff (UBT) is associated with collapse of the Valles Caldera, whereas eruption of the lower Bandelier Tuff (LBT) resulted in formation of the Toledo Caldera. These events were previously dated by K-Ar at 1.12 ± 0.03 Ma and 1.45 ± 0.06 Ma, respectively. Pre-Bandelier explosive eruptions produced the San Diego Canyon (SDC) ignimbrites. SDC ignimbrite “B” has been dated at 2.84 ± 0.07 Ma, whereas SDC ignimbrite “A”, which underlies “B”, has been dated at 3.64 ± 1.64 Ma. Both of these dates are based on single K-Ar analyses.40Ar/39Ar dating of single sanidine crystals from these units indicates revision of the previously reported dates. Isochron analysis of 26 crystals from the UBT gives a common trapped 40Ar/36Ar component of 304.5, indicating the presence of excess 40Ar in this unit, and defines an age of 1.14 ± 0.02 Ma. Isochron analysis of 26 crystals from the LBT indicates an atmospheric trapped component and an age of 1.51 ± 0.03 Ma. An age of 1.78 ± 0.04 Ma, based on the weighted mean of 5 individual analyses, is indicated for SDC ignimbrite “B”, whereas 3 analyses from SDC ignimbrite “A” give a weighted mean age of 1.78 ± 0.07 Ma. Evidence for xenocrystic contamination in the SDC ignimbrites comes from analyses of a correlative air-fall pumice unit in the Puye Formation alluvial fan giving ages of 1.75 ± 0.08 and 3.50 ± 0.09 Ma. The presence of xenocrysts in bulk separates used for the original K-Ar analyses could account for the significantly older ages reported.Geochemical data indicate that SDC ignimbrites are early eruptions from the magma chamber which evolved to produce the LBT, as compositions of SDC ignimbrite “B” are virtually identical to least evolved LBT samples. Differentiation during the 270-ka interval between eruption of SDC ignimbrite “B” and the LBT produced an array of high-silica rhyolite compositions which were erupted to form the LBT. Mixed pumices associated with eruption of the LBT indicated an influx of more mafic magma into the system which produced shifts in some incompatible trace-element ratios. Lavas and tephras of the Cerro Toledo Rhyolite record the geochemical evolution of the Bandelier magma system during the 370-ka interval between eruption of the LBT and the UBT.The combined geochronologic and geochemical data place the establishment and evolution of the Bandelier silicic magma system within a precise temporal framework, beginning with eruption of the SDC ignimbrites at 1.78 Ma, and define a periodicity of 270–370 ka to ash-flow eruptions in the JMVF. These intervals are comparable to those in other multicyclic caldera complexes and are a measure of the timescales over which substantial fractionation of large silicic magma bodies occur.  相似文献   

20.
Rare earth element (REE) and other trace element compositions of 16 lavas from all historic and 2 prehistoric eruptions on 5 islands of the Azores Archipelago show notable intra-and inter-island differences. Fe enrichment and “compatible” element depletion due to fractional crystallization have been superimposed on variations established in the source area. Fractionation of La/Sm, U/Th, K/Na and “large ion lithophile” (LIL) element abundances are probably related to variable fusion of a source peridotite whose LIL element distribution cannot be exactly specified in view of its possible heterogeneity. Relative light-REE enrichment in basalt appears greatest on the “potassic” island São Miguel, the more sodic island Fayal and one lava from Pico, and least in basalts from the “sodic” islands Terceira, São Jorge and Pico. This variation is matched by most other LIL elements, although P shows unexpected enrichment in Terceira lavas, otherwise the least LIL element-enriched and most heavy-REE-enriched. Upper mantle phase chemistry is probably critical in establishing the patterns. In particular, P—REE covariance may reflect phase stabilities of apatite and (P-bearing) garnet in the upper mantle. Distribution patterns of REE in the historic lavas are similar to those of basalts from the Atlantic median rift at the crest of the Azores “platform”. Transition to light-REE-depleted rift-erupted basalts to the southwest is believed to be step-wise with increasing water depth, possibly indicating retention of a light-REE-rich phase in the residue from partial fusion as intersection of geotherm and peridotite solidus occur at lower pressures. The source mantle for the Azores basalts is probably light-REE- and LIL element-enriched but we find no evidence so far to suggest its emplacement by thermal “plume” activity.  相似文献   

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