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1.
Climate change during the Last Glacial is considered as a major forcing factor of fluvial system changes. A continuous succession of fluvial sediments, reflecting adaptations to climate change from the Weichselian Middle Pleniglacial (oxygen isotope stage 3) onwards, occurs in lowland river basins in the Netherlands.A comparison of the Pleniglacial and Late Glacial fluvial record in the Netherlands shows that climatic oscillations of similar magnitude did not produce changes in the fluvial sedimentary system of equal magnitude. The Late Glacial fluvial system proves to be highly sensitive to climate change. By contrast, many of the rapid climate changes that have occurred during oxygen isotope stage 3, according to the Greenland ice core record, are not detectable in the fluvial sediments. This can be explained by differences in the impact of the climate variations on drainage basin vegetation. During the Late Glacial, the tree line repeatedly shifted through the Netherlands, whereas the area remained within the tundra zone during the Middle Pleniglacial. Precipitation variations and permafrost aggradation and degradation have played a secondary role.The Weichselian fluvial succession in the Netherlands demonstrates that detection of a change in the fluvial sedimentary system and relating this change to climate change is subject to methodological limitations. The climatic significance of changes in the fluvial record should be carefully evaluated, as well as their chronology. The possibility that climate did not influence the fluvial system should always be considered as a null hypothesis in studies on fluvial successions.  相似文献   

2.
Abstract— We report noble gas, oxygen isotope, 14C and 10Be data of Itqiy as well as noble gas, 14C and 10Be results for Zak?odzie. Both samples have been recently classified as anomalous enstatite meteorites and have been compared in terms of their mineralogy and chemical composition. The composition of enstatite and kamacite and the occurrence of specific sulfide phases in Itqiy indicate it formed under similar reducing conditions to those postulated for enstatite chondrites. The new results now seem to point at a direct spatial link. The noble gas record of Itqiy exhibits the presence of a trapped subsolar component, which is diagnostic for petrologic types 4–6 among enstatite chondrites. The concentration of radiogenic 4He is very low in Itqiy and indicates a recent thermal event. Its 21Ne cosmic‐ray exposure age is 30.1 ± 3.0 Ma and matches the most common age range of enstatite chondrites (mostly EL6 chondrites) but not that of Zak?odzie. Itqiy's isotopic composition of oxygen is in good agreement with that observed in Zak?odzie as well as those found in enstatite meteorites suggesting an origin from a common oxygen pool. The noble gas results, on the other hand, give reason to believe that the origin and evolution of Itqiy and Zak?odzie are not directly connected. Itqiy's terrestrial age of 5800 ± 500 years sheds crucial light on the uncertain circumstances of its recovery and proves that Itqiy is not a modern fall, whereas the 14C results from Zak?odzie suggest it hit Earth only recently.  相似文献   

3.
Abstract— The carbonate mineralogy of several complex carbonate‐rich regions in Allan Hills (ALH) 84001 has been examined. These regions contain familiar forms of carbonate, as well as textural forms previously unreported including carbonate rosettes, planiform “slab” carbonates, distinct “post‐slab” magnesites, and carbonates interstitial to feldspathic glass and orthopyroxene. Slab carbonates reveal portions of the carbonate growth sequence not seen in the rosettes and suggest that initial nucleating compositions were calcite‐rich. The kinetically controlled growth of rosettes and slab carbonates was followed by an alteration event that formed the magnesite‐siderite layers on the exterior surfaces of the carbonate. Post‐slab magnesite, intimately associated with silica glass, is compositionally similar to the magnesite in these exterior layers but represents a later generation of carbonate growth. Feldspathic glasses had little or no thermal effect on carbonates, as indicated by the lack of thermal decomposition or any compositional changes associated with glass/carbonate contacts.  相似文献   

4.
The Chinese Loess Plateau (CLP) comprises an extensive record of eolian deposition that contains important information about climate change. The objective of this study is to investigate if mineralogy can provide more insight into the long-term evolution of the East Asian monsoon. Comparisons between mineralogy and other paleoclimatic records (grain size and magnetic susceptibility) from the CLP have been made to evaluate the efficacy of mineralogy as a paleoclimatic tool.Here we present data from a mineralogical study of a red clay–loess sequence at Lingtai, central Chinese Loess Plateau. Changes related to source area(s), transport processes and weathering regime over time are recorded in mineral variation.Higher average concentrations of kaolinite, chlorite and quartz in the red clay, together with abrupt changes in relative mineral abundances across the red clay–loess boundary suggest a change of source area at 2.6 Ma. From 2.6 Ma to about 1.7 Ma the summer monsoon influence increases, destroying chlorite and contributing fine illite particles to the sediment. At around 1.7 Ma the mineralogy becomes relatively constant, suggesting that the monsoon was fairly stable during this period. At 0.7–0.5 Ma an increase of both summer monsoon and winter monsoon activity is inferred from illite, kaolinite, chlorite and plagioclase concentrations. Over the last 0.5 Ma mineralogy suggests an aridification of source area(s) as chlorite and plagioclase concentrations increase where illite concentration decreases. The last major change occurred around 0.07 Ma and indicates reducing summer monsoon influence as chlorite and quartz concentrations increase and illite concentration, as well as the < 2 μm size fraction, decreases. The mineralogical trends and differences between loess and paleosols units suggest different source areas in the last 0.5 Ma.  相似文献   

5.
The carbon-isotope and palynological record through 580 m thick almost continuous brown coal in southeast Australia's Gippsland Basin is a relatively comprehensive southern hemisphere Middle Eocene to Middle Miocene record for terrestrial change. The carbon isotope δ13Ccoal values of these coals range from ? 27.7‰ to ? 23.2. This isotopic variability follows gymnosperm/angiosperm fluctuations, where higher ratios coincide with heavier δ13C values. There is also long-term variability in carbon isotopes through time. From the Eocene greenhouse world of high gymnosperm-heavier δ13Ccoal values, there is a progressive shift to lighter δ13Ccoal values that follows the earliest (Oi1?) glacial events around 33 Ma (Early Oligocene). The overlying Oligocene–Early Miocene brown coals have lower gymnosperm abundance, associated with increased %Nothofagus (angiosperm), and lightening of isotopes during Oligocene cooler conditions.The Miocene palynological and carbon-isotope record supports a continuation to the Oligocene trends until around the late Early Miocene (circa 19 Ma) when a warming commenced, followed by an even stronger isotope shift around 16 Ma that peaked in the Middle Miocene when higher gymnosperm abundance and heavier isotopes prevailed. The cycle between the two major warm peaks of Middle Eocene and Middle Miocene was circa 30 Ma long. This change corresponds to a fall in inferred pCO2 levels for the same period. The Gippsland data suggest a link between gymnosperm abundance, long-term plant δ13C composition, climatic change, and atmospheric pCO2. Climatic deterioration in the Late Miocene terminated peat accumulation in the Gippsland Basin and no further significant coals formed in southeast Australia.The poor correspondence between this terrestrial isotope data and the marine isotope record is explained by the dominant control on δ13C by the gymnosperm/angiosperm abundance, although in turn this poor correspondence may reflect palaeoclimate control. From the brown coal seam dating, the coal appears to have accumulated during a considerable part of the allocated 30 Ma Cenozoic time period. These brown coal carbon isotope and palynological data appear to record a more gradual atmospheric carbon isotope change compared to the marine record.  相似文献   

6.
There is a continuous record of planktonic foraminifers for oxygen isotope stages 50 to 26 (ca. 1.5–1.0 Ma) in the early Pleistocene Omma Formation near Kanazawa City, Central Japan, on the Sea of Japan coast. The warm-water species Globigerinoides ruber entered the Sea of Japan with the Tsushima Current during all interglacial periods and went locally extinct in the succeeding glacial periods. This implies that the marine climate of the Sea of Japan varied predominantly with the 41,000-year period of Earth's orbital obliquity. However, the relative abundances of G. ruber in marine isotope stages 47, 43 and 31 are significantly higher than those in other interglacial stages. These stages correspond to periods when eccentricity-modulated precession extremes were aligned with obliquity maxima. The Tsushima Current is a branch of the warm Kuroshio Current which is the strong northwestern component of the subtropical North Pacific Ocean gyre. Our data imply that the early Pleistocene climate in the northwestern Pacific was influenced not only by obliquity cycles but also by eccentricity cycles. This study also supports the climate model regarding eccentricity's role in the origin of low-frequency climate changes before the late Pleistocene ice ages.  相似文献   

7.
Analyses of Eemian climate dynamics based on different reconstruction methods were conducted for several pollen sequences in the northern alpine foreland. The modern analogue and mutual climate sphere techniques used, which are briefly presented, complement one another with respect to comparable results. The reconstructions reveal the occurrence of at least two similar thermal periods, representing temperate oceanic conditions warmer and with a higher humidity than today. Intense changes of climate processes become obvious with a shift of winter temperatures of about 15 °C from the late Rissian to the first thermal optimum of the Eemian. The transition shows a pattern of summer temperatures and precipitation increasing more rapidly than winter temperatures. With the first optimum during the Pinus–Quercetum mixtum–Corylus phase (PQC) at an early stage of the Eemian and a second optimum period at a later stage, which is characterised by widespread Carpinus, climate gradients across the study area were less intense than today. Average winter temperatures vary between −1.9 and 0.4 °C (present-day −3.6 to 1.4 °C), summer temperatures between 17.8 and 19.6 °C (present-day 14 to 18.9 °C). The timberline expanded about 350 m when compared to the present-day limit represented by Pinus mugo. Whereas the maximum of temperature parameters is related to the first optimum, precipitation above 1100 mm is higher during the second warm period concomitant to somewhat reduced temperatures. Intermediate, smaller climate oscillations and a cooling becomes obvious, which admittedly represent moderate deterioration but not extreme chills. During the boreal semicontinental Eemian Pinus–Picea–Abies phase, another less distinct fluctuation occurs, initiating the oscillating shift from temperate to cold conditions.  相似文献   

8.
A palynological study of oil exploration wells in the Gippsland Basin southeastern Australia has provided a record of southern high latitude climate variability for the last 12 million years of the Cretaceous greenhouse world. During this time, the vegetation was dominated by a cool to temperate flora of Podocarpaceae, Proteaceae and Nothofagidites spp. at a latitude of 60°S. Milankovitch forced cyclic alternations from drier to wetter climatic periods caused vegetation variability from 72 to 77 Ma. This climate change was probably related to the waxing and waning of ephemeral (100 ky) small ice sheets in Antarctica during times of insolation minima and maxima. Drying and cooling after 72 Ma culminated from 68 to 66 Ma, mirroring trends in global δ18O data. Quantitative palynofloral analyses have the potential to provide realistic proxies for small-scale climate variability in the predominantly ice-free Late Cretaceous.  相似文献   

9.
Abstract— The newly found meteorite Northwest Africa 6234 (NWA 6234) is an olivine (ol)‐phyric shergottite that is thought, based on texture and mineralogy, to be paired with Martian shergottite meteorites NWA 2990, 5960, and 6710. We report bulk‐rock major‐ and trace‐element abundances (including Li), abundances of highly siderophile elements, Re‐Os isotope systematics, oxygen isotope ratios, and the lithium isotope ratio for NWA 6234. NWA 6234 is classified as a Martian shergottite, based on its oxygen isotope ratios, bulk composition, and bulk element abundance ratios, Fe/Mn, Al/Ti, and Na/Al. The Li concentration and δ7Li value of NWA 6234 are similar to that of basaltic shergottites Zagami and Shergotty. The rare earth element (REE) pattern for NWA 6234 shows a depletion in the light REE (La‐Nd) compared with the heavy REE (Sm‐Lu), but not as extreme as the known “depleted” shergottites. Thus, NWA 6234 is suggested to belong to a new category of shergottite that is geochemically “intermediate” in incompatible elements. The only other basaltic or ol‐phyric shergottite with a similar “intermediate” character is the basaltic shergottite NWA 480. Rhenium‐osmium isotope systematics are consistent with this intermediate character, assuming a crystallization age of 180 Ma. We conclude that NWA 6234 represents an intermediate compositional group between enriched and depleted shergottites and offers new insights into the nature of mantle differentiation and mixing among mantle reservoirs in Mars.  相似文献   

10.
Abstract— The role of oxygen isotope exchange during evaporation and condensation of silicate melt is quantitatively evaluated. Silicate dusts instantaneously heated above liquidus temperature are assumed to cool in gas and experience partial evaporation and subsequent recondensation. The results show that isotopic exchange effectively suppresses mass‐dependent O‐isotope fractionation even if the degree of evaporation is large, which is the fundamental difference from the case without isotopic exchange. The final composition of silicate melt strongly depends on the initial abundance of oxygen in the ambient gas relative to that in silicate dust, but not on the cooling rate of the system. The model was applied to O‐isotope evolution of silicate melts in isotopically distinct gas of the protoplanetary disk. It was found that deviation from a straight mixing line toward the δ18O‐rich side on the three‐oxygen isotope diagram is inevitable when mass‐dependent fractionation and isotopic exchange take place simultaneously; the degree of deviation depends on the abundance of oxygen in an ambient gas and isotopic exchange efficiency. The model is applied to explain O‐isotopic compositions of igneous CAIs and chondrules.  相似文献   

11.
The Northwest Africa (NWA) 7475 meteorite is one of the several stones of paired regolith breccias from Mars based on petrography, oxygen isotope, mineral compositions, and bulk rock compositions. Its inventory of lithic clasts is dominated by vitrophyre impact melts that were emplaced while they were still molten. Other clast types include crystallized impact melt rocks, evolved plutonic rocks, possible basalts, contact metamorphosed rocks, and siltstones. Impact spherules and vitrophyre shards record airborne transport, and accreted dust rims were sintered on most clasts, presumably during residence in an ejecta plume. The clast assemblage records at least three impact events, one that formed an impact melt sheet on Mars ≤4.4 Ga ago, a second that assembled NWA 7475 from impactites associated with the impact melt sheet at 1.7–1.4 Ga, and a third that launched NWA 7475 from Mars ~5 Ma ago. Mildly shocked pyroxene and plagioclase constrain shock metamorphic conditions during launch to >5 and <15 GPa. The mild postshock‐heating that resulted from these shock pressures would have been insufficient to sterilize this water‐bearing lithology during launch. Magnetite, maghemite, and pyrite are likely products of secondary alteration on Mars. Textural relationships suggest that calcium‐carbonate and goethite are probably of terrestrial origin, yet trace element chemistry indicates relatively low terrestrial alteration. Comparison of Mars Odyssey gamma‐ray spectrometer data with the Fe and Th abundances of NWA 7475 points to a provenance in the ancient southern highlands of Mars. Gratteri crater, with an age of ~5 Ma and an apparent diameter of 6.9 km, marks one possible launch site of NWA 7475.  相似文献   

12.
Abstract— The original mass (15915 g) of the Twannberg IIG (low Ni‐, high P) iron was found in 1984. Five additional masses (12 to 2488 g) were recovered between 2000 and 2007 in the area. The different masses show identical mineralogy consisting of kamacite single crystals with inclusions of three types of schreibersite crystals: cm‐sized skeletal (10.5% Ni), lamellar (17.2% Ni), and 1–3 × 10 μm‐sized microprismatic (23.9% Ni). Masses I and II were compared in detail and have virtually identical microstructure, hardness, chemical composition, cosmic‐ray exposure (CRE) ages, and 10Be and 26Al activities. Bulk concentrations of 5.2% Ni and 2.0% P were calculated. The preatmospheric mass is estimated to have been at least 11,000 kg. The average CRE age for the different Twannberg samples is 230 ± 50 Ma. Detrital terrestrial mineral grains in the oxide rinds of the three larger masses indicate that they oxidized while they were incorporated in a glacial till deposited by the Rhône glacier during the last glaciation (Würm). The find location of mass I is located at the limit of glaciation where the meteorite may have deposited after transport by the glacier over considerable distance. All evidence indicates pairing of the six masses, which may be part of a larger shower as is indicated by the large inferred pre‐atmospheric mass.  相似文献   

13.
The Amazonian period of Mars has been described as static, cold, and dry. Recent analysis of high-resolution imagery of equatorial and mid-latitude regions has revealed an array of young landforms produced in association with ice and liquid water; because near-surface ice in these regions is currently unstable, these ice-and-water-related landforms suggest one or more episodes of martian climate change during the Amazonian. Here we report on the origin and evolution of valley systems within a degraded crater in Noachis Terra, Asimov Crater. The valleys have produced a unique environment in which to study the geomorphic signals of Amazonian climate change. New high-resolution images reveal Hesperian-aged layered basalt with distinctive columnar jointing capping interior crater fill and providing debris, via mass wasting, for the surrounding annular valleys. The occurrence of steep slopes (>20°), relatively narrow (sheltered) valleys, and a source of debris have provided favorable conditions for the preservation of shallow-ice deposits. Detailed mapping reveals morphological evidence for viscous ice flow, in the form of several lobate debris tongues (LDT). Superimposed on LDT are a series of fresh-appearing gullies, with typical alcove, channel, and fan morphologies. The shift from ice-rich viscous-flow formation to gully erosion is best explained as a shift in martian climate, from one compatible with excess snowfall and flow of ice-rich deposits, to one consistent with minor snow and gully formation. Available dating suggests that the climate transition occurred >8 Ma, prior to the formation of other small-scale ice-rich flow features identified elsewhere on Mars that have been interpreted to have formed during the most recent phases of high obliquity. Taken together, these older deposits suggest that multiple climatic shifts have occurred over the last tens of millions of years of martian history.  相似文献   

14.
Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.  相似文献   

15.
Bunburra Rockhole is a unique basaltic achondrite that has many mineralogical and petrographic characteristics in common with the noncumulate eucrites, but differs in its oxygen isotope composition. Here, we report a study of the mineralogy, petrology, geochemistry, and chronology of Bunburra Rockhole to better understand the petrogenesis of this meteorite and compare it to the eucrites. The geochemistry of bulk samples and of pyroxene, plagioclase, and Ca‐phosphate in Bunburra Rockhole is similar to that of typical noncumulate eucrites. Chronological data for Bunburra Rockhole indicate early formation, followed by slow cooling and perhaps multiple subsequent heating events, which is also similar to some noncumulate eucrites. The 26Al‐26Mg extinct radionuclide chronometer was reset in Bunburra Rockhole after the complete decay of 26Al, but a slight excess in the radiogenic 26Mg in a bulk sample allows the determination of a model 26Al‐26Mg age that suggests formation of the parent melt for this meteorite from its source magma within the first ~3 Ma of the beginning of the solar system. The 207Pb‐206Pb absolute chronometer is also disturbed in Bunburra Rockhole minerals, but a whole‐rock isochron provides a re‐equilibration age of ~4.1 Ga, most likely caused by impact heating. The mineralogy, geochemistry, and chronology of Bunburra Rockhole demonstrate the similarities of this achondrite to the eucrites, and suggest that it formed from a parent melt with a composition similar to that for noncumulate eucrites and subsequently experienced a thermal history and evolution comparable to that of eucritic basalts. This implies the formation of multiple differentiated parent bodies in the early solar system that had nearly identical bulk elemental compositions and petrogenetic histories, but different oxygen isotope compositions inherited from the solar nebula.  相似文献   

16.
The Pliocene epoch represents an important transition from a climate regime with high-frequency, low-amplitude oscillations when the Northern Hemisphere lacked substantial ice sheets, to the typical high-frequency, high-amplitude Middle to Late Pleistocene regime characterized by glacial—interglacial cycles that involve waxing and waning of major Northern Hemisphere ice sheets. Analysis of middle Pliocene (3 Ma) marine and terrestrial records throughout the Northern Hemisphere forms the basis of an integrated synoptic Pliocene paleoclimate reconstruction of the last significantly warmer than present interval in Earth history. This reconstruction, developed primarily from paleontological data, includes middle Pliocene sea level, vegetation, land—ice distribution, sea—ice distribution, and sea-surface temperature (SST), all of which contribute to our conceptual understanding of this climate system. These data indicate middle Pliocene sea level was at least 25 m higher than present, presumably due in large part to a reduction in the size of the East Antarctic Ice Sheet. Sea surface temperatures were essentially equivalent to modern temperatures in tropical regions but were significantly warmer at higher latitudes. Due to increased heat flux to high latitudes, both the Arctic and Antarctic appear to have been seasonally ice free during the middle Pliocene with greatly reduced sea ice extent relative to today during winter. Vegetation changes, while more complex, are generally consistent with marine SST changes and show increased warmth and moisture at higher latitudes during the middle Pliocene.  相似文献   

17.
Northwest Africa (NWA) 11042 is a heavily shocked achondrite with medium‐grained cumulate textures. Its olivine and pyroxene compositions, oxygen isotopic composition, and chromium isotopic composition are consistent with L chondrites. Sm‐Nd dating of its primary phases shows a crystallization age of 4100 ± 160 Ma. Ar‐Ar dating of its shocked mineral maskelynite reveals an age of 484.0 ± 1.5 Ma. This age coincides roughly with the breakup event of the L chondrite parent body evident in the shock ages of many L chondrites and the terrestrial record of fossil L chondritic chromite. NWA 11042 shows large depletions in siderophile elements (<0.01×CI) suggestive of a complex igneous history involving extraction of a Fe‐Ni‐S liquid on the L chondrite parent body. Due to its relatively young crystallization age, the heat source for such an igneous process is most likely impact. Because its mineralogy, petrology, and O isotopes are similar to the ungrouped achondrite NWA 4284 (this work), the two meteorites are likely paired and derived from the same parent body.  相似文献   

18.
New high-resolution spectral and morphologic imaging of deposits on walls and floor of Ius Chasma extend previous geomorphic mapping, and permit a new interpretation of aqueous processes that occurred during the development of Valles Marineris. We identify hydrated mineralogy based on visible-near infrared (VNIR) absorptions. We map the extents of these units with CRISM spectral data as well as morphologies in CTX and HiRISE imagery. Three cross-sections across Ius Chasma illustrate the interpreted mineral stratigraphy. Multiple episodes formed and transported hydrated minerals within Ius Chasma. Polyhydrated sulfate and kieserite are found within a closed basin at the lowest elevations in the chasma. They may have been precipitates in a closed basin or diagenetically altered after deposition. Fluvial or aeolian processes then deposited layered Fe/Mg smectite and hydrated silicate on the chasma floor, postdating the sulfates. The smectite apparently was weathered out of Noachian-age wallrock and transported to the depositional sites. The overlying hydrated silicate is interpreted to be an acid-leached phyllosilicate transformed from the underlying smectite unit, or a smectite/jarosite mixture. The finely layered smectite and massive hydrated silicate units have an erosional unconformity between them, that marks a change in surface water chemistry. Landslides transported large blocks of wallrock, some altered to contain Fe/Mg smectite, to the chasma floor. After the last episode of normal faulting and subsequent landslides, opal was transported short distances into the chasma from a few m-thick light-toned layer near the top of the wallrock, by sapping channels in Louros Valles. Alternatively, the material was transported into the chasma and then altered to opal. The superposition of different types of hydrated minerals and the different fluvial morphologies of the units containing them indicate sequential, distinct aqueous environments, characterized by alkaline, then circum-neutral, and finally very acidic surface or groundwater chemistry.  相似文献   

19.
Abstract— We have used a variety of complementary microanalytical techniques to constrain the mineralogy, trace‐element distributions, and oxygen‐isotopic compositions in a 50 × 50 μm area of Acfer 094 matrix. The results reveal the exceptional mineralogical and compositional heterogeneity of this material at the sub‐μm level. We observe μm‐scale and sub‐μm grains with elemental associations suggesting feldspar, metal with widely varying Ni contents, and a Cr‐Fe alloy (in addition to forsterite, pyroxene, sulfide, ferrihydrite, and amorphous groundmass previously described). A new class of μm‐scale CAI (μCAI) is also observed, which show sub‐μm compositional zoning, and a range of oxygen isotopic compositions. Unlike the larger CAIs in Acfer 094, which are uniformly 16O‐enriched, two of the three μCAIs we analyzed are isotopically normal. We also observed a Li‐rich hotspot that detailed analysis by ToF‐SIMS suggests may be a LiCr‐oxide grain. Within the resolution of the NanoSIMS, this grain has isotopically normal Li. Finally, in our 50 × 50 μm area, we positively identified a presolar grain that is the most 18O‐rich silicate found so far in meteorites. The grain may originate from an asymptotic giant branch (AGB) star, or more likely, a supernova. In line with previous TEM studies (Greshake 1997), we find no evidence for clastic material (e.g., fragmental chondrules) in the matrix of Acfer 094: although the matrix is volatile‐depleted, this depletion does not appear to result from dilution of a primordial starting material with (depleted) chondrule fragments. Assuming that matrix experienced the depletion event, our data on the detailed mineralogy of Acfer 094 are currently equivocal in constraining the nature of that event. We observe carrier phases for several elements consistent with conditions approaching equilibrium condensation; however, the presence of an amorphous groundmass is suggestive of more rapid cooling.  相似文献   

20.
In this account we present estimates of nannofossil fluxes in four sections and one borehole all belonging to the Early Jurassic western Tethys. This study aims to map the distribution of pelagic carbonate production across the Early Toarcian anoxic event (T-OAE), and to understand which environmental parameters did control such production. Our results indicate important changes in carbonate production by nannoplankton occurring within the western Tethys and its variations through time. Nannofossil fluxes (specimens per m2 per year) are extremely low during the T-OAE in all the studied settings. Higher fluxes are encountered in the westernmost part of the Tethys Ocean before the T-OAE, whilst pelagic carbonate production shifted towards the northern margin of the Tethys after the recovery from anoxic conditions. The dramatic decrease in nannoplankton production during the T-OAE has been interpreted in previous works as a biocalcification crisis related to high pCO2 in the atmosphere/hydrosphere system. Although a high pCO2 may have lowered the carbonate saturation state of Early Jurassic oceans and finally hampered biocalcification, we speculate that the most important effects of CO2 increase were indirect, and affected pelagic producers via changes on climate and sea-level. Namely, it seems that precipitation/evaporation budgets and continental runoff that controlled nutrient levels and salinity in surface oceanic waters were important factors for pelagic biocalcifiers.  相似文献   

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