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1.
《Applied Geochemistry》2004,19(8):1217-1232
Laboratory experiments were conducted with volcanic ash soils from Mammoth Mountain, California to examine the dependence of soil dissolution rates on pH and CO2 (in batch experiments) and on oxalate (in flow-through experiments). In all experiments, an initial period of rapid dissolution was observed followed by steady-state dissolution. A decrease in the specific surface area of the soil samples, ranging from 50% to 80%, was observed; this decrease occurred during the period of rapid, initial dissolution. Steady-state dissolution rates, normalized to specific surface areas determined at the conclusion of the batch experiments, ranged from 0.03 μmol Si m−2 h−1 at pH 2.78 in the batch experiments to 0.009 μmol Si m−2 h−1 at pH 4 in the flow-through experiments. Over the pH range of 2.78–4.0, the dissolution rates exhibited a fractional order dependence on pH of 0.47 for rates determined from H+ consumption data and 0.27 for rates determined from Si release data. Experiments at ambient and 1 atm CO2 demonstrated that dissolution rates were independent of CO2 within experimental error at both pH 2.78 and 4.0. Dissolution at pH 4.0 was enhanced by addition of 1 mM oxalate. These observations provide insight into how the rates of soil weathering may be changing in areas on the flanks of Mammoth Mountain where concentrations of soil CO2 have been elevated over the last decade. This release of magmatic CO2 has depressed the soil pH and killed all vegetation (thus possibly changing the organic acid composition). These indirect effects of CO2 may be enhancing the weathering of these volcanic ash soils but a strong direct effect of CO2 can be excluded. 相似文献
2.
Chemical weathering is an integral part of the earth surface processes, whose spatial patterns and controlling factors on continental scale are still not fully understood. Highlands of the Asian continent have been shown having some of the highest observed rates of chemical weathering yet reported. However, the paucity of river gauge data in many of these terrains has limited determination of chemical weathering budget in a continental scale. A dataset of three large watersheds throughout northern Xinjiang in Central Asia is used to empirically identify chemical weathering regimes and interpret the underlying controlling factors. Detailed analysis of major ion ratios and a forward model of mass budget procedure are presented to distinguish the relative significances and contributions of silicate, carbonate weathering and evaporite dissolution. The analytical results show that carbonic acid is the most important weathering agent to the studied watersheds. Silicate weathering contributes, on average, ∼17.8% (molar basis) of total cations on a basin wide scale with an order of Zhungarer > Erlqis > Yili, indicating that silicate weathering, however, does not seem to be intense in the study basins. Evaporite dissolution, carbonate weathering and precipitation input contribute 43.6%, 29.7% and 8.9% of the total dissolved cations on average for the whole catchment, respectively. The three main morphological and hydrological units are reflected in water chemistry. Rivers from the montane areas (recharge area) of the three watersheds are very dilute, dominated by carbonate and silicate weathering, whereas the rivers of piedmont areas as well as the rivers of the sedimentary platform (runoff area) are dominated by carbonate weathering, and rivers of desert plain in the central Zhungarer basin (discharge area) are dominated by evaporite dissolution and are SO4 rich. This spatial pattern indicates that, beside lithology, runoff conditions have significant role on the regional chemical weathering regimes. Chemical weathering processes in the areas appear to be significantly climate controlled, displaying a tight correlation with runoff and aridity. Carbonate weathering are mostly influenced by runoff, which is higher in the mountainous part of the studied basins. The identification of chemical weathering regimes from our study confirmed the weathering potential and complexity of temperate watersheds in arid environment and that additional studies of these terrains are warranted. However, because the dominant weathering reactions in the sedimentary platform of northern Xinjiang are of carbonates and evaporites rather than silicate minerals, and the climatic factors have important role on the rock weathering regimes, we think that weathering at the arid temperate drainage system (Central Asia) is maybe not an important long-term sink for atmospheric CO2, if the future climate has no great change. 相似文献
3.
《Quaternary Science Reviews》1999,18(4-5):671-695
Percentage, concentration and accumulation pollen data together with diatom and non-siliceous microfossil data are presented for the site of Gölhisar Gölü (37°8′N, 29°36′E; elevation 930 m), a small intramontane lake in Burdur Province, southwest Turkey. Microfossil assemblages from the longest sediment core (GHA: 813 cm) record changes in local and regional vegetation and lake productivity over the last ∼9500 years. Pollen spectra indicate that vegetation progressed from an open landscape with an increase in arboreal pollen occurring ∼8500 bp to mixed forest comprising oak, pine and juniper until around 3000 bp (Cal ∼1240 BC) when a human occupation phase becomes discernible from the pollen spectra. This occurs shortly after the deposition of a volcanic tephra layer which originated from the Minoan eruption of Santorini (Thera) and radiocarbon dated to 3330±70 yr bp (Cal ∼1600 BC). This human occupation phase is comparable to the Beyşehir Occupation phase recorded at other sites in southwest Turkey and involved forest clearance and the cultivation of fruit trees such as Olea, Juglans, Castanea and Vitis together with arable cereal growing and pastoralism. The presence of pollen types associated with the Beyşehir Occupation phase in deposits above the Santorini tephra layer confirms a Late Bronze Age/early Anatolian Dark Age date for its commencement. Since ∼3000 bp notable changes in aquatic ecology associated with tephra deposition and subsequent nutrient and sediment flux from the lake catchment are recorded. The Beyşehir Occupation phase at Gölhisar Gölü came to an end around 1300 bp (Cla AD ∼700) when pine appears to have become the dominant forest tree. 相似文献
4.
A distinctive white sediment in the caves of Mulu, Sarawak, Borneo is a well-preserved tephra, representing a fluvially transported surface air-fall deposit, re-deposited inside the caves. We show that the tephra is not the Younger Toba Tephra, formerly considered as most likely. The shards are rod-shaped with elongate tubular vesicles; the largest grains ~ 170 μm in length; of rhyolitic composition; and 87Sr/86Sr ratio of 0.70426 ± 0.00001. U–Th dating of associated calcites suggest that the tephra was deposited before 125 ± 4 ka, and probably before 156 ± 2 ka. Grain size and distance from closest potential source suggests an eruption of VEI 7. Prevailing winds, grain size, thickness of deposit, location of potential sources, and Sr isotopic ratio limit the source to the Philippines. Comparisons with the literature give the best match geochemically with layer 1822 from Ku et al. (2009a), dated by ocean core stratigraphy to 189 ka. This tephra represents a rare terrestrial repository indicating a very substantial Plinian/Ultra-Plinian eruption that covered the Mulu region of Borneo with ash, a region that rarely receives tephra from even the largest known eruptions in the vicinity. It likely will be a valuable chronostratigraphic marker for sedimentary, palaeontological and archaeological studies. 相似文献
5.
Long wavelength gravity anomalies over India were obtained from terrestrial gravity data through two independent methods: (i) wavelength filtering and (ii) removing crustal effects. The gravity fields due to the lithospheric mantle obtained from two methods were quite comparable. The long wavelength gravity anomalies were interpreted in terms of variations in the depth of the lithosphere–asthenosphere boundary (LAB) and the Moho with appropriate densities, that are constrained from seismic results at certain points. Modeling of the long wavelength gravity anomaly along a N–S profile (77°E) suggest that the thickness of the lithosphere for a density contrast of 0.05 g/cm3 with the asthenosphere is maximum of ∼190 km along the Himalayan front that reduces to ∼155 km under the southern part of the Ganga and the Vindhyan basins increasing to ∼175 km south of the Satpura Mobile belt, reducing to ∼155–140 km under the Eastern Dharwar craton (EDC) and from there consistently decreasing south wards to ∼120 km under the southernmost part of India, known as Southern Granulite Terrain (SGT).The crustal model clearly shows three distinct terrains of different bulk densities, and thicknesses, north of the SMB under the Ganga and the Vindhyan basins, and south of it the Eastern Dharwar Craton (EDC) and the Southern Granulite Terrain (SGT) of bulk densities 2.87, 2.90 and 2.96 g/cm3, respectively. It is confirmed from the exposed rock types as the SGT is composed of high bulk density lower crustal rocks and mafic/ultramafic intrusives while the EDC represent typical granite/gneisses rocks and the basement under the Vindhyan and Ganga basins towards the north are composed of Bundelkhand granite massif of the lower density. The crustal thickness along this profile varies from ∼37–38 km under the EDC, increasing to ∼40–45 km under the SGT and ∼40–42 km under the northern part of the Ganga basin with a bulge up to ∼36 km under its southern part. Reduced lithospheric and crustal thicknesses under the Vindhyan and the Ganga basins are attributed to the lithospheric flexure of the Indian plate due to Himalaya. Crustal bulge due to lithospheric flexure is well reflected in isostatic Moho based on flexural model of average effective elastic thickness of ∼40 km. Lithospheric flexure causes high heat flow that is aided by large crustal scale fault system of mobile belts and their extensions northwards in this section, which may be responsible for lower crustal bulk density in the northern part. A low density and high thermal regime in north India north of the SMB compared to south India, however does not conform to the high S-wave velocity in the northern part and thus it is attributed to changes in composition between the northern and the southern parts indicating a reworked lithosphere. Some of the long wavelength gravity anomalies along the east and the west coasts of India are attributed to the intrusives that caused the breakup of India from Antarctica, and Africa, Madagascar and Seychelles along the east and the west coasts of India, respectively. 相似文献
6.
Unlike pahoehoe, documentation of true a′a lavas from a modern volcanological perspective is a relatively recent phenomenon in the Deccan Trap (e.g. Brown et al., 2011, Bull. Volcanol. 73(6): 737–752) as most lava flows previously considered to be a′a (e.g. GSI, 1998) have been shown to be transitional (e.g. Rajarao et al., 1978, Geol. Soc. India Mem. 43: 401–414; Duraiswami et al., 2008 J. Volcanol. Geothermal. Res. 177: 822–836). In this paper we demonstrate the co-existence of autobrecciation products such as slabby pahoehoe, rubbly pahoehoe and a′a in scattered outcrops within the dominantly pahoehoe flow fields. Although volumetrically low in number, the pattern of occurrence of the brecciating lobes alongside intact ones suggests that these might have formed in individual lobes along marginal branches and terminal parts of compound flow fields. Complete transitions from typical pahoehoe to ‘a′a lava flow morphologies are seen on length scales of 100–1000 m within road and sea-cliff sections near Uruli and Rajpuri. We consider the complex interplay between local increase in the lava supply rates due to storage or temporary stoppage, local increase in paleo-slope, rapid cooling and localized increase in the strain rates especially in the middle and terminal parts of the compound flow field responsible for the transitional morphologies. Such transitions are seen in the Thakurwadi-, Bushe- and Poladpur Formation in the western Deccan Traps. These are similar to pahoehoe–a′a transitions seen in Cenozoic long lava flows (Undara ∼160 km, Toomba ∼120 km, Kinrara ∼55 km) from north Queensland, Australia and Recent (1859) eruption of Mauna Loa, Hawaii (a′a lava flow ∼51 km) suggesting that flow fields with transitional tendencies cannot travel great lengths despite strong channelisation. If these observations are true, then it arguably limits long distance flow of Deccan Traps lavas to Rajahmundry suggesting polycentric eruptions at ∼65 Ma in Peninsular India. 相似文献
7.
The biologically mediated weathering of the ocean crust has received increasing attention in recent decades, but the rates and the possible mechanism of elemental release during microbe–basalt interactions occurring below the seafloor have not been studied in detail. In this study, we established an experimental weathering study of seafloor natural basaltic glass comparing the effect of microbial activity (Pseudomonas fluorescens) in P-rich and P-poor media with parallel controls containing either nonviable cells or organic acid. The changes in the chemical parameters, including pH, bacterial densities, and ion concentrations (Ca, Mg, Si, Mn, Al, Fe, and P) in the solution, were examined during the different batch experiments. The results showed that the pH decreased from 7.0 to 3.5 and the bacterial density increased from 105 to 108 cells/ml during the first 120 h, and the cell numbers remained constant at 108 cells/ml and the pH increased from 3.5 to 6 between 120 h and 864 h in the P-bearing reactors containing bacteria. In contrast, during all the experimental time, the pH remained close to neutral condition in the abiotic control systems and the dissolution rates increased markedly with a decrease in pH and became minimal at near-neutral pH in P-bearing reactors containing bacteria, where Ca, Si, and Mg release rates were 2- to 4-fold higher than those obtained in chemical systems and biotic P-limited systems. Furthermore, the surfaces of the natural volcanic glass from the biotic systems were colonized by bacteria. Simultaneously, the etch pits were observed by Scanning Electron Microscope, which further indicate that the bacteria may promote the mineral dissolution for energy gain. Some elements (e.g., Fe, Mn, and Al) releasing from natural volcanic glass are likely an important source of the elemental budget in the ocean, and thus the element release and its possible mechanism conducted in this experimental study have potential implications on the biogeochemical cycling process in the Mid-Oceanic Ridge setting. 相似文献
8.
Chemical weathering of Mg, Ca-silicates and alumino-silicates contributes significantly to the drawdown of atmospheric CO2 over long time scales. The present work focuses on how this mode of weathering may change in the presence of free-living bacteria in oligotrophic waters, which compose most of the surface freshwaters of the Earth. Forsterite (Fo90) was reacted for 1 week with a stable Escherichia coli population in water maintained at 37 °C and neutral pH in a batch reactor. Control samples with suspensions of pure olivine powders and E. coli cells in pure water were also used for reference. Olivine controls reproduce the Mg, Si and Fe release in solutions predicted from rates published in the literature with pH shifts of less than 0.5 unit. After 1 week, under abiotic conditions, weathered surfaces are enriched in Fe and Fe3+ relative to the initial composition of the mineral. Bacterial controls (without minerals) show decreasing Eh with increasing cell concentrations (−50 mV with 7 × 107 cells/mL and −160 mV with 8 × 108 cells/mL). Magnesium concentrations in bacterial control solutions are in the μg/L range and can be accounted for by the release of Mg from dead cells. More than 80% of the cells were still alive after 1 week. The solutions obtained in the experiments in which olivine reacts in the presence of cells show Mg and Si concentrations a few tens of percent lower than in the mineral control samples, with a prominent depletion of Fe(III) content of the mineral surfaces. Magnesium mass balance discounts both significant bacterial uptake and inhibition of the Mg dissolution rates as a consequence of changing pH and Eh. Coating by bacterial cell layers is also negligible. E. coli reduces the chemical weathering of olivine. This study infers that the presence of free-living Proteobacteria, a prevalent group of subsurface bacteria, should decrease the amount of riverine Mg released by chemical weathering of mafic rocks. 相似文献
9.
The leaching behaviour of fly ash from a Co smelter situated in the Zambian Copperbelt was studied as a function of pH (5–12) using the pH-static leaching test (CEN/TS 14997). Various experimental time intervals (48 h and 168 h) were evaluated. The leaching results were combined with the ORCHESTRA modelling framework and a detailed mineralogical investigation was performed on the original FA and leached solid residues. The largest amounts of Co, Cu, Pb and Zn were leached at pH 5, generally with the lowest concentrations between pH 9 and 11 and slightly increased concentrations at pH 12. For most elements, the released concentrations were very similar after 48 h and 168 h, indicating near-equilibrium conditions in the system. Calcite, clinopyroxenes, quartz and amorphous phases predominated in the fly ash. Various metallic sulfides, alloys and the presence of Cu, Co and Zn in silicates and glass were detected using SEM/EDS and/or TEM/EDS. The leaching of metals was mainly attributed to the dissolution of metallic particles. Partial dissolution of silicate and glass fractions was assumed to significantly influence the release of Ca, Mg, Fe, K, Al and Si as well as Cu, Co and Zn. The formation of illite was suggested by the ORCHESTRA modelling to be one of the main solubility-controlling phases for major elements, whereas Co and Zn were controlled by CoO and zincite, respectively. Sorption of metals on hydrous ferric oxides was assumed to be an important attenuation mechanism, especially for the release of Pb and Cu. However, there is a high risk of Co, Cu, Pb and Zn mobility in the acidic soils around the smelter facility. Therefore, potential local options for “stabilisation” of the fly ash were evaluated on the basis of the modelling results using the PHREEQC code. 相似文献
10.
Rapid weathering and erosion rates in mountainous tropical watersheds lead to highly variable soil and saprolite thicknesses which in turn impact nutrient fluxes and biological populations. In the Luquillo Mountains of Puerto Rico, a 5-m thick saprolite contains high microorganism densities at the surface and at depth overlying bedrock. We test the hypotheses that the organisms at depth are limited by the availability of two nutrients, P and Fe. Many tropical soils are P-limited, rather than N-limited, and dissolution of apatite is the dominant source of P. We document patterns of apatite weathering and of bioavailable Fe derived from the weathering of primary minerals hornblende and biotite in cores augered to 7.5 m on a ridgetop as compared to spheroidally weathering bedrock sampled in a nearby roadcut.Iron isotopic compositions of 0.5 N HCl extracts of soil and saprolite range from about δ56Fe = 0 to ? 0.1‰ throughout the saprolite except at the surface and at 5 m depth where δ56Fe = ? 0.26 to ? 0.64‰. The enrichment of light isotopes in HCl-extractable Fe in the soil and at the saprolite–bedrock interface is consistent with active Fe cycling and consistent with the locations of high cell densities and Fe(II)-oxidizing bacteria, identified previously. To evaluate the potential P-limitation of Fe-cycling bacteria in the profile, solid-state concentrations of P were measured as a function of depth in the soil, saprolite, and weathering bedrock. Weathering apatite crystals were examined in thin sections and an apatite dissolution rate of 6.8 × 10? 14 mol m? 2 s? 1 was calculated. While surface communities depend on recycled nutrients and atmospheric inputs, deep communities survive primarily on nutrients released by the weathering bedrock and thus are tightly coupled to processes related to saprolite formation including mineral weathering. While low available P may limit microbial activity within the middle saprolite, fluxes of P from apatite weathering should be sufficient to support robust growth of microorganisms in the deep saprolite. 相似文献
11.
Far-from equilibrium, steady state forsterite dissolution rates were measured at pH ∼3 and 25 °C in aqueous solutions containing 0.1 m/kg NaCl and up to 0.1 mol/kg of 13 distinct dissolved organic ligands in mixed-flow reactors. The organic ligands considered in this study include those common in Earth surface environments and those considered as potential catalysts for use in CO2 sequestration efforts: acetate, oxalate, citrate, EDTA4−, glutamate, gluconate, malonate, aspartate, tartrate, malate, alginate, salycilate and humate. The presence of up to 0.1 mol/kg of each organic ligand altered forsterite dissolution rates less than 0.2 log units, which is the estimated uncertainty of the measured rates. Results obtained in this study, therefore, suggest that the presence of aqueous organic anions negligibly affects forsterite far-from equilibrium dissolution rates in most natural environments, and indicate that forsterite carbonation may not be appreciably accelerated by organic ligand catalysis. 相似文献
12.
The Reed Bank Basin in the southern margin of the South China Sea is considered to be a Cenozoic rifted basin. Tectono-thermal history is widely thought to be important to understand tectonics as well as oil and gas potential of basin. In order to investigate the Cenozoic tectono-thermal history of the Reed Bank Basin, we carried out thermal modeling on one drill well and 22 pseudo-wells using the multi-stage finite stretching model. Two stages of rifting during the time periods of ∼65.5–40.4 Ma and ∼40.4–28.4 Ma can be recognized from the tectonic subsidence rates, and there are two phases of heating corresponding to the rifting. The reconstructed average basal paleo-heat flow values at the end of the rifting events are ∼60 and ∼66.3 mW/m2, respectively. Following the heating periods, this basin has undergone a persistent thermal attenuation phase since ∼28.4 Ma and the basal heat flow cooled down to ∼57.8–63.5 mW/m2 at present. In combination with the radiogenic heat production of the sedimentary sequences, the surface heat flow of the Reed Bank Basin ranges from ∼60.4 to ∼69.9 mW/m2. 相似文献
13.
A detailed investigation of the fluvial geochemistry of the Han River system allows to estimate the rates of chemical weathering and the consumption of CO2. The Han River drains approximately 26,000 km2 and is the largest river system in South Korea in terms of both water discharge and total river length. It consists of two major tributaries: the North Han River (NHR) and the South Han River (SHR). Distinct differences in basin lithology (silicate vs. carbonate) between the NHR and SHR provide a good natural laboratory in which to examine weathering processes and the influence of basin geology on water quality. The concentrations of major elements and the Sr isotopic compositions were obtained from 58 samples collected in both summer and winter along the Han River system in both 2000 and 2006. The concentrations of dissolved loads differed considerably between the NHR and SHR; compared with the SHR, the NHR had much lower total dissolved solids (TDS), Sr, and major ion concentrations but a higher Si concentration and 87Sr/86Sr ratio. A forward model showed that the dissolved loads in the NHR came primarily from silicate weathering (55 ± 11%), with a relatively small portion from carbonates (30 ± 14%), whereas the main contribution to the dissolved loads in the SHR was carbonate weathering (82 ± 3%), with only 11 ± 4% from silicates. These results are consistent with the different lithologies of the two drainage basins: silicate rocks in the NHR versus carbonate rocks in the SHR. Sulfuric acid derived from sulfide dissolution in coal-containing sedimentary strata has played an important role in carbonate weathering in the SHR basin, unlike in the NHR basin. The silicate weathering rate (SWR) was similar between the NHR and SHR basins, but the rate of CO2 consumption in the SHR basin was lower than in the NHR basin due to an important role of sulfuric acid derived from pyrite oxidation. 相似文献
14.
A.C. Rocha-Campos M.A. Basei A.P. Nutman Laura E. Kleiman R. Varela E. Llambias F.M. Canile O. de C.R. da Rosa 《Gondwana Research》2011,19(2):509-523
We present four SHRIMP U–Pb zircon ages for the Choiyoi igneous province from the San Rafael Block, central–western Argentina. Dated samples come from the Yacimiento Los Reyunos Formation (281.4 ± 2.5 Ma) of the Cochicó Group (Lower Choiyoi section: andesitic breccias, dacitic to rhyolitic ignimbrites and continental conglomerates), Agua de los Burros Formation (264.8 ± 2.3 Ma and 264.5 ± 3.0 Ma) and Cerro Carrizalito Formation (251.9 ± 2.7 Ma Upper Choiyoi section: rhyolitic ignimbrites and pyroclastic flows) spanning the entire Permian succession of the Choiyoi igneous province. A single zircon from the El Imperial Formation, that is overlain unconformably by the Choiyoi succession, yielded an early Permian age (297.2 ± 5.3 Ma), while the main detrital zircon population indicated an Ordovician age (453.7 ± 8.1 Ma). The new data establishes a more precise Permian age (Artinskian–Lopingian) for the section studied spanning 30 Ma of volcanic activity. Volcanological observations for the Choiyoi succession support the occurrence of explosive eruptions of plinian to ultraplinian magnitudes, capable of injecting enormous volumes of tephra in the troposphere–stratosphere. The new SHRIMP ages indicate contemporaneity between the Choyoi succession and the upper part of the Paraná Basin late Paleozoic section, from the Irati up to the Rio do Rasto formations, encompassing about 24 Ma. Geochemical data show a general congruence in compositional and tectonic settings between the volcanics and Paraná Basin Permian ash fall derived layers of bentonites. Thickness and granulometry of ash fall layers broadly fit into the depletion curve versus distance from the remote source vent of ultraplinian eruptions. Thus, we consider that the Choiyoi igneous province was the source of ash fall deposits in the upper Permian section of the Paraná Basin. Data presented here allow a more consistent correlation between tectono-volcanic Permian events along the paleo-Pacific margin of southwestern Gondwana and the geological evolution of neighboring Paleozoic foreland basins in South America and Africa. 相似文献
15.
《Quaternary Science Reviews》2003,22(2-4):225-244
The Thebes Section in unglaciated southwestern Illinois contains a well preserved ∼500 kyr loess–paleosol sequence with four loesses and three interglacial soils. Various magnetic, mineralogical, and elemental properties were analyzed and compared over the thickness of soil sola. These proxies for soil development intensity have the following trend: Yarmouth Geosol>Sangamon Geosol>modern soil. Quartz/plagioclase, Zr/Sr, and TiO2/Na2O ratios were most sensitive to weathering. Frequency dependent magnetic susceptibility and anhysteretic remanent magnetization, greatest in A horizons, also correspond well with soil development intensity. Neoformed mixed-layered kaolinite/expandables, suggestive of a warm/humid climate, were detected in the Sangamon and Yarmouth soil sola. Clay illuviation in soils was among the least sensitive indicators of soil development. Differences in properties among interglacial soils are interpreted to primarily reflect soil development duration, with climatic effects being secondary. Assuming logarithmic decreases in weathering rates, the observed weathering in the Sangamon Geosol is consistent with 50 kyr of interglacial weathering (Oxygen Isotope Stage 5) compared to 10 kyr for the modern soil (Oxygen Isotope Stage 1). We propose that the Yarmouth Geosol in the central Midwest formed over 180 kyr of interglacial weathering (including oxygen isotope stages 7, 9, and 11). 相似文献
16.
《Chemie der Erde / Geochemistry》2014,74(3):311-329
Brachinites are ultramafic, dunitic to wherlitic, unbrecciated and essentially unshocked rocks that are low in SiO2 (∼36–39 wt.%), high in MgO (∼27–30 wt.%) and notably high in FeO (∼26–37 wt.%), and low in Al2O3 (∼0.2–2.5 wt.%) and combined alkalis Na2O and K2O (∼0–0.7 wt.%). They consist mostly of olivine (∼71–96 vol.%; ∼Fo64–73), major clinopyroxene (minor to ∼15 vol.%; ∼En40–63Wo36–48), with variable small amounts of plagioclase (0 to ∼10 vol.%; ∼An15–33), and minor to trace amounts of orthopyroxene (none to ∼20 vol.%; En69–73Wo2–4), Fe-sulfides (trace to ∼7 vol.%), chromite (none to ∼5 vol.%), phosphates (none to ∼3 vol.%) and metallic Fe,Ni (trace to ∼2 vol.%). Minerals tend to be homogeneous, and textures are medium to coarse-grained (∼0.1–1.5 mm), with olivine commonly displaying triple junctions. Brachina has near-chondritic lithophile element abundances, whereas other brachinites show variable depletions in Al, Ca, Rb, K, Na, and LREE. Siderophile element abundance patterns vary and range from ∼0.01 to ∼0.9 CI. Oxygen isotope composition (Δ17O) ranges from ∼−0.09 to −0.39‰, with the mean = −0.23 ± 0.14‰. Brachinites are ancient rocks, as was recognized early by the detection, in some brachinites, of excess 129Xe from the decay of short-lived 129I (half-life 17 Ma) and of fission tracks from the decay of 244Pu (half-life 82 Ma) in phosphate, high-Ca clinopyroxene and olivine. The first precise crystallization age was determined for Brachina using 53Mn–53Cr systematics, relative to the Pb–Pb age of the angrite LEW 86010, and yielded an age of 4563.7 ± 0.9 Ma. Thus, Brachina is at most ∼4 Ma younger that the CAIs whose age is 4567.2 ± 0.6 Ma. There is no consensus on the origin of brachinites, but they most likely are primitive achondrites, i.e., ultra-mafic residues from various low degrees of partial melting. Partial melting experiments suggest that they possibly formed from a parent lithology chemically similar but not identical to the Rumuruti (R) chondrites, although the different oxygen isotopic compositions of the R chondrites and the brachinites put a serious constraint on this hypothesis. The apparent lack of abundant rocks representing the partial melts suggests that brachinites may have formed on a parent body <∼100 km in radius, where early partial melts were removed from the parent body by explosive pyroclastic volcanism. Graves Nunataks 06128 and 06129 are felsic, andesitic basalts which have properties that suggest a relationship to brachinites and thus, may be samples of the elusive partial melts. 相似文献
17.
Chemical weathering of silicate minerals consumes atmospheric CO2 and is a fundamental component of geochemical cycles and of the climate system on long timescales. Artificial acceleration of such weathering (“enhanced weathering”) has recently been proposed as a method of mitigating anthropogenic climate change, by adding fine-grained silicate materials to continental surfaces. The efficacy of such intervention in the carbon cycle strongly depends on the mineral dissolution rates that occur, but these rates remain uncertain. Dissolution rates determined from catchment scale investigations are generally several orders of magnitude slower than those predicted from kinetic information derived from laboratory studies. Here we present results from laboratory flow-through dissolution experiments which seek to bridge this observational discrepancy by using columns of soil returned to the laboratory from a field site. We constrain the dissolution rate of olivine added to the top of one of these columns, while maintaining much of the complexity inherent in the soil environment. Continual addition of water to the top of the soil columns, and analysis of elemental composition of waters exiting at the base was conducted for a period of five months, and the solid and leachable composition of the soils was also assessed before and after the experiments. Chemical results indicate clear release of Mg2+ from the dissolution of olivine and, by comparison with a control case, allow the rate of olivine dissolution to be estimated between 10−16.4 and 10−15.5 moles(Mg) cm−2 s−1. Measurements also allow secondary mineral formation in the soil to be assessed, and suggest that no significant secondary uptake of Mg2+ has occurred. The olivine dissolution rates are intermediate between those of pure laboratory and field studies and provide a useful constraint on weathering processes in natural environments, such as during soil profile deepening or the addition of mineral dust or volcanic ash to soils surfaces. The dissolution rates also provide critical information for the assessment of enhanced weathering including the expected surface-area and energy requirements. 相似文献
18.
A total of 24 tephra-bearing volcanic layers have been recognized between 550 and 987 m depth in the Siple Dome A (SDM-A) ice core, in addition to a number already recognized tephra in the upper 550 m (Dunbar et al., 2003, Kurbatov et al., 2006). The uniform composition and distinctive morphological of the particles composing these tephra layers suggest deposition as a result of explosive volcanic eruptions and that the layers therefore represent time-stratigraphic markers in the ice core. Despite the very fine grain size of these tephra (mostly less than 20 microns), robust geochemical compositions were determined by electron microprobe analysis. The source volcanoes for these tephra layers are largely found within the Antarctic plate. Statistical geochemical correlations tie nine of the tephra layers to known eruptions from Mt. Berlin, a West Antarctic volcano that has been very active for the past 100,000 years. Previous correlations were made to an eruption of Mt. Takahe, another West Antarctic volcano, and one to Mt. Hudson, located in South America (Kurbatov et al., 2006). The lowest tephra layer in the ice core, located at 986.21 m depth, is correlated to a source eruption with an age of 118.1 ± 1.3 ka, suggesting a chronological pinning point for the lower ice. An episode of anomalously high volcanic activity in the ice in the SDM-A core between 18 and 35 ka (Gow and Meese, 2007) appears to be related to eruptive activity of Mt. Berlin volcano. At least some of the tephra layers found in the SDM-A core appear to be the result of very explosive eruptions that spread ash across large parts of West Antarctica, off the West Antarctic coast, as well as also being recognized in East Antarctica (Basile et al., 2001, Narcisi et al., 2005, Narcisi et al., 2006). Some of these layers would be expected to should be found in other deep Antarctic ice cores, particularly ones drilled in West Antarctica, providing correlative markers between different cores. The analysis of the tephra layers in the Siple Dome core, along with other Antarctic cores, provides a timing framework for the relatively proximal Antarctic and South American volcanic eruptive events, allowing these to be distinguished from the tropical eruptions that may play a greater role in climate forcing. 相似文献
19.
Dissolution rates of sediments obtained from the Oued Cherf reservoir were measured in closed-system batch reactors at 25 °C in fluids sampled concurrently from the same locations as the sediments. The BET surface areas of the sediments ranged from 16 to 45 m2/g and consisted primarily of quartz, calcite, and clay minerals. After a brief initial period, release rates of Si, Mg, Ca, Cl, SO4, and NO3 from these sediments are approximately linear with time over the course of the experiments, which lasted from 3 to 5 months. BET surface area normalized Si release rates ranged from 10–17.4 to 10–18.4 mol/cm2/s. These release rates match closely Si release rates from quartz and clay minerals determined from laboratory dissolution rates reported in the literature. This coherence suggests that laboratory measured silicate dissolution rates can be used with confidence to predict the dissolution behavior of sediments in natural surface waters. 相似文献
20.
《Quaternary International》2006,142(1):44-57
In order to understand human response to Holocene ashfall events, tephra layers found in archaeological sites along the upper Limay River basin, Northern Patagonia, Argentina were bracketed with radiocarbon dates and correlated with tephra from a lacustrine sediment core and from outcrops and the archaeological evidence was analyzed.A dark tephra associated with seismic activity was identified in the El Trébol rockshelter filling interstices between fallen blocks together with remains of human activity and bones of extinct fauna, marking a seismo-volcanic event occurring between 11 758 and 12 866 cal yr BP. This same seismic event affected the Cuyín Manzano site, where the roof collapse made the site uninhabitable for a time. A white tephra, present in Epullán Grande, Epullán Chica and Traful I caves is correlated with Nahuel Huapi tephra (NHT), equivalent to Laya's Río Blanco and Río Pereyra members, (Río Pireco Formation). NHT is considered to have been derived from the same eruptive event, with dates ranging between ca. 1950–2500 cal yr BP. A dark tephra from Ortega's cave and several tephra from Puerto Tranquilo I rockshelter ranging between 521 and 2069 cal yr BP show how the mobile hunters–gatherers of Northern Patagonia were able to cope with the changing circumstances. 相似文献