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Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m‐2 d‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m‐2 d‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g‐1 d‐1) compared to alternating sites (<220 nmol g‐1 d‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

3.
The primary objective of this study was to compute a detailed budget for a small semiarid tropical drainage basin in Kenya. Results indicated that transfer of sediments (‘inputs’) from primary source areas was minor in comparison to changes in storage. The major sediment source area within the Katiorin drainage basin was the colluvial hillslope zone. The net change in storage within this zone was approximately 2100 Mg yr?1. Surface wash and rilling were the dominant transport processes responsible for the remobilization of colluvial sediments. Sediment storage within the in-channel reservoir increased by 60 Mg yr?1, which was minor when compared to the total store of sediment in this reservoir. During 1986, the channel network stored only a small fraction ( < 3 per cent) of the sediment delivered from the hillslope subsystem. Therefore, the in-channel reservoir had limited influence on sediment conveyance to the basin outlet. These data indicate that a static equilibrium condition cannot be assumed within the Katiorin drainage basin. Such an assumption would result in erosion estimates of approximately 5.5 mm yr?1 for the entire basin (based on a sediment output of 7430 Mg km?2 yr?1 and a measured bulk density of 1.35 Mg m?3). However, this masked the actual rates of 1.2 to 7.1 mm yr?1 in subbasin primary source areas, and rates of 0.6 to 17 mm yr?1 for colluvial material in the various subbasins. The extreme accelerated erosion rates resulted from minimal ground vegetation, steep slopes, soil crust formation, an erodible substrate, and a well-integrated drainage network for rapid conveyance of sediments from the hillslope subsystem to the basin outlet.  相似文献   

4.
The effects of temperature, diffusive boundary-layer thickness, and sediment composition on fluxes of inorganic N and P were estimated for sediment cores with oxidized surfaces from nearshore waters (2?C10?m) of a montane oligotrophic lake. Fluxes of N and P were not affected by diffusive boundary-layer thickness but were strongly affected by temperature. Below 16?°C, sediments sequestered small amounts of P and released small amounts of N. Above 16?°C, the seasonal maximum water temperature, sediments were substantial sources of N (NH4 +?CN?=?2?C24?mg?m?2 d?1; NO3 ??+?NO2 ??CN?=?2?C5?mg?m?2 d?1) and P (0.1?C0.4?mg?m?2 d?1), indicating potential responsiveness of sediment?Cwater nutrient exchange, and of corresponding phytoplankton growth, to synoptic warming.  相似文献   

5.
In twelve flowing water (Q 1.04… 30.4 m3/s, 0.5… 1.2 m/s) the self-purification efficiency in 110 river sections (L 1.3… 26.4 km) is determined as the load difference in kg · d?1 COD-Mn as well as in g · m?3 referred to the daily passage. In the economical comparison, the self-purification efficiency is valued as substitution for wastewater treatment plants of the same capacity. At a mean specific capacity of 8.6 g · m?3, the self-purification efficiency of the investigated waters is equivalent to economical values of 124 · 103… 534 · 103 M km?1 investment costs, 11 · 103… 80 · 103 M · a?1km?1 operating costs and 5… 81 MWh · a?1 km?1 expenditure of energy. The specific capacity in g · m?3 COD-Mn shows an exponential regression to the degree of saprobity (L = 0.015 · exp (1.7358 · S)). From this empirical model the limits of the self-purification capacity of aerobic waters by oxygen input can be detected: in respective examples more than 50% of the required oxygen input are due to weirs.  相似文献   

6.
Most sulphur diagenesis models predict that SO42- concentrations decrease exponentially with increasing sediment depth and are lower than that of the overlying water throughout the sediments. Low SO42- concentrations (less than 0.2 mM) are common in the sediments of Lake Anna that receive acid mine drainage; however, sediment with as much as 20 mM SO42- at about 20cm below the sediment surface is also seen in this section of the lake. A decision tree was proposed to investigate the cause of the high SO42- concentrations at depth (HSD) in the sediment. The first possibility proposed was that an increase in the quantity of groundwater flowing through Lake Anna sediments may increase groundwater advection of SO42- or oxygen which would induce sulphide oxidation. This hypothesis was tested by measuring groundwater flow. HSD profiles were found in a discrete region of the lake; however, stations having these profiles did not have higher groundwater flow than other sites sampled. Alternate explanations for the HSD profiles were that the region in which they occurred had: (1) unusual sediment chemical compositions; (2) a different source of regional groundwater, or (3) a lateral intrusion of high SO42- groundwater. There were no differences in sulphide and organic matter concentrations between the two regions. The area which has HSD in the sediment covers a large area in the middle of the lake, so it is unlikely that it has a unique source of regional groundwater. The third alternative was supported by the fact that in all three sample years, HSD stations were located in the preimpoundment stream channel, which is a likely lateral flow path for groundwater containing high SO42- concentrations.  相似文献   

7.
The significance of organic matter origin for carbon oxidation via sulfate and iron reduction in the sediments of three acid mine lakes is analyzed. Carbon reactivity was estimated by fitting first‐order expressions to measured rates. Carbon oxidation rates via sulfate and ferric iron reduction ranged from 3.4 to 4.7 mmol m–2 d–1 and resembled those reported for freshwater lakes. The estimated reaction constants increased from about 10–3 a–1 at the interface to the former mine grounds to 0.05 to 0.2 a–1 at the current sediment‐water interface. Aquatic organic matter accounted for an estimated 45...75% of total carbon oxidation rates while it amounted only to about 5...14% of the total organic matter that had been deposited. The results of this study suggest that in highly acidic mine lakes the reactivity of the deposited organic matter can rapidly increase after flooding, enhancing carbon oxidation and internal neutralization rates in the sediments.  相似文献   

8.
An Erratum has been published for this article in Earth Surface Processes and Landforms 29(13) 2004, 1707. In the semi‐arid Arroyo Chavez basin of New Mexico, a 2·28 km2 sub‐basin of the Rio Puerco, we contrasted short‐term rates (3 years) of sediment yield measured with sediment traps and dams with long‐term, geologic rates (~10 000 years) of sediment production measured using 10Be. Examination of erosion rates at different time‐scales provides the opportunity to contrast the human impact on erosion with background or geologic rates of sediment production. Arroyo Chavez is grazed and we were interested in whether differences in erosion rates observed at the two time‐scales are due to grazing. The geologic rate of sediment production, 0·27 kg m?2 a?1 is similar to the modern sediment yields measured for geomorphic surfaces including colluvial slopes, gently sloping hillslopes, and the mesa top which ranged from 0·12 to 1·03 kg m?2 a?1. The differences between modern sediment yield and geologic rates of sediment production were most noticeable for the alluvial valley ?oor, which had modern sediment yields as high as 3·35 kg m?2 a?1. The hydraulic state of the arroyo determines whether the alluvial valley ?oor is aggrading or degrading. Arroyo Chavez is incised and the alluvial valley ?oor is gullied and piped and is a source of sediment. The alluvial valley ?oor is also the portion of the basin most modi?ed by human disturbance including grazing and gas pipeline activity, both of which serve to increase erosion rates. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

9.
Measurements made on the floors of the temporarily-drained Glenfarg and Glenquey Reservoirs indicate that sediments with wet volumes of 63.94 × 103 m3 and 12.64 × 103 m3 were deposited in 56 and 73 years respectively. These figures represent 2.5 per cent and 1.1 per cent losses of original storage capacity. When corrected for water, organic, and diatom skeleton contents, and reservoir trap efficiency inorganic sediment yields of at least 31.3 tonnes km?2 yr?1 and of 9.0 tonnes km?2 yr?1 are suggested. The difference is probably related to contrasts of land use.  相似文献   

10.
Field observations suggest that burrowing activity is the primary mode of sediment transport currently active in a small grassland drainage basin in Marin County, California. Spatial concentrations of the 1150 gopher mounds surveyed vary from 0-16 mounds m?2 on interfluves to 0.32 mounds m?2 on sideslopes and in the topographic hollow, with localized concentrations of up to 2.88 mounds m?2 on the margins of the colluvial deposit. Simple models of sediment transport by burrowing activity yield estimates of between 0.91 and 2.33 cm3 cm?1 yr?1 for the basin as a whole, with absolute minimum and maximum rates of 0.48 and 631 cm3 cm?1 yr?1. These values are similar to those previously estimated for this area (Lehre, 1982) and are nearly an order-of-magnitude less than average long-term sediment transport rates at the same site (Reneau, 1988).  相似文献   

11.
Soil salinity and sodicity is considered one of the most import impediments to agricultural development in Northeast China. The contents of TP and TK decrease with soil depth and high coefficients of variation were found in TOC, AN, and AP. Mean EC in the 0–50 cm soil layers ranged from 0.61 to 0.89 dS m?1 and the average soluble ion concentrations in the topsoil (0–10 cm) were approximately 11.38 mmol L?1 for Na+, 1.21 mmol L?1 for Ca2+, and 0.40 mmol L?1 for Mg2+. High SAR existed in the layers 10–50 cm, indicating the studied soil was bearing low salinity in the top layer and high sodic layer in the subsurface. The soil presented strong alkali reactions all through the profile with pH over 9.5. To improve and utilize saline sodic soil rationally, several strategies were put forward based on long‐term field studies and demonstration works. The results implied that ameliorating with sand, applying farm yard manure, regenerating salt tolerant grasses and leaching with groundwater, and growing rice were effective measures for improving physical and chemical qualities of saline sodic soil.  相似文献   

12.
The Gru?a Reservoir (located at 238…269 m a. s. l., volume 64.6 · 106 m3, surface 934 ha, drainage area 318 km2, max. depth 31 m, mean theoretical retention time 22 months) was investigated during the years 1996 to 2001. The obtained values of trophic state parameters (9…200 μg L?1 total phosphorus, 3…99 μg L?1 chlorophyll‐a, and 0.5…2 m transparency) indicate that water of the Gru?a Reservoir is eutrophic according to three types of classification: Carlson, OECD, and Jones and Lee. It was noticed that values of average biomass abundance are large in the Gru?a Reservoir, and they could indicate a richer trophic state. When these indices are cited in connection with parameters of the trophic state, it is apparent that the Gru?a Reservoir can be classified as a eutrophic water on the basis of total phosphorus content of chlorophyll‐a and hypertrophic water with respect to transparency.  相似文献   

13.
Sediment yields were calculated on the ?anks of Merapi and Semeru volcanoes in Java, Indonesia, using two different methods. During the ?rst year following the 22 November 1994 eruption of Merapi, a sediment yield in excess of 1·5 × 105 m3 km?2 yr?1 was calculated in the Boyong River drainage basin, based on the volumes of sediment that were trapped by ?ve check dams. At Semeru, sediment discharges were assessed in the Curah Lengkong River from direct measurements on the lahars in motion and on the most signi?cant stream?ows. The calculated rate of sediment yield during one year of data in 2000 was 2·7 × 105 m3 km?2 yr?1. Sediment yields are dominated by rain‐triggered lahars, which occur every rainy season in several drainage basins of Merapi and Semeru volcanoes, mostly during the rainy season extending from October to April. The return period of lahars carrying sediment in excess of 5 × 105 m3 is about one year in the Curah Lengkong River at Semeru. At Merapi, the volume of sediments transported by a lahar did not exceed 2·8 × 105 m3 in the Boyong River during the rainy season 1994–95. On both volcanoes, the sediments are derived from similar sources: pyroclastic‐?ow/surges deposits, rockfalls from the lava domes, and old material from the riverbed and banks. However, daily explosions of vulcanian type at Semeru provide a more continuous sediment supply than at Merapi. Therefore, sediment yields are larger at Semeru. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

14.
As one component of ChinaFLUX, the measurement of CO2 flux using eddy covariance over subtropical planted coniferous ecosystem in Qianyanzhou was conducted for a long term. This paper discusses the seasonal dynamics of net ecosystem exchange (NEE), ecosystem respiration (RE) and gross ecosystem exchange (GEE) between the coniferous ecosystem and atmosphere along 2003 and 2004. The variations of NEE, RE and GEE show obvious seasonal variabilities and correlate to each other, i.e. lower in winter and drought season, but higher in summer; light, temperature and soil water content are the main factors determining NEE; air temperature and water vapor pressure deficit (VPD) influence NEE with stronger influence from VPD. Under the proper light condition, drought stress could decrease the temperature range for carbon capture in planted coniferous, air temperature and precipitation controlled RE; The NEE, RE, and GEE for planted coniferous in Qianyanzhou are ?387.2 g C·m?2 a?1, 1223.3 g C·m?2 a?1, ?1610.4 g C·m?2 a?1 in 2003 and ?423.8 g C·m?2 a?1, 1442.0 g C·m?2 a?1, ?1865.8 g C·m?2 a?1 in 2004, respectively, which suggest the intensive ability of plantation coniferous forest on carbon absorbing in Qianyanzhou.  相似文献   

15.
东巢湖沉积物水界面氮、磷、氧迁移特征及意义   总被引:2,自引:0,他引:2  
以东巢湖近城市湖湾沉积物为研究对象,在沉积物氮、磷营养盐分析的基础上,采用沉积物柱状芯样静态释放模拟法定量评估研究区域沉积物—水界面氨氮、溶解性活性磷酸盐营养盐释放潜力,利用微电极非损伤测定技术获得沉积物—水微界面溶解氧(DO)剖面分布及微界面DO消耗和扩散特征.结果表明:东巢湖近城市湖湾沉积物氮、磷污染物蓄积量较高,受TN、TP污染程度较重.沉积物内源氨氮、磷酸盐释放明显,平均释放速率分别达到32.44 mg/(m~2·d)和1.25mg/(m~2·d),区域内沉积物已成为水柱中氮、磷营养盐的污染源.研究区域上覆水体处于好氧状态,沉积物—水微界面平均DO穿透深度(OPD)达到5.3 mm,平均DO扩散通量为4.56 mmol/(m~2·d),表现出良好的DO扩散能力.沉积物内源氨氮和磷酸盐释放能力与表层沉积物TN/TP物质含量及沉积物—水微界面DO穿透深度有关,在沉积物氮、磷污染较重的情况下,DO穿透深度越低越有利于氮、磷污染物从沉积物向上覆水体释放.  相似文献   

16.
There is very thin soil layer in karst rocky desertification areas in Southwest China,sediment deposition and sediment yield in the karst area affects the development of vegetation greatly.In the present study,the 137Cs technique was used to assess the rate of sediment deposition and sediment yield in a small karst catchment.The 137Cs inventory within the depression varied between 800 m-2 and 2,200 Bq m-2,with the mean value of 1,500.1 Bq m-2.The 137Cs reference inventory at a nearby reference site was 805.9 Bq m-2.It could be inferred to that sediment deposition had occurred in the catchment.The mean depth of sediments deposition in the depression was 6 cm and the deposition rate was approximately 0.13 cm yr-1.The analysis of the topographic characteristics of the catchment revealed that the sediment deposition occurred mainly at the lower part of the small catchment.Although,there was a sinkhole in the depression,little sediment had drained out with runoff through the sinkhole,because the local people built ridges around the sinkholes for storing water.According to this,sediment yield rate in the small catchment was estimated to be approximately 19.25 to 27.5 t km-2 yr-1,and the extremely low sediment yield was maybe the main obstacle to vegetation restoration in karst rocky desertification areas.  相似文献   

17.
Inorganic fine sediments are easily carried into streams and rivers from disturbed land. These sediments can affect the stream biota, including detritivorous invertebrates (shredders) and impair ecosystem functions, such as leaf litter decomposition. We hypothesized that fine sediment (kaolin) deposited on leaves would reduce or suppress fungal development, reducing decomposition rates of leaves. Moreover, we predicted that shredders would act as ecosystem engineers by perturbing sediment deposition, reducing its impact on decomposition and fungi. We used a fully crossed experimental design of sediment addition (control, 400?mg?L?1) and shredders (none, Gammarus, Potamophylax) in laboratory aquaria. Leaf mass loss, suspended solids, microbial respiration, fungal biomass and spore production were measured. Sediment addition had no significant effects on the leaf mass remaining nor on shredders?? consumption rates. However, sediment slightly reduced fungal assemblage richness and the sporulation rate of three fungal species. The presence of shredders substantially increased the resuspension of fine sediments (>300%), resulting in higher suspended loads. However, the action of shredders did not have a significant effect on fungal biomass nor on leaf mass loss. Even if shredders did not enhance fungal colonisation, they affected the settlement of fine sediment, serving as allogenic engineers. Our study suggests that concentrations of fine sediment of 400?mg?L?1 with short exposure times (192?h) can have some effect on leaf decomposition.  相似文献   

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Excess delivery of land‐based sediments is an important control on the overall condition of nearshore coral reef ecosystems. Unpaved roads have been identified as a dominant sediment source on St John in the US Virgin Islands. An improved understanding of road sediment production rates is needed to guide future development and erosion control efforts. The main objectives of this study were to: (1) measure sediment production rates at the road segment scale; (2) evaluate the importance of precipitation, slope, contributing area, traffic, and grading on road sediment production; (3) develop an empirical road erosion predictive model; and (4) compare our measured erosion rates to other published data. Sediment production from 21 road segments was monitored with sediment traps from July 1998 to November 2001. The selected road segments had varying slopes, contributing areas, and traffic loads. Precipitation was measured by four recording rain gauges. Sediment production was related to total precipitation and road segment slope. After normalizing by precipitation and slope, the mean sediment production rate for roads that had been graded within the last two years was 0·96 kg m?2 cm?1 m m?1 or approximately 11 kg m?2 a?1 for a typical road with a 10 per cent slope and an annual rainfall of 115 cm a?1. The mean erosion rate for ungraded roads was 42 per cent lower, or 0·56 kg m?2 cm?1 m m?1. The normalized mean sediment production rate for road segments that had been abandoned for over fifteen years was only about 10 per cent of the mean value for ungraded roads. Sediment production was not related to traffic loads. Multiple regression analysis led to the development of an empirical model based on precipitation, slope to the 1·5 power, and a categorical grading variable. The measured and predicted erosion rates indicate that roads are capable of increasing hillslope‐scale sediment production rates by up to four orders of magnitude relative to undisturbed conditions. The values from St John are at the high end of reported road erosion rates, a finding that is consistent with the high rainfall erosivities and steep slopes of many of the unpaved roads on St John. Other than paving, the most practical methods to reduce current erosion rates are to minimize the frequency of grading and improve road drainage. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

20.
The nature and rates of fluvial and slope processes change over time and space as urbanized areas replace forested land in Singapore. Storm-based and time-based data, from undisturbed rainforests, heavily disturbed construction sites, urban grass-covered slopes and an experimental plot, are collected to observe the impact of rainwater on the soil moisture conditions, surface microtopography, runoff generation, sediment movement, and ground lowering in the three different categories of land use. The undisturbed forested environment is characterized by high throughfall (58% of total rainfall) and frequent negative soil moisture suctions. The slow and unconcentrated overland flow during heavy storms is restricted by the forest floor microtopography. No rills develop. Ground lowering is recorded as 3·2–3·4 mm a?1. But sediment movement is episodic and suspended sediment concentrations in overland flow are 172–222 mg l?1. During urban construction, gully development is rapid on the bare slopes, runoff generation, voluminous, and sediment-laden discharges (5200–75498 mg l?1) lead to sediment plumes at channel mouths. Ground lowering rates are measured at 132·4 mm a?1. Once grass-covered, runoff carries less suspended sediment (800 mg l?1) and ground lowering rates are reduced, but depend on the condition of the cover, ranging from 0·2 to 8·2 mm a?1. As urban development continues, environments are altered both in time as well as spatially.  相似文献   

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