共查询到20条相似文献，搜索用时 109 毫秒
1.
塔里木盆地寒武系—奥陶系海相烃源岩地球化学特征 总被引：1，自引：0，他引：1
塔里木盆地寒武系－奥陶系属广阔的台地和槽盆沉积,是塔里木盆地海相主力烃源岩,通过对寒武系一下奥陶统及中－上奥陶统烃源岩的饱和和芳香烃的部析,发现11个分子系列参数在两套烃源岩中具有明显的区别,寒武系一下奥陶统烃源岩Tmax较高,烃指数极低,产率指数较高,两套烃源岩的TOC玎当,Ph/nC18值较高,藿烷／甾烷值较低（＜2．0）,甲藻甾烷含量较高,重排甾烷含量较低,姥鲛烷／植烷值较低,伽马蜡烷／C30藿烷值较高,表明寒武系处于厌氧环境的时间较长,水体盐度较高,有利于有机质的堆积和保存。 相似文献
2.
塔里木盆地寒武系—奥陶系属广阔的台地和槽盆沉积,是塔里木盆地的海相主力烃源岩。通过对寒武系—下奥陶统及中—上奥陶统烃源岩的饱和烃和芳香烃的剖析,发现11个分子系列参数在两套烃源岩中具有明显的区别。寒武系—下奥陶统烃源岩 T_(max) 较高,烃指数极低,产率指数较高;两套烃源岩的 TOC 值相当;Ph/nC_(18)值较高,藿烷/甾烷值较低(<2.0);甲藻甾烷含量较高,重排甾烷含量较低;姥鲛垸/植皖值较低,伽马蜡烷/C_(30)藿烷值较高,表明寒武系处于厌氧环境的时间较长,水体盐度较高,有利于有机质的堆积和保存。 相似文献
3.
柯坪地区中-上奥陶统萨尔干组与上奥陶统印干组海相烃源岩是塔里木盆地重要的烃源岩组成部分,对其特征及其成因机制的研究具有重要的科学意义和经济价值。在通过岩石热解分析对比研究萨尔干组与印干组海相烃源岩现今地球化学特征的基础上,通过微量和稀土元素从地球生物学的角度对其特征差异性成因机制进行了探讨。结果表明,萨尔干组和印干组黑色页岩现今均处于成熟-高成熟阶段,萨尔干组的有机质丰度和古生产力水平都比印干组高,而古氧相和埋藏效率均较差。与印干组相比,Caradoc早期大洋缺氧事件使得柯坪地区同时期沉积的萨尔干组页岩古生产力水平得到了显著提高,在埋藏效率低、氧化还原条件差的情况下仍为高有机质丰度烃源岩。 相似文献
4.
中—上奥陶统：塔里木盆地的主要油源层 总被引：14，自引：0，他引：14
塔里木盆地下古生界存在中－下寒武统一和中－上奥陶统两套有效烃源层。前者Ｒ０已达２．０％以上,只能作为有效气源岩;后者成熟度适中且能一定分布范围,是塔里木盆地最现实的烃源层,可分为三段,其中以上奥陶统中部的印干组和良里塔格组最具重要意义。对盆地中海相原油与寒武系和奥陶系岩石抽提物中甲基甾烷、三芳甲基甾烷及降胆甾烷的分布进行直观对比,表明原油与中－上奥陶统存在亲缘关系,而与寒武系无明显相关。全盆地所有 相似文献
5.
塔里木盆地下古生界存在中一下寒武统和中一上奥陶统两套有效烃源层。前者R。已达2．0％以上,只能作为有效气源岩;后者成熟度适中且有一定分布范围,是塔里木盆地最现实的烃源层,可分为三段,其中以上奥陶统中部的印干组和良里塔格组最具重要意义。对盆地中海相原油与寒武系和奥陶系岩石抽提物中甲基甾烷、三芳甲基甾烷及降胆甾烷的分布进行直观对比,表明原油与中—上奥陶统存在亲缘关系,而与寒武系无明显相关。全盆地所有钻遇的寒武系岩样,C27—C28—C2。甾烷碳数分布呈“斜线”型或反“L”型,而绝大部分中—上奥陶统岩样则呈不对称“V”字型分布。所分析的储层沥青的甾烷碳数分布与上述寒武系岩样一致,说明寒武系生油岩在地质历史上确曾生过油。包括塔中4、轮南、桑塔木和东河塘等在内的工业性油田产出的油,其甾烷碳数都呈不对称“V”字型分布,只有极少数的油样呈“斜线”或反“L”型分布,因此塔里木盆地的原油主要与中—上奥陶统相关,而与寒武系相关极少。运用G温度参数评价原油成熟度,结果为塔里木盆地主要油区原油的形成温度在117～133℃之间,对应的R。值为0．78％～0．92％,只相当干中等成熟阶段,可以推断它们不可能源干寒武系,只能源干奥陶系。 相似文献
6.
大王北洼陷烃源岩有机地球化学特征 总被引：3，自引：0，他引：3
根据烃源岩可溶抽提物的色谱和色谱- 质谱分析结果,对大王北洼陷沙四段、沙三段和沙一段烃源岩的饱和烃和芳烃生物标志化合物组合特征进行了对比研究,揭示了三套烃源岩在沉积环境和有机母源输入的不同特征,总结了应用生物标志化合物鉴别三套烃源岩的组合参数特征,为精细的油源对比奠定了基础。研究表明,沙四段烃源岩具有较低的Pr /Ph,4-甲基甾烷同类物中C28 4-甲基系列含量最低、较高的甲藻甾烷含量、较低的重排甾烷含量、异常的C35 升藿烷含量、高伽马蜡烷异常指数、含一定量的奥利烷和较高的硫芴系列化合物含量等特征,反映了沙四段烃源岩形成于高盐度含硫强还原沉积环境,低等水生生物为主,高等植物有明显贡献的混合母源特征。沙三段烃源岩具有较高的Pr /Ph,4-甲基甾烷同类物中C29 4-甲基系列含量最低、几乎不含甲藻甾烷、较高的重排甾烷含量、基本正常的升藿烷分布、低伽马蜡烷异常指数和较低的奥利烷含量等特征,反映了沙三段烃源岩形成于半咸水的一般还原环境,低等水生生物为主,有一定量高等植物有机输入的混合母源特征。沙一段烃源岩具有极低的Pr /Ph,4-甲基甾烷同类物中C28 4-甲基系列含量最低、较高的甲藻甾烷含量、很低的重排甾烷含量、异常的C33 升藿烷含量、高伽马蜡烷异常指数、极低的奥利烷含量和较高的脱羟基维生素E 含量等特征,反映了沙一段烃源岩形成于高盐度强还原沉积环境,低等水生生物占绝对优势的有机母源特征。对研究区烃源岩生物标志化合物成熟度参数随深度的变化进行了分析,结果表明在不同层系中成熟度参数的演化存在显著差异,沉积埋藏历史和沉积环境可能是导致这些差异的原因,为此在应用这些参数进行烃源岩乃至生成石油的成熟度评价时,应使用不同的标准。 相似文献
7.
塔里木阿瓦提凹陷乌鲁桥油苗地化特征及来源 总被引：1，自引：0，他引：1
阿瓦提凹陷乌鲁桥油苗全油碳同位素较重(-29.4‰)。在甲基菲分布分数图版上落在高成熟油区;甲基菲比值为2.03,高于塔里木盆地现已发现的高成熟凝析油和成熟度较高的原油,表明该油苗的成熟度高。萜烷、甾烷分布具有C29Ts、重排藿烷含量低,伽玛蜡烷丰度较高,中等—高丰度C28甾烷,低重排甾烷等分布特征。这与凹陷及其周缘的石炭系—二叠系、三叠系及中—上奥陶统这三套烃源岩的明显不同,而与寒武系烃源岩相似。综合分析认为乌鲁桥油苗来源于寒武系烃源岩成熟晚期阶段生成的烃类。 相似文献
8.
银额盆地查干凹陷原油地化特征及油源对比 总被引：11，自引：1，他引：11
银额盆地东部查干凹陷首次发现轻质低硫成熟原油，其饱和径含量在90％以上，成熟度相当于镜煤反射率Ro1．0％左右，是生油高峰阶段的产物；原油全碳同位素δ^13C值－31．1‰。原油生物标志物中类异戊二烯含量较高，植烷与姥皖烷均势；三环萜烷含量高于五环萜烷；含有较高的TS C29、Ts、C30重排藿烷、伽马蜡烷；藿烷中以C50藿烷为主，C32以上升藿烷含量极低；孕甾烷含量高；甾烷中以C29甾烷为主，C27甾烷含量也较高，异胆甾烷含量高于胆甾烷；重排甾烷含量低；甾烷的含量与萜烷含量相当，是典型的湖相原油。已发现的天然气中甲烷含量达80％，为湿气。原油和源岩生物标志物组成特征分析对比表明下白垩统巴音戈壁组源岩是主要油源岩。生物标志物特征示原油具有一定的运移效应。 相似文献
9.
塔里木盆地下古生界存在中—下寒武统和中—上奥陶统两套有效烃源层。前者 R。已达2.0％以上,只能作为有效气源岩;后者成熟度适中且有一定分布范围,是塔里木盆地最现实的烃源层,可分为三段,其中以上奥陶统中部的印干组和良里塔格组最具重要意义。对盆地中海相原油与寒武系和奥陶系岩石抽提物中甲基甾垸、三芳甲基甾烷及降胆甾烷的分布进行直观对比,表明原油与中—上奥陶统存在亲缘关系,而与寒武系无明显相关。全盆地所有钻遇的寒武系岩样,C_(27)—C_(28)—C_(29)甾烷碳数分布呈“斜线”型或反“L”型,而绝大部分中一上奥陶统岩样则呈不对称“V”字型分布。所分析的储层沥青的甾烷碳数分布与上述寒武系岩样一致,说明寒武系生油岩在地质历史上确曾生过油。包括塔中4、轮南、桑塔木和东河塘等在内的工业性油田产出的油,其甾烷碳数都呈不对称“V”字型分布,只有极少数的油样呈“斜线”或反“L”型分布,因此塔里木盆地的原油主要与中—上奥陶统相关,而与寒武系相关极少。运用C_7温度参数评价原油成熟度,结果为塔里木盆地主要油区原油的形成温度在117～133℃之间,对应的 R。值为0.78％～0.92％,只相当于中等成熟阶段,可以推断它们不可能源于寒武系,只能源于奥陶系。 相似文献
10.
以气相色谱、气相色谱-质谱为技术手段,对额济纳旗大狐狸山地区干泉组烃源岩的生物标志化合物进行研究,剖析生物标志化合物指示的母质来源、沉积环境、成熟度等方面的信息.干泉组烃源岩饱和烃气相色谱为”前峰型”的单峰分布,主峰碳以C1s为主,说明有机质来源以海相有机质为主,Pr/Ph介于0.3～0.6之间,指示强还原的沉积环境.干泉组烃源岩具有长侧链的三环萜烷丰富、伽马蜡烷含量高和C27甾烷分布占优势的生物标志化合物组合特征,高伽马蜡烷含量揭示烃源岩有机相为咸水沉积环境,藿烷/甾烷比值的平均值为0.59,表明藻类对有机质的贡献高于细菌.C27甾烷丰度较高,说明低等水生生物藻类是生烃母质的主要生源.干泉组烃源岩甲基菲指数介于0.35～0.50,其折算的镜质体反射率R.为2.00～2.09,与实测的镜质体反射率指示意义一致,说明干泉组烃源岩热演化处于过成熟阶段. 相似文献
11.
1 Introduction Since the 1990’s of the 20th century, oil & gas geochemists have shifted their research focus on hydrocarbon source rocks in the past to that on reservoir rocks and oil reservoirs at present; their research field has been expanded from oil & gas exploration to the assessment of oil reservoirs and production & management. Therefore, reservoir geochemistry as a branch disciplinary of organic geochemistry is now attracting great concern of many oil & gas explorers and oilfield en… 相似文献
12.
塔里木盆地寒武系烃源岩的研究新进展 总被引：3，自引：0，他引：3
塔里木盆地的勘探程度较低,下古生界不同烃源岩的特征及其展布仍是困扰地质家的重大问题。通过详细分析已钻揭的寒武系烃源岩,深入探讨了寒武系烃源岩的地球化学特征。结果表明由于不同地区寒武系烃源岩的沉积环境存在差别,因此不同地区有机质的丰度、甾萜烷的分布特征以及“三芴”组成均存在一定的差异,因此进行寒武系的油源对比时应考虑到这种差别,以提高油源对比的精度。总体来讲,寒武系烃源岩的标志性特征主要包括甾烷中的C28含量较高（>25%）、伽马蜡烷的含量较高（峰高与C31H接近,G/C31H22R>0.89）、碳同位素比值偏重（δ13C饱重于-30‰,δ13C芳接近或重于-28‰）,三芳甾烷的分布特征也明显区别于中—上奥陶统烃源岩。 相似文献
13.
Chunfang Cai Kaikai Li Ma Anlai Chunming Zhang Zhiming Xu Richard H. Worden Guanhui Wu Baoshou Zhang Lixin Chen 《Organic Geochemistry》2009,40(7):755-768
The reported source rocks for the abundant petroleum in the Tarim Basin, China range from Cambrian to Lower Ordovician and/or Upper Ordovician in age. However, the difference between the two groups of source rocks is not well characterized. In this study, pyrite was removed from eleven mature to over mature kerogen samples from source rocks using the method of CrCl2 reduction and grinding. The kerogen and coexisting pyrite samples were then analyzed for δ34S values. Results show that the kerogen samples from the Cambrian have δ34S values between +10.4‰ and +19.4‰. The values are significantly higher than those from the Lower Ordovician kerogen (δ34S of between +6.7‰ and +8.7‰), which in turn are generally higher than from the Upper Ordovician kerogen samples (δ34S of between ?15.3 and +6.8‰). The associated pyrite shows a similar trend but with much lower δ34S values. This stratigraphically controlled sulfur isotope variation parallels the evolving contemporary marine sulfate and dated oil δ34S values from other basins, suggesting that seawater sulfate and source rock age have an important influence on kerogen and pyrite δ34S values. The relatively high δ34S values in the Cambrian to Lower Ordovician source rocks are associated with abundant aryl isoprenoids, gammacerane and C35 homohopanes in the extractable organic matter, indicating that these source rocks were deposited in a bottom water euxinic environment with water stratification. Compared with the Upper Ordovician, the Cambrian to Lower Ordovician source rocks show abundance in C28 20R sterane, C23 tricyclic terpanes, 4,23,24-trimethyl triaromatic dinosteroids and depletion in C24 tetracyclic terpane, C29 hopane. Thus, δ34S values and biomarkers of source rock organic matter can be used for distinguishing the Cambrian and Upper Ordovician source rocks in the Tarim Basin. 相似文献
14.
PAUL Philp 《中国地球化学学报》2012,31(3):264-275
Based on the systematic analyses of fifteen typical crude oils and ten typical potential source rocks col-lected from the Qaidam,Tarim and Turpan basins,Northwest China,the geochemical characteristics of the oils and source rocks were investigated and oil-source rock correlations undertaken.The oils and source rocks deposited in saline lacustrine environment from the western Qaidam Basin were characterized by n-alkanes with even car-bon-number preference in the C20-C28 range,low pristane/phytane(Pr/Ph) ratios(less than 0.5),and high abundances of C27 steranes,gammacerane and C35 hopanes.The oils and source rocks deposited in marine environment from the Tarim Basin were characterized by n-alkanes with even carbon-number preference in the C14-C18 range,relatively low Pr/Ph ratios(near to 1),high abundance of C28 steranes,and relatively high gammacerane.In contrast,the oils and source rocks deposited in terrigenous bog environment from the Turpan Basin were characterized by relatively high Pr/Ph ratios(oil samples greater than 6) high abundance of C29 steranes,and relatively low gammacerane and C31-35 hopanes.The higher amounts of C37 and C38 n-alkanes of source rocks from the western Qaidam Basin and the Tarim Basin suggest an origin of these alkanes from functionalized C37 and C38 n-alkadienes and alkenones in prymnesiophytes living in lacustrine and marine environments.Oil-source rock correlations suggest oils in the west-ern Qaidam Basin were derived from the Oligocene Lower Ganchaigou Formation(E3),oils in the Tabei and Tazhong uplifts from the Tarim Basin have a genetic relationship with the Middle-Upper Ordovician source beds.Oils in the Turpan Basin generally fall into two genetic types.Most oils in the Taibei depression from the Turpan Basin were derived from the Lower-Middle Jurassic coal measures,but the fewer oils in this region are a mixed source derived from the Lower-Middle Jurassic coal measure and the Upper Permian source rocks. 相似文献
15.
塔里木盆地一类新海相原油的地球化学特征 总被引：1，自引：0，他引：1
对塔中52等井奥陶系储层产出的原油进行的分析结果表明,它们的三环萜烷系列较为特殊,主要表现为其相对丰度呈C19>C20>C21>C23>C24>C25>C26阶梯状的模式,C24四环萜烷异常丰富,且其丰度远高于C26三环萜烷,这一分布模式一般出现在淡水沼泽相和浅湖相沉积地层与原油中。在三萜烷分布特征上,其伽马蜡烷含量很低,甾烷系列和藿烷系列的分布与组成特征与该地区来源于中上奥陶统烃源岩的海相原油十分接近,同时它们的全油均具有轻的碳同位素组成,其δ13Ｃ值都小于-30‰,具有海相成因原油的特征。而塔中12井上奥陶统良里塔格组4-5段烃源岩中生物标志物的分析结果进一步证实了该类原油与那些富含宏观藻残片,且有机质类型偏腐殖型的上奥陶统海相烃源岩关系密切,是该地区油气勘探中值得关注的对象。 相似文献
16.
Two oil families in Ordovician reservoirs from the cratonic region of the Tarim Basin are distinguished by the distribution of regular steranes, triaromatic steroids, norcholestanes and dinosteroids. Oils with relatively lower contents of C28 regular steranes, C26 20S, C26 20R + C27 20S and C27 20R regular triaromatic steroids, dinosteranes, 24-norcholestanes and triaromatic dinosteroids originated from Middle–Upper Ordovician source rocks. In contrast, oils with abnormally high abundances of the above compounds are derived from Cambrian and Lower Ordovician source rocks. Only a few oils have previously been reported to be of Cambrian and Lower Ordovician origin, especially in the east region of the Tarim Basin. This study further reports the discovery of oil accumulations of Cambrian and Lower Ordovician origin in the Tabei and Tazhong Uplifts, which indicates a potential for further discoveries involving Cambrian and Lower Ordovician sourced oils in the Tarim Basin. Dinosteroids in petroleum and ancient sediments are generally thought to be biomarkers for dinoflagellates and 24-norcholestanes for dinoflagellates and diatoms. Therefore, the abnormally high abundance of these compounds in extracts from the organic-rich sediments in the Cambrian and Lower Ordovician and related oils in the cratonic region of the Tarim Basin suggests that phytoplankton algae related to dinoflagellates have appeared and might have flourished in the Tarim Basin during the Cambrian Period. Steroids with less common structural configurations are underutilized and can expand understanding of the early development history of organisms, as well as define petroleum systems. 相似文献
17.
生物标志化合物在地层划分与对比中的应用——以塔里木盆地下古生界为例 总被引：1，自引：0，他引：1
生物标志化合物是指沉积岩或原油和煤中碳—碳骨架稳定的特征化合物 ,它通常是用于油源对比和古沉积环境的恢复。本次研究在地层划分与对比中尝试利用正常甾烷分布的差异 ,研究表明 ,塔里木盆地寒武系—下奥陶统和中上奥陶统的甾烷分布特征完全不同 :前者的 C2 8甾烷含量高于后者 ,正常甾烷的分布是 C2 9>C2 8>C2 7,呈反“L”型分布 ;后者的 C2 7甾烷含量高于前者 ,甾烷的分布是 C2 9>C2 7>C2 8,呈“V”字型分布。寒武系—下奥陶统和中上奥陶统甾烷分布由反“L”型变为“V”型 ,说明生物在演化过程中 ,有机质的来源及化学结构组成发生了明显变化 ,据此可用于塔里木盆地下古生界的地层划分与对比。 相似文献
18.
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields. 相似文献
19.
北部湾盆地流沙港组二段湖相烃源岩是盆地的主力烃源岩,其中检测到甲藻甾烷和三芳甲藻甾烷,以及丰富的4-甲基甾烷等重要分子化石。通过对北部湾盆地北部地区古近系流二段烃源岩的元素地球化学和有机地球化学特征等分析,研究了富有机质页岩的古氧化还原条件和古盐度,并进行甾类生物标志物对比,探讨了甲藻甾烷,三芳甲藻甾烷和C30-4-甲基甾烷分布特征及其与沟鞭藻的成因关系。研究结果表明:流二段底部富有机质页岩中的C30-4-甲基甾烷和三芳甲藻甾烷丰度呈负相关关系,表明弱还原的淡水—微咸水沉积条件可能不适宜甲藻甾烷和三芳甲藻甾烷的形成,而可以形成高丰度的C30-4-甲基甾烷。油页岩中高丰度的C30-4-甲基甾烷与其较高的成熟度有密切的关系。 相似文献
20.
黔北下寒武统牛蹄塘组烃源岩的生物标志物
特征和沉积环境 总被引：1，自引：0，他引：1
为研究黔北地区下寒武统牛蹄塘组烃源岩母质来源和沉积环境,开展了生物标志化合物分析,结果表明：①正构烷烃OEP接近1.0,无明显奇偶优势,受轻微生物降解影响,正构烷烃多表现为双峰型(C18/C25),(nC21+nC22)/(nC28+nC29)值为0.54~1.01,显示重烃组分占绝对优势;Pr/Ph值范围在0.51~0.82之间,具有植烷优势。②烃源岩样品组成相对丰度五环三萜烷>三环萜烷>四环萜烷,三环萜烷中C21、C23、C24呈倒V字形分布,Ts/(Tm+Ts)为0.45~0.50。③C27规则甾烷/C29规则甾烷略小于1或者接近1,芳烃化合物DBT/P为0.05~0.09。根据这些特征并结合干酪根同位素及正构烷烃同位素组成和变化规律,认为该区域下寒武统牛蹄塘组烃源岩形成于浅海还原环境,且有机质主要来源于细菌、藻类等低等水生生物,有机质热演化程度较高。根据常量、微量元素指标并结合有机地化指标刻划出从灯影组到牛蹄塘组和明心寺组沉积时期的水体环境,将牛蹄塘组烃源岩的形成分为3个阶段,第一阶段为早寒武世初始快速海侵阶段,第二阶段为深水还原高有机质产力阶段,第三阶段为海水缓慢变浅高有机质产力阶段,而到了明心寺组沉积时期为浅水氧化非烃源岩阶段。 相似文献