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1.
Particulates amounting to 0.1–2.0 g efficiently collected from large volumes of Atlantic and Pacific surface waters have been analyzed for carbonate, opal, quartz and several natural and man-made radioisotopes.The concentrations of particles range between 10 and 600 μg/kg. In the equatorial regions particle concentrations are low and similar in both the oceans. At higher latitudes (>30°N or S), the Atlantic waters, however, have higher concentrations of particles compared to those in the Pacific. The latitudinal distribution exhibits a north-south symmetry with higher concentrations in the 30°–60° belt. Based on the particulate abundance for CaCO3 and opal and their sedimentation, we have estimated their production and in-situ integrated dissolution rates for a few regions.Radioisotopes having different source functions, namely14C and239Pu injected due to nuclear weapon tests,234Th,230Th and228Th produced in-situ in seawater,232Th which derives primarily from land,210Pb introduced via wet precipitations and226Ra introduced through diffusion from deep-sea sediments have been measured in the particulates. The relative enrichment factors for these nuclides in particles vary as Th ? Pu > Pb > Ra. The atmospheric bomb fallout pattern is discernible in the surface particulates; the239Pu concentration increases with latitude in both the hemispheres; however, the values are about a factor of two lower in the southern hemisphere.The distribution pattern of radioisotopes is found to be complex, even for234Th whose source function in the oceans is uniform. In view of the differences in the source functions it becomes possible to delineate the principal geochemical/geophysical processes which determine the concentrations of these nuclides in surface waters.  相似文献   

2.
130 sites were occupied in a magnetic survey of Slovakia. About half of those occupied in previous surveys (1952.5, 1958.5, and 1967.5) were unsuitable because of increased man made noises. New stations were substituted. A combination of classical magnetometers (forH andD) and a proton magnetometer (forF) was used.Z was computed fromH andF. Instruments were calibrated at Hurbanovo magnetic observatory before the survey and at regular size intervals during it.Reduction to epoch was made on the assumption that the scale variation is everywhere the same and equal to that at Hurbanovo. Preliminary maps are hand drawn, but the data have been transferred to computer tape and computer plotted maps are being prepared.  相似文献   

3.
Petroleum hydrocarbons in the sediments of the Bothnian Bay, Baltic proper, Öresund, Kattegatt and Skagerrak were analysed in a survey of oil pollution along the Swedish coast in 1974 and 1975. Sixty-one of these sediment stations were revisited in 1982 and analysed with the methods used in the first survey. The mean content of petroleum hydrocarbons (paraffin-naphthene fraction) in the sediment surface showed a statistically significant increase from 199 to 252 μg g?1 dry wt. The main increase had taken place in the coastal areas. Within 0–20 km distance of urbanized areas (>20 000 inhabitants) petroleum hydrocarbons had increased from 371 to 447 μg g?1. Sediment levels increased from 76 to 117 μg g?1, 20–50 km from urbanized areas. The increase in these areas was equivalent to 0.119 g m?2 yr?1.  相似文献   

4.
Magnetic Resonance Sounding (MRS) is nowadays accepted as a new geophysical method that can be used for a reliable determination of the ground water content distribution in the top 150 m. A great effort has also been made in MRS development to deduce the hydraulic transmissivity, based on empiric relationships of the permeability with a factor F which is calculated with NMR parameters measured at laboratory scale. To use this relationship under field conditions a calibration coefficient CT = Tpt / F has to be previously established, which demands the knowledge of the transmissivity Tpt evaluated in the pumping test. The transmissivity can then be calculated at any other site of the same aquifer using the relation Tmrs = CTF. The CT values reported suggest a certain relationship with the lithology, but with a great dispersion and contradictory results. MRS surveys carried out in alluvial aquifers in Spain have shown that the value of CT evaluated at one site may not be valid at another place of the same aquifer, because of the great heterogeneity of this kind of geological environment. The demand of a pumping test at each site where a MRS is measured invalidates the method actually used for MRS transmissivity evaluation. More than 50 MRS have been used to propose a new methodology. The aquifers visited cover a great range of transmissivities (from 2 × 10− 6 to 9 × 10− 3 m2/s). The MRS signal amplitude varies between 20 and 1400 nV, the signal/noise ratio is in the range from 0.6 to 42, and the value of the decay time constant varies from 200 to 800 ms. It has been demonstrated that when the transmissivity increases, the value of F decreases, and CT increases, except for certain groups of MRS taken at the same aquifer or part of one aquifer, for which F increases with Tpt, keeping CT constant. A function CT(F) of the type CT = mF− n has been obtained that allows the transmissivity evaluation without the need of Tpt. Considering that both values of transmissivity, Tpt and Tmrs, are subjected to deviations due to the experimental errors as well as due to evaluation errors, the prediction achieved by the proposed equation is rather good. To perform a better evaluation of the values of the coefficients m and n it is necessary to have a greater number of MR soundings of good quality and with a trustworthy inversion at locations where a really comparable and good performed pumping test is available, covering a sufficient range of transmissivities. Though the data we have used do not always fulfil these conditions, the result is promising. Once a trustable function is available, the forecast of the transmissivity using MRS will not need the existence of any pumping test in the area. The general extension of this methodology demands the availability of MRS taken at all kinds of geological and hydrogeological environments, which is impossible without the existence of a universal MRS data base.  相似文献   

5.
Since 1986, with a sharp decrease in water dis-charges, the Yellow River has entered a period charac-terized by low discharges and seasonally occurring dry-ups[1,2]. Since 1999, more strict management of water diversion has been imposed, and therefore the dry-ups have been well under control. However, the lower reaches of the Yellow River is still predominated by low-discharges, and has become a man-induced shrinking river. In the past 40 years, significant effect of soil and water conservat…  相似文献   

6.
The speedv, especially the problem whether super S-wave velocity in the classical model (linear elasticity fracture mechanics) exists, of spontaneous propagation of a shear fault is investigated theoretically. An in-plane shear crack propagating in the crack plane is taken as the model of the shear fault. The results obtained firstly by Kostrov (1975) is extended from sub-Rayleigh wave velocity to super S-wave velocity, and the analytical expression for the stress intensity factorK 2 in the case ofα>v>β is derived. It is proved that for Poisson mediumK 2 is positive and real in the velocity range (β, 1.70β). This demonstrates that (β, 1.70β) is the velocity range which fulfils the conditions for spontaneous crack propagation. The existence, convergence and positiveness or negativeness ofK 2 forv in individual sections are examined, and it is found that for an in-plane shear crack: 1. There are three sections forv, i.e., [0.v R], (β, 1.70β), andα, respectively, and 2. There are two physically reasonable sections forv, the first is [v R, β], and the second is [1.70β, α]. These two forbidden sections behave as barriers to fault propagation. The analytical expressions derived in this paper are not only suitable to classical model, but also to the other derivative models (e. g., the slip-weakening model and the renomalization model etc.). The model considered in this paper is more realistic than the static model employed by previous authors. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica, 15, 9–14, 1993.  相似文献   

7.
In this paper we suggest that conditional estimator/predictor of rockburst probability (and rockburst hazard, P T (t)) can be approximated with the formula P T (t) = P 1(θ 1)…P N (θ N )·P dyn T (t), where P dyn T (t) is a time-dependent probability of rockburst given only the predicted seismic energy parameters, while P i (θ i ) are amplifying coefficients due to local geologic and mining conditions, as defined by the Expert Method of (rockburst) Hazard Evaluation (MRG) known in the Polish mining industry. All the elements of the formula are (approximately) calculable (on-line) and the resulting P T value satisfies inequalities 0 ≤ P T (t) ≤ 1. As a result, the hazard space (0–1) can be always divided into smaller subspaces (e.g., 0–10−5, 10−5–10−4, 10−4–10−3, 10−3–1), possibly named with symbols (e.g., A, B, C, D, …) called “hazard states” — which saves the prediction users from worrying of probabilities. The estimator P T can be interpreted as a formal statement of (reformulated) Comprehensive Method of Rockburst State of Hazard Evaluation, well known in Polish mining industry. The estimator P T is natural, logically consistent and physically interpretable. Due to full formalization, it can be easily generalized, incorporating relevant information from other sources/methods.  相似文献   

8.
This study investigates the influence of Ca2+ and Mg2+ on the removal of F? by magnesium potassium phosphate (MPP) from water. The kinetic experiments reveal that the F? concentration decreased from 3.5 to 3.31 mg L?1 in a single (F?) system and to 1.45 mg L?1 in a ternary system (F?, Ca2+, and Mg2+) after 1 min, respectively. Thus, the F? removal efficiencies are found to increase by about 53% with the co‐active effect of Ca2+ and Mg2+ in the solution. Moreover, Ca2+ and Mg2+ are almost completely removed in the F?, Ca2+, and Mg2+ system. According to the pseudo‐first‐order modeling, the rate constants k for F?, Ca2+, and Mg2+ are 0.00348, 0.0106, and 0.0159 min?1 respectively; thus, Mg2+ > Ca2+ > F?. In the ternary system, the removal efficiencies are 53.29–66.03% for F?, 99.99–100% for Ca2+, and 87.21–95.19% for Mg2+ with initial pH 5–10. The removal efficiencies of F? increases with increases in initial concentrations of F?, Ca2+, and Mg2+. The removal of F? is governed by two routes: 1) adsorption by electrostatic interactions and outer sphere surface complexation; 2) co‐precipitation with Ca3(PO4)2, CaHPO4, Mg3(PO4)2, and Mg(OH)2.  相似文献   

9.
The palaeo-intensities (F a) of the geomagnetic field in Egypt at some ages are determined by archaeomagnetic measurements and found to be:F a=36.2 T at 3100 B.C., Fa=46.8 T at 3000 B.C.,F a=36.5 T at 2780 B.C., 49.0 T at 2500 B.C., 36.4 T at 2200 B.C., 57.5 T at 1990 B.C., 62.1 T atca 1400 B.C., 61.5 T at 1400 B.C., 69.9 T at 600 B.C., 59.3 T at 550 B.C., 79.9 T at 460 B.C., 73.7 T at 450 B.C., 69.7 T at 320 B.C., 56.2 T at A.D. 50, 64.9 T, at A.D. 400, 54.4 T at A.D. 300, 57.5 T at A.D. 700 and 43.0 T at A.D. 1975.The palaeo-inclinations (I a) at some ages are found to be:I a=24.2° at 420 B.C., 44° at A.D. 50, 60.7° at A.D. 703 and 42° at A.D. 1795.The measured values ofF a are affected by the anisotropy of magnetic susceptibility of the samples by 13% to 20% of the expected correct value. The suitable correction of this effect is by multiplyingF by 1/((1+0.2(/90)) andF by 1/((1–0.13 (/90)), whereF andF are the resultant values ofF a if the laboratory field is perpendicular or parallel to the wall of the sample during the Thelliers' experiments, respectively, and is the angle between the direction of natural remnant magnetization of the sample and the direction of the laboratory field.The results of this paper, together with the previous results for Egypt and the neighbourhoods, lead to the production of the secular variation curve of the geomagnetic field in Egypt for the last 5000 years. The intensity of the field shows a periodicity of about 400 years with multiples.  相似文献   

10.
Rain and surface water samples from Southern Germany were investigated from 1991 to 1995 for terbuthylazine and one of its major metabolites, deethylterbuthylazine. The concentrations observed were compared to the concentrations found for atrazine and deethylatrazine in the same water samples. Concentrations ranged from < 0.02 μg/L to 0.7 μg/L for terbuthylazine and from < 0.02 μg/L to 0.6 μg/L for deethylterbuthylazine, compared to concentrations of < 0.02 μg/L to 3 μg/L and < 0.02 μg/L to 0.5 μg/L for atrazine and deethylatrazine, respectively. The ratios of metabolite concentrations to parent compound concentrations were calculated for deethylterbuthylazine to terbuthylazine (DTR) and deethylatrazine to atrazine (DAR). In rain water, DTR of 0.8…3.0 and DAR of 0.3… 1.9 were determined with mean values of 0.9… 1.7 for DTR and 0.6…0.9 for DAR in the different years. The ratios increased during summer periods. The highest ratios were observed in samples from forest stands, showing that degradation of the herbicide has occurred during transport between the source and the sampling site. The DTR in rain water were about 50… 100% higher than the DAR. This indicates a higher degradation rate of terbuthylazine during atmospheric transport. In surface water, DTR of 0.3… 1.2 with mean values of 0.5…0.8 and DAR of 0.2…2.2 with mean values of 0.2… 1.3 were observed. The ratios increased from June to September.  相似文献   

11.
Response surface methodology (RSM) employing the three‐level Box–Behnken factorial design was used to optimize the biosorption of Ag(I) by the macrofungus Pleurotus platypus. The initial Ag(I) concentration (100–300 mg/L), pH (3.0–9.0), and biomass dosage (1.0–5.0 g/L) were chosen as the process variables for the optimization. A coefficient of determination (R2) value (0.99), model F value (234.18), and its low p‐value (F < 0.0001) along with the lower value of coefficient of variation (2.44%) indicated the fitness of response surface quadratic model during the present study. At the optimum pH (6.0), initial metal concentration (220 mg/L), and biomass dosage (3.0 g/L), the model predicted 46.7 mg/g Ag(I) uptake and an experimental 46.77 mg/g Ag(I) uptake by P. platypus was obtained. This is the first report on Ag(I) sorption by P. platypus using statistical experimental design employing RSM which may be helpful towards the treatment of industrial effluent containing silver.  相似文献   

12.
The expression of equi-risk line derived by the authors represents the relationship between discharge capacityy 0 u and storage capacityz 0 u to keep flood frequency under a certain risk level represented by the return periodT, i.e.,z 0/z 0 u ={(y 0 u –y 0 u )/y 0 u } S , wherey 0 u andz 0 u areT-year probability peak discharge and total volume of a hydrograph. The shape parametersS is evaluated in this paper for various release rules of the storage facilities and correlations of durations and peaks of hydrographs. The expression forS is: , whereS 0 andS are the values ofS forp=0 and , andp is the exponent of a general storage-release relation,q=az' p, wherea is the storage constant, andz' andq are the volume of stored water and the corresponding release. The values ofS 0 andS are expressed in terms of the correlation coefficient of durations and peaks of inflow hydrographs.  相似文献   

13.
Summary WWSSN seismograms for the Caucasus earthquake of May 14, 1970, and the Alma-Ata earthquake of June 5, 1970, were scaled form b using techniques employed by USSR (P amplitude during first 20 seconds) and USA (P amplitude during first few cycles). USSR seismograms will be used in a second phase of this study. Using both techniques, the scatter at each station form b (SPZ) was 0.0–0.3 with half of the stations having no scatter. The scatter among all of the stations was over 1 unit. Using both techniques, the scatter at each station form b (LPZ) was zero except for NUR on May 14. The scatter among all of the stations was 1 unit on May 14 and 0.4 on June 5. This preliminary study indicates the scaling techniques have no effect in computingm b (SPZ) andm b (LPZ) but the differences are more likely related to source functions, crust and upper mantle response functions, and instrumental band pass.NOS Seismology personnel were transferred to NOAA-ESL in 1971.  相似文献   

14.
Sulfur removal using adsorption requires a proper process parametric study to determine its optimal performance characteristics. In this study, response surface methodology was employed for sulfur removal from model oil (dibenzothiophene; DBT dissolved in iso‐octane) using commercial activated carbon (CAC) as an adsorbent. Experiments were carried out as per central composite design with four input parameters such as initial concentration (C0: 100–900 mg/L), adsorbent dosage (m: 2–22 g/L), time of adsorption (t: 15–735 min), and temperature (T: 10–50°C). Regression analysis showed good fit of the experimental data to the second‐order polynomial model with coefficient of determination R2‐value of 0.9390 and Fisher F‐value of 16.5. The highest removal of sulfur by CAC was obtained with m = 20 g/L, t = 6 h, and T = 30°C.  相似文献   

15.
We investigate optimal predictors of the peak (S) and distance to peak (T) of the width function of drainage networks under the assumption that the networks are topologically random with independent and exponentially distributed link lengths. Analytical results are derived using the fact that, under these assumptions, the width function is a homogeneous Markov birth-death process. In particular, exact expressions are derived for the asymptotic conditional expectations ofS andT given network magnitudeN and given mainstream lengthH. In addition, a simulation study is performed to examine various predictors ofS andT, includingN, H, and basin morphometric properties; non-asymptotic conditional expectations and variances are estimated. The best single predictor ofS isN, ofT isH, and of the scaled peak (S divided by the area under the width function) isH. Finally, expressions tested on a set of drainage basins from the state of Wyoming perform reasonably well in predictingS andT despite probable violations of the original assumptions.  相似文献   

16.
The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω1 > 8.5 cm?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.  相似文献   

17.
The plankton collected from three fish ponds shows a considerable variability within a pond, between the ponds and in the course of the year. The individual volumes or weights are (minimum—mean—maximum): Gleotrichia echinulata 41–252–879 μg3, Chlorella vulgaris 18–42–94 μm3, Oscillatoria amphigranulata 99–306–827 μm3, Brachionus plicatilis 1–4.918 μg, nauplia 0.5–1.25–2.35 μg, Mesocyclops hyalinus 4–45–369—μg, Heliodiaptomus viduus 41–202–288 μg, Daphnia carinata 186–1468–4578 μg.  相似文献   

18.
Concentrations of polycyclic aromatic hydrocarbons were determined in species of commercial fish and lobsters following an oil-spill just off the protected Madagascan coastline. Samples were collected along the coastline within and outside the affected area. Summed PAH concentrations ranged from 1.9 μg kg−1 to 63 μg kg−1 wet weight, but with no higher molecular weight PAHs (>202 Da) being detected. All concentrations of benzo[a]pyrene, benz[a]anthracene and dibenz[a,h]anthracene were <0.1 μg kg−1 wet weight, well within the EU and UK set limits for the protection of human health. Additionally, samples were calculated as the benzo[a]pyrene toxic equivalency quotient (TEQ) and found to be well below the level of concern in relation to health of human consumers. Evaluation of the biota PAH data indicated the origin of PAH was predominantly petrogenic with >80% arising from oil sources. Profile studies indicate a low-level multisource petrogenic contamination probably representing a pre-spill background for the area.  相似文献   

19.
The annual and life-cycle mercury bioaccumulation pattern in selected tissues of the economically relevant Elasmobranchii species Scyliorhinus canicula was studied, and the risks associated with its consumption evaluated.Preferential mercury bioaccumulation occurred in muscle tissue, and followed the order muscle > heart > liver > gills > pancreas. Total mercury in muscle tissue ranged from 0.13 mg kg−1 (wwt) in 1+ year old males to 0.8 mg kg−1 (wwt) in 8+ year old mature females, with no significant differences found between genders, and no clear lifespan bioaccumulation pattern observed, except for mature females. Organic mercury in the muscle ranged from 0.05 mg kg−1 (wwt) to 0.52 mg kg−1 (wwt), corresponding to an average of 70% of total mercury content. In mature females, a significant correlation (R = 0.99, P = 0.01) was found between size and organic mercury fraction, suggesting reproduction as an important factor controlling organic mercury bioaccumulation in the spotted dogfish.  相似文献   

20.
Several large-scale revegetation programs in China have resulted in significant changes in forest cover (ΔF) during the past three decades. As forests have important effects on catchment hydrology, evaluating the effects of ΔF on hydrology is essential. Using data from 44 catchments across China, this study derived a rational analytical equation to link changes in actual evapotranspiration (ΔET) with those in F within the Budyko framework, and further quantified the effects of ΔF on ET variation during 1976–2015. The elasticity of ET to ΔF was found to be the greatest in the dry catchments in northwest China, followed by the humid catchments in south China, and was the smallest in the subhumid and semiarid catchments in north China. F averaged across all the catchments has increased, and has further led to the increase in ET. The F-ET relationship has become more prominent in the recent decade (2006–2015), with 68.0% of the catchments showing an average increase in F of 4.5% and a resultant average increase in ET of 8.2% compared with the baseline period (1976–1985). These results are helpful for quantitative assessment of hydrological responses to afforestation, especially in water-limited regions.  相似文献   

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